CN106567247A - Preparation method of regenerated cellulose fabric capable of preventing protein pollution - Google Patents
Preparation method of regenerated cellulose fabric capable of preventing protein pollution Download PDFInfo
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- CN106567247A CN106567247A CN201610932282.8A CN201610932282A CN106567247A CN 106567247 A CN106567247 A CN 106567247A CN 201610932282 A CN201610932282 A CN 201610932282A CN 106567247 A CN106567247 A CN 106567247A
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- regenerated cellulose
- protein
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- cellulose fabric
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- 239000004744 fabric Substances 0.000 title claims abstract description 81
- 239000004627 regenerated cellulose Substances 0.000 title claims abstract description 65
- 238000002360 preparation method Methods 0.000 title claims abstract description 26
- 102000004169 proteins and genes Human genes 0.000 title abstract description 13
- 108090000623 proteins and genes Proteins 0.000 title abstract description 13
- 238000001035 drying Methods 0.000 claims abstract description 27
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 24
- VFPFQHQNJCMNBZ-UHFFFAOYSA-N ethyl gallate Chemical compound CCOC(=O)C1=CC(O)=C(O)C(O)=C1 VFPFQHQNJCMNBZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000005406 washing Methods 0.000 claims abstract description 18
- 241000234314 Zingiber Species 0.000 claims abstract description 16
- 235000006886 Zingiber officinale Nutrition 0.000 claims abstract description 16
- 235000008397 ginger Nutrition 0.000 claims abstract description 16
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 15
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 15
- 239000011780 sodium chloride Substances 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000010438 heat treatment Methods 0.000 claims abstract description 11
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000008367 deionised water Substances 0.000 claims abstract description 5
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 5
- 238000007598 dipping method Methods 0.000 claims abstract description 5
- 238000011109 contamination Methods 0.000 claims description 55
- 241000196324 Embryophyta Species 0.000 claims description 16
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 15
- 241000220259 Raphanus Species 0.000 claims description 14
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 claims description 14
- 238000004140 cleaning Methods 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 13
- 238000000605 extraction Methods 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 11
- 238000001994 activation Methods 0.000 claims description 10
- 238000002386 leaching Methods 0.000 claims description 10
- 230000010355 oscillation Effects 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 230000004913 activation Effects 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 8
- 238000003851 corona treatment Methods 0.000 claims description 8
- 102000005158 Subtilisins Human genes 0.000 claims description 6
- 108010056079 Subtilisins Proteins 0.000 claims description 6
- 239000004480 active ingredient Substances 0.000 claims description 2
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 abstract description 7
- 230000003213 activating effect Effects 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract description 2
- 244000000626 Daucus carota Species 0.000 abstract 2
- 235000002767 Daucus carota Nutrition 0.000 abstract 2
- 239000000419 plant extract Substances 0.000 abstract 2
- 239000004262 Ethyl gallate Substances 0.000 abstract 1
- 108090000787 Subtilisin Proteins 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 235000019277 ethyl gallate Nutrition 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 238000000227 grinding Methods 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 238000007781 pre-processing Methods 0.000 description 7
- 239000004753 textile Substances 0.000 description 6
- 244000063299 Bacillus subtilis Species 0.000 description 5
- 235000014469 Bacillus subtilis Nutrition 0.000 description 5
- 102000004190 Enzymes Human genes 0.000 description 5
- 108090000790 Enzymes Proteins 0.000 description 5
- 239000008267 milk Substances 0.000 description 5
- 210000004080 milk Anatomy 0.000 description 5
- 235000013336 milk Nutrition 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 241000193830 Bacillus <bacterium> Species 0.000 description 3
- 108091005804 Peptidases Proteins 0.000 description 3
- 239000004365 Protease Substances 0.000 description 3
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000010985 leather Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000003373 anti-fouling effect Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 230000003389 potentiating effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- -1 spot Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 239000005543 nano-size silicon particle Substances 0.000 description 1
- 239000002103 nanocoating Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000006213 oxygenation reaction Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 210000004885 white matter Anatomy 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
- D06M10/025—Corona discharge or low temperature plasma
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/01—Stain or soil resistance
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- Engineering & Computer Science (AREA)
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
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- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention provides a preparation method of a regenerated cellulose fabric capable of preventing the protein pollution. The preparation method comprises the following steps: (1) washing and grinding fresh ginger slices and carrots, adding grinded gingers and carrots into sodium chloride and deionized water, heating the solution until the solution is boiling, filtering the solution to obtain a plant extract, adding subtilisin, nano titanium dioxide, and polyethylene glycol into the plant extract, and fully stirring the mixture to obtain a finishing agent capable of preventing the protein pollution; (2) adding a regenerated cellulose fabric into an ethanol solution, washing the fabric under vibration, taking out the fabric, washing the fabric by water, drying the fabric, and finally activating the fabric to obtain a preprocessed regenerated cellulose fabric; and (3) dipping the activated regenerated cellulose fabric into an ethyl gallate solution, taking out the fabric, then dipping the fabric into the finishing agent capable of preventing the protein pollution, carrying out two dipping and padding, taking out the fabric, pre-drying the fabric, washing the fabric by an ethanol water solution, and drying the fabric to obtain the regenerated cellulose fabric capable of preventing the protein pollution.
Description
Technical field
The invention belongs to textile material technical field, and in particular to a kind of regenerated cellulose fabric of anti-protein-contamination
Preparation method.
Background technology
With the continuous development of modern technology, to functional requirement of textile also more and more higher.It is well known that
The excellent adsorption of textile, after contacting with the material such as spot, milk stain, oil stain, will be difficult to clean, therefore anti-protein-contamination
Textile is also operated and is formed.
A kind of potent anti-soil fibrous material disclosed in Chinese patent CN 104419998A, by castor oil ethylene oxide condensation
Thing and butyl titanate anti-protein-contamination agent are added in the raw material of polytetrafluoroethylene (PTFE) and nylon, and Jing melt spinnings prepare tool
There is the fibrous material of potent anti-soil effect.A kind of anti-protein-contamination leather disclosed in Chinese patent CN202047291U, by skin
Leather includes nano coating, conventional oil process layer, PVC surface layers, PVC foam layer and base fabric, and by nano material the anti-of leather is improved
Protein contamination ability.A kind of nano antifouling uvioresistant coated fabric disclosed in Chinese patent CN 1710179A, clothes and add
Work technique, by nano-titanium oxide, nano zine oxide, nano silicon oxide nanometer finishing agent is made, and is carried out arrangement to fabric and is refused
Water refuses the antifouling textile product or clothes of oil.
From above-mentioned prior art, the anti-protein-contamination arrangement currently for textile is for oil stain and dirt mostly
Stain, actually rare for the soil-release finish of protein milk stain class, milk stain falls within spot relatively conventional in daily life, milk stain
Belong to protein, its soil-release finish is different from oil stain and water stain, study a kind of fabric with anti-protein-contamination and also have one
Fixed market prospects.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of preparation side of the regenerated cellulose fabric of anti-protein-contamination
Method, the present invention combines subtilopeptidase A, nano titanium oxide and polyethylene glycol from the effective ingredients in plant of ginger splices and radish
Used as anti-protein-contamination finishing agent, the regenerated cellulose fabric to activating carries out anti-protein-contamination arrangement, obtains green ring
The anti-protein-contamination regenerated cellulose fabric of guarantor.
To solve above-mentioned technical problem, the technical scheme is that：
A kind of preparation method of the regenerated cellulose fabric of anti-protein-contamination, comprises the following steps：
(1) after fresh ginger splices and radish clean up, smash to pieces, in adding sodium chloride and deionized water, heating is boiled, mistake
Filter obtains plant extraction liquid, adds subtilopeptidase A, nano titanium oxide and polyethylene glycol, is sufficiently stirred for obtaining anti-egg
White matter pollutes finishing agent；
(2) regenerated cellulose fabric is placed in ethanol solution, oscillation cleaning, is taken out, washing drying, after activated process
Obtain the regenerated cellulose fabric for pre-processing；
(3) regenerated cellulose fabric of the activation for preparing step (2) first impregnated in progallin A solution, take
Go out, then impregnated in the anti-protein-contamination finishing agent of step (1) preparation, two leachings two are rolled, and are taken out, and preliminary drying uses ethanol water
Cleaning, drying, obtains the regenerated cellulose fabric of anti-protein-contamination.
Used as the preferred of above-mentioned technical proposal, in the step (1), the mass ratio of ginger splices, radish and sodium chloride is 1:1-2：
0.5-0.8。
Used as the preferred of above-mentioned technical proposal, in the step (1), the time that heating is boiled is 2-3h.
Used as the preferred of above-mentioned technical proposal, in the step (1), the mass fraction of active ingredient is in plant extraction liquid
5-12%.
As the preferred of above-mentioned technical proposal, in the step (1), plant extraction liquid, subtilopeptidase A, nanometer two
The liquor ratio of chatting of titanium oxide and polyethylene glycol is 50ml:0.3-0.5g:0.2-0.3g：2-5g.
Used as the preferred of above-mentioned technical proposal, in the step (2), the time of oscillation cleaning is 24h.
Used as the preferred of above-mentioned technical proposal, in the step (2), activation process is corona treatment and alkali process.
Used as the preferred of above-mentioned technical proposal, in the step (3), the mass fraction of progallin A solution is 1-
2%.
Used as the preferred of above-mentioned technical proposal, in the step (3), the bath raio of dipping is 1:50-80.
Used as the preferred of above-mentioned technical proposal, in the step (3), the temperature rolled of two leaching two are 80-100 DEG C, and the time is
60-90min, pick-up is 85-90%.
Compared with prior art, the invention has the advantages that：
(1) anti-protein-contamination regenerated cellulose fabric prepared by the present invention adopts regenerated cellulose fabric as substrate,
Regenerated cellulose fabric green is capable of circulation, transparent glossy, and mechanical strength and elongation are good, by regenerated cellulose fabric
After carrying out oxygenation pretreatment and plasma-activated arrangement, substantial amounts of hydroxyl and micropore knot are contained in the surface of regenerated cellulose fabric
Structure, Jing gallic acids suppress under the protection of antioxidant, can be with the effective ingredients in plant of ginger splices and radish, bacillus subtilis protein
Chemical bond and hydrogen bond are formed between enzyme, nano titanium oxide and polyethylene glycol, the work(of regenerated cellulose anti-protein-contamination is given
Can property.
(2) ginger splices is contained on anti-protein-contamination regenerated cellulose fabric surface prepared by the present invention and the plant of radish is effective
The effective ingredients in plant of composition, subtilopeptidase A, nano titanium oxide and polyethylene glycol, ginger splices and radish and hay bacillus
Protease, sodium chloride effect can decompose to protein materials such as milk stain, blood, and nano titanium oxide is understood in cellulose
Surface form the absorption that film suppresses the spot such as protein, polyethylene glycol has unique effectively anti-protein adsorption capacity,
Additionally, this several raw material is all nontoxic without protein contamination, environmental protection is good with the compatibility of skin, by this several coating substance
The performance of fabric anti-protein-contamination is given with the surface of anti-protein-contamination regenerated cellulose fabric.
(3) anti-protein-contamination regenerated cellulose fabric preparation technology prepared by the present invention is easy, low cost, efficiency high,
Fabric has good anti-protein-contamination performance, and environmental protection can be used for industrial production, good in economic efficiency, can be used for
The fields such as weaving, medical treatment, packaging for foodstuff.
Specific embodiment
Describe the present invention, the illustrative examples of the here present invention and explanation in detail below in conjunction with specific embodiment
It is for explaining the present invention but not as a limitation of the invention.
Embodiment 1：
(1) after the fresh ginger splices of 1g and the radish of 1g clean up, smash to pieces, add the sodium chloride of 0.5g and going for 50ml
In ionized water, 2h is boiled in heating, is filtrated to get the plant extraction liquid that mass fraction is 5%, adds 0.3g bacillus subtilis proteins
Enzyme, 0.2g nano titanium oxides and 2g polyethylene glycol, are sufficiently stirred for obtaining anti-protein-contamination finishing agent.
(2) regenerated cellulose fabric is placed in ethanol solution, oscillation cleaning 24h, is taken out, washing drying first impregnated in
Alkali process 5min in the sodium hydroxide solution of 5g/l, take out, after washing drying, then the corona treatment under 150W power
5min, obtains the regenerated cellulose fabric for pre-processing.
(3) regenerated cellulose fabric of the activation for preparing step (2), with bath raio 1:50, first impregnated in mass fraction is
5min in 1% progallin A solution, takes out, then impregnated in the anti-protein-contamination finishing agent of step (1) preparation, two
Leaching two is rolled, and temperature is 80 DEG C, and the time is 60min, and pick-up is 85%, is taken out, and 110 DEG C of preliminary drying 15min are clear with ethanol water
Wash, dry at 60 DEG C, obtain the regenerated cellulose fabric of anti-protein-contamination.
Embodiment 2：
(1) after the fresh ginger splices of 1g and the radish of 2g clean up, smash to pieces, add the sodium chloride of 0.8g and going for 50ml
In ionized water, 3h is boiled in heating, is filtrated to get the plant extraction liquid that mass fraction is 12%, adds 0.5g bacillus subtilis proteins
Enzyme, 0.3g nano titanium oxides and 5g polyethylene glycol, are sufficiently stirred for obtaining anti-protein-contamination finishing agent.
(2) regenerated cellulose fabric is placed in ethanol solution, oscillation cleaning 24h, is taken out, washing drying first impregnated in
Alkali process 20min in the sodium hydroxide solution of 15g/l, take out, after washing drying, then the corona treatment under 200W power
10min, obtains the regenerated cellulose fabric for pre-processing.
(3) regenerated cellulose fabric of the activation for preparing step (2), with bath raio 1:80, first impregnated in mass fraction is
10min in 2% progallin A solution, takes out, then impregnated in the anti-protein-contamination finishing agent of step (1) preparation,
Two leachings two are rolled, and temperature is 100 DEG C, and the time is 90min, and pick-up is 90%, are taken out, and 110 DEG C of preliminary drying 20min are water-soluble with ethanol
Liquid is cleaned, and is dried at 80 DEG C, obtains the regenerated cellulose fabric of anti-protein-contamination.
Embodiment 3：
(1) after the fresh ginger splices of 1g and the radish of 1.5g clean up, smash to pieces, add the sodium chloride and 50ml of 0.6g
In deionized water, 2.5h is boiled in heating, is filtrated to get the plant extraction liquid that mass fraction is 8%, adds 0.4g hay bacilluses
Protease, 0.25g nano titanium oxides and 3g polyethylene glycol, are sufficiently stirred for obtaining anti-protein-contamination finishing agent.
(2) regenerated cellulose fabric is placed in ethanol solution, oscillation cleaning 24h, is taken out, washing drying first impregnated in
Alkali process 15min in the sodium hydroxide solution of 10g/l, take out, after washing drying, then the corona treatment under 180W power
7min, obtains the regenerated cellulose fabric for pre-processing.
(3) regenerated cellulose fabric of the activation for preparing step (2), with bath raio 1:60, first impregnated in mass fraction is
7min in 1.5% progallin A solution, takes out, then impregnated in the anti-protein-contamination finishing agent of step (1) preparation,
Two leachings two are rolled, and temperature is 90 DEG C, and the time is 70min, and pick-up is 88%, are taken out, and 110 DEG C of preliminary drying 18min use ethanol water
Cleaning, dries at 70 DEG C, obtains the regenerated cellulose fabric of anti-protein-contamination.
Embodiment 4：
(1) after the fresh ginger splices of 1g and the radish of 1.6g clean up, smash to pieces, add the sodium chloride and 50ml of 0.7g
In deionized water, 2.4h is boiled in heating, is filtrated to get the plant extraction liquid that mass fraction is 8%, adds 0.3g hay bacilluses
Protease, 0.2g nano titanium oxides and 4g polyethylene glycol, are sufficiently stirred for obtaining anti-protein-contamination finishing agent.
(2) regenerated cellulose fabric is placed in ethanol solution, oscillation cleaning 24h, is taken out, washing drying first impregnated in
Alkali process 15min in the sodium hydroxide solution of 12g/l, take out, after washing drying, then the corona treatment under 200W power
5min, obtains the regenerated cellulose fabric for pre-processing.
(3) regenerated cellulose fabric of the activation for preparing step (2), with bath raio 1:70, first impregnated in mass fraction is
5min in 2% progallin A solution, takes out, then impregnated in the anti-protein-contamination finishing agent of step (1) preparation, two
Leaching two is rolled, and temperature is 95 DEG C, and the time is 70min, and pick-up is 85%, is taken out, and 110 DEG C of preliminary drying 20min are clear with ethanol water
Wash, dry at 60 DEG C, obtain the regenerated cellulose fabric of anti-protein-contamination.
Embodiment 5：
(1) after the fresh ginger splices of 1g and the radish of 2g clean up, smash to pieces, add the sodium chloride of 0.5g and going for 50ml
In ionized water, 3h is boiled in heating, is filtrated to get the plant extraction liquid that mass fraction is 10%, adds 0.5g bacillus subtilis proteins
Enzyme, 0.2g nano titanium oxides and 5g polyethylene glycol, are sufficiently stirred for obtaining anti-protein-contamination finishing agent.
(2) regenerated cellulose fabric is placed in ethanol solution, oscillation cleaning 24h, is taken out, washing drying first impregnated in
Alkali process 20min in the sodium hydroxide solution of 5g/l, take out, after washing drying, then the corona treatment under 150W power
10min, obtains the regenerated cellulose fabric for pre-processing.
(3) regenerated cellulose fabric of the activation for preparing step (2), with bath raio 1:80, first impregnated in mass fraction is
5min in 2% progallin A solution, takes out, then impregnated in the anti-protein-contamination finishing agent of step (1) preparation, two
Leaching two is rolled, and temperature is 100 DEG C, and the time is 60min, and pick-up is 90%, is taken out, and 110 DEG C of preliminary drying 15min use ethanol water
Cleaning, dries at 80 DEG C, obtains the regenerated cellulose fabric of anti-protein-contamination.
Embodiment 6：
(1) after the fresh ginger splices of 1g and the radish of 2g clean up, smash to pieces, add the sodium chloride of 0.7g and going for 50ml
In ionized water, 3h is boiled in heating, is filtrated to get the plant extraction liquid that mass fraction is 10%, adds 0.5g bacillus subtilis proteins
Enzyme, 0.2g nano titanium oxides and 5g polyethylene glycol, are sufficiently stirred for obtaining anti-protein-contamination finishing agent.
(2) regenerated cellulose fabric is placed in ethanol solution, oscillation cleaning 24h, is taken out, washing drying first impregnated in
Alkali process 10min in the sodium hydroxide solution of 12g/l, take out, after washing drying, then the corona treatment under 200W power
10min, obtains the regenerated cellulose fabric for pre-processing.
(3) regenerated cellulose fabric of the activation for preparing step (2), with bath raio 1:60, first impregnated in mass fraction is
8min in 1% progallin A solution, takes out, then impregnated in the anti-protein-contamination finishing agent of step (1) preparation, two
Leaching two is rolled, and temperature is 100 DEG C, and the time is 80min, and pick-up is 90%, is taken out, and 110 DEG C of preliminary drying 15min use ethanol water
Cleaning, dries at 80 DEG C, obtains the regenerated cellulose fabric of anti-protein-contamination.
After testing, embodiment 1-6 prepare anti-protein-contamination regenerated cellulose fabric mechanical performance and anti-protein,
The result of the performance of spot is as follows：
As seen from the above table, the mechanical strength of the regenerated cellulose fabric of anti-protein-contamination prepared by the present invention is good, thoroughly
Gas is good, has more good rejection to sludge and protein.
The principle and its effect of above-described embodiment only illustrative present invention, it is of the invention not for limiting.It is any ripe
Know the personage of this technology all can carry out modifications and changes under the spirit and the scope without prejudice to the present invention to above-described embodiment.Cause
This, such as those of ordinary skill in the art is complete with institute under technological thought without departing from disclosed spirit
Into all equivalent modifications or change, should by the present invention claim be covered.
Claims (10)
1. a kind of preparation method of the regenerated cellulose fabric of anti-protein-contamination, it is characterised in that comprise the following steps：
(1) after fresh ginger splices and radish clean up, smash to pieces, in adding sodium chloride and deionized water, heating is boiled, and is filtered
To plant extraction liquid, subtilopeptidase A, nano titanium oxide and polyethylene glycol are added, be sufficiently stirred for obtaining anti-protein
Pollution finishing agent；
(2) regenerated cellulose fabric is placed in ethanol solution, oscillation cleaning, is taken out, washing drying is obtained after activated process
The regenerated cellulose fabric of pretreatment；
(3) regenerated cellulose fabric of the activation for preparing step (2) first impregnated in progallin A solution, take out, then
In impregnated in the anti-protein-contamination finishing agent of step (1) preparation, two leachings two are rolled, and are taken out, and preliminary drying is cleaned with ethanol water,
Drying, obtains the regenerated cellulose fabric of anti-protein-contamination.
2. a kind of preparation method of the regenerated cellulose fabric of anti-protein-contamination according to claim 1, its feature exists
In：In the step (1), the mass ratio of ginger splices, radish and sodium chloride is 1:1-2：0.5-0.8.
3. a kind of preparation method of the regenerated cellulose fabric of anti-protein-contamination according to claim 1, its feature exists
In：In the step (1), the time that heating is boiled is 2-3h.
4. a kind of preparation method of the regenerated cellulose fabric of anti-protein-contamination according to claim 1, its feature exists
In：In the step (1), the mass fraction of active ingredient is 5-12% in plant extraction liquid.
5. a kind of preparation method of the regenerated cellulose fabric of anti-protein-contamination according to claim 1, its feature exists
In：In the step (1), the liquor ratio of chatting of plant extraction liquid, subtilopeptidase A, nano titanium oxide and polyethylene glycol is
50ml:0.3-0.5g:0.2-0.3g：2-5g.
6. a kind of preparation method of the regenerated cellulose fabric of anti-protein-contamination according to claim 1, its feature exists
In：In the step (2), the time of oscillation cleaning is 24h.
7. a kind of preparation method of the regenerated cellulose fabric of anti-protein-contamination according to claim 1, its feature exists
In：In the step (2), activation process is corona treatment and alkali process.
8. a kind of preparation method of the regenerated cellulose fabric of anti-protein-contamination according to claim 1, its feature exists
In：In the step (3), the mass fraction of progallin A solution is 1-2%.
9. a kind of preparation method of the regenerated cellulose fabric of anti-protein-contamination according to claim 1, its feature exists
In：In the step (3), the bath raio of dipping is 1:50-80.
10. a kind of preparation method of the regenerated cellulose fabric of anti-protein-contamination according to claim 1, its feature exists
In：In the step (3), the temperature that two leachings two are rolled is 80-100 DEG C, and the time is 60-90min, and pick-up is 85-90%.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108374290A (en) * | 2018-03-26 | 2018-08-07 | 陕西理工大学 | A method of cotton fiber modification is dyed |
| CN109023963A (en) * | 2018-06-18 | 2018-12-18 | 东莞市联洲知识产权运营管理有限公司 | A kind of water-fastness medical cotton fabric of anti-protein-contamination and preparation method thereof |
| CN109881479A (en) * | 2019-03-07 | 2019-06-14 | 青岛雪达集团有限公司 | A kind of textile fabric and preparation method thereof with antibacterial heating function |
| CN113463422A (en) * | 2021-07-08 | 2021-10-01 | 孚升草科技(江苏)有限公司 | Nanocellulose for textile pretreatment |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3552910A (en) * | 1965-11-26 | 1971-01-05 | Hooker Chemical Corp | Method of shrinkproofing a proteinaceous textile material and product thereof |
| CN1174140C (en) * | 1998-09-30 | 2004-11-03 | 宝洁公司 | Textile finishing process |
| CN101180431A (en) * | 2005-06-06 | 2008-05-14 | 巴斯福股份公司 | Method for coating fibre substrate surfaces |
| CN202047291U (en) * | 2011-04-26 | 2011-11-23 | 南通亿华塑胶有限公司 | Anti-pollution leather |
| CN104419998A (en) * | 2013-09-10 | 2015-03-18 | 上海炬通实业有限公司 | High-performance anti-fouling fiber material |
| CN105064040A (en) * | 2015-09-14 | 2015-11-18 | 北京化工大学 | Method for modifying hydrophilia on surface of porous hydrophobic material |
| CN105603716A (en) * | 2016-02-29 | 2016-05-25 | 苏州印丝特纺织数码科技有限公司 | Soil-releasing finishing method of pure cotton fabric |
-
2016
- 2016-10-25 CN CN201610932282.8A patent/CN106567247A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3552910A (en) * | 1965-11-26 | 1971-01-05 | Hooker Chemical Corp | Method of shrinkproofing a proteinaceous textile material and product thereof |
| CN1174140C (en) * | 1998-09-30 | 2004-11-03 | 宝洁公司 | Textile finishing process |
| CN101180431A (en) * | 2005-06-06 | 2008-05-14 | 巴斯福股份公司 | Method for coating fibre substrate surfaces |
| CN202047291U (en) * | 2011-04-26 | 2011-11-23 | 南通亿华塑胶有限公司 | Anti-pollution leather |
| CN104419998A (en) * | 2013-09-10 | 2015-03-18 | 上海炬通实业有限公司 | High-performance anti-fouling fiber material |
| CN105064040A (en) * | 2015-09-14 | 2015-11-18 | 北京化工大学 | Method for modifying hydrophilia on surface of porous hydrophobic material |
| CN105603716A (en) * | 2016-02-29 | 2016-05-25 | 苏州印丝特纺织数码科技有限公司 | Soil-releasing finishing method of pure cotton fabric |
Non-Patent Citations (1)
| Title |
|---|
| 张金伟等: "抗蛋白吸附材料及其在海洋防污领域的应用前景", 《材料开发与应用》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108374290A (en) * | 2018-03-26 | 2018-08-07 | 陕西理工大学 | A method of cotton fiber modification is dyed |
| CN109023963A (en) * | 2018-06-18 | 2018-12-18 | 东莞市联洲知识产权运营管理有限公司 | A kind of water-fastness medical cotton fabric of anti-protein-contamination and preparation method thereof |
| CN109881479A (en) * | 2019-03-07 | 2019-06-14 | 青岛雪达集团有限公司 | A kind of textile fabric and preparation method thereof with antibacterial heating function |
| CN113463422A (en) * | 2021-07-08 | 2021-10-01 | 孚升草科技(江苏)有限公司 | Nanocellulose for textile pretreatment |
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