CN108441364A - The preparation method of the washing powder for spot of efficiently dispelling - Google Patents

The preparation method of the washing powder for spot of efficiently dispelling Download PDF

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Publication number
CN108441364A
CN108441364A CN201810309894.0A CN201810309894A CN108441364A CN 108441364 A CN108441364 A CN 108441364A CN 201810309894 A CN201810309894 A CN 201810309894A CN 108441364 A CN108441364 A CN 108441364A
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Prior art keywords
mixed
added
washing powder
sodium
parts
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CN201810309894.0A
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Chinese (zh)
Inventor
丁爱平
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Anqing One Zhi Mei Chemical Industry Co Ltd
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Anqing One Zhi Mei Chemical Industry Co Ltd
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Priority to CN201810309894.0A priority Critical patent/CN108441364A/en
Publication of CN108441364A publication Critical patent/CN108441364A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/042Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/045Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143Sulfonic acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146Sulfuric acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention provides a kind of preparation method of the washing powder for spot of efficiently dispelling, the washing powder is mainly added with the intermixture of sodium tripolyphosphate, silica and fatty alcohol-ether sodium sulfate compared to existing laundry meal component in the ingredient of washing powder.Reasonable design of the present invention, it is simple to manufacture, mainly pass through the intermixture added with sodium tripolyphosphate, silica and fatty alcohol-ether sodium sulfate in meal component of doing washing, pass through three's effective stain removal ability by force, the ability that washing powder dispels spot can be effectively improved, the cleanliness factor of the clothes after cleaning is improved.

Description

The preparation method of the washing powder for spot of efficiently dispelling
Technical field
The invention mainly relates to the technical fields that laundry system of mourning is made, and in particular to the preparation side of the washing powder for spot of efficiently dispelling Method.
Background technology
With world economy integration and trade globalization development, culture background, technical merit and environmental regulation by Gradually becoming three large driving forces of articles for washing development of globalization, global articles for washing is diversified by trend, but energy saving, water-saving, Efficiently, product that is mild, easy to use and meeting safety and environmental requirement by be the development of current and future cleaning product master Flow direction.It is well known that containing largely the filler anhydrous sodium sulphate without any cleaning function, mass fraction are more than in washing powder 40%, great waste is caused in terms of resource and the energy, can also be caused dust pollution in production, is unfavorable for environmental protection.And Liquid detergent with resourceful and inexpensive water instead of anhydrous sodium sulphate, using biodegradable surfactant as main component And it is aided with phosphorus-free adjuvant and compounds.Due to liquid detergent have production technology is easy, performance is mild, it is non-stimulated, easy to dissolve, make The features such as with facilitating, overcomes some disadvantages of washing powder, have developed rapidly, be gradually accepted by people.
In people's daily life, due to some small detailed problems, cause usually adhere to some greasy dirt stains on clothing, profit Be difficult with washing powder, the liquid detergent on existing market enough clean up, so, need to develop a kind of washing powder being completely newly formulated, It oils the washing powder formula of spot to remove clothing.
Invention content
Present invention generally provides a kind of preparation methods of the washing powder for spot of efficiently dispelling, to solve in above-mentioned background technology It is proposed, existing liquid detergent, washing powder can not potent removal clothing oil spot the technical issues of.
The present invention solve the technical solution that uses of above-mentioned technical problem for:The described washing powder is mainly by 50-80 parts Soap base, 1-10 parts of fabric fibre scale preventative, 1-12 parts of anion surfactant, 1-12 parts of non-ionic surface active Agent, 1-2 parts of water softener, 1-2 parts of soil suspender, 5-10 parts of amylase, 0.5-1 parts of fluorescer, 1-2 parts of perfume (or spice) Material, 1-5 parts of sodium tripolyphosphate intermixture, 1-2 parts of silica and the mixing of 5-10 parts of fatty alcohol-ether sodium sulfate intermixture It forms.
In anion surfactant set forth above, according to 3 sodium alklyarylsulfonates:1 sodium alkyl sulfate:1.5 secondary alkane Base sodium sulphate, is mixed;And the nonionic surfactant is mainly by benzene sulfonic acid, toluenesulfonic acid, xylene monosulfonic acid, hydroxyl Base benzene sulfonic acid and sodium hydroxide numerous compositions are mixed at 25 DEG C of temperature;The sodium tripolyphosphate intermixture mainly by Sodium tripolyphosphate, sodium alkyl sulfate, saponin and ammonium hydroxide are mixed;The fatty alcohol-ether sodium sulfate intermixture is mainly by alkyl Sodium sulfonate, fatty alcohol-ether sodium sulfate, foaming agent, solubilizer, essence, water, pigment and preservative are mixed.
According to above-mentioned proposed, the preparation method for stating washing powder is as follows:
A. suitable soap base is first weighed, is put into grinder, pulverulence is ground, is added by the soap base after grinding Enter into batcher;
B. according to 3:1:1.5 ratio weighs sodium alklyarylsulfonate, sodium alkyl sulfate, Teepol, after weighing Raw material is added in reaction kettle and is mixed evenly, and anion surfactant is made, anti-weighing a certain amount of fabric fibre Dirty agent is added in anion surfactant, after being mixed evenly, is added to mixing in batcher;
C. suitable benzene sulfonic acid, toluenesulfonic acid, xylene monosulfonic acid, hydroxy benzene sulfonic acid and sodium hydroxide are weighed, is added in reaction kettle, And after reaction kettle is warming up to 25 DEG C, it is mixed after ten minutes, mixed liquor is to get nonionic surfactant everywhere, Nonionic surfactant obtained is added in batcher;
D. in the mixed ingredients made from above-mentioned steps C, one by one be added water softener, soil suspender, amylase, fluorescer and Fragrance, and batcher is warming up to 25 DEG C, stirring continues 15 minutes, staticly settles 5 minutes, by residue filter, obtains cleaner liquid;
E. sodium tripolyphosphate, sodium alkyl sulfate, saponin are added in the reaction kettle for fill ammonium hydroxide and are mixed, work as surface After not having apparent floccule to float, export is added in the mixed solution that above-mentioned steps D is obtained and stirs;
F. add by the mixing of sodium alkyl sulfonate, fatty alcohol-ether sodium sulfate, foaming agent, solubilizer, essence, water, pigment and preservative Enter into reaction kettle, also, reaction kettle is heated up, after temperature in the kettle reaches between 35 DEG C -50 DEG C, stops heating, unlatching is stirred Machine is mixed, is mixed, at such a temperature, is stirred 15-20 minutes, the mixed liquor after stirring is being added to step E In obtained mixed liquor, and fraction of silica is added;
G. after adding silica to be sufficiently stirred 30 minutes, export both obtains mixed emulsion, will mixed emulsion be added to drying room Inside dried, it is ensured that dehydration rate reaches 98% or more, you can the washing powder.
Compared with prior art, beneficial effects of the present invention are:Reasonable design of the present invention, is simple to manufacture, mainly by The intermixture added with sodium tripolyphosphate, silica and fatty alcohol-ether sodium sulfate, effective by force by three in laundry meal component Stain removal ability, can effectively improve the ability that washing powder dispels spot, improve the cleanliness factor of the clothes after cleaning.
Detailed explanation is carried out to the present invention below with reference to specific embodiment.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common The every other embodiment that technical staff is obtained without creative efforts belongs to the model that the present invention protects It encloses.
Embodiment 1
A. the soap base for first weighing 50 parts, is put into grinder, is ground pulverulence, is added by the soap base after grinding Enter into batcher;
B. according to 3:1:1.5 ratio weighs 0.6 part of sodium alklyarylsulfonate, 0.2 part of sodium alkyl sulfate and 0.4 part Raw material after weighing is added in reaction kettle and is mixed evenly by Teepol, and anion surfactant is made, It weighs a certain amount of fabric fibre scale preventative to be added in anion surfactant, after being mixed evenly, is added to batcher Interior mixing;
C. 0.4 part of benzene sulfonic acid, 0.2 part of toluenesulfonic acid, 0.3 part of xylene monosulfonic acid, 0.05 part of hydroxy benzenes sulphur are weighed Acid and 0.05 part of sodium hydroxide are added in reaction kettle, and after reaction kettle is warming up to 25 DEG C, are mixed after ten minutes, Mixed liquor is added to by nonionic surfactant obtained in batcher to get nonionic surfactant everywhere;
D. in the mixed ingredients made from above-mentioned steps C, be added one by one 1 part of water softener, 1 part of soil suspender, 5 parts Amylase, 0.5 part of fluorescer and 1 part of fragrance, and batcher is warming up to 25 DEG C, stirring continues 15 minutes, and it is heavy to stand It forms sediment 5 minutes, by residue filter, obtains cleaner liquid;
E. 0.5 part of sodium tripolyphosphate, 0.2 part of sodium alkyl sulfate, 0.2 part of saponin are added to and fill 0.1 part of ammonium hydroxide Reaction kettle in be mixed, after surface does not have apparent floccule to float, export is added to what above-mentioned steps D was obtained It is stirred in mixed solution;
F. by 2 parts of sodium alkyl sulfonate, 1 part of fatty alcohol-ether sodium sulfate, 0.5 part of foaming agent, 0.5 part of solubilizer, 0.2 Part essence, 1 part of water, 0.05 part of pigment and 0.05 part of preservative be mixed to join in reaction kettle, also, by reaction kettle Heating stops heating after temperature in the kettle reaches between 35 DEG C -50 DEG C, opens blender, is mixed, in the temperature Under, it stirs 15-20 minutes, is added in the mixed liquor that step E is obtained by the mixed liquor after stirring, and be added a little Silica;
G. after adding silica to be sufficiently stirred 30 minutes, export both obtains mixed emulsion, will mixed emulsion be added to drying room Inside dried, it is ensured that dehydration rate reaches 98% or more, you can the washing powder.
Embodiment 2
A. the soap base for first weighing 80 parts, is put into grinder, is ground pulverulence, is added by the soap base after grinding Enter into batcher;
B. according to 3:1:1.5 ratio weighs 6 parts of sodium alklyarylsulfonate, 2 parts of sodium alkyl sulfate and 4 parts of secondary alkyl Raw material after weighing is added in reaction kettle and is mixed evenly by sodium sulphate, and anion surfactant is made, is weighing one Quantitative fabric fibre scale preventative is added in anion surfactant, after being mixed evenly, is added to mixing in batcher;
C. 4 parts of benzene sulfonic acid, 2 parts of toluenesulfonic acid, 3 parts of xylene monosulfonic acid, 0.5 part of hydroxy benzene sulfonic acid and 0.5 are weighed Part sodium hydroxide, be added in reaction kettle, and after reaction kettle is warming up to 25 DEG C, be mixed after ten minutes, mix everywhere Liquid is added to by nonionic surfactant obtained in batcher to get nonionic surfactant;
D. in the mixed ingredients made from above-mentioned steps C, one by one be added 2 parts of water softener, 2 parts of soil suspender, 10 parts Amylase, 1 part of fluorescer and 2 parts of fragrance, and batcher is warming up to 25 DEG C, stirring continues 15 minutes, and it is heavy to stand It forms sediment 5 minutes, by residue filter, obtains cleaner liquid;
E. 2.5 parts of sodium tripolyphosphate, 1 part of sodium alkyl sulfate, 1 part of saponin are added to fill 0.5 part ammonium hydroxide it is anti- It answers in kettle and is mixed, after surface does not have apparent floccule to float, export is added to the mixing that above-mentioned steps D is obtained It is stirred in solution;
F. by 4 parts of sodium alkyl sulfonate, 1.5 parts of fatty alcohol-ether sodium sulfate, 1 part of foaming agent, 1 part of solubilizer, 0.5 part Essence, 2 parts of water, 0.1 part of pigment and 0.1 part of preservative be mixed to join in reaction kettle, also, by reaction kettle liter Temperature stops heating after temperature in the kettle reaches between 35 DEG C -50 DEG C, opens blender, is mixed, at such a temperature, Stirring 15-20 minutes is added in the mixed liquor that step E is obtained by the mixed liquor after stirring, and is added fraction of Silica;
G. after adding silica to be sufficiently stirred 30 minutes, export both obtains mixed emulsion, will mixed emulsion be added to drying room Inside dried, it is ensured that dehydration rate reaches 98% or more, you can the washing powder.
Analysis comparison is carried out by above-described embodiment and the prior art, the clothing after being cleaned using the washing powder can not only Enough potent spots dispelled on clothing, meanwhile, within effective time, adhesive rate of the greasy dirt on clothing can be effectively reduced, is increased The practicability of the washing powder.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, all protection models in the present invention Any modification, equivalent replacement etc., should all be included in the protection scope of the present invention made by enclosing.

Claims (7)

1. the preparation method of the washing powder for spot of efficiently dispelling, which is characterized in that the washing powder compared to existing laundry meal component, The mainly intermixture added with sodium tripolyphosphate, silica and fatty alcohol-ether sodium sulfate in the ingredient of washing powder.
2. the preparation method of the washing powder of spot according to claim 1 of efficiently dispelling, which is characterized in that the described washing powder Mainly by 50-80 parts of soap base, 1-10 parts of fabric fibre scale preventative, 1-12 parts of anion surfactant, 1-12 parts Nonionic surfactant, 1-2 parts of water softener, 1-2 parts of soil suspender, 5-10 parts of amylase, 0.5-1 parts Fluorescer, 1-2 parts of fragrance, 1-5 parts of sodium tripolyphosphate intermixture, 1-2 parts of silica and 5-10 parts of fatty alcohol ether Sodium sulphate intermixture mixes.
3. the preparation method of the washing powder of spot according to claim 2 of efficiently dispelling, which is characterized in that the anion table Face activating agent is according to 3 sodium alklyarylsulfonates:1 sodium alkyl sulfate:1.5 Teepols, are mixed.
4. the preparation method of the washing powder of spot according to claim 2 of efficiently dispelling, which is characterized in that the nonionic table Face activating agent is mainly by benzene sulfonic acid, toluenesulfonic acid, xylene monosulfonic acid, hydroxy benzene sulfonic acid and sodium hydroxide numerous compositions in temperature It is mixed at 25 DEG C of degree.
5. the preparation method of the washing powder of spot according to claim 2 of efficiently dispelling, which is characterized in that the tripolyphosphate Sodium intermixture is mainly mixed by sodium tripolyphosphate, sodium alkyl sulfate, saponin and ammonium hydroxide.
6. the preparation method of the washing powder of spot according to claim 2 of efficiently dispelling, which is characterized in that the fatty alcohol ether Sodium sulphate intermixture mainly by sodium alkyl sulfonate, fatty alcohol-ether sodium sulfate, foaming agent, solubilizer, essence, water, pigment and is prevented Rotten agent is mixed.
7. the preparation method of the washing powder of the spot of efficiently dispelling according to claim 2-6 any claims, feature exist In the preparation method of the washing powder is as follows:
A. suitable soap base is first weighed, is put into grinder, pulverulence is ground, is added by the soap base after grinding Enter into batcher;
B. according to 3:1:1.5 ratio weighs sodium alklyarylsulfonate, sodium alkyl sulfate, Teepol, after weighing Raw material is added in reaction kettle and is mixed evenly, and anion surfactant is made, anti-weighing a certain amount of fabric fibre Dirty agent is added in anion surfactant, after being mixed evenly, is added to mixing in batcher;
C. suitable benzene sulfonic acid, toluenesulfonic acid, xylene monosulfonic acid, hydroxy benzene sulfonic acid and sodium hydroxide are weighed, is added in reaction kettle, And after reaction kettle is warming up to 25 DEG C, it is mixed after ten minutes, mixed liquor is to get nonionic surfactant everywhere, Nonionic surfactant obtained is added in batcher;
D. in the mixed ingredients made from above-mentioned steps C, one by one be added water softener, soil suspender, amylase, fluorescer and Fragrance, and batcher is warming up to 25 DEG C, stirring continues 15 minutes, staticly settles 5 minutes, by residue filter, obtains cleaner liquid;
E. sodium tripolyphosphate, sodium alkyl sulfate, saponin are added in the reaction kettle for fill ammonium hydroxide and are mixed, work as surface After not having apparent floccule to float, export is added in the mixed solution that above-mentioned steps D is obtained and stirs;
F. add by the mixing of sodium alkyl sulfonate, fatty alcohol-ether sodium sulfate, foaming agent, solubilizer, essence, water, pigment and preservative Enter into reaction kettle, also, reaction kettle is heated up, after temperature in the kettle reaches between 35 DEG C -50 DEG C, stops heating, unlatching is stirred Machine is mixed, is mixed, at such a temperature, is stirred 15-20 minutes, the mixed liquor after stirring is being added to step E In obtained mixed liquor, and fraction of silica is added;
G. after adding silica to be sufficiently stirred 30 minutes, export both obtains mixed emulsion, will mixed emulsion be added to drying room Inside dried, it is ensured that dehydration rate reaches 98% or more, you can the washing powder.
CN201810309894.0A 2018-04-09 2018-04-09 The preparation method of the washing powder for spot of efficiently dispelling Pending CN108441364A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108998192A (en) * 2018-09-20 2018-12-14 王晓霞 A kind of chemical industry equipment lubricant agent special
CN112358917A (en) * 2020-11-10 2021-02-12 江苏千雅日用品有限公司 Detergent for silk and/or down clothes

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1081204A (en) * 1992-07-09 1994-01-26 匡元正 Efficient disinfecting soap powder
CN1318524A (en) * 2000-04-17 2001-10-24 邓武强 Efficient scour for water cooling heat exchanger system
CN101802161A (en) * 2007-09-14 2010-08-11 花王株式会社 Alkaline nonionic surfactant composition
CN104789394A (en) * 2015-04-29 2015-07-22 青岛东昌瑞纺织品有限公司 Softening enzymatic laundry powder
CN105858668A (en) * 2016-03-30 2016-08-17 广州市飞雪材料科技有限公司 Preparation method of silicon dioxide with high oil absorption value and high water absorption capacity for washing powder
CN106854513A (en) * 2015-12-09 2017-06-16 西安网清生物科技有限公司 A kind of green non-phosphide detergent and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN1081204A (en) * 1992-07-09 1994-01-26 匡元正 Efficient disinfecting soap powder
CN1318524A (en) * 2000-04-17 2001-10-24 邓武强 Efficient scour for water cooling heat exchanger system
CN101802161A (en) * 2007-09-14 2010-08-11 花王株式会社 Alkaline nonionic surfactant composition
CN104789394A (en) * 2015-04-29 2015-07-22 青岛东昌瑞纺织品有限公司 Softening enzymatic laundry powder
CN106854513A (en) * 2015-12-09 2017-06-16 西安网清生物科技有限公司 A kind of green non-phosphide detergent and preparation method thereof
CN105858668A (en) * 2016-03-30 2016-08-17 广州市飞雪材料科技有限公司 Preparation method of silicon dioxide with high oil absorption value and high water absorption capacity for washing powder

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陈克复: "《轻工重点行业节约资源和保护环境的战略研究》", 31 March 2011, 中国轻工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108998192A (en) * 2018-09-20 2018-12-14 王晓霞 A kind of chemical industry equipment lubricant agent special
CN112358917A (en) * 2020-11-10 2021-02-12 江苏千雅日用品有限公司 Detergent for silk and/or down clothes

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Application publication date: 20180824