CN108456063A - A kind of dedicated complexing nano enhanced fertilizer of excavating machine of underground tuber and preparation method thereof - Google Patents
A kind of dedicated complexing nano enhanced fertilizer of excavating machine of underground tuber and preparation method thereof Download PDFInfo
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- CN108456063A CN108456063A CN201810183914.4A CN201810183914A CN108456063A CN 108456063 A CN108456063 A CN 108456063A CN 201810183914 A CN201810183914 A CN 201810183914A CN 108456063 A CN108456063 A CN 108456063A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
Abstract
The invention discloses a kind of excavating machine of underground tuber special-purpose nanometer complex compound enhanced fertilizers and preparation method thereof.The fertilizer is made of urea, monoammonium phosphate, the fibert dregs of rice, potassium sulfate, nanometer selenium, zinc ion porphyrin nano complex compound, water soluble chitosan, zeolite powder, polyacrylamide, mica powder, plant ash according to certain weight proportion.The fertilizer can alleviate soil hardening, increase the gas permeability of soil, the activity of zinc ion porphyrin nano complex compound and a variety of biological enzyme in a variety of nutrients synergistic effect energy Effective Regulation root crop body, promote photosynthesis, it can promote root Rapid development, expand, inhibit the overgrowing of ground tendril, improve fruit density, improve fruit quality and increase yield, especially potato, pachyrhizus, taro is increased production apparent.
Description
Technical field
The present invention relates to a kind of complexing nano enhanced fertilizer, specifically a kind of dedicated nanometer network of excavating machine of underground tuber
Close enhanced fertilizer and preparation method thereof.
Background technology
Countries in the world are just towards saving, environment-friendly type social development, and as developing country, agricultural is the base in China in China
This, China is large agricultural country and Fertilizer application big country.So development green, environment-friendly type fertilizer are that China's fertilizer is given priority to
Direction.Currently, China's fertilizer application during there are fertilizer qualities it is low, dosage is excessive, method of administration is improper the problems such as, cause
China's utilization rate of fertilizer is relatively low.Data show, the return rate of China's fertilizer not as good as the U.S. one third, less than global two
/ mono-, a large amount of fertilizer nutrients are lost in the waste for not only causing resource, also bring a series of environmental problem.From current fertilizer
From the point of view of technology development, promote that fertilizer quality, improving fertilizer technical, plant recovery of nutrient is low to ask to solve by technological innovation
Topic is the contradictory effective way in part for solving current agricultural fertilising and facing.Currently, China's enhanced fertilizer is divided into several classes, first
Class is stable fertilizer, and the comparison applied on the market is more, and fertilizer efficiency period length is, it can be achieved that the single fertilization of broadacre agriculture exempts to chase after
Fertilizer production；Second is coated fertilizer, and field crop is applied more at home, but is mainly used in the form of Blending Fertilizer；
Third class is the ureaformaldehyde class fertilizer risen in recent years, and urea and formaldehyde, which are carried out reaction, forms urea formaldehyde polymer, is added to compound
Ureaformaldehyde class fertilizer is formed in fertilizer production.Although current enhanced fertilizer kind is more, its specific aim is not strong, cannot meet a variety of
Class crop is to the different demands of nutrient, and utilization rate of fertilizer cannot maximize, and part fertilizer also has negative effect, thus this to environment
Greatly limit the application of enhanced fertilizer.
Invention content
For problems of the prior art, the present invention provides a kind of dedicated complexing nanos of excavating machine of underground tuber to increase
Imitate fertilizer.Zinc ion-the nutrients such as porphyrin nano complex compound and polyacrylamide synergistic effect in the fertilizer, can Effective Regulation root
The activity of a variety of biological enzyme in stem class crop body promotes reasonable distribution of the photosynthate in plant body, control branches and tendrils crazy
It is long, accelerate nutriment to be transported to underground rhizome, promotes rhizome to expand, to the undergrounds such as potato, pachyrhizus, Chinese yam, taro stem tuber
The effect of increasing production of crop is fairly obvious.
The present invention also provides a kind of preparation methods of the dedicated complexing nano enhanced fertilizer of excavating machine of underground tuber.
The present invention uses following technical scheme：
A kind of dedicated complexing nano object enhanced fertilizer of excavating machine of underground tuber, it is made of the raw material of following parts by weight：
30-50 parts of urea, 20-40 parts of monoammonium phosphate, 20-60 parts of the fibert dregs of rice, 10-50 parts of potassium sulfate, 0.05-0.3 parts of nanometer selenium, zinc from
Son -0.5-1.5 parts of porphyrin nano complex compound, 10-20 parts of water soluble chitosan, 20-30 parts of zeolite powder, 1-3 parts of polyacrylamide,
20-50 parts of mica powder, 50-80 parts of plant ash.
Preferably, the dedicated complexing nano object enhanced fertilizer of the excavating machine of underground tuber is by the raw material of following parts by weight
It is made：40 parts of urea, 30 parts of monoammonium phosphate, 40 parts of the fibert dregs of rice, 30 parts of potassium sulfate, 0.2 part of nanometer selenium, zinc ion-porphyrin nano
1 part of complex compound, 15 parts of water soluble chitosan, 25 parts of zeolite powder, 2 parts of polyacrylamide, 35 parts of mica powder, 60 parts of plant ash.
The zinc ion-porphyrin nano complex compound is prepared using following methods：By 10ml 1mol/L zinc acetates
Solution is added in reaction bulb together with the acetum of four pyridylporphyrins of 1.5ml 0.05mmol/L and is mixed at room temperature
After reacting 24 hours to obtain the final product.
A kind of preparation method of the dedicated complexing nano object enhanced fertilizer of excavating machine of underground tuber, it includes the following steps：
1) by 10ml 1mol/L acetic acid zinc solutions together with the acetum of four pyridylporphyrins of 1.5ml 0.05mmol/L
It is added in reaction bulb spare up to zinc ion-porphyrin nano complex compound mixed liquor after reaction being mixed at room temperature 24 hours；
2) by urea, monoammonium phosphate, the fibert dregs of rice, potassium sulfate, nanometer selenium, zeolite powder, polyacrylamide, mica powder and vegetation
Ash is uniformly mixed, and is added in comminutor and is granulated, it is spare to go out particle of the diameter in 1.5-3mm for sub-sieve after the completion of granulation；
3) water soluble chitosan is completely dissolved in the zinc ion-porphyrin nano being prepared in 5 times of amount water and with step 1)
Complex compound mixed liquor is uniformly mixed to obtain coating liquid, spare；
4) particle prepared by step (2) is added in coating machine, 50-55 DEG C is preheated to, then by coating solution spraying
It is dried in particle surface.
The beneficial effects of the invention are as follows：The fertilizer of the present invention can alleviate soil hardening, increase the gas permeability of soil, zinc ion-
The activity of porphyrin nano complex compound and a variety of biological enzyme in a variety of nutrients synergistic effect energy Effective Regulation root crop body, promotes
Photosynthesis can promote root Rapid development, expand, and inhibit the overgrowing of ground tendril, improve fruit density, improve fruit quality and increase
Add yield, especially potato, pachyrhizus, taro is increased production apparent.Meanwhile fertilizer of the invention can also enhance crop disease-resistant, degeneration-resistant
Ability resists abnormal cracking resistance, improves the commodity performance of product and resistance to energy storage power.
Specific implementation mode
With reference to specific embodiment, the present invention is described in further detail.
Embodiment 1
A kind of dedicated complexing nano object enhanced fertilizer of excavating machine of underground tuber, it is made of the raw material of following parts by weight：
30 parts of urea, 20 parts of monoammonium phosphate, 20 parts of the fibert dregs of rice, 10 parts of potassium sulfate, 0.05 part of nanometer selenium, zinc ion-porphyrin nano complexing
0.5 part of object, 10 parts of water soluble chitosan, 20 parts of zeolite powder, 1 part of polyacrylamide, 20 parts of mica powder, 50 parts of plant ash.
The preparation method of the dedicated complexing nano object enhanced fertilizer of above-mentioned excavating machine of underground tuber, it includes the following steps：
1) by 10ml 1mol/L acetic acid zinc solutions together with the acetum of four pyridylporphyrins of 1.5ml 0.05mmol/L
It is added in reaction bulb spare up to zinc ion-porphyrin nano complex compound mixed liquor after reaction being mixed at room temperature 24 hours；
2) by urea, monoammonium phosphate, the fibert dregs of rice, potassium sulfate, nanometer selenium, zeolite powder, polyacrylamide, mica powder and vegetation
Ash is uniformly mixed, and is added in comminutor and is granulated, it is spare to go out particle of the diameter in 1.5-3mm for sub-sieve after the completion of granulation；
3) water soluble chitosan is completely dissolved in the zinc ion-porphyrin nano being prepared in 5 times of amount water and with step 1)
Complex compound mixed liquor is uniformly mixed to obtain coating liquid, spare；
4) particle prepared by step (2) is added in coating machine, 50-55 DEG C is preheated to, then by coating solution spraying
It is dried in particle surface.
Embodiment 2
A kind of dedicated complexing nano object enhanced fertilizer of excavating machine of underground tuber, it is made of the raw material of following parts by weight：
50 parts of urea, 40 parts of monoammonium phosphate, 60 parts of the fibert dregs of rice, 50 parts of potassium sulfate, 0.3 part of nanometer selenium, zinc ion-porphyrin nano complex compound
1.5,20 parts of water soluble chitosan, 30 parts of zeolite powder, 3 parts of polyacrylamide, 50 parts of mica powder, 80 parts of plant ash.
The preparation method of the dedicated complexing nano object enhanced fertilizer of above-mentioned excavating machine of underground tuber, it includes the following steps：
1) by 10ml 1mol/L acetic acid zinc solutions together with the acetum of four pyridylporphyrins of 1.5ml 0.05mmol/L
It is added in reaction bulb spare up to zinc ion-porphyrin nano complex compound mixed liquor after reaction being mixed at room temperature 24 hours；
2) by urea, monoammonium phosphate, the fibert dregs of rice, potassium sulfate, nanometer selenium, zeolite powder, polyacrylamide, mica powder and vegetation
Ash is uniformly mixed, and is added in comminutor and is granulated, it is spare to go out particle of the diameter in 1.5-3mm for sub-sieve after the completion of granulation；
3) water soluble chitosan is completely dissolved in the zinc ion-porphyrin nano being prepared in 5 times of amount water and with step 1)
Complex compound mixed liquor is uniformly mixed to obtain coating liquid, spare；
4) particle prepared by step (2) is added in coating machine, 50-55 DEG C is preheated to, then by coating solution spraying
It is dried in particle surface.
Embodiment 3
A kind of dedicated complexing nano object enhanced fertilizer of excavating machine of underground tuber, it is made of the raw material of following parts by weight：
40 parts of urea, 30 parts of monoammonium phosphate, 40 parts of the fibert dregs of rice, 30 parts of potassium sulfate, 0.2 part of nanometer selenium, zinc ion-porphyrin nano complex compound
1 part, 15 parts of water soluble chitosan, 25 parts of zeolite powder, 2 parts of polyacrylamide, 35 parts of mica powder, 60 parts of plant ash.
The preparation method of the dedicated complexing nano object enhanced fertilizer of above-mentioned excavating machine of underground tuber, it includes the following steps：
1) by 10ml 1mol/L acetic acid zinc solutions together with the acetum of four pyridylporphyrins of 1.5ml 0.05mmol/L
It is added in reaction bulb spare up to zinc ion-porphyrin nano complex compound mixed liquor after reaction being mixed at room temperature 24 hours；
2) by urea, monoammonium phosphate, the fibert dregs of rice, potassium sulfate, nanometer selenium, zeolite powder, polyacrylamide, mica powder and vegetation
Ash is uniformly mixed, and is added in comminutor and is granulated, it is spare to go out particle of the diameter in 1.5-3mm for sub-sieve after the completion of granulation；
3) water soluble chitosan is completely dissolved in the zinc ion-porphyrin nano being prepared in 5 times of amount water and with step 1)
Complex compound mixed liquor is uniformly mixed to obtain coating liquid, spare；
4) particle prepared by step (2) is added in coating machine, 50-55 DEG C is preheated to, then by coating solution spraying
It is dried in particle surface.
Comparative example 1
A kind of dedicated complexing nano object enhanced fertilizer of excavating machine of underground tuber, it is made of the raw material of following parts by weight：
40 parts of urea, 30 parts of monoammonium phosphate, 40 parts of the fibert dregs of rice, 30 parts of potassium sulfate, 0.2 part of nanometer selenium, 15 parts of water soluble chitosan, zeolite
25 parts of powder, 2 parts of polyacrylamide, 35 parts of mica powder, 60 parts of plant ash.The dedicated complexing nano object of above-mentioned excavating machine of underground tuber
The preparation method of enhanced fertilizer, it includes the following steps：
1) by urea, monoammonium phosphate, the fibert dregs of rice, potassium sulfate, nanometer selenium, zeolite powder, polyacrylamide, mica powder and vegetation
Ash is uniformly mixed, and is added in comminutor and is granulated, it is spare to go out particle of the diameter in 1.5-3mm for sub-sieve after the completion of granulation；
2) water soluble chitosan is completely dissolved in 5 times of amount water and stirs evenly to obtain coating liquid, it is spare；
3) particle prepared by step (1) is added in coating machine, 50-55 DEG C is preheated to, then by coating solution spraying
It is dried in particle surface.
Application examples 1
Tangshan, Hebei Province Luan County somewhere is chosen as experimental plot, experimental plot is divided into 5 processing groups, respectively T1, T2,
T3, T4, T5, often processing group plantation potato density is identical, is 5000 plants/acre, experimental cultivar Dongnong303；Wherein T1-T3 is
The fertilizer for using embodiment 1-3 to prepare respectively；T4 is using 1 gained fertilizer of comparative example；T5 is Routine control group, using commercially available general
Logical ternary compound fertilizer, wherein N-P2O5-K2O 16-16-16, total nutrient >=48%.The processing method of each processing group is in Ma Ling
When planting potato in base manure is manured into soil, each processing group dose is identical, and each processing group all same of other field management is received
It obtains the whole fruits of phase picking to weigh statistics yield, and counts in entire growth cycle that a situation arises for pest and disease damage, concrete outcome such as table 1
It is shown.
1 potato yield result of table counts
| Test group | Single fruit reality counterpoise (g) | Total output (kg/ mus) | Pest and disease damage frequency (secondary) |
| T1 | 495 | 2895 | 2 |
| T2 | 502 | 2847 | 2 |
| T3 | 505 | 2889 | 1 |
| T4 | 420 | 2402 | 3 |
| T5 | 413 | 2215 | 4 |
As can be seen that the excavating machine of underground tuber special-purpose nanometer complexing enhanced fertilizer of the present invention makes from the result of above-mentioned table 1
The yield of potato can be made to obviously increase after, single fruit weight is also larger.In addition, passing through the yield knot of embodiment 1-3 and comparative example
Fruit compares, and for fertilizer of the invention when addition is not with zinc ion-porphyrin nano complex compound is added, crop yield is entirely different, fruit
Real character is also different, this is because the zinc ion added in fertilizer of the present invention-porphyrin nano complex compound can be assisted with other nutrients
Same-action, the activity of a variety of biological enzyme in Effective Regulation root crop body, promotes photosynthesis, root can be promoted quickly to send out
It educates, expand, inhibit the overgrowing of ground tendril, improve fruit density, improve fruit quality and increase yield.In addition the fertilizer of the present invention is used
Material, the pest and disease damage frequency of potato also significantly reduce.
Application examples 2
Weifang City of Shandong Province Linqu County somewhere is chosen as experimental plot, experimental plot is divided into 5 processing groups, respectively T1,
T2, T3, T4, T5, often processing group plantation pachyrhizus density is identical, is 3500 plants/acre, experimental cultivar Ji potato 21；Wherein T1-T3 is
The fertilizer for using embodiment 1-3 to prepare respectively；T4 is using 1 gained fertilizer of comparative example；T5 is Routine control group, using commercially available general
Logical composite fertilizer, wherein N-P2O5-K2O 15-15-15, total nutrient >=45%.The processing method of each processing group is to be transplanted in pachyrhizus
When in base manure is manured into soil, each processing group dose is identical, other field management each processing group all same harvest time adopts
It plucks whole fruits to weigh statistics yield, and counts in entire growth cycle that a situation arises for pest and disease damage, concrete outcome is as shown in table 2.
2 pachyrhizus yield result of table counts
| Test group | Single potato counterpoise (kg) | Fresh sweet potato total output (kg/ mus) | Commodity potato rate (%) |
| T1 | 0.52 | 2979 | 98.7 |
| T2 | 0.49 | 2843 | 97.6 |
| T3 | 0.51 | 2989 | 99.1 |
| T4 | 0.32 | 2205 | 85.3 |
| T5 | 0.35 | 2321 | 88.2 |
As can be seen that the excavating machine of underground tuber special-purpose nanometer complexing enhanced fertilizer of the present invention is used from the result of above-mentioned table 2
The yield of pachyrhizus can be made also to obviously increase after pachyrhizus, single potato counterpoise is also larger, and commodity potato rate is also higher.In addition, passing through implementation
The comparison of the yield result of example 1-3 and comparative example, fertilizer of the invention is in addition and does not add zinc ion-porphyrin nano complex compound
When, crop yield is entirely different, and fruit properties are also different.In addition, it is also higher using the sugar content of pachyrhizus after the fertilizer of the present invention,
Sugariness is better than comparative example, and eating mouth feel is preferable.
Claims (4)
1. a kind of dedicated complexing nano object enhanced fertilizer of excavating machine of underground tuber, which is characterized in that it is by following parts by weight
Raw material is made：30-50 parts of urea, 20-40 parts of monoammonium phosphate, 20-60 parts of the fibert dregs of rice, 10-50 parts of potassium sulfate, nanometer selenium 0.05-
0.3 part, zinc ion -0.5-1.5 parts of porphyrin nano complex compound, 10-20 parts of water soluble chitosan, 20-30 parts of zeolite powder, polypropylene
1-3 parts of amide, 20-50 parts of mica powder, 50-80 parts of plant ash.
2. the dedicated complexing nano object enhanced fertilizer of excavating machine of underground tuber according to claim 1, which is characterized in that it is
It is made of the raw material of following parts by weight：40 parts of urea, 30 parts of monoammonium phosphate, 40 parts of the fibert dregs of rice, 30 parts of potassium sulfate, nanometer selenium 0.2
Part, zinc ion -1 part of porphyrin nano complex compound, 15 parts of water soluble chitosan, 25 parts of zeolite powder, 2 parts of polyacrylamide, mica powder
35 parts, 60 parts of plant ash.
3. the dedicated complexing nano object enhanced fertilizer of excavating machine of underground tuber according to claim 1 or 2, which is characterized in that
The zinc ion-porphyrin nano complex compound is prepared using following methods：By 10ml 1mol/L acetic acid zinc solutions with
It is small that the acetum of four pyridylporphyrins of 1.5ml0.05mmol/L is added in reaction bulb mixing reaction 24 at room temperature together
When after to obtain the final product.
4. a kind of preparation method of the dedicated complexing nano object enhanced fertilizer of excavating machine of underground tuber described in claim 3, special
Sign is that it includes the following steps：
1) 10ml 1mol/L acetic acid zinc solutions are added together with the acetum of four pyridylporphyrins of 1.5ml 0.05mmol/L
It is spare up to zinc ion-porphyrin nano complex compound mixed liquor to after reaction being mixed in reaction bulb at room temperature 24 hours；
2) urea, monoammonium phosphate, the fibert dregs of rice, potassium sulfate, nanometer selenium, zeolite powder, polyacrylamide, mica powder and plant ash are mixed
It closes uniformly, is added in comminutor and is granulated, it is spare to go out particle of the diameter in 1.5-3mm for sub-sieve after the completion of granulation；
3) water soluble chitosan the zinc ion-porphyrin nano being prepared in 5 times of amount water and with step 1) is completely dissolved in be complexed
Object mixed liquor is uniformly mixed to obtain coating liquid, spare；
4) by step (2) prepare particle be added in coating machine, be preheated to 50-55 DEG C, then by coating solution spraying
Grain skin drying.
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| CN201810183914.4A CN108456063A (en) | 2018-03-06 | 2018-03-06 | A kind of dedicated complexing nano enhanced fertilizer of excavating machine of underground tuber and preparation method thereof |
Applications Claiming Priority (1)
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| CN201810183914.4A CN108456063A (en) | 2018-03-06 | 2018-03-06 | A kind of dedicated complexing nano enhanced fertilizer of excavating machine of underground tuber and preparation method thereof |
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Citations (5)
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|---|---|---|---|---|
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| CN104650104A (en) * | 2015-01-26 | 2015-05-27 | 深圳市一正科技有限公司 | Preparation method of zinc ion-porphyrin nanometer complex |
| CN106905046A (en) * | 2017-03-17 | 2017-06-30 | 甘肃省农业科学院旱地农业研究所 | A kind of potato soybean interplanting special fertilizer and preparation method thereof |
| CN107141069A (en) * | 2017-05-17 | 2017-09-08 | 贵州天宝丰原生态农业科技有限公司 | Compound fertilizer, preparation method and applications |
| CN107337539A (en) * | 2017-08-14 | 2017-11-10 | 史丹利化肥扶余有限公司 | A kind of Special fertilizer for potato with prevention and control pest and disease damage function and preparation method thereof |
-
2018
- 2018-03-06 CN CN201810183914.4A patent/CN108456063A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6372007B1 (en) * | 1999-01-29 | 2002-04-16 | Rafael Munoz | Organic compost |
| CN104650104A (en) * | 2015-01-26 | 2015-05-27 | 深圳市一正科技有限公司 | Preparation method of zinc ion-porphyrin nanometer complex |
| CN106905046A (en) * | 2017-03-17 | 2017-06-30 | 甘肃省农业科学院旱地农业研究所 | A kind of potato soybean interplanting special fertilizer and preparation method thereof |
| CN107141069A (en) * | 2017-05-17 | 2017-09-08 | 贵州天宝丰原生态农业科技有限公司 | Compound fertilizer, preparation method and applications |
| CN107337539A (en) * | 2017-08-14 | 2017-11-10 | 史丹利化肥扶余有限公司 | A kind of Special fertilizer for potato with prevention and control pest and disease damage function and preparation method thereof |
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Application publication date: 20180828 |