CN108467687A - 一种气凝胶贴膜制作方法 - Google Patents

一种气凝胶贴膜制作方法 Download PDF

Info

Publication number
CN108467687A
CN108467687A CN201810540242.8A CN201810540242A CN108467687A CN 108467687 A CN108467687 A CN 108467687A CN 201810540242 A CN201810540242 A CN 201810540242A CN 108467687 A CN108467687 A CN 108467687A
Authority
CN
China
Prior art keywords
added
water
gel
airsetting
room temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810540242.8A
Other languages
English (en)
Inventor
孙晔
孙梅
崔伟腾
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TIANJIN MORGAN-KUNDOM HI-TECH DEVELOPMENT Co Ltd
Original Assignee
TIANJIN MORGAN-KUNDOM HI-TECH DEVELOPMENT Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TIANJIN MORGAN-KUNDOM HI-TECH DEVELOPMENT Co Ltd filed Critical TIANJIN MORGAN-KUNDOM HI-TECH DEVELOPMENT Co Ltd
Priority to CN201810540242.8A priority Critical patent/CN108467687A/zh
Publication of CN108467687A publication Critical patent/CN108467687A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/10—Adhesives in the form of films or foils without carriers
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/157—After-treatment of gels
    • C01B33/158—Purification; Drying; Dehydrating
    • C01B33/1585—Dehydration into aerogels
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/44—Polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4825—Polyethers containing two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6625—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/34
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/326—Applications of adhesives in processes or use of adhesives in the form of films or foils for bonding electronic components such as wafers, chips or semiconductors
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/414—Additional features of adhesives in the form of films or foils characterized by the presence of essential components presence of a copolymer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2475/00—Presence of polyurethane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Silicon Polymers (AREA)

Abstract

本发明公开了一种气凝胶贴膜制作方法，包括如下步骤：制备气凝胶和制备贴膜；本发明方法简单，可工业大批量进行生产，具有防爆性、抗磨性、防紫外线、私密性、防眩光和隔热防晒的特点，可减少工序的浪费并提高产品质量，它改变了高聚物分子及链段的排列，使其具有了高度平面取向性、结晶度提高，使贴膜的机械强度和表面光洁度明显提高，而且还可以根据自己的个性和喜好，来挑选和制作自己专属的贴膜，可以更好的满足人们现在的需求。

Description

一种气凝胶贴膜制作方法
技术领域
本发明涉及气凝胶贴膜技术领域，具体为一种气凝胶贴膜制作方法。
背景技术
气凝胶，又称为干凝胶。当凝胶脱去大部分溶剂，使凝胶中液体含量比固体含量少得多，或凝胶的空间网状结构中充满的介质是气体，外表呈固体状，这即为干凝胶，也称为气凝胶。如明胶、阿拉伯胶、硅胶、毛发、指甲等。气凝胶也具凝胶的性质，即具膨胀作用、触变作用、离浆作用。现代电子产品携带越来越轻便化，体积越来越小，功能越来越强大，这样导致集成度越来越高。这样导致体积在缩小，功能变强大，直接导致电子元器件的散热要求越来越高。而以前采用的风扇式散热，由于体积大，会产生噪音等问题，逐渐被市场淘汰。进而产生了其它的散热材料，如铜箔、铝箔类散热，但是由于资源有限，而且价格昂贵，散热效果也没有想象中的好，慢慢的，都在寻找新的高效的散热材料。其次，由于电子产品的多样性，现有的产品往往需要定制，从而难适用具体的使用场合且限制了其应用的推广；因此，如果设计一种针对电子产品特点的具有高性能散热胶带，成为本领域普通技术人员努力的方向而气凝胶贴膜。
所以，如何设计一种气凝胶贴膜制作方法，成为我们当前要解决的问题。
发明内容
本发明提供一种气凝胶贴膜制作方法，方法简单，可工业大批量进行生产，具有防爆性、抗磨性、防紫外线、私密性、防眩光和隔热防晒的特点，可减少工序的浪费并提高产品质量，它改变了高聚物分子及链段的排列，使其具有了高度平面取向性、结晶度提高，使贴膜的机械强度和表面光洁度明显提高，而且还可以根据自己的个性和喜好，来挑选和制作自己专属的贴膜，可以更好的满足人们现在的需求，可以有效解决上述背景技术中的问题。
为实现上述目的，本发明提供如下技术方案：一种气凝胶贴膜制作方法，包括如下步骤：
1)制备气凝胶：首先将原料按照摩尔比正硅酸乙酯：丙酮：无水乙醇：水＝1：4：4：4的比例充分混合搅拌均匀，然后加入稀盐酸调节溶胶的pH值到3-4，然后加入稀氨水调节溶胶的pH值到6-7，然后室温下静置使之成为凝胶，将凝胶在室温下老化，再加入无水乙醇，使凝胶浸泡于其中，无水乙醇没过凝胶，在50℃环境中老化一天，然后冷却至室温后进行表面疏水处理，三甲基氯硅烷正己烷溶液缓慢倒入已老化后降至室温的凝胶中，将凝胶完全淹没，并将容器密封，室温下反应两天，然后在55℃鼓风式烘箱中继续反应两天，将剩余液体倒出后用丙酮浸泡至少一天，以使残留在凝胶中的正己烷溶剂置换出来，然后将凝胶置于55℃烘箱中干燥一个星期，即得到气凝胶；
2)制备贴膜：选择聚醚多元醇和步骤1)中制得的气凝胶分别加入到三口瓶中，先进行加热升温，然后10-2-10-3Pa的条件下进行脱水，然后在常温环境中进行降温后，即制得备用反应液；采用多层共挤工艺，通过T膜头将异佛尔酮二异氰酸酯挤出，然后通过急冷辊进行冷却，得到挤出料A；将辛酸亚锡加入到备用反应液中，然后加入挤出料A进行反应，冷却至室温后得到混合料B；向混合料B中依次加入1,4-丁二醇、二羟甲基丙酸进行反应，在常温环境中进行降温后加入三乙胺进行中和，再加入成膜剂、消泡剂、去离子水进行搅拌，得到混合料C，然后将混合料C加入到缠绕膜系机器中进行制膜，得的气凝胶贴膜。
根据上述技术方案：所述成膜剂的制备方法为：向异佛尔酮二异氰酸酯中加入聚碳酸酯二醇进行反应，在常温环境中进行降温后，加入聚氧化丙烯二醇、二羟甲基丁酸和三乙胺进行中和，再加入成膜剂、消泡剂、去离子水进行搅拌，得到混合料；然后降温至40℃，加入乙二胺和水进行乳化扩链1-2h，得到成膜剂。
根据上述技术方案：所述消泡剂的制备方法为：在氮气氛围中将含氢硅油和乙烯基硅树脂混合加入到反应釜中，边搅拌边加热，使温度加热至100℃时，加入催化剂进行反应，在高温环境下进行保温，得到聚合物；将聚合物与白炭黑、低粘度二甲基硅油、高粘度二甲基硅油和强碱催化剂混合，在高温环境下进行搅拌，冷却至室温得粘稠状混合物，即为硅膏；将硅膏与三元共聚体进行复配，即得到消泡剂。
根据上述技术方案：所述去离子水的制备方法为先启动第一水泵，第一水泵将自来水抽入第一反渗透柱内，在水压的作用下自来水顺次通过第二反渗透柱、第三反渗透柱进入中间水箱内暂存，随后启动第二水泵，第二水泵将中间水箱内去掉阴阳离子的水抽入超滤器内，在超滤器内制得水分子团，水分子团极大提高了油污的分解能力，最后在水压的作用下水分子团进入储水槽内收集，进而制得去离子水。
根据上述技术方案：所述气凝胶制备工艺还包括包装工艺。
与现有技术相比，本发明的有益效果：方法简单，可工业大批量进行生产，具有防爆性、抗磨性、防紫外线、私密性、防眩光和隔热防晒的特点，可减少工序的浪费并提高产品质量，它改变了高聚物分子及链段的排列，使其具有了高度平面取向性、结晶度提高，使贴膜的机械强度和表面光洁度明显提高，而且还可以根据自己的个性和喜好，来挑选和制作自己专属的贴膜，可以更好的满足人们现在的需求。
附图说明
附图用来提供对本发明的进一步理解，并且构成说明书的一部分，与本发明的实施例一起用于解释本发明，并不构成对本发明的限制。
在附图中：
图1是本发明的制作流程图。
具体实施方式
以下结合附图对本发明的优选实施例进行说明，应当理解，此处所描述的优选实施例仅用于说明和解释本发明，并不用于限定本发明。
实施例：如图1所示，本发明提供一种气凝胶贴膜制作方法，包括如下步骤：
1)制备气凝胶：首先将原料按照摩尔比正硅酸乙酯：丙酮：无水乙醇：水＝1：4：4：4的比例充分混合搅拌均匀，然后加入稀盐酸调节溶胶的pH值到3-4，然后加入稀氨水调节溶胶的pH值到6-7，然后室温下静置使之成为凝胶，将凝胶在室温下老化，再加入无水乙醇，使凝胶浸泡于其中，无水乙醇没过凝胶，在50℃环境中老化一天，然后冷却至室温后进行表面疏水处理，三甲基氯硅烷正己烷溶液缓慢倒入已老化后降至室温的凝胶中，将凝胶完全淹没，并将容器密封，室温下反应两天，然后在55℃鼓风式烘箱中继续反应两天，将剩余液体倒出后用丙酮浸泡至少一天，以使残留在凝胶中的正己烷溶剂置换出来，然后将凝胶置于55℃烘箱中干燥一个星期，即得到气凝胶；
2)制备贴膜：选择聚醚多元醇和步骤1)中制得的气凝胶分别加入到三口瓶中，先进行加热升温，然后10-2-10-3Pa的条件下进行脱水，然后在常温环境中进行降温后，即制得备用反应液；采用多层共挤工艺，通过T膜头将异佛尔酮二异氰酸酯挤出，然后通过急冷辊进行冷却，得到挤出料A；将辛酸亚锡加入到备用反应液中，然后加入挤出料A进行反应，冷却至室温后得到混合料B；向混合料B中依次加入1,4-丁二醇、二羟甲基丙酸进行反应，在常温环境中进行降温后加入三乙胺进行中和，再加入成膜剂、消泡剂、去离子水进行搅拌，得到混合料C，然后将混合料C加入到缠绕膜系机器中进行制膜，得的气凝胶贴膜。
根据上述技术方案：所述成膜剂的制备方法为：向异佛尔酮二异氰酸酯中加入聚碳酸酯二醇进行反应，在常温环境中进行降温后，加入聚氧化丙烯二醇、二羟甲基丁酸和三乙胺进行中和，再加入成膜剂、消泡剂、去离子水进行搅拌，得到混合料；然后降温至40℃，加入乙二胺和水进行乳化扩链1-2h，得到成膜剂。
根据上述技术方案：所述消泡剂的制备方法为：在氮气氛围中将含氢硅油和乙烯基硅树脂混合加入到反应釜中，边搅拌边加热，使温度加热至100℃时，加入催化剂进行反应，在高温环境下进行保温，得到聚合物；将聚合物与白炭黑、低粘度二甲基硅油、高粘度二甲基硅油和强碱催化剂混合，在高温环境下进行搅拌，冷却至室温得粘稠状混合物，即为硅膏；将硅膏与三元共聚体进行复配，即得到消泡剂。
根据上述技术方案：所述去离子水的制备方法为先启动第一水泵，第一水泵将自来水抽入第一反渗透柱内，在水压的作用下自来水顺次通过第二反渗透柱、第三反渗透柱进入中间水箱内暂存，随后启动第二水泵，第二水泵将中间水箱内去掉阴阳离子的水抽入超滤器内，在超滤器内制得水分子团，水分子团极大提高了油污的分解能力，最后在水压的作用下水分子团进入储水槽内收集，进而制得去离子水。
根据上述技术方案：所述气凝胶制备工艺还包括包装工艺。
基于上述，本发明的优点在于，方法简单，可工业大批量进行生产，具有防爆性、抗磨性、防紫外线、私密性、防眩光和隔热防晒的特点，可减少工序的浪费并提高产品质量，它改变了高聚物分子及链段的排列，使其具有了高度平面取向性、结晶度提高，使贴膜的机械强度和表面光洁度明显提高，而且还可以根据自己的个性和喜好，来挑选和制作自己专属的贴膜，可以更好的满足人们现在的需求。
最后应说明的是：以上所述仅为本发明的优选实例而已，并不用于限制本发明，尽管参照前述实施例对本发明进行了详细的说明，对于本领域的技术患者来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (5)

1.一种气凝胶贴膜制作方法，其特征在于：包括如下步骤：
1)制备气凝胶：首先将原料按照摩尔比正硅酸乙酯：丙酮：无水乙醇：水＝1：4：4：4的比例充分混合搅拌均匀，然后加入稀盐酸调节溶胶的pH值到3-4，然后加入稀氨水调节溶胶的pH值到6-7，然后室温下静置使之成为凝胶，将凝胶在室温下老化，再加入无水乙醇，使凝胶浸泡于其中，无水乙醇没过凝胶，在50℃环境中老化一天，然后冷却至室温后进行表面疏水处理，三甲基氯硅烷正己烷溶液缓慢倒入已老化后降至室温的凝胶中，将凝胶完全淹没，并将容器密封，室温下反应两天，然后在55℃鼓风式烘箱中继续反应两天，将剩余液体倒出后用丙酮浸泡至少一天，以使残留在凝胶中的正己烷溶剂置换出来，然后将凝胶置于55℃烘箱中干燥一个星期，即得到气凝胶；
2)制备贴膜：选择聚醚多元醇和步骤1)中制得的气凝胶分别加入到三口瓶中，先进行加热升温，然后10-2-10-3Pa的条件下进行脱水，然后在常温环境中进行降温后，即制得备用反应液；采用多层共挤工艺，通过T膜头将异佛尔酮二异氰酸酯挤出，然后通过急冷辊进行冷却，得到挤出料A；将辛酸亚锡加入到备用反应液中，然后加入挤出料A进行反应，冷却至室温后得到混合料B；向混合料B中依次加入1,4-丁二醇、二羟甲基丙酸进行反应，在常温环境中进行降温后加入三乙胺进行中和，再加入成膜剂、消泡剂、去离子水进行搅拌，得到混合料C，然后将混合料C加入到缠绕膜系机器中进行制膜，得的气凝胶贴膜。
2.根据权利要求1所述的一种气凝胶贴膜制作方法，其特征在于：所述成膜剂的制备方法为：向异佛尔酮二异氰酸酯中加入聚碳酸酯二醇进行反应，在常温环境中进行降温后，加入聚氧化丙烯二醇、二羟甲基丁酸和三乙胺进行中和，再加入成膜剂、消泡剂、去离子水进行搅拌，得到混合料；然后降温至40℃，加入乙二胺和水进行乳化扩链1-2h，得到成膜剂。
3.根据权利要求1所述的一种气凝胶贴膜制作方法，其特征在于：所述消泡剂的制备方法为：在氮气氛围中将含氢硅油和乙烯基硅树脂混合加入到反应釜中，边搅拌边加热，使温度加热至100℃时，加入催化剂进行反应，在高温环境下进行保温，得到聚合物；将聚合物与白炭黑、低粘度二甲基硅油、高粘度二甲基硅油和强碱催化剂混合，在高温环境下进行搅拌，冷却至室温得粘稠状混合物，即为硅膏；将硅膏与三元共聚体进行复配，即得到消泡剂。
4.根据权利要求1所述的一种气凝胶贴膜制作方法，其特征在于：所述去离子水的制备方法为先启动第一水泵，第一水泵将自来水抽入第一反渗透柱内，在水压的作用下自来水顺次通过第二反渗透柱、第三反渗透柱进入中间水箱内暂存，随后启动第二水泵，第二水泵将中间水箱内去掉阴阳离子的水抽入超滤器内，在超滤器内制得水分子团，水分子团极大提高了油污的分解能力，最后在水压的作用下水分子团进入储水槽内收集，进而制得去离子水。
5.根据权利要求1所述的一种气凝胶贴膜制作方法，其特征在于：所述气凝胶制备工艺还包括包装工艺。
CN201810540242.8A 2018-05-30 2018-05-30 一种气凝胶贴膜制作方法 Pending CN108467687A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810540242.8A CN108467687A (zh) 2018-05-30 2018-05-30 一种气凝胶贴膜制作方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810540242.8A CN108467687A (zh) 2018-05-30 2018-05-30 一种气凝胶贴膜制作方法

Publications (1)

Publication Number Publication Date
CN108467687A true CN108467687A (zh) 2018-08-31

Family

ID=63261758

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810540242.8A Pending CN108467687A (zh) 2018-05-30 2018-05-30 一种气凝胶贴膜制作方法

Country Status (1)

Country Link
CN (1) CN108467687A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115651393A (zh) * 2022-10-14 2023-01-31 深圳市泰美斯科技有限公司 一种低密度柔性高的导热凝胶及其制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110071231A1 (en) * 2009-09-24 2011-03-24 Samsung Electronics Co., Ltd. Organic aerogel and composition and method for manufacturing the organic aerogel
CN105238032A (zh) * 2015-11-13 2016-01-13 淄博正大聚氨酯有限公司 防辐射手机贴膜及其制备方法
CN205398300U (zh) * 2016-02-19 2016-07-27 四川同庆南风洗涤用品有限责任公司 一种去离子水制备系统
CN107446150A (zh) * 2017-08-29 2017-12-08 湖北硅金凝节能减排科技有限公司 一种气凝胶塑料薄膜及其制备方法
CN107936815A (zh) * 2017-12-13 2018-04-20 苏州赛斯德工程设备有限公司 一种高强度聚氨酯防水涂料及其制备工艺

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110071231A1 (en) * 2009-09-24 2011-03-24 Samsung Electronics Co., Ltd. Organic aerogel and composition and method for manufacturing the organic aerogel
CN105238032A (zh) * 2015-11-13 2016-01-13 淄博正大聚氨酯有限公司 防辐射手机贴膜及其制备方法
CN205398300U (zh) * 2016-02-19 2016-07-27 四川同庆南风洗涤用品有限责任公司 一种去离子水制备系统
CN107446150A (zh) * 2017-08-29 2017-12-08 湖北硅金凝节能减排科技有限公司 一种气凝胶塑料薄膜及其制备方法
CN107936815A (zh) * 2017-12-13 2018-04-20 苏州赛斯德工程设备有限公司 一种高强度聚氨酯防水涂料及其制备工艺

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115651393A (zh) * 2022-10-14 2023-01-31 深圳市泰美斯科技有限公司 一种低密度柔性高的导热凝胶及其制备方法
CN115651393B (zh) * 2022-10-14 2023-09-26 深圳市泰美斯科技有限公司 一种低密度柔性高的导热凝胶及其制备方法

Similar Documents

Publication Publication Date Title
CN105236912B (zh) 一种复合纤维增强疏水SiO2气凝胶及其制备方法
CN108467687A (zh) 一种气凝胶贴膜制作方法
CN109517208B (zh) 用于床垫的高导热石墨烯聚氨酯复合海绵的连续生产方法
CN110577661A (zh) 一种硅胶膜、导热硅胶片及其制备方法
CN105482363A (zh) 量子点环氧树脂复合胶体及荧光膜制备方法
CN102352213A (zh) 用于大功率led照明的有机硅导热粘合剂及其制备方法
CN113135732A (zh) 一种短切玻璃纤维二氧化硅气凝胶复合材料及其制备方法
CN103435809B (zh) 双螺杆连续生产乙烯基硅油的生产方法及其生产系统
CN110252341A (zh) 一种Bi2O2SiO3/Bi2O3/BiOBr异质复合光材料的制备方法
CN109385140A (zh) 一种3d生物打印纳米纤维素水凝胶墨水
CN106281208A (zh) 一种有机硅三防胶及其制备方法与应用
CN113185947A (zh) 混合交联体系双组份中空密封胶
CN108455619A (zh) 疏水性SiO2气凝胶合成工艺
CN115074079A (zh) 一种单组分加成型有机硅导热胶粘剂及其制备方法
JPH02196015A (ja) シリカの製造方法
CN107699190A (zh) 一种灯丝胶及其制备方法
WO2024153007A1 (zh) 一种耐雨蚀、耐天候性能优异的聚氨酯改性材料及其制备方法与应用
CN108117833A (zh) 二氧化钛/聚合物复合介电疏水材料及制备方法
CN203794820U (zh) 一种连续化生产高含氢硅油的水解环路系统
CN105272184B (zh) 一种低介电常数陶瓷粉体及其制备方法
CN115322577B (zh) 一种导热凝胶及其制备方法
CN110452659A (zh) 一种触变型导热绝缘密封胶及其制备方法
CN211329093U (zh) 一种硅油冷却装置
US10696867B2 (en) Thermal insulation porous film, and method for manufacturing the same
CN111040188B (zh) 一种有机硅乳化剂及制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20180831