CN108469390B - Detachable loop type single-phase flow erosion test device - Google Patents

Detachable loop type single-phase flow erosion test device Download PDF

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CN108469390B
CN108469390B CN201810088615.2A CN201810088615A CN108469390B CN 108469390 B CN108469390 B CN 108469390B CN 201810088615 A CN201810088615 A CN 201810088615A CN 108469390 B CN108469390 B CN 108469390B
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storage tank
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CN108469390A (en
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金浩哲
偶国富
欧阳鹏威
吕文超
徐晓峰
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Zhejiang University of Technology ZJUT
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Abstract

本发明公开了一种可拆卸环道式单相流冲蚀试验装置。储液罐内部设有加热器,储液罐底部出口与磁力传动泵连接,磁力传动泵经流量控制阀连接到储液罐,同时磁力传动泵出口端经第一截止阀连接到试验段,试验段经第二截止阀、压力控制阀后连接到储液罐顶部入口;储液罐顶部连接有进料阀,储液罐侧面布置有液位计,储液罐顶部布置有安全阀、排气阀和第二压力表,储液罐顶部布置有放空阀。本发明实现了试验管道在工业环境中的实际模拟工况条件,研究在实际工况下高压单相流冲蚀作用管路系统的冲刷腐蚀规律和冲刷腐蚀临界特性,为煤化工、石油化工管道的冲蚀预测、优化设计、风险检验、安全评估及寿命预测提供理论基础。The invention discloses a detachable annular channel type single-phase flow erosion test device. There is a heater inside the liquid storage tank, the bottom outlet of the liquid storage tank is connected to the magnetic drive pump, the magnetic drive pump is connected to the liquid storage tank through the flow control valve, and the outlet end of the magnetic drive pump is connected to the test section through the first stop valve. The section is connected to the top inlet of the liquid storage tank after passing through the second stop valve and the pressure control valve; the top of the liquid storage tank is connected with a feed valve, the side of the liquid storage tank is arranged with a liquid level gauge, and the top of the liquid storage tank is arranged with a safety valve, exhaust valve valve and a second pressure gauge, and a vent valve is arranged on the top of the liquid storage tank. The invention realizes the actual simulated working conditions of the test pipeline in the industrial environment, and studies the erosion corrosion law and erosion corrosion critical characteristics of the pipeline system under the erosion action of high-pressure single-phase flow under the actual working conditions, and is suitable for coal chemical and petrochemical pipelines. It provides a theoretical basis for erosion prediction, optimal design, risk inspection, safety assessment and life prediction.

Description

可拆卸环道式单相流冲蚀试验装置Detachable loop type single-phase flow erosion test device

技术领域technical field

本发明涉及冲蚀试验装置,具体地说是涉及用于工业生产中的一种可拆卸环道式单相流冲蚀试验装置。The invention relates to an erosion test device, in particular to a detachable annular channel type single-phase flow erosion test device used in industrial production.

背景技术Background technique

流体管道作为一种工作在一定压力下运输流体的特种设备,其失效形式多样,机理复杂,常见的失效形式有:材料缺陷、介质腐蚀、外力破坏等,其中冲刷所引起的腐蚀失效是管道系统中最广泛也是常见的破坏形式。冲蚀具有明显的局部性、突发性和风险性,特别在含水、腐蚀性、单相流介质流动作用下引起的冲蚀穿孔已成为困扰流体管道安全运行的关键技术问题。As a special equipment that transports fluids under certain pressure, fluid pipelines have various failure modes and complex mechanisms. Common failure modes include: material defects, medium corrosion, external force damage, etc. Among them, the corrosion failure caused by scouring is the pipeline system. The most widespread and common form of vandalism. Erosion has obvious locality, suddenness and risk. Erosion perforation caused by water-containing, corrosive and single-phase flow media has become a key technical problem that plagues the safe operation of fluid pipelines.

近年来,在石油化工领域随着重质、含硫原油的加工比例不断增加,石化工业管道及管束型的设备(换热器、空冷器等)冲蚀失效较为常见,例:加氢反应流出物空冷器(REAC)失效的事故日益突出,已成为严重制约加氢裂化装置安全、稳定、长周期运行的主要障碍,如不采取相应的技术措施和对策,我国炼油行业将会面临越来越严峻的设备冲蚀失效及装置生产的安全问题。In recent years, with the increasing proportion of heavy and sulfur-containing crude oil in the petrochemical industry, the erosion failure of petrochemical industry pipelines and tube bundle-type equipment (heat exchangers, air coolers, etc.) is common, for example: hydrogenation reaction effluent The failure of the air cooler (REAC) has become increasingly prominent and has become a major obstacle to the safe, stable and long-term operation of hydrocracking units. If no corresponding technical measures and countermeasures are taken, my country's oil refining industry will face more and more severe problems Erosion failure of equipment and safety problems of device production.

目前国内各大炼油厂处理原油的劣质化日趋严重,原油中硫、氮含量增高,势必会加剧加氢装置高压空冷器系统的腐蚀,预计REAC系统的失效、非计划停工等事故的发生会更加突出。尽管国内外学者进行了大量的REAC系统失效的相关研究,如国外的NACE、UOP、API等机构针对REAC系统已经开展了几十年的研究并取得一定的成绩,但是至今为止还没有一套可靠的预测方法来预测加工高硫原油的加氢空冷器系统的冲蚀破坏程度。At present, the quality of crude oil processed by major domestic refineries is becoming more and more serious. The increase of sulfur and nitrogen content in crude oil will inevitably aggravate the corrosion of the high-pressure air cooler system of the hydrogenation unit. It is expected that the failure of the REAC system and unplanned shutdowns will occur more frequently protrude. Although domestic and foreign scholars have carried out a large number of researches on the failure of REAC systems, such as foreign institutions such as NACE, UOP, API, etc., have carried out research on REAC systems for decades and achieved certain results, but so far there is no reliable system. A prediction method to predict the degree of erosion damage of hydrotreating air cooler systems processing high-sulfur crude oil.

针对目前煤化工、石油化工、天然气输送领域存在的冲蚀问题,进一步研究管道的冲蚀机理,一些科研院所设计了一系列的冲蚀试验装置,通过试验研究手段来研究管道的冲蚀机理,以期找到管道冲蚀的临界流速。但目前的冲蚀试验装置存在的一些不足之处主要在于:In view of the current erosion problems in the fields of coal chemical industry, petrochemical industry, and natural gas transportation, to further study the erosion mechanism of pipelines, some scientific research institutes have designed a series of erosion test devices to study the erosion mechanism of pipelines through experimental research methods. , in order to find the critical velocity of pipeline erosion. However, some shortcomings of the current erosion test device mainly lie in:

(1)常规的冲蚀试验装置常通过称重或测厚的方法测试平均冲蚀速率,无法实现流体冲蚀破坏的临界值和瞬态特性的测试研究。(1) Conventional erosion test devices often test the average erosion rate by weighing or thickness measurement, which cannot realize the test and study of the critical value and transient characteristics of fluid erosion damage.

(2)目前相关设备测试的时间较长,实验结果难以推广工程应用。(2) At present, the relevant equipment is tested for a long time, and the experimental results are difficult to promote engineering applications.

发明内容SUMMARY OF THE INVENTION

针对上述背景技术中所存在的问题及国内外冲蚀试验装置存在的不足,本发明的目的在于提供一种可拆卸环道式单相流冲蚀试验装置,适合于腐蚀与流动耦合作用的冲蚀机理、流体动力学的仿真分析、保护膜冲蚀破坏临界特性或瞬态特性的试验研究及冲蚀失效预测工业应用推广等完整的研究体系。In view of the problems existing in the above-mentioned background technology and the shortcomings of erosion test devices at home and abroad, the purpose of the present invention is to provide a detachable annular channel type single-phase flow erosion test device, which is suitable for the erosion test of the coupling effect of corrosion and flow. It is a complete research system such as corrosion mechanism, simulation analysis of fluid dynamics, experimental research on critical characteristics or transient characteristics of protective film erosion failure, and industrial application promotion of erosion failure prediction.

为了达到上述目的,本发明采用的技术方案是:In order to achieve the above object, the technical scheme adopted in the present invention is:

本发明包括储液罐、加热器、流量控制阀、磁力传动泵、直管管路、第一截止阀、试验段、第二截止阀、自动仪表控制系统、压力控制阀、第二压力表、排气阀、安全阀、进料阀、液位计、放空阀和电化学测试传感器;储液罐内部设有加热器,储液罐底部出口和磁力传动泵的入口端连接,磁力传动泵的出口端经流量控制阀连接到储液罐的中部入口,同时磁力传动泵的出口端经第一截止阀连接到试验段的入口端,试验段的出口端依次经第二截止阀、压力控制阀后连接到储液罐的顶部入口;储液罐顶部连接有用于加入试验原料的进料阀,储液罐侧面布置有液位计,储液罐的顶部布置有安全阀、排气阀和第二压力表,储液罐的顶部布置有放空阀,主要用于排空装置残留液。The invention includes a liquid storage tank, a heater, a flow control valve, a magnetic drive pump, a straight pipe, a first cut-off valve, a test section, a second cut-off valve, an automatic instrument control system, a pressure control valve, a second pressure gauge, Exhaust valve, safety valve, feed valve, liquid level gauge, vent valve and electrochemical test sensor; there is a heater inside the liquid storage tank, and the outlet at the bottom of the liquid storage tank is connected with the inlet end of the magnetic drive pump. The outlet end is connected to the middle inlet of the liquid storage tank through the flow control valve, while the outlet end of the magnetic drive pump is connected to the inlet end of the test section through the first cut-off valve, and the outlet end of the test section passes through the second cut-off valve and the pressure control valve in turn. It is then connected to the top inlet of the liquid storage tank; the top of the liquid storage tank is connected with a feed valve for adding test raw materials, a liquid level gauge is arranged on the side of the liquid storage tank, and a safety valve, an exhaust valve and a first pressure valve are arranged on the top of the liquid storage tank. Two pressure gauges, a vent valve is arranged on the top of the liquid storage tank, which is mainly used to empty the residual liquid of the device.

还包括自动仪表控制系统,第二截止阀和压力控制阀之间的管路上设有第一压力表、温度计和流量表,自动仪表控制系统分别连接第二压力表、第一压力表、温度计和流量表。It also includes an automatic instrument control system. The pipeline between the second shut-off valve and the pressure control valve is provided with a first pressure gauge, a thermometer and a flow meter, and the automatic instrument control system is respectively connected to the second pressure gauge, the first pressure gauge, the thermometer and the flow meter. flow meter.

所述的磁力传动泵分别和第一截止阀、流量控制阀之间均通过直管管路连接,第二截止阀和压力控制阀之间通过直管管路连接。The magnetic drive pump is respectively connected with the first cut-off valve and the flow control valve through a straight pipe pipeline, and the second cut-off valve and the pressure control valve are connected through a straight pipe pipeline.

试验原料自进料阀进入储液罐中,经加热器加热,通过磁力传动泵输出分成两路,一路经流量控制阀回流到储液罐中,另一路经第一截止阀进入试验段,试验段输出后经第二截止阀和压力控制阀后流回储液罐,第二截止阀和压力控制阀之间的沿途通过温度计、第一压力表、流量表采集数据传输至自动仪表控制系统。The test material enters the liquid storage tank from the feeding valve, is heated by the heater, and is divided into two paths through the output of the magnetic drive pump, one path is returned to the liquid storage tank through the flow control valve, and the other path enters the test section through the first stop valve. After the output of the segment, it flows back to the liquid storage tank through the second stop valve and the pressure control valve. The data collected between the second stop valve and the pressure control valve is transmitted to the automatic instrument control system through the thermometer, the first pressure gauge and the flow meter.

所述的试验段为1/4圆弧管道结构,上面布置有电化学测试传感器,具体布置方式为:试验段分为各自对应圆心角为30°度的三段子圆弧段,每段子圆弧段的内边沿弧线的中点处的试验段管道表面均设有电化学测试传感器,每段子圆弧段的外边沿弧线中点处以及相邻子圆弧段的外边沿弧线相接处的试验段管道表面均电化学测试传感器;在试验段管道表面的内边沿弧线分别到两侧的侧边沿弧线之间的中间各作一条平行弧线,作为内平行弧线,两条内平行弧线中点处的试验段管道表面设置有电化学测试传感器;在试验段管道表面的外边沿弧线分别到两侧的侧边沿弧线之间的中间各作一条平行弧线,作为外平行弧线,两条外平行弧线均分为各自对应圆心角为30°度的三段子圆弧线,每段子圆弧线中点处的试验段管道表面均设有电化学测试传感器。The test section is a 1/4 arc pipe structure, and electrochemical test sensors are arranged on it. The specific arrangement is as follows: the test section is divided into three sub-arc sections with respective corresponding central angles of 30°. Electrochemical test sensors are installed on the pipe surface of the test section at the midpoint of the inner edge arc of the segment, and the outer edge arc of each sub-arc segment is connected to the outer edge arc of the adjacent sub-arc segment The surface of the pipeline in the test section is all electrochemical test sensors; in the middle of the inner edge arc of the pipeline surface of the test section to the side edge arcs on both sides, a parallel arc is made, as an inner parallel arc, two parallel arcs are made. An electrochemical test sensor is arranged on the surface of the pipeline of the test section at the midpoint of the inner parallel arc; a parallel arc is made in the middle between the outer edge arc of the pipe surface of the test section and the side edge arcs on both sides, as Outer parallel arcs, the two outer parallel arcs are divided into three sub-arcs with a corresponding central angle of 30°, and the surface of the test section pipeline at the midpoint of each sub-arc is equipped with an electrochemical test sensor.

所述的试验段的入口端和出口端分别安装第一截止阀和第二截止阀,通过连接到管路中,由此通过第一截止阀和第二截止阀实现了试验段的可拆卸。The inlet end and the outlet end of the test section are respectively equipped with a first stop valve and a second stop valve, and are connected to the pipeline, thereby realizing the disassembly of the test section through the first stop valve and the second stop valve.

圆心角为试验段的1/4圆弧所对应的圆心角。The central angle is the central angle corresponding to the 1/4 arc of the test section.

本发明具有的有益效果是:The beneficial effects that the present invention has are:

本发明实现了试验管道在工业环境中的实际真实模拟工况,实时检测材料冲蚀破坏瞬态特性和临界值的冲蚀试验装置,能够实现流体冲蚀破坏的临界值和瞬态特性的测试研究,研究在实际工况下高压单相流冲蚀作用管路系统的冲刷腐蚀规律。The invention realizes the actual real simulated working conditions of the test pipeline in the industrial environment, the erosion test device for real-time detection of the transient characteristics and critical value of material erosion damage, and can realize the test of the critical value and transient characteristics of fluid erosion damage Research, study the erosion and corrosion law of the pipeline system under the erosion effect of high-pressure single-phase flow under actual working conditions.

本发明能进行更真实的实际工作状态模拟,能通过与冲蚀装置的试验过程进行流体动力学仿真分析所得的结果对比分析,得到冲刷腐蚀临界条件,构建冲刷腐蚀临界腐蚀数据库,为煤化工、石油化工管道的冲蚀预测、优化设计、风险检验、安全评估及寿命预测提供理论基础。The invention can simulate the actual working state more realistically, and can obtain the critical conditions of scouring corrosion by comparing and analyzing the results obtained by the fluid dynamic simulation analysis with the test process of the scouring device, and construct the database of the scouring and corrosion critical corrosion. It provides theoretical basis for erosion prediction, optimal design, risk inspection, safety assessment and life prediction of petrochemical pipelines.

本发明可以模拟加氢空冷系统管束等一系列实际工程冲蚀失效案例,进行冲蚀破坏的失效研究、冲蚀预测、优化设计、风险检验、安全评估及寿命预测等管道及管束类设备的安全保障技术研究。另外,本发明结构简单,易于推广。The invention can simulate a series of actual engineering erosion failure cases such as the tube bundle of the hydrogenation air cooling system, and carry out the failure research of erosion damage, erosion prediction, optimization design, risk inspection, safety assessment and life prediction. Safeguard technology research. In addition, the present invention has a simple structure and is easy to popularize.

附图说明Description of drawings

图1是本发明的结构原理示意图。FIG. 1 is a schematic diagram of the structural principle of the present invention.

图2是图1区域A(试验段7)的放大图。Fig. 2 is an enlarged view of area A (test section 7) of Fig. 1 .

图3是试验段7的左视图。FIG. 3 is a left side view of the test section 7 .

图4是试验段7的右视图。FIG. 4 is a right side view of the test section 7 .

图中:包括1、储液罐,2、加热器,3、流量控制阀,4、磁力传动泵,5、直管管路,6、第一截止阀,7、试验段,8、第二截止阀,9、自动仪表控制系统,10、温度计,11、第一压力表,12、流量表,13、压力控制阀,14、第二压力表,15、排气阀,16、安全阀,17、进料阀,18、液位计,19、放空阀,20-35、电化学测试传感器。In the picture: including 1, liquid storage tank, 2, heater, 3, flow control valve, 4, magnetic drive pump, 5, straight pipe, 6, first stop valve, 7, test section, 8, second Globe valve, 9, Automatic instrument control system, 10, Thermometer, 11, First pressure gauge, 12, Flow meter, 13, Pressure control valve, 14, Second pressure gauge, 15, Exhaust valve, 16, Safety valve, 17. Feed valve, 18, Level gauge, 19, Vent valve, 20-35, Electrochemical test sensor.

具体实施方式Detailed ways

下面结合附图和实施例对本发明作进一步说明。The present invention will be further described below with reference to the accompanying drawings and embodiments.

如图1所示,本发明具体实施包括储液罐1、加热器2、流量控制阀3、磁力传动泵4、直管管路5、第一截止阀6、试验段7、第二截止阀8、自动仪表控制系统9、压力控制阀13、第二压力表14、排气阀15、安全阀16、进料阀17、液位计18、放空阀19和电化学测试传感器20-35;储液罐1内部设有加热器2,储液罐1底部出口和磁力传动泵4的入口端连接,磁力传动泵4的出口端经流量控制阀3连接到储液罐1的中部入口,同时磁力传动泵4的出口端经第一截止阀6连接到试验段7的入口端,试验段7的出口端依次经第二截止阀8、压力控制阀13后连接到储液罐1的顶部入口;储液罐1顶部连接有用于加入试验原料的进料阀17,储液罐1侧面布置有液位计18,储液罐1的顶部布置有安全阀16、排气阀15和第二压力表14,储液罐的顶部布置有放空阀19。As shown in FIG. 1 , the specific implementation of the present invention includes a liquid storage tank 1, a heater 2, a flow control valve 3, a magnetic drive pump 4, a straight pipeline 5, a first stop valve 6, a test section 7, and a second stop valve. 8. Automatic instrument control system 9, pressure control valve 13, second pressure gauge 14, exhaust valve 15, safety valve 16, feed valve 17, liquid level gauge 18, vent valve 19 and electrochemical test sensors 20-35; There is a heater 2 inside the liquid storage tank 1, the bottom outlet of the liquid storage tank 1 is connected to the inlet end of the magnetic drive pump 4, and the outlet end of the magnetic drive pump 4 is connected to the middle inlet of the liquid storage tank 1 through the flow control valve 3, and at the same time. The outlet end of the magnetic drive pump 4 is connected to the inlet end of the test section 7 through the first stop valve 6, and the outlet end of the test section 7 is connected to the top inlet of the liquid storage tank 1 through the second stop valve 8 and the pressure control valve 13 in turn. ; The top of the liquid storage tank 1 is connected with a feed valve 17 for adding test raw materials, a liquid level gauge 18 is arranged on the side of the liquid storage tank 1, and a safety valve 16, an exhaust valve 15 and a second pressure are arranged on the top of the liquid storage tank 1 Table 14, a vent valve 19 is arranged on the top of the liquid storage tank.

具体实施还设置有自动仪表控制系统9,第二截止阀8和压力控制阀13之间的管路上设有第一压力表11、温度计10和流量表12,自动仪表控制系统9分别连接第二压力表14、第一压力表11、温度计10和流量表12。In the specific implementation, an automatic instrument control system 9 is also provided. The pipeline between the second shut-off valve 8 and the pressure control valve 13 is provided with a first pressure gauge 11, a thermometer 10 and a flow meter 12. The automatic instrument control system 9 is connected to the second The pressure gauge 14 , the first pressure gauge 11 , the thermometer 10 and the flow gauge 12 .

自动仪表控制系统9采集试验段对温度计10、第一压力表11、流量表11的实时数据,并传输至自动控制系统9进行储存,并在实验结束时自动打印实时实验报告。自动仪表控制系统9通过对温度计10、第一压力表11、流量表11的数据采集与控制,调整对应参数实现了对试验段7实际工况的自动实时调节。The automatic instrument control system 9 collects the real-time data of the thermometer 10, the first pressure gauge 11, and the flow meter 11 in the test section, transmits it to the automatic control system 9 for storage, and automatically prints a real-time experimental report at the end of the experiment. The automatic instrument control system 9 realizes automatic real-time adjustment of the actual working conditions of the test section 7 by adjusting the corresponding parameters by collecting and controlling the data of the thermometer 10 , the first pressure gauge 11 and the flow meter 11 .

磁力传动泵4分别和第一截止阀6、流量控制阀3之间均通过直管管路5连接,第二截止阀8和压力控制阀13之间通过直管管路5连接。The magnetic drive pump 4 is respectively connected with the first cut-off valve 6 and the flow control valve 3 through the straight pipe 5 , and the second cut-off valve 8 and the pressure control valve 13 are connected with the straight pipe 5 .

试验原料自进料阀17进入储液罐1中,经加热器2加热,通过磁力传动泵4泵入直管管路5后输出分成两路,一路经流量控制阀3回流到储液罐1中,另一路经第一截止阀6进入试验段7,试验段7输出后经第二截止阀8、直管管路5和压力控制阀13后流回储液罐1,第二截止阀8和压力控制阀13之间的沿途通过温度计10、第一压力表11、流量表12采集数据传输至自动仪表控制系统9。The test raw material enters the liquid storage tank 1 from the feeding valve 17, is heated by the heater 2, and is pumped into the straight pipe line 5 through the magnetic drive pump 4. The output is divided into two paths, and one path is returned to the liquid storage tank 1 through the flow control valve 3. In the test section 7, the other path enters the test section 7 through the first cut-off valve 6, and the output of the test section 7 flows back to the liquid storage tank 1 through the second cut-off valve 8, the straight pipe 5 and the pressure control valve 13, and the second cut-off valve 8 The data is collected and transmitted to the automatic instrument control system 9 through the thermometer 10 , the first pressure gauge 11 , and the flow meter 12 along the way with the pressure control valve 13 .

本发明工作原理:The working principle of the present invention:

如图1所示,安装好可拆卸单相流冲蚀试验装置,试验前首先打开进料阀17引入现场实际工况原料至合适液位,后根据预设试验条件调制好流量控制阀3、加热器2、压力控制阀13的控制参数,打开第一截止阀6、第二截止阀8,试验原料在储液罐1中,经加热器2加热至预设值后,通过磁力传动泵4加压进入直管管路5,后分成两路,一路经流量控制阀3回流到储液罐1中,保证另一路以实验预定流量值进入试验段7后经第二截止阀8沿管路流回储液罐1,沿途温度计10采集试验段实时温度数值,通过与预定值对比,经自动控制系统判断是否开启加热器2;温度计10、第一压力表11、流量表12采集试验段实时流量数值,并传输至自动控制系统9储存,实验结束是自动打印;流量表12采集试验段实时流量数值,传输至自动控制系统9储存,实验结束是自动打印实时实验数据。As shown in Figure 1, the detachable single-phase flow erosion test device is installed. Before the test, first open the feed valve 17 to introduce the actual working conditions on the site to a suitable liquid level, and then adjust the flow control valve according to the preset test conditions. 3, The control parameters of the heater 2 and the pressure control valve 13, open the first cut-off valve 6 and the second cut-off valve 8, the test material is in the liquid storage tank 1, heated to the preset value by the heater 2, and then passed through the magnetic drive pump 4 Pressurized into the straight pipe line 5, and then divided into two paths, one of which is returned to the liquid storage tank 1 through the flow control valve 3 to ensure that the other path enters the test section 7 with the predetermined flow value of the experiment, and then passes through the second stop valve 8 along the pipeline. It flows back to the liquid storage tank 1, and the thermometer 10 collects the real-time temperature value of the test section along the way. By comparing with the predetermined value, the automatic control system judges whether to turn on the heater 2; The flow rate value is transmitted to the automatic control system 9 for storage, and the test is automatically printed after the end of the experiment; the flow meter 12 collects the real-time flow rate value of the test section and transmits it to the automatic control system 9 for storage, and the real-time experimental data is automatically printed at the end of the experiment.

为在线测试流动腐蚀瞬态特性和冲蚀临界特性,本发明采用了电化学在线测试传感器,实时监测腐蚀产物保护膜的电化学特性,通过计算分析捕捉腐蚀产物保护膜状态发生突变的临界状态。In order to test the transient characteristics and erosion critical characteristics of flow corrosion on-line, the present invention adopts an electrochemical online test sensor, monitors the electrochemical characteristics of the corrosion product protective film in real time, and captures the critical state of the sudden change of the corrosion product protective film state through calculation and analysis.

试验段7上的三电极电化学在线测试传感器安装方式如下,见图2-4:试验段7为1/4圆弧管道结构,将试验段7分为各自对应圆心角为30°度的三段子圆弧段,如图2所示,每段子圆弧段的内边沿弧线71的中点处的试验段7管道表面均设有电化学测试传感器20,21,22,每段子圆弧段的外边沿弧线72中点处以及相邻子圆弧段的外边沿弧线72相接处的试验段7管道表面均电化学测试传感器25,26,27,28,29;如图3所示,在试验段7管道表面的内边沿弧线71分别到两侧的侧边沿弧线73之间的中间各作一条平行弧线,作为内平行弧线74,两条内平行弧线74中点处的试验段7管道表面设置有电化学测试传感器23,24;如图4所示,在试验段7管道表面的外边沿弧线72分别到两侧的侧边沿弧线73之间的中间各作一条平行弧线,作为外平行弧线75,两条外平行弧线75均分为各自对应圆心角为30°度的三段子圆弧线,每段子圆弧线中点处的试验段7管道表面均设有电化学测试传感器30,33,31,34,32,35。The installation method of the three-electrode electrochemical online test sensor on the test section 7 is as follows, as shown in Figure 2-4: The test section 7 is a 1/4 arc pipe structure, and the test section 7 is divided into three parts with a corresponding central angle of 30°. The sub-arc segment, as shown in Figure 2, the surface of the test section 7 pipeline at the midpoint of the inner edge arc 71 of each sub-arc segment is provided with electrochemical test sensors 20, 21, 22, and each sub-arc segment is The test section 7 pipeline surfaces at the midpoint of the outer edge arc 72 and at the junction of the outer edge arc 72 of the adjacent sub-arc segments are electrochemically tested sensors 25, 26, 27, 28, 29; as shown in Figure 3 As shown, a parallel arc is made in the middle between the inner edge arc 71 of the pipe surface of the test section 7 and the side edge arc 73 on both sides respectively, as the inner parallel arc 74, among the two inner parallel arcs 74 Electrochemical test sensors 23 and 24 are arranged on the surface of the pipeline of the test section 7 at the point; as shown in FIG. One parallel arc is made for each, as the outer parallel arc 75, and the two outer parallel arcs 75 are divided into three sub-arcs with a corresponding central angle of 30°, and the test section at the midpoint of each sub-arc is 7 The surface of the pipeline is equipped with electrochemical test sensors 30, 33, 31, 34, 32, 35.

自动控制系统9的PLC控制方案:控制系统硬件采用西门子1214C先进可靠的微处理器,控制代码自行编译。本发明中的温度控制方法为:温度计10实时温度数据传输至自动控制系统9,该系统中使用的A/D转换模块,将由温度值标定的4~20mA电流信号转换成0-12000的数字量,通过与预设门槛值对比,经判断,对加热器2发出加热或停止加热指令。PLC control scheme of automatic control system 9: The control system hardware adopts Siemens 1214C advanced and reliable microprocessor, and the control code is compiled by itself. The temperature control method in the present invention is as follows: the real-time temperature data of the thermometer 10 is transmitted to the automatic control system 9, and the A/D conversion module used in the system converts the 4-20 mA current signal calibrated by the temperature value into a digital quantity of 0-12000 , by comparing with the preset threshold value, it is judged that the heater 2 is given a heating or heating stop instruction.

本发明中的压力控制方法为:第一压力表11将实时压力数据传输至自动控制系统9,该系统中使用的A/D转换模块,将由压力值标定的4~20mA电流信号转换成0-12000的数字量,通过与预设门槛值对比,经判断,对压力控制阀13发出开启或关闭指令。The pressure control method in the present invention is as follows: the first pressure gauge 11 transmits real-time pressure data to the automatic control system 9, and the A/D conversion module used in the system converts the 4-20 mA current signal calibrated by the pressure value into a 0- The digital quantity of 12000 is compared with the preset threshold value, and after judgment, an opening or closing command is issued to the pressure control valve 13.

本发明中的流速控制方法为:流量表12将实时流量数据传输至自动控制系统9,该系统中使用的A/D转换模块,将由流量值标定的4~20mA电流信号转换成0-12000的数字量,通过与预设门槛值对比,经判断,对流量控制阀3发出开启或关闭指令。The flow rate control method in the present invention is as follows: the flow meter 12 transmits real-time flow data to the automatic control system 9, and the A/D conversion module used in the system converts the 4-20 mA current signal calibrated by the flow value into a 0-12000 current signal. The digital quantity, through comparison with the preset threshold value, is judged to issue an opening or closing command to the flow control valve 3.

本发明具体实施中,采用实际的腐蚀介质并利用温度、压力、流量控制调节系统进行较为真实的实际工作状态模拟。实验装置的功能实现过程具体如下:气密性试验→系统除氧→温度调节→压力调节→配液→电化学传感器预腐蚀过程→实验。In the specific implementation of the present invention, the actual corrosive medium is used and the temperature, pressure and flow control and adjustment system are used to carry out a more realistic simulation of the actual working state. The functional realization process of the experimental device is as follows: air tightness test→system deoxygenation→temperature adjustment→pressure adjustment→liquid preparation→electrochemical sensor pre-corrosion process→experiment.

(1)气密性试验:为保证系统压力、介质含量稳定,同时保证实验安全性,实验前检验实验装置气密性。关闭所有出口阀门,通过进气口向装置内通氮气至10kgf·cm-2,用肥皂水检验所有可能的泄露点,保压1小时后,泄至常压,向装置内加4/5容积的水,再充氮气至1kgf·cm-2,采用同样的方法检验气密性。(1) Air tightness test: In order to ensure the stability of the system pressure and medium content, and at the same time to ensure the safety of the experiment, the air tightness of the experimental device is checked before the experiment. Close all outlet valves, pass nitrogen to the device through the air inlet to 10kgf·cm-2, check all possible leak points with soapy water, keep the pressure for 1 hour, vent it to normal pressure, and add 4/5 volume to the device The water is filled with nitrogen to 1kgf·cm-2, and the air tightness is checked by the same method.

(2)装置除氧:为保证实验为无氧状态,气密合格后,继续充氮将系统压力升至10Kgf·cm-2,泄至常压,重复上述过程10次。而后,将40kg蒸馏水通过耐腐蚀自吸泵通入到系统中,加热至60℃,从容器底部鼓氮,至压力为5kgf·cm-2,将容器内压力泄至常压,如此反复10次,认为此时装置内为无氧状态。(2) Deoxygenation of the device: In order to ensure that the experiment is in an oxygen-free state, after the airtightness is qualified, continue to fill with nitrogen to raise the system pressure to 10Kgf·cm-2, vent it to normal pressure, and repeat the above process 10 times. Then, 40kg of distilled water was introduced into the system through a corrosion-resistant self-priming pump, heated to 60°C, nitrogen was bubbled from the bottom of the container to a pressure of 5kgf cm-2, and the pressure in the container was released to normal pressure, repeated 10 times. , it is considered that the device is in an anaerobic state at this time.

(3)温度调节:通过电加热器和自动控制系统同时控制温度,当温度上升到指定值后,加热器自动跳断,停止加热,温度降低后,加热器自动加热,实现控温过程。(3) Temperature adjustment: The temperature is controlled by the electric heater and the automatic control system at the same time. When the temperature rises to the specified value, the heater automatically trips and stops heating. When the temperature decreases, the heater automatically heats up to realize the temperature control process.

(4)压力调节:通过压力控制阀和自动控制系统同时控制压力,当压力上升到指定值后,阀门自动关闭,压力降低后,阀门自动缓缓开启,实现控压过程。(4) Pressure regulation: The pressure is controlled by the pressure control valve and the automatic control system at the same time. When the pressure rises to the specified value, the valve automatically closes, and when the pressure decreases, the valve automatically opens slowly to realize the pressure control process.

(5)溶液配制:在试验中,拟定两套实验方案。(5) Solution preparation: In the test, two sets of experimental plans were drawn up.

方案一:直接在工厂厂区安全区接引物料管线,进实验装置,以实际物料介质直接进行实验。但需遵照现场安全管理要求,根据现场实际情况考虑操作方式。Option 1: Directly connect the material pipeline in the safety area of the factory area, enter the experimental device, and conduct the experiment directly with the actual material medium. However, it is necessary to comply with the on-site safety management requirements and consider the operation mode according to the actual situation on site.

方案二:自行配制实验溶液。采用液氨、H2S气体和蒸馏水中配置NH4HS溶液。Option 2: Prepare the experimental solution by yourself. The NH4HS solution is prepared with liquid ammonia, H2S gas and distilled water.

配制溶液的原理如下:NH3+H2S→NH4HSThe principle of preparing the solution is as follows: NH 3 +H 2 S→NH 4 HS

冲蚀实验装置总容积Vtotal=50L,设定实验介质总体积Vliquid=36.00L,m为NH4HS物质的量,原料浓度计算公式如下:The total volume of the erosion experiment device is V total = 50L, the total volume of the experimental medium is set to V liquid = 36.00L, m is the amount of NH 4 HS substance, and the calculation formula of the raw material concentration is as follows:

Figure BDA0001560375220000061
Figure BDA0001560375220000061

式中,c表示原料浓度,WNH4HS表示NH4HS的质量,WH2O表示H2O的质量,WNH3表示NH3的质量,WH2S表示H2S的质量。In the formula, c represents the raw material concentration, W NH4HS represents the mass of NH 4 HS, W H2O represents the mass of H 2 O, W NH3 represents the mass of NH 3 , and W H2S represents the mass of H 2 S.

装置内通入定量蒸馏水并除氧,将排气管中的空气排空后,先后加入定量NH3和H2S气体,操作过程中采用质量计量法,精确度为0.01Kg。由于NH3和H2S在水中的溶解过程为放热反应,因此在溶液配制过程中系统的温度将升高。NH3极易溶于水,在水中的溶解度为1:700(体积比),因此通入NH3后会形成氨水。H2S易溶于水,在水中溶解度为1:2.6(体积比),然而,氨水的存在增大了H2S的溶解度,当氨水中溶解的H2S达到饱和后,多余的H2S全部存在于气相中,使装置内气相的压力升高。待温度降低到室温后,H2S完全溶于氨水,压力降至常压。Quantitative distilled water was introduced into the device to remove oxygen. After the air in the exhaust pipe was evacuated, quantitative NH 3 and H 2 S gases were added successively. The mass measurement method was adopted during the operation, with an accuracy of 0.01Kg. Since the dissolution of NH3 and H2S in water is an exothermic reaction, the temperature of the system will increase during solution preparation. NH 3 is very soluble in water, and the solubility in water is 1:700 (volume ratio), so ammonia water will be formed after NH 3 is introduced. H 2 S is easily soluble in water, and the solubility in water is 1:2.6 (volume ratio). However, the presence of ammonia water increases the solubility of H 2 S. When the H 2 S dissolved in ammonia water reaches saturation, the excess H 2 All of S is present in the gas phase, which increases the pressure of the gas phase in the device. After the temperature was lowered to room temperature, H 2 S was completely dissolved in ammonia water, and the pressure was reduced to normal pressure.

(6)预膜实验:先用水砂纸将预膜探头待测面逐级打磨至800#,先后用丙酮和去离子水冲洗,无水乙醇擦洗,经冷风吹干置入干燥器,干燥后将预膜探头安装到预膜装置上,安装过程中,准确定位,保证预膜探头工作表面与预膜装置内壁平齐。(6) Pre-filming experiment: first grind the test surface of the pre-filming probe to 800# with water sandpaper, rinse with acetone and deionized water successively, scrub with absolute ethanol, dry with cold air and place it in a desiccator. The pre-film probe is installed on the pre-film device. During the installation process, it is accurately positioned to ensure that the working surface of the pre-film probe is flush with the inner wall of the pre-film device.

实施例利用扫描电子显微镜(SEM)、X射线光能子谱(XPS)、X射线衍射(XRD)观察腐蚀形貌,分析腐蚀产物特性,通过与冲蚀装置的试验过程进行流体动力学仿真分析所得的结果对比分析,研究在实际工况下高压单相流冲蚀作用管路系统的冲刷腐蚀规律,得到冲刷腐蚀临界条件,构建冲刷腐蚀临界腐蚀数据库。冲蚀临界特性具体测试顺序如下:样品制备→实验准备→冲蚀临界特性测试。Example Corrosion morphology was observed by scanning electron microscope (SEM), X-ray photon spectroscopy (XPS), and X-ray diffraction (XRD), and the characteristics of corrosion products were analyzed, and the fluid dynamics simulation analysis was carried out through the test process with the erosion device. The obtained results were compared and analyzed, and the scour corrosion law of the pipeline system under the effect of high pressure single-phase flow erosion was studied under the actual working conditions, and the scour corrosion critical conditions were obtained, and the scour corrosion critical corrosion database was constructed. The specific test sequence of the erosion critical characteristic is as follows: sample preparation → experiment preparation → erosion critical characteristic test.

(1)试样准备:在进行腐蚀试验之前,先用水砂纸将电化学测试传感器待测面逐级打磨至800#,先后用丙酮和去离子水冲洗,无水乙醇擦洗,经冷风吹干后置入干燥器内备用。(1) Sample preparation: Before the corrosion test, first grind the surface to be measured of the electrochemical test sensor to 800# with water sandpaper, rinse with acetone and deionized water, scrub with absolute ethanol, and dry with cold air. Put in a desiccator for later use.

(2)实验准备:将镶嵌有待测试样的电化学测试传感器安装到试验段对应位置,准确定位,使待测端面与内壁齐平,试件安装好后,按照上述功能实现方法来操作,包括气密性试验、系统除氧、配液、二次除氧过程,电化学传感器预腐蚀过程与实际实验预膜过程相同,腐蚀环境相同。腐蚀产物膜制备完毕后,正式开始实验,进行不同控制因素下的冲蚀瞬态特性测试。(2) Experiment preparation: Install the electrochemical test sensor embedded with the sample to be tested in the corresponding position of the test section, and position it accurately so that the end face to be tested is flush with the inner wall. The process of air tightness test, system deoxygenation, liquid dispensing, and secondary deoxygenation process, electrochemical sensor pre-corrosion process is the same as the actual experimental pre-film process, and the corrosion environment is the same. After the corrosion product film was prepared, the experiment was officially started, and the erosion transient characteristics test under different control factors was carried out.

(3)冲蚀临界特性测试:待腐蚀试样在指定腐蚀环境下预腐蚀,完毕后按照实验方案,进行电化学测试,测试不同控制因素下腐蚀产物膜的开路电位、Tafel曲线、交流阻抗谱,通过对比分析以上电化学参数,得出腐蚀产物膜发生冲蚀破坏的临界特性。(3) Erosion critical characteristic test: the samples to be corroded are pre-corroded in a designated corrosion environment, and then electrochemical tests are performed according to the experimental plan to test the open circuit potential, Tafel curve, and AC impedance spectrum of the corrosion product film under different control factors. , through the comparative analysis of the above electrochemical parameters, the critical characteristics of erosion damage of the corrosion product film are obtained.

本发明实施中根据前期计算分析结果,在上述典型的腐蚀高风险区域布置传感器能实现在少量传感器布置的情况下,能精准、经济地实行试验段的数据采集。In the implementation of the present invention, according to the previous calculation and analysis results, arranging sensors in the above-mentioned typical high-risk corrosion areas can realize the accurate and economical data collection of the test section with a small number of sensor arrangements.

Claims (4)

1. The utility model provides a can dismantle circuit formula single-phase flow erosion test device which characterized in that: the device comprises a liquid storage tank (1), a heater (2), a flow control valve (3), a magnetic transmission pump (4), a straight pipe pipeline (5), a first stop valve (6), a test section (7), a second stop valve (8), an automatic instrument control system (9), a pressure control valve (13), a second pressure gauge (14), an exhaust valve (15), a safety valve (16), a feed valve (17), a liquid level meter (18), a vent valve (19) and electrochemical test sensors (20-35); a heater (2) is arranged in the liquid storage tank (1), an outlet at the bottom of the liquid storage tank (1) is connected with an inlet end of a magnetic transmission pump (4), an outlet end of the magnetic transmission pump (4) is connected to an inlet in the middle of the liquid storage tank (1) through a flow control valve (3), an outlet end of the magnetic transmission pump (4) is connected to an inlet end of a test section (7) through a first stop valve (6), and an outlet end of the test section (7) is connected to an inlet in the upper side face of the liquid storage tank (1) after sequentially passing through a second stop valve (8) and a pressure control valve (13); the top of the liquid storage tank (1) is connected with a feed valve (17) for adding test raw materials, the side surface of the liquid storage tank (1) is provided with a liquid level meter (18), the top of the liquid storage tank (1) is provided with a safety valve (16), an exhaust valve (15) and a second pressure gauge (14), and the bottom of the liquid storage tank is provided with an emptying valve (19);
the test section (7) is of an 1/4 arc pipeline structure, electrochemical test sensors (20-35) are arranged on the test section, and the specific arrangement mode is as follows: the test section (7) is divided into three sub-arc sections which correspond to the central angles of 30 degrees respectively, electrochemical test sensors (20,21,22) are arranged on the surface of the test section (7) at the middle point of the inner edge arc line (71) of each sub-arc section, and the electrochemical test sensors (25,26,27,28,29) are arranged on the surface of the test section (7) at the connection position of the middle point of the outer edge arc line (72) of each sub-arc section and the outer edge arc line (72) of the adjacent sub-arc section; an inner edge arc line (71) on the surface of the pipeline of the test section (7) is respectively connected with the middle between the side edge arc lines (73) at two sides to form a parallel arc line which is used as an inner parallel arc line (74), and the surface of the pipeline of the test section (7) at the midpoint of the two inner parallel arc lines (74) is provided with electrochemical test sensors (23, 24); the method is characterized in that a parallel arc line is respectively made from an outer edge arc line (72) of the surface of the test section (7) to the middle between side edge arc lines (73) at two sides and is used as an outer parallel arc line (75), the two outer parallel arc lines (75) are equally divided into three sub-arc lines respectively corresponding to the central angles of 30 degrees, and the surface of the test section (7) at the midpoint of each sub-arc line is provided with an electrochemical test sensor (30,33,31,34,32, 35).
2. The detachable loop type single-phase flow erosion test device according to claim 1, wherein: the automatic flow meter is characterized by further comprising an automatic meter control system (9), a first pressure meter (11), a thermometer (10) and a flow meter (12) are arranged on a pipeline between the second stop valve (8) and the pressure control valve (13), and the automatic meter control system (9) is respectively connected with the second pressure meter (14), the first pressure meter (11), the thermometer (10) and the flow meter (12).
3. The detachable loop type single-phase flow erosion test device according to claim 1, wherein: the magnetic transmission pump (4) is respectively connected with the first stop valve (6) and the flow control valve (3) through straight pipe pipelines (5), and the second stop valve (8) is connected with the pressure control valve (13) through the straight pipe pipelines (5).
4. The detachable loop type single-phase flow erosion test device according to claim 1, wherein: the test raw materials enter the liquid storage tank (1) from the feeding valve (17), are heated by the heater (2), are output by the magnetic transmission pump (4) and divided into two paths, one path flows back to the liquid storage tank (1) through the flow control valve (3), the other path enters the test section (7) through the first stop valve (6), the test section (7) flows back to the liquid storage tank (1) after being output through the second stop valve (8) and the pressure control valve (13), and data collected by the second stop valve (8) and the pressure control valve (13) are transmitted to the automatic instrument control system (9) along the way through the thermometer (10), the first pressure gauge (11) and the flow meter (12).
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