CN108468218A - A kind of indoor wallpaper harmless treatment process for building - Google Patents

A kind of indoor wallpaper harmless treatment process for building Download PDF

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Publication number
CN108468218A
CN108468218A CN201810282979.4A CN201810282979A CN108468218A CN 108468218 A CN108468218 A CN 108468218A CN 201810282979 A CN201810282979 A CN 201810282979A CN 108468218 A CN108468218 A CN 108468218A
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China
Prior art keywords
wallpaper
building
fluorescence
treatment process
harmless treatment
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CN201810282979.4A
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Chinese (zh)
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不公告发明人
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Individual
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Priority to CN201810282979.4A priority Critical patent/CN108468218A/en
Publication of CN108468218A publication Critical patent/CN108468218A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18Paper- or board-based structures for surface covering
    • D21H27/20Flexible structures being applied by the user, e.g. wallpaper
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3562Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/59Polyamides; Polyimides
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/02Chemical or biochemical treatment
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/04Physical treatment, e.g. heating, irradiating
    • D21H25/06Physical treatment, e.g. heating, irradiating of impregnated or coated paper

Abstract

A kind of indoor wallpaper harmless treatment process for building, it is characterised in that:The indoor wallpaper for building has textle layers, and after carrying out pattern printing and dyeing or coating to textle layers, fluorescence operation is removed using fluorescence remover.

Description

A kind of indoor wallpaper harmless treatment process for building
The application is entitled one kind indoor wallpaper harmless treatment for building application No. is 2016101238124 Technique, the divisional application for the application for a patent for invention that the applying date is 20160306.
Technical field
The present invention relates to a kind of indoor wallpaper harmless treatment process for building, belong to the technology neck of building facilities processing Domain.
Background technology
With the development of the social economy, people's living standard increasingly improves, the requirement to Indoor environment finishing is also It improves, many crowds have been not content with mopping etc. on wall indoors at present, and to hang wall paper, with aobvious top grade.
However, the base material of wallpaper is often the textiles such as non-woven fabrics, the spraying of wallpaper, preparation etc. can often bring some first Aldehyde, benzene etc. pollute product, and in wallpaper base material manufacturing process, often have the generation of fluorescer.Through research, fluorescer is not using When with great harm, the chemical composition unlike is easy to be decomposed like that, but is accumulated in human body, generation is many harmful Substance, cut down body immunity significantly.Fluorescer is combined with the protein outside wound, can also be hindered the healing of wound, be made one There is variation sexual orientation in body cell, and cumulative toxicity can become potential carcinogenic factor in liver or other vitals.If Remain fluorescer on wallpaper, and make skin contact to fluorescent material, at this time skin surface contain the cutin of protein will be with Fluorescer is combined generates stimulation to skin, causes allergy and itches, increases the morbidity chance of allergic dermatitis.Therefore, weaving system In product, due to be mixed into fluorescent material in raw material or work in-process attaches fluorescent whitening agent or improper addition fluorescent whitening agent and With fluorescence, it is often necessary to be removed.The report for the method eliminated at present to fluorescent material is more common in paper recovery processing, right The removing method of fluorescent whitening agent there is no open report on the textiles such as wallpaper.
Invention content
The technical problem to be solved by the present invention is to overcome the deficiencies in the prior art, and it is harmless to provide a kind of indoor wallpaper for building Change treatment process, be combined by chemically and physically two kinds of removing methods, fluorescence common in wallpaper production can either be destroyed and increased The color development system of white agent, thoroughly eliminates fluorescence, can also realize and be minimized to wallpaper strength damage.
To solve the above problems, the present invention adopts the following technical scheme that:
A kind of indoor wallpaper harmless treatment process for building, it is characterised in that:The indoor wallpaper for building has textle layers, After carrying out pattern printing and dyeing or coating to textle layers, fluorescence operation is removed using fluorescence remover.
The above-mentioned opportunity that fluorescence operation is removed using fluorescence remover can also carry out pattern printing and dyeing to textle layers Or before coating.
Preferably, the fluorescence remover contains the component of following mass parts:Dimethyl diallyl ammonium chloride 120-150 Part, 69-70 parts of acrylamide, sodium borohydride or 0.7-0.8 parts of 3-8 parts of sodium sulfite, Sodium Allyl Sulfonate or mercaptoethanol gather 0.2-0.5 parts of aspartic acid, 1-2 parts of sodium chlorite, 2-3 parts of aluminium salt, 0.1-0.2 parts of polyamine.
Preferably, the fluorescence remover is made of following steps, with blender, condenser, thermometer and nitrogen Dimethyl diallyl ammonium chloride and acrylamide are added in the container of interface, stirring is passed through nitrogen, and aluminium salt stirring and dissolving is added, Sodium borohydride or sodium sulfite are added at 70-90 DEG C, with inorganic acid for adjusting pH value to 4-5, keeps 15-30min, is eventually adding Remaining ingredient.
Obtained fluorescence remover, solid content 40-50wt%, viscosity is 60-780cps at 25 DEG C.Wherein aluminium salt is Aluminum sulfate or aluminium chloride.
Preferably, the indoor wallpaper harmless treatment process for building includes the following steps:
1. handling pending wallpaper surface with penetrating agent JFC, wetting is padded;
2. padding the fluorescence remover at 50-60 DEG C, 70 DEG C are warming up to the temperature of 2-3 DEG C/min, heat preservation operating is added Soda ash keeps the temperature 20-30min;
3. hot and cold water alternately washing three times, then by being clean gas (filtered compressed air, CO2, such as semiconductor Or mixtures thereof inert gas of the nitrogen of quality) with more than 2m/s's, preferably greater than 10m/s, more preferably greater than 100m/s Speed is advertised to pending wallpaper surface;
Or by being clean gas (filtered compressed air, CO2, such as semiconducting qualities nitrogen inert gas Or mixtures thereof body) dry ice particles are accelerated in nozzle under 1 to 20 bar, preferably 3 to 10 bars of pressure, and to be more than Thus 2m/s, preferably greater than 10m/s, the speed for being more preferably greater than 100m/s are advertised to pending wallpaper surface;
4. the textile after step 3 immerses soda ash solution, 2-5min is impregnated at room temperature, citric acid 1-2g/L is added, then Clear water washs, and can eliminate the fluorescence on wallpaper.
Air, carbon dioxide or other inert gases can be used as compressed air, such as nitrogen or argon gas.May be used also To consider arbitrary admixture of gas, or the additives gas with additional chemically cleaning effect, such as ozone.It is preferred that with 1 The nozzle that dry ice particles are carried out to 20 bars, more preferable 5 to 10 bars of gas pressure accelerates.Or at least 2m/s, preferably greater than 10m/s, the gas velocity for being more preferably greater than 100m/s blow to the surface of wallpaper.Work of the gas jet in wallpaper surface Can also be the lasting jet stream of several seconds or a few minutes with the one or more short pulses that can be less than 1 second.It is preferred that using drying (dew point be less than 40 DEG C), not oil-containing and grease, be clean gas, particularly preferably grasped with the gas of semiconducting qualities Make,
By the CO for advertising prepared dry ice particles form2By high speed nozzle, by by the kinetic energy of dry ice, high wind-warm syndrome It is combined with sublimation, fluorescent component is made to be detached from.It is preferred that plastic lining (such as PU, PP or PE) is held for dry ice storage Device.If with the block running equipment of dry ice, preferably by the machining tool made of wear-resisting ceramics or hard metal for manufacturing Temperature is about -80 DEG C of icy particle.Using the ultrapure dry ice of the carbon dioxide gas for example based on food quality, because without It is polluted by foreign particle.Here, the consumption of dry ice changes according to nozzle configuration and pressure limit.
Another preferred embodiment is, will be combined with using the method for dry ice using the method for compressed air.
The advantage of the invention is that the fluorescent material on wallpaper is thoroughly removed by the combination of physics and chemical means, and it is right The damage of the performances such as intensity, elongation, flexibility and the surface gloss of wallpaper is small.
Specific implementation mode
The preparation of 1 fluorescence remover of embodiment
123 parts of dimethyl diallyl ammonium chloride is added in the container with blender, condenser, thermometer and nitrogen interface With 69 parts of acrylamide, stirring is passed through nitrogen, and 2.3 parts of stirring and dissolvings of aluminium salt are added, and sodium borohydride or sulfurous are added at 75 DEG C 3.8 parts of sour sodium is kept 16min, is eventually adding Sodium Allyl Sulfonate or mercaptoethanol 0.7- with inorganic acid for adjusting pH value to 4.5 0.8 part, 0.2-0.5 parts of poly-aspartate, 1.2 parts of sodium chlorite, 0.12 part of polyamine, obtained fluorescence remover, solid content For 45wt%, viscosity is 678cps at 25 DEG C, and wherein aluminium salt is aluminum sulfate.
2 fluorescence remover of embodiment handles wallpaper
The pending wallpaper surface containing fluorescent whitening agent is handled with penetrating agent JFC, pads wetting;Institute is padded at 50-60 DEG C Fluorescence remover is stated, is warming up to 70 DEG C with the temperature of 2-3 DEG C/min, heat preservation operating is added soda ash, keeps the temperature 20-30min;It is cold and hot Water alternately washing three times, then by being clean gas (filtered compressed air, CO2, such as semiconducting qualities nitrogen Or mixtures thereof inert gas) dry ice particles are accelerated in nozzle under 12 bars of pressure, and with the speed of 15m/s Thus degree is advertised to pending wallpaper surface;Textile is immersed into soda ash solution again, impregnates 2.5min at room temperature, lemon is added Sour 1.2g/L, subsequent clear water washing, can eliminate the fluorescence on wallpaper.
Comparative example 1
The wallpaper containing fluorescent whitening agent that need to be handled is handled by following condition:
Pad (room temperature, pick-up 80~85%) → decatize (102 DEG C, 120~180 minutes) → washing → dechlorination (60 DEG C) → water It washes.Padding liquid forms:
Fluorescence Quenching Agent (by preparation method in chlorine dioxide/sodium chlorite method) 60g/L
HAc 4.5g/L
Dechlorination liquid forms:
Sodium thiosulfate: 20g/L
Soda ash: 15g/L
Remove fluorometric investigation:
The fluorescence removal effect prepared by embodiment and comparative example is evaluated using one non-fluorescence whiteness differential technique of fluorescent whiteness, profit Wallpaper fluorescent whiteness and non-fluorescence whiteness are tested with whiteness instrument, the ratio between the two difference and non-fluorescence whiteness are smaller, then in wallpaper Residual fluorescence agent relative amount is fewer.The evaluation of fluorescence removal effect be compare added with before and after fluorescence remover two pieces of wallpapers it is glimmering The ratio between the difference of light whiteness and non-fluorescence whiteness, i.e. relative fluorescence (%)=(ARF/ARM)/100%.Ratio is smaller, and fluorescence is gone Except effect is better (if fluorescent whiteness is less than non-fluorescence whiteness, AR is in terms of 0).
Table 1 removes fluorometric investigation situation
Sample number into spectrum Relative fluorescence % Strength retention(%) Cloth cover finish(Grade) Elongation retention(%)
Embodiment 2 1.08 98 5 96
Comparative example 1 5.65 87 4 80
It can be found that the holding of the wallpapers performance such as fluorescence removal effect and intensity of the present invention is superior to adopt from table 1 The wallpaper made from other fluorescence removers and fluorescence minimizing technology.
Embodiment described above is only that prefer embodiments of that present invention will be describe, not to the scope of the present invention into Row limits, and without departing from the spirit of the design of the present invention, those of ordinary skill in the art make technical solution of the present invention Various modifications and improvement are each fallen in the range of claims of the present invention restriction.

Claims (3)

1. a kind of indoor wallpaper harmless treatment process for building, it is characterised in that:The indoor wallpaper for building has weaving Layer is removed fluorescence operation after carrying out pattern printing and dyeing or coating to textle layers using fluorescence remover.
2. indoor wallpaper harmless treatment process for building as described in claim 1, which is characterized in that the interior for building Wallpaper harmless treatment process includes the following steps:
By being clean gas (filtered compressed air, CO2, such as semiconducting qualities nitrogen inert gas or its Mixture) dry ice particles are accelerated in nozzle under 1 to 20 bar, preferably 3 to 10 bars of pressure, and be more than 2m/s, Thus preferably greater than 10m/s, the speed for being more preferably greater than 100m/s are advertised to pending wallpaper surface.
3. indoor wallpaper harmless treatment process for building as claimed in claim 2, which is characterized in that and then immerse wallpaper Soda ash solution impregnates 2-5min at room temperature, and citric acid 1-2g/L is added, and subsequent clear water washing can eliminate the fluorescence on wallpaper.
CN201810282979.4A 2016-03-06 2016-03-06 A kind of indoor wallpaper harmless treatment process for building Pending CN108468218A (en)

Priority Applications (1)

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CN201810282979.4A CN108468218A (en) 2016-03-06 2016-03-06 A kind of indoor wallpaper harmless treatment process for building

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CN201810282979.4A CN108468218A (en) 2016-03-06 2016-03-06 A kind of indoor wallpaper harmless treatment process for building
CN201610123812.4A CN105648841A (en) 2016-03-06 2016-03-06 Harmless treatment technology for indoor wallpaper for construction

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CN201810283637.4A Withdrawn CN108468219A (en) 2016-03-06 2016-03-06 A kind of indoor wallpaper harmless treatment process for building
CN201810282979.4A Pending CN108468218A (en) 2016-03-06 2016-03-06 A kind of indoor wallpaper harmless treatment process for building

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CN201810283637.4A Withdrawn CN108468219A (en) 2016-03-06 2016-03-06 A kind of indoor wallpaper harmless treatment process for building

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101187150A (en) * 2007-12-07 2008-05-28 东华大学 Method for suppressing and eliminating fluorescence of textile product by fluorescence quenching agent
CN101446050A (en) * 2008-12-17 2009-06-03 盛虹集团有限公司 Fluorescence stripping method of terylene fabric
CN102383194A (en) * 2010-08-25 2012-03-21 瓦克化学股份公司 Polycrystalline silicon and method for production thereof
CN104098747A (en) * 2014-07-10 2014-10-15 浙江九本生物化学有限公司 Preparation method of fluorescence eliminating agent
CN104711897A (en) * 2015-04-02 2015-06-17 天津科技大学 Fluorescent reduction agent

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CN101161926A (en) * 2006-10-10 2008-04-16 日本化药株式会社 Regeneration processing method for waste paper
CN103614943B (en) * 2013-12-04 2016-01-20 天津科技大学 Reduce the method for fluorescent brightener levels in paper manufacturing systems

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Publication number Priority date Publication date Assignee Title
CN101187150A (en) * 2007-12-07 2008-05-28 东华大学 Method for suppressing and eliminating fluorescence of textile product by fluorescence quenching agent
CN101446050A (en) * 2008-12-17 2009-06-03 盛虹集团有限公司 Fluorescence stripping method of terylene fabric
CN102383194A (en) * 2010-08-25 2012-03-21 瓦克化学股份公司 Polycrystalline silicon and method for production thereof
CN104098747A (en) * 2014-07-10 2014-10-15 浙江九本生物化学有限公司 Preparation method of fluorescence eliminating agent
CN104711897A (en) * 2015-04-02 2015-06-17 天津科技大学 Fluorescent reduction agent

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Application publication date: 20180831