CN108461824A - A kind of lithium ion battery structure and matrix over cladding process - Google Patents

A kind of lithium ion battery structure and matrix over cladding process Download PDF

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Publication number
CN108461824A
CN108461824A CN201711485924.5A CN201711485924A CN108461824A CN 108461824 A CN108461824 A CN 108461824A CN 201711485924 A CN201711485924 A CN 201711485924A CN 108461824 A CN108461824 A CN 108461824A
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China
Prior art keywords
negative
copper foil
negative plate
foil
plate
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CN201711485924.5A
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Chinese (zh)
Inventor
肖世玲
龙梅
宋金涛
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Huizhou Wes New Energy Ltd Co
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Huizhou Wes New Energy Ltd Co
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Priority to CN201711485924.5A priority Critical patent/CN108461824A/en
Publication of CN108461824A publication Critical patent/CN108461824A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/058Construction or manufacture
    • H01M10/0587Construction or manufacture of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/70Carriers or collectors characterised by shape or form
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00Batteries for particular applications
    • H01M2220/20Batteries in motive systems, e.g. vehicle, ship, plane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Cell Electrode Carriers And Collectors (AREA)

Abstract

The invention discloses a kind of lithium ion battery structure and matrix over cladding process, including positive plate, negative plate and external conductive casing, the positive plate, negative plate and external conductive casing are successively wound on the outside of battery core, it is equipped with diaphragm between the positive plate and battery core and negative plate, the negative plate includes negative copper foil, the side end that the negative copper foil is connect with external conductive casing is equipped with an empty foil region being in direct contact with external conductive casing, and the length in the sky foil region is more than or equal to the length of a battery core greatest circle place perimeter.There is the matrix in free foil region to carry out battery outsourcing using above-mentioned band, sky foil region is made to be in direct contact with external conductive casing.Lithium ion battery structure and matrix over cladding process of the present invention has many advantages, such as to be skillfully constructed, saves cost, improves unit energy density, reduces battery core internal resistance, improves electric core conductive and improve safety.

Description

A kind of lithium ion battery structure and matrix over cladding process
Technical field
The present invention relates to the lithium ion battery in basic electrical component field and manufacturing method, specially a kind of lithium ion battery Structure and matrix over cladding process.
Background technology
The Sony of 1990 Japan is succeeded in developing first using the carbon material of graphite-structure as matrix, and cobalt acid lithium is positive Commercial lithium-ion batteries have opened the fast-developing course of lithium ion battery from this, with the increasing of research and development dynamics, newly Material, new process are constantly studied, while the expansion of application field also proposes higher to the properties of lithium ion battery Requirement.Lithium ion battery is high, light-weight with voltage by it, bigger than energy, self discharge is few, has extended cycle life, is memoryless Effect, it is low in the pollution of the environment the features such as, be widely used in Mobile portable formula equipment, electric automobile energy technology, big power station The fields such as energy-storage battery, ups power, Medical Instruments power supply, communication base station and national defence space technology, be especially applied to energy storage and Electric vehicle field, with advances in technology with the expansion of demand, it will generate a huge market.At this stage, with generation The aggravation of boundary's energy crisis and the national further policy guidance to developing electric vehicle, electric vehicle have obtained more Quickly development.Electric vehicle is more demanding to providing the power lithium-ion battery of energy for it, such as requires larger High rate performance, can be large current discharge, higher energy density, good cycle life, reliable safety and cheap valence Lattice etc., it will be the theme studied from now on that research and development can meet the power battery of these rigors simultaneously.It at present can quotient Industry applies the positive electrode on power lithium-ion battery few, predominantly LiMn2O4, nickel-cobalt-manganese ternary, LiFePO4, nickel Cobalt acid lithium these types material, wherein LiFePO4 are the power battery anode material of Current Domestic mainstream.
The main structure body of lithium ion battery includes positive plate, base sheet, diaphragm, electrolyte and shell, the making of positive plate It is the two sides that the mixed slurry for being configured to positive active material, conductive agent and binder is coated on current collector aluminum foil, base sheet Making be design position that the mixed slurry for being configured to base activated substance, conductive agent and binder is coated on copper foil of affluxion body It sets, electrolyte is the mixed solution of lithium salts and organic solvent.When charging the battery, lithium ion is deviate from from anode, passes through Electrolyte and diaphragm are embedded into matrix, while electronics flows to matrix by external circuit from anode;When discharging battery, lithium from Son is deviate from from matrix, moves back anode again by electrolyte and diaphragm, while electronics flows to anode by external circuit from matrix.Lithium from Usually there are two types of external forms for sub- battery:Cylindrical type and square, use winding-structure battery core inside cylindrical battery, inside rectangular cell Using winding-structure battery core or lamination battery core.While in order to ensure that the safety of battery will also be fitted with safety valve or PTC members Part, to ensure that battery is not caused danger in abnormal state and output short-circuit.
For lithium ion battery when as electrical source of power, needing to have being capable of transient large current discharge and lasting heavy-current discharge Characteristic, to meet power demand of the electric vehicle under different service conditions, this requires used battery have it is higher High rate performance and lower internal resistance such as have 10C to 25C or even higher high rate performance.Battery is single in high power charging-discharging Being increased by the electric current of inside battery in the time of position, under identical ohmic internal resistance, the calorific value of battery is more relative to low range, this The warm increasing degree degree of battery is resulted in increase, each material in battery can all have the temperature in use window of itself, excessively high temperature Degree can influence the electrical property and security performance of battery, especially security performance, this is that power battery primarily solves the problems, such as.Pass through The warm increasing degree degree of battery can be reduced in a certain range by reducing the ohmic internal resistance of battery, to improve battery high rate performance and Ensure security performance.
The core of existing cylindrical type lithium ion battery is mainly winding-structure, winding when first matrix is integrally wrapped every In film, positive plate is then put, is wound according to certain elasticity, core is fitted into after being rolled into conductive shell.Pass through a little On tab welding to conductive shell on electrode holder core negative plate, conductive shell is integrally used as matrix.Since negative plate integrally wraps In diaphragm, core negative plate and conductive shell by the lug on negative plate not in contact with being only connected, contact internal resistance is opposite The battery bigger that present invention process makes, this affects the high rate performance of battery and safety to a certain extent.It is universal at present A kind of way be to increase the contact area of pole piece and conductive shell by increasing the quantity of lug on pole piece, to reach drop The purpose of low contact internal resistance.Excessive lug occupies limited space in battery when in this way, reduces battery appearance Amount, and increase manufacturing cost, spot welding difficulty and process time.
Invention content
The present invention provides one kind to be skillfully constructed, saves cost, improves unit energy density, reduces battery core internal resistance, improves Electric core conductive and the lithium ion battery structure and matrix over cladding process for improving safety.
The present invention can be achieved through the following technical solutions:
A kind of lithium ion battery structure, including positive plate, negative plate and external conductive casing, the positive plate, negative plate and lead Electric shell is equipped with diaphragm, the negative plate between the outside of battery core, the positive plate and battery core and negative plate successively Including negative copper foil, the negative copper foil is the collector of battery, the side end that the negative copper foil is connect with external conductive casing End is equipped with an empty foil region being in direct contact with external conductive casing, and the length in the sky foil region is more than or equal to a battery core greatest circle The length of place perimeter.Lithium ion battery structure of the present invention in negative copper foil, that is, collector with external conductive casing inner wall by connecting One side there are one section of empty foil regions to be not coated with, the sky foil region is in direct contact with external conductive casing when winding, the structure design structure Think ingenious, increase effectively the contact area of collector and external conductive casing, reduces contact internal resistance between the two, and then reduce electricity In-core hinders, and improves the electric conductivity and high rate performance of battery core, while reducing the warm increasing degree degree of battery core, increasing the energy density of battery core, The usage safety performance for carrying city's battery reduces the cost of battery.
Further, the negative copper foil is one side coating negative electrode powder structure or double spread negative electrode powder structure.
One of preferred embodiment as lithium ion battery structure of the present invention, the negative copper foil are one side coating negative electrode powder knot When structure, dew foil is placed in outside and is in direct contact with external conductive casing on one side when winding.
Two of preferred embodiment as lithium ion battery structure of the present invention, the negative copper foil are double spread negative electrode powder knot When structure, there are an empty foil regions to be not coated with for the outside pole piece end of negative copper foil, and the length in the sky foil region is at least one Perimeter length where battery core greatest circle, when winding, make sky foil region be in direct contact with external conductive casing.
Still further, being set on the negative copper foil there are two lug, two lugs are respectively distributed to the two of negative copper foil End;Or two lugs, one one end for being located at negative copper foil, another is located at the middle part of negative copper foil.The cathode copper On foil other than two lugs are set, multiple lugs can also be set according to actual needs.
One of the scheme of the matrix over cladding process of above-mentioned lithium ion battery, includes the following steps,
The first step, negative plate one side coating or negative plate double spread, when negative plate double spread, negative plate first uses Single side slotted mode carries out one side coating, and there are a part of negative copper foils to be not coated with, and is not coated with part and is located just at negative copper foil End, then the second two-sided face is carried out to negative copper foil using coating machine and is coated with;
Second step, positive/negative plate cut out appropriate length by technological requirement, between positive plate and battery core between negative plate It is separated by diaphragm, negative plate reveals foil one side and is located at outside;
Third walks, electric core winding, and first pre-roll diaphragm 1 encloses the first above diaphragm in battery core, then puts negative plate, pre-roll one Negative plate more than circle, then positive plate is placed between negative plate and the first diaphragm places one the between positive plate and negative plate Two diaphragms, then winding makes anode ring forming, and negative plate dew foil one side is located at outside and is in direct contact with external conductive casing inner wall after winding.
Lithium ion battery structure of the present invention has following advantageous effect:
Lithium ion battery structure of the present invention passes through the one side being connect with external conductive casing inner wall in negative copper foil, that is, collector There are one section of empty foil regions to be not coated with, and the sky foil region is in direct contact with external conductive casing when winding, which is skillfully constructed, The contact area for increasing effectively collector and external conductive casing reduces contact internal resistance between the two, and then reduces battery core internal resistance, The electric conductivity and high rate performance of battery core are improved, while reducing the warm increasing degree degree of battery core, increasing the energy density of battery core, carries city's battery Usage safety performance, reduce the cost of battery.
Description of the drawings
Attached drawing 1 is that lithium ion battery monolithic of the present invention splits structural schematic diagram;
Attached drawing 2 is the structural schematic diagram of negative copper foil one side coating negative electrode powder in attached drawing 1;
Attached drawing 3 is the structural schematic diagram of negative copper foil double spread negative electrode powder in attached drawing 1.
Specific implementation mode
In order that those skilled in the art will better understand the technical solution of the present invention, with reference to embodiment and attached drawing Product of the present invention is described in further detail.
As shown in Figure 1 to Figure 3, a kind of lithium ion battery structure, including positive plate 3, negative plate and external conductive casing 7, it is described Positive plate 3, negative plate and external conductive casing 7 are successively between the outside of battery core 1, the positive plate 3 and battery core 1 and negative plate It is equipped with diaphragm, the negative plate includes negative copper foil 6, and the negative copper foil 6 is the collector of battery, the negative copper foil 6 side ends being connect with external conductive casing 7 are equipped with an empty foil region 10 being in direct contact with external conductive casing 7, the sky foil region 10 length is more than or equal to the length of 1 perimeter of battery core.The negative copper foil 6 is one side coating negative electrode powder structure or two-sided It is coated with negative electrode powder structure.As shown in Fig. 2, when the negative copper foil 6 is one side coating negative electrode powder structure, the negative copper foil 6 Inner face is coated with the first negative electrode powder 5, when winding negative copper foil 6 it is outer show foil and be placed in outside on one side directly connect with external conductive casing 7 It touches.As shown in figure 3, when the negative copper foil 6 is double spread negative electrode powder structure, the inner face of the negative copper foil 6 is coated with the One negative electrode powder 5, the second negative electrode powder 9 is coated with outside the negative copper foil, and 6 outside of negative copper foil is coated with the second negative electrode powder 9 There are an empty foil regions 10 to be not coated with for a face pole piece end, the length in the sky foil region 10 is at least 1 perimeter of battery core Length, when winding, make sky foil region 10 be in direct contact with external conductive casing 7.Lug 8 there are two being set on the negative copper foil 6, two Lug 8 is respectively distributed to the both ends of negative copper foil 6;Or two lugs, 8 one one ends for being located at negative copper foil 6, it is another It is a positioned at the middle part of negative copper foil 6.On the negative copper foil 6 other than two lugs 8 are set, it can also set according to actual needs Set multiple lugs 8.Lithium ion battery structure of the present invention is by being being connect with 7 inner wall of external conductive casing for collector in negative copper foil 6 One side there are one section of empty foil regions 10 to be not coated with, the sky foil region 10 is in direct contact with external conductive casing 7 when winding, which sets Meter is skillfully constructed, and increases effectively the contact area of collector and external conductive casing 7, reduces contact internal resistance between the two, in turn 1 internal resistance of battery core is reduced, the electric conductivity and high rate performance of battery core 1 are improved, while reducing the warm increasing degree degree of battery core 1, increasing battery core 1 Energy density carries the usage safety performance of city's battery, reduces the cost of battery.
As shown in Figure 1 to Figure 3, the matrix over cladding process of above-mentioned lithium ion battery, includes the following steps,
The first step, negative plate one side coating or negative plate double spread, when negative plate double spread, negative plate first uses Single side slotted mode carries out one side coating, the coating siding-to-siding block length of negative plate is controlled by adjusting coating clearance, there are a parts Negative copper foil 6 is not coated with, and is not coated with region and is located just at 6 end of negative copper foil, be not coated with region length be battery core 1 be more than etc. In the length of 1 perimeter of battery core, then the second two-sided face is carried out to negative copper foil 6 using coating machine and is coated with;;
Second step, positive/negative plate cuts out appropriate length by technological requirement, between positive plate 3 and battery core 1 between negative plate It is separated by diaphragm, negative plate reveals foil one side and is located at outside;
Third walks, and battery core 1 is wound, and first 2 pre-roll 1.2 of the first diaphragm of pre-roll is enclosed in battery core 1, then puts negative plate, and pre-roll is negative Pole piece 1.2 encloses, then positive plate 3 is placed between negative plate and the first diaphragm 2, and one second is placed between positive plate 3 and negative plate Diaphragm 4, then winding makes battery core 1 be molded, and negative plate dew foil one side directly connects positioned at external with 7 inner wall of external conductive casing after winding It touches, realizes 1 negative plate collector of battery core and external conductive casing by adjusting elasticity of the battery core 1 in external conductive casing 7 when winding 7 keep good contact, increase the contact area of collector and 7 inner wall of external conductive casing, both reductions contact internal resistance.
It is after tested two in 8 quantity of lug when carrying out cell matrix outsourcing using above-mentioned matrix over cladding process, two poles 8 position of ear is located at the both ends of negative plate, and when cathode 100% outsourcing of sheet matrix, influence of the matrix outsourcing to the internal resistance of cell Such as table one.
Table one
It is after tested two in 8 quantity of lug when carrying out cell matrix outsourcing using above-mentioned matrix over cladding process, two poles 8 position of ear is located at the both ends of negative plate, and when cathode 20% outsourcing of sheet matrix, and influence of the matrix outsourcing to the internal resistance of cell is such as Table two.
Table two
It is after tested two in 8 quantity of lug when carrying out cell matrix outsourcing using above-mentioned matrix over cladding process, two poles The one end for being located at negative plate of 8 position of ear one, another is located at the centre position of negative plate, and outside cathode sheet matrix 100% Bao Shi, influence of the matrix outsourcing to the internal resistance of cell such as table three.
Table three
Lithium ion battery matrix over cladding process of the present invention allows anode or cathode matrix directly to be connect with 7 inner wall of external conductive casing It touches, effectively increases the contact area of collector and external conductive casing 7, matrix outsourcing ratio more large access area is bigger, to have Effect reduces the internal resistance of cell, and the ratio of matrix outsourcing is bigger, and internal resistance reduces also bigger.
The foregoing is only a preferred embodiment of the present invention, is not intended to limit the present invention in any form;It is all The those of ordinary skill of the industry can be shown in by specification attached drawing and described above and swimmingly implement the present invention;But it is all Those skilled in the art without departing from the scope of the present invention, using disclosed above technology contents The equivalent variations for a little variation, modification and evolution made are the equivalent embodiment of the present invention;Meanwhile it is all according to the present invention Substantial technological to the variation, modification and evolution etc. of any equivalent variations made by above example, still fall within the present invention's Within the protection domain of technical solution.

Claims (7)

1. a kind of lithium ion battery structure, including positive plate, negative plate and external conductive casing, the positive plate, negative plate and conduction Shell is equipped with diaphragm between the outside of battery core, the positive plate and battery core and negative plate successively, it is characterised in that:Institute It includes negative copper foil to state negative plate, and it is direct with external conductive casing that the side end that the negative copper foil is connect with external conductive casing is equipped with one The empty foil region of contact, the length in the sky foil region are more than or equal to the length of a battery core greatest circle place perimeter.
2. lithium ion battery structure according to claim 1, it is characterised in that:The negative copper foil is one side coating cathode Powder structure or double spread negative electrode powder structure.
3. lithium ion battery structure according to claim 2, it is characterised in that:The negative copper foil is one side coating cathode When powder structure, dew foil is placed in outside and is in direct contact with external conductive casing on one side when winding.
4. lithium ion battery structure according to claim 2, it is characterised in that:The negative copper foil is double spread cathode When powder structure, there are an empty foil regions to be not coated with for the outside pole piece end of negative copper foil, and the length in the sky foil region is at least Perimeter length where one battery core greatest circle, when winding, make sky foil region be in direct contact with external conductive casing.
5. lithium ion battery structure according to claim 3 or 4, it is characterised in that:There are two being set on the negative copper foil Lug, two lugs are respectively distributed to the both ends of negative copper foil;Or two lugs, one one end for being located at negative copper foil, Another is located at the middle part of negative copper foil.
6. lithium ion battery structure according to claim 3 or 4, it is characterised in that:The negative copper foil is equipped with multiple Lug.
7. the matrix over cladding process of the lithium ion battery described in any one of claim 1 to 6 claim, it is characterised in that:Packet Include following steps,
The first step, negative plate one side coating or negative plate double spread, when negative plate double spread, negative plate first uses single side Slotted mode carries out one side coating, and there are a part of negative copper foils to be not coated with, and is not coated with part and is located just at negative copper foil end, It uses coating machine to carry out the second two-sided face to negative copper foil again to be coated with;
Second step, positive/negative plate cut out appropriate length by technological requirement, pass through between negative plate between positive plate and battery core Diaphragm separates, and negative plate reveals foil one side and is located at outside;
Third walks, electric core winding, and first pre-roll diaphragm 1 encloses the first above diaphragm in battery core, then puts negative plate, and pre-roll one is enclosed Above negative plate, then positive plate is placed between negative plate and the first diaphragm, one second is placed between positive plate and negative plate Diaphragm, then winding makes anode ring forming, and negative plate dew foil one side is located at outside and is in direct contact with external conductive casing inner wall after winding.
CN201711485924.5A 2017-12-29 2017-12-29 A kind of lithium ion battery structure and matrix over cladding process Pending CN108461824A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109244556A (en) * 2018-10-16 2019-01-18 联动天翼新能源有限公司 A kind of rectangular lithium ion battery core that improves is crumpled the anode ring forming device and method of deformation
CN113285056A (en) * 2021-05-31 2021-08-20 珠海冠宇电池股份有限公司 Positive plate and battery
CN114284572A (en) * 2021-12-31 2022-04-05 四川启睿克科技有限公司 Roll up core structure and lithium ion battery

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CN102683751A (en) * 2012-05-25 2012-09-19 浙江振龙电源股份有限公司 High-capacity high-magnification square lithium ion power battery and manufacturing method thereof
CN203218345U (en) * 2013-05-07 2013-09-25 北京鼎能开源电池科技股份有限公司 Steel-housing battery
CN207993992U (en) * 2017-12-29 2018-10-19 惠州市纬世新能源有限公司 A kind of lithium ion battery structure

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Publication number Priority date Publication date Assignee Title
CN102683751A (en) * 2012-05-25 2012-09-19 浙江振龙电源股份有限公司 High-capacity high-magnification square lithium ion power battery and manufacturing method thereof
CN203218345U (en) * 2013-05-07 2013-09-25 北京鼎能开源电池科技股份有限公司 Steel-housing battery
CN207993992U (en) * 2017-12-29 2018-10-19 惠州市纬世新能源有限公司 A kind of lithium ion battery structure

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109244556A (en) * 2018-10-16 2019-01-18 联动天翼新能源有限公司 A kind of rectangular lithium ion battery core that improves is crumpled the anode ring forming device and method of deformation
CN109244556B (en) * 2018-10-16 2020-03-24 联动天翼新能源有限公司 Battery cell forming device and method for improving wrinkle deformation of square lithium ion battery cell
CN113285056A (en) * 2021-05-31 2021-08-20 珠海冠宇电池股份有限公司 Positive plate and battery
CN113285056B (en) * 2021-05-31 2023-11-21 珠海冠宇电池股份有限公司 Positive plate and battery
CN114284572A (en) * 2021-12-31 2022-04-05 四川启睿克科技有限公司 Roll up core structure and lithium ion battery

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