CN108456966A - A kind of preparation method of the soft tencel fabric of environmental protection parent - Google Patents

A kind of preparation method of the soft tencel fabric of environmental protection parent Download PDF

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Publication number
CN108456966A
CN108456966A CN201810616136.3A CN201810616136A CN108456966A CN 108456966 A CN108456966 A CN 108456966A CN 201810616136 A CN201810616136 A CN 201810616136A CN 108456966 A CN108456966 A CN 108456966A
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fiber
tencel
preparation
water
environmental protection
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CN108456966B (en
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张秀仙
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Shantou fulaimei garment industry Co.,Ltd.
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张秀仙
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    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/103Agents inhibiting growth of microorganisms
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F11/00Chemical after-treatment of artificial filaments or the like during manufacture
    • D01F11/02Chemical after-treatment of artificial filaments or the like during manufacture of cellulose, cellulose derivatives, or proteins
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D01F2/02Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from solutions of cellulose in acids, bases or salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/04Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of yarns, threads or filaments
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/02Cotton
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • D10B2201/22Cellulose-derived artificial fibres made from cellulose solutions

Abstract

The present invention relates to a kind of preparation methods of the soft tencel fabric of environmental protection parent.The preparation method is using log as raw material, pass through enzyme hydrolysis after log is crushed successively, after being mixed again with natural antibacterial agent, natural, spin finish aid after hydrophobically modified, tencel fiber is made by electrostatic spinning technique, citric acid is used in combination to carry out intensive treatment to tencel fiber;Cotton fiber is carried out to hydrophobically modified, the cotton fiber of obtained hydrophobically modified;Finally by the cotton fiber of tencel fiber and hydrophobically modified carry out it is blended after to get the environmentally friendly soft tencel fabric of parent.Good through the parent's soft tencel fabric skin-friendly of the invention prepared and water-fastness ability, mechanical property and anti-microbial property are good.

Description

A kind of preparation method of the soft tencel fabric of environmental protection parent
Technical field
The present invention relates to fabric preparing technical fields, the specially a kind of preparation method of the soft tencel fabric of environmental protection parent.
Background technology
It is more and more stronger for the Functional Requirement of garment material with the promotion of people's living standard, the gas permeability of clothing It is closely bound up with the health of human skin, therefore paid close attention to by many consumers.Compared with general chemical fibre, tencel fiber Feel is smooth, and pendency degree is high, and elegant property is good.Tencel fiber has a comfort and hygroscopicity of cotton, the feel of silk and good outstanding Hang down property, the solid sense of wool, the intensity of polyester fiber, be at present in the world unique set at fiber and natural fiber advantage in one The novel environment-friendlyfiber fiber of body.Since this fibrous mechanical property is bad and cost is higher, cause occupation rate of market insufficient.Cotton fiber With good moisture absorbing and sweat releasing characteristic, however simple cotton fiber cloth is easy hair wrinkle.In rainy season, pure cotton clothing be easy by Mold corrosion, and be difficult to remove mould stain.Cotton fiber also have intensity it is relatively low, not water-fastness the shortcomings of.Therefore it is fine to improve tencel The mechanical property of dimension and the antibacterial characteristics of cotton fiber have the application for expanding tencel fabric and cotton fiber fabric important Meaning.
Invention content
In order to meet fabric Functional Requirement, the poor mechanical property of tencel fiber, cotton fiber water resistance, antibacterial characteristics are solved The problems such as poor, the present invention provides a kind of preparation methods of the soft tencel fabric of environmental protection parent.
To solve the above-mentioned problems, a kind of preparation method for the soft tencel fabric of environmental protection parent that this hair provides includes following step Suddenly:
(1)Raw material is prepared using log as fiber, particles is obtained after squeezing and crushing, it is small to impregnate 2-4 using phosphate buffer Enzyme is added in Shi Hou, and after hydrolyzing a period of time under the conditions of 35-45 DEG C, cellulose solution is obtained after filtering;
(2)After cellulose solution oxidative degradation for a period of time, cellulose is set to be precipitated using acid solution, to prepare pure wood-fibred Plain pulp after the water of 3-5 times of volume is added into pure lignose pulp, will must be received using high speed shear after the processing of its nanosizing The pH value of dispersion liquid is transferred to 3-4, after stirring 2 hours at room temperature after addition hydrophobic silane reagent by rice cellulose dispersion liquid Filtering, after the fiber being obtained by filtration is washed 2-3 times with water and ethyl alcohol respectively, is dried to obtain hydrophobic nano cellulose;
(3)Hydrophobic nano cellulose, natural antibacterial agent, natural, water, spin finish aid are prepared into after mixing It to tencel fiber spinning solution, is handled through electrostatic spinning, antibacterial tencel fiber is made and is soaked in citric acid solution 2-3 hours Afterwards, after being washed with water 2-3 times after taking-up, dry antibacterial tencel fiber;
(4)After cotton washes clean, by 1:After the mass volume ratio of 80-100 is mixed with glycerine-water mixed liquid, 2-3 is impregnated After hour, it is washed with water 2-3 times after being drawn off, then be positioned in the aqueous solution of hydrophobic silane reagent, impregnates at room temperature It after 4-6 hours, is washed with water 2-3 times, the cotton fiber of dry hydrophobically modified;
(5)By step(3)The antibacterial tencel fiber and step of gained(4)The cotton fiber of the hydrophobically modified of gained carry out it is blended after, Up to the environmentally friendly soft tencel fabric of parent.
Preferably, step(1)Described in log be China fir, elm, one kind in lignum cinnamomi camphorae.
Preferably, step(1)Described in phosphate buffer pH value be 5-7;The enzyme is cellulase, is added Amount is the 0.5-1% of log quality;The hydrolysis time is 4-6 hours.
Preferably, step(2)Described in oxidative degradation conditions be:Solution ph is 11-13, and degradation time is that 2-3 is small When;The acid solution is the acetum that pH value is 1.5-2.5.
Preferably,(2)Described in high speed shear condition be:Shear velocity 8000-12000rpm/min, shear time 10-15min;The hydrophobic silane reagent is ten alkyl triethoxysilanes, dodecyl triethoxysilane, 16 One kind in alkyl triethoxysilane;The addition of the hydrophobic silane reagent is pure lignose pulp quality 1-2%。
Preferably, step(3)Described in natural antibacterial agent be the coptis, hypericum perforatum, in honeysuckle ethanol extract One kind, the natural are one kind in vitamin E, gallic acid;The spin finish aid be polyacrylamide, One kind in polyacrylonitrile, polycarbonate;The hydrophobic nano cellulose, natural antibacterial agent, natural, water, Spin finish aid is figured by mass parts is followed successively by 15-20 parts, 0.1-0.2 parts, 0.1-0.2 parts, 80-90 parts, 2-5 parts.
Preferably, step(3)Described in citric acid solution in citric acid a concentration of 0.2-0.4g/mL.
Preferably, step(4)Described in glycerine water mixed liquid in mass fraction shared by glycerine be 40-50%;Described Hydrophobic silane reagent is ten alkyl triethoxysilanes, dodecyl triethoxysilane, cetyl triethoxysilicane One kind in alkane;The quality of hydrophobic silane reagent is cotton yarn line mass in the aqueous solution of the hydrophobic silane reagent 2-4%.
Preferably, step(5)Described in it is blended when, the mass ratio of the cotton fiber of antibacterial tencel fiber and hydrophobically modified is 1:0.5-2.
Compared with prior art, a kind of preparation method of the soft tencel fabric of environmental protection parent of the present invention has beneficial below Effect, for the present invention using natural wood as tencel fiber raw material, abundance is at low cost;Nanosizing processing is carried out to fiber And it is hydrophobically modified after, the water resistance ability of the tencel fiber increased;Tencel fiber is handled using citric acid, is added The strong mechanical property of tencel fiber;It is hydrophobically modified to cotton fiber progress, strengthen the water resistance performance of cotton fiber;By cotton fibre Dimension and tencel fiber carry out blended so that the fabric good permeability of preparation, water imbibition is high, strong to skin compatibility.In addition, It is added to natural and natural antibacterial agent in the preparation process of fiber, significantly improves the anti-microbial property of fabric.Through The soft tencel fabric skin-friendly of parent prepared by the present invention is good and water-fastness ability, mechanical property and anti-microbial property are good.
Specific implementation mode
【Embodiment 1】
The preparation method of the soft tencel fabric of a kind of environmental protection parent, it is characterised in that include the following steps:
(1)Raw material is prepared using China fir as fiber, particles is obtained after squeezing and crushing, is soaked for 6 phosphate buffers using pH value Bubble after the cellulase for adding log quality 1%, after being hydrolyzed 4 hours under the conditions of 40 DEG C, filters to obtain cellulose solution after 4 hours;
(2)By cellulose solution in the solution that pH value is 13 after oxidative degradation 2 hours, it is the acetic acid of 1.5-2.5 to utilize pH value Solution makes cellulose be precipitated, to prepare pure lignose pulp, after the water of 3-5 times of volume is added into pure lignose pulp, Nano-cellulose dispersion liquid will be obtained after the shear velocity of 10000rpm/min shears 20min using high speed shear, by dispersion liquid PH value be transferred to 3-4, stir 2 hours, filter at room temperature after dodecyl triethoxysilane is added, the fiber being obtained by filtration point After not washed 2-3 times with water and ethyl alcohol, it is dried to obtain hydrophobic nano cellulose;
(3)By 16 parts of hydrophobic nano celluloses, 0.2 part of vitamin E, 0.2 part of coptis ethanol extract, 80.6 parts of water, 3 parts of spinnings Silk auxiliary agent tencel fiber spinning solution is prepared after mixing, handled through electrostatic spinning, be made antibacterial tencel fiber and by its After being soaked in 0.3g/mL citric acid solutions 3 hours, after taking-up is washed with water 2-3 times, dry antibacterial tencel fiber;
(4)After cotton washes clean, by 1:After the mass volume ratio of 80-100 is mixed with 50% glycerine-water mixed liquid, leaching Bubble after being washed with water 2-3 times after being drawn off, then is positioned in the aqueous solution of hexadecyl, room after 3 hours Temperature is lower impregnate 5 hours after, after being washed with water 2-3 times, the cotton fiber of dry hydrophobically modified;
(5)By step(3)The antibacterial tencel fiber and step of gained(4)The cotton fiber of the hydrophobically modified of gained presses 1:1 quality To get the environmentally friendly soft tencel fabric of parent after more blended than progress.
【Embodiment 2】
The preparation method of the soft tencel fabric of a kind of environmental protection parent, it is characterised in that include the following steps:
(1)Raw material is prepared using elm as fiber, particles is obtained after squeezing and crushing, is 5.5 phosphate buffers using pH value Impregnate 4 hours after, after the cellulase for adding log quality 0.5%, after being hydrolyzed 4 hours under the conditions of 40 DEG C, filter cellulose is molten Liquid;
(2)By cellulose solution in the solution that pH value is 13 after oxidative degradation 2 hours, it is the acetic acid of 1.5-2.5 to utilize pH value Solution makes cellulose be precipitated, to prepare pure lignose pulp, after the water of 3-5 times of volume is added into pure lignose pulp, Nano-cellulose dispersion liquid will be obtained after the shear velocity of 10000rpm/min shears 20min using high speed shear, by dispersion liquid PH value be transferred to 3-4, stir 2 hours, filter at room temperature after hexadecyl is added, the fiber being obtained by filtration point After not washed 2-3 times with water and ethyl alcohol, it is dried to obtain hydrophobic nano cellulose;
(3)By 15 parts of hydrophobic nano celluloses, 0.2 part of gallic acid, 0.2 part of honeysuckle ethanol extract, 81.6 parts of water, 3 Tencel fiber spinning solution is prepared in part spin finish aid after mixing, is handled through electrostatic spinning, and antibacterial tencel fiber is made simultaneously After being soaked in 0.3g/mL citric acid solutions 3 hours, after taking-up is washed with water 2-3 times, dry antibacterial tencel fiber;
(4)After cotton washes clean, by 1:After the mass volume ratio of 80-100 is mixed with 50% glycerine-water mixed liquid, leaching Bubble after being washed with water 2-3 times after being drawn off, then is positioned in the aqueous solution of dodecyl triethoxysilane, room after 3 hours Temperature is lower impregnate 5 hours after, after being washed with water 2-3 times, the cotton fiber of dry hydrophobically modified;
(5)By step(3)The antibacterial tencel fiber and step of gained(4)The cotton fiber of the hydrophobically modified of gained presses 1:0.6 matter To get the environmentally friendly soft tencel fabric of parent after amount is more blended than progress.
【Embodiment 3】
The preparation method of the soft tencel fabric of a kind of environmental protection parent, it is characterised in that include the following steps:
(1)Raw material is prepared using lignum cinnamomi camphorae as fiber, particles is obtained after squeezing and crushing, is 6 phosphate buffers using pH value Impregnate 4 hours after, after the cellulase for adding log quality 0.8%, after being hydrolyzed 4 hours under the conditions of 40 DEG C, filter cellulose is molten Liquid;
(2)By cellulose solution in the solution that pH is 13 values after oxidative degradation 2 hours, it is the acetic acid of 1.5-2.5 to utilize pH value Solution makes cellulose be precipitated, to prepare pure lignose pulp, after the water of 3-5 times of volume is added into pure lignose pulp, Nano-cellulose dispersion liquid will be obtained after the shear velocity of 11000rpm/min shears 20min using high speed shear, by dispersion liquid PH value be transferred to 3-4, stir 2 hours, filter at room temperature after hexadecyl is added, the fiber being obtained by filtration point After not washed 2-3 times with water and ethyl alcohol, it is dried to obtain hydrophobic nano cellulose;
(3)By 16 parts of hydrophobic nano celluloses, 0.2 part of gallic acid, 0.2 part of honeysuckle ethanol extract, 81.6 parts of water, 2 Tencel fiber spinning solution is prepared in part spin finish aid after mixing, is handled through electrostatic spinning, and antibacterial tencel fiber is made simultaneously After being soaked in 0.35g/mL citric acid solutions 3 hours, after taking-up is washed with water 2-3 times, dry antibacterial tencel fiber;
(4)After cotton washes clean, by 1:After the mass volume ratio of 80-100 is mixed with 50% glycerine-water mixed liquid, leaching Bubble after being washed with water 2-3 times after being drawn off, then is positioned in the aqueous solution of hexadecyl, room after 3 hours Temperature is lower impregnate 5 hours after, after being washed with water 2-3 times, the cotton fiber of dry hydrophobically modified;
(5)By step(3)The antibacterial tencel fiber and step of gained(4)The cotton fiber of the hydrophobically modified of gained presses 1:1.2 matter To get the environmentally friendly soft tencel fabric of parent after amount is more blended than progress.
For the ordinary skill in the art, specific embodiment is only exemplarily described the present invention, it is clear that Present invention specific implementation is not subject to the restrictions described above, as long as using inventive concept and technical scheme of the present invention progress The improvement of various unsubstantialities, or it is not improved by the present invention design and technical solution directly apply to other occasions, Within protection scope of the present invention.

Claims (9)

1. a kind of preparation method of the soft tencel fabric of environmental protection parent, which is characterized in that include the following steps:
(1)Raw material is prepared using log as fiber, particles is obtained after squeezing and crushing, it is small to impregnate 2-4 using phosphate buffer Enzyme is added in Shi Hou, and after hydrolyzing a period of time under the conditions of 35-45 DEG C, cellulose solution is obtained after filtering;
(2)After cellulose solution oxidative degradation for a period of time, cellulose is set to be precipitated using acid solution, to prepare pure wood-fibred Plain pulp after the water of 3-5 times of volume is added into pure lignose pulp, will must be received using high speed shear after the processing of its nanosizing The pH value of dispersion liquid is transferred to 3-4, after stirring 2 hours at room temperature after addition hydrophobic silane reagent by rice cellulose dispersion liquid Filtering, after the fiber being obtained by filtration is washed 2-3 times with water and ethyl alcohol respectively, is dried to obtain hydrophobic nano cellulose;
(3)Hydrophobic nano cellulose, natural antibacterial agent, natural, water, spin finish aid are prepared into after mixing It to tencel fiber spinning solution, is handled through electrostatic spinning, antibacterial tencel fiber is made and is soaked in citric acid solution 2-3 hours Afterwards, after being washed with water 2-3 times after taking-up, dry antibacterial tencel fiber;
(4)After cotton washes clean, by 1:After the mass volume ratio of 80-100 is mixed with glycerine-water mixed liquid, 2-3 is impregnated After hour, it is washed with water 2-3 times after being drawn off, then be positioned in the aqueous solution of hydrophobic silane reagent, impregnates at room temperature It after 4-6 hours, is washed with water 2-3 times, the cotton fiber of dry hydrophobically modified;
(5)By step(3)The antibacterial tencel fiber and step of gained(4)The cotton fiber of the hydrophobically modified of gained carry out it is blended after, Up to the environmentally friendly soft tencel fabric of parent.
2. a kind of preparation method of the soft tencel fabric of environmental protection parent according to claim 1, it is characterised in that step(1)Middle institute The log stated is one kind in China fir, elm, lignum cinnamomi camphorae.
3. a kind of preparation method of the soft tencel fabric of environmental protection parent according to claim 1, it is characterised in that step(1)Middle institute The pH value for the phosphate buffer stated is 5-7;The enzyme is cellulase, and addition is the 0.5-1% of log quality;It is described Hydrolysis time be 4-6 hours.
4. a kind of preparation method of the soft tencel fabric of environmental protection parent according to claim 1, it is characterised in that step(2)Middle institute The oxidative degradation conditions stated are:Solution ph is 11-13, and degradation time is 2-3 hours;The acid solution is that pH value is The acetum of 1.5-2.5.
5. a kind of preparation method of the soft tencel fabric of environmental protection parent according to claim 1, it is characterised in that step(2)Middle institute The high speed shear condition stated is:Shear velocity 8000-12000rpm/min, shear time 10-15min;The hydrophobicity silicon Alkylators are one in ten alkyl triethoxysilanes, dodecyl triethoxysilane, hexadecyl Kind;The addition of the hydrophobic silane reagent is the 1-2% of pure lignose pulp quality.
6. a kind of preparation method of the soft tencel fabric of environmental protection parent according to claim 1, it is characterised in that step(3)Middle institute The natural antibacterial agent stated is one kind in the coptis, hypericum perforatum, honeysuckle ethanol extract, and the natural is dimension One kind in raw element E, gallic acid;The spin finish aid is one kind in polyacrylamide, polyacrylonitrile, polycarbonate; The hydrophobic nano cellulose, natural antibacterial agent, natural, water, spin finish aid are figured by mass parts and are followed successively by 15-20 parts, 0.1-0.2 parts, 0.1-0.2 parts, 80-90 parts, 2-5 parts.
7. a kind of preparation method of the soft tencel fabric of environmental protection parent according to claim 1, it is characterised in that step(3)Middle institute A concentration of 0.2-0.4g/mL of citric acid in the citric acid solution stated.
8. a kind of preparation method of the soft tencel fabric of environmental protection parent according to claim 1, it is characterised in that step(4)Middle institute Mass fraction in the glycerine-water mixed liquid stated shared by glycerine is 40-50%;The hydrophobic silane reagent is ten alkyl One kind in triethoxysilane, dodecyl triethoxysilane, hexadecyl;The hydrophobicity silicon The quality of hydrophobic silane reagent is the 2-4% of cotton yarn line mass in the aqueous solution of Alkylators.
9. a kind of preparation method of the soft tencel fabric of environmental protection parent according to claim 1, it is characterised in that step(5)Middle institute State it is blended when, the mass ratio of the cotton fiber of antibacterial tencel fiber and hydrophobically modified is 1:0.5-2.
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CN109247627A (en) * 2018-10-22 2019-01-22 唐卫兵 A kind of preparation method of Chinese medicine antibacterial underwear fabric
CN109468719A (en) * 2018-10-22 2019-03-15 唐卫兵 A kind of preparation method of high resiliency chitosan underwear fabric
CN110218014A (en) * 2019-06-20 2019-09-10 福建农林大学 A kind of natural bacteriostatic method for cement composite material plant fiber
CN110607692A (en) * 2019-09-18 2019-12-24 界首市双鑫纺织有限公司 Preparation method of cotton-based antibacterial composite fabric
CN111455659A (en) * 2020-04-23 2020-07-28 宁波市中迪鞋业有限公司 Waterproof and dustproof children garment fabric
CN112708977A (en) * 2020-12-08 2021-04-27 苏州维杰纺织有限公司 Hydrophobic nanofiber blended yarn and production process thereof
CN112708993A (en) * 2020-12-23 2021-04-27 广东荣昌纺织实业有限公司 Ultra-soft tencel fiber textile fabric dyeing and finishing device and fabric preparation method
EP3868789A1 (en) 2020-02-18 2021-08-25 The Hong Kong Research Institute of Textiles and Apparel Limited Method for preparing water repellent textile substrates and products thereof

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CN109247627A (en) * 2018-10-22 2019-01-22 唐卫兵 A kind of preparation method of Chinese medicine antibacterial underwear fabric
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