FI72740B - TEXTILMJUKGOERANDE HOEGEFFEKTIVT FLYTANDE TVAETMEDELEL. - Google Patents

Description

72740

This invention relates to a fabric softening, high performance liquid detergent composition. More specifically, it relates to a liquid detergent consisting of a synthetic organic detergent and soap enhancing ingredients together with swellable bentonite and insoluble soap in an aqueous medium. The product of the invention can be poured and is a good detergent and fabric softener that cleans and softens well with it. washed laundry. The improved fabric softening effect is based on the presence of insoluble soap, which enhances the softening effect of bentonite, especially in hand-washing laundry products.

High-performance liquid detergents that can be used in machine washing of laundry have been marketed and reported in several patents and literature. Bentonite has been added to particulate detergent compositions as a fabric softener and has been used in aqueous compositions as a thickener to facilitate the retention of insoluble particulate materials such as abrasives suspended in a liquid medium. Insoluble metal soaps such as aluminum and calcium stearates have been used as lubricants and have been added to some detergent compositions due to their fabric softening effect. But prior to the present invention, bentonite is not considered to have been used successfully in the preparation of a high performance liquid detergent of the type described herein having a relatively high bentonite content and in which the softening effect of bentonite is greatly enhanced by a water insoluble metal soap also present in the liquid detergent composition.

2,72740

According to the present invention, a textile softening high performance liquid detergent contains 5-20% of a synthetic organic detergent which is an anionic detergent, 5-35% of a soap builder salt such as phosphate or mixtures thereof, 8-20% of swellable bentonite, 0.5-10% of water insoluble a higher fatty acid metal soap with a metal of aluminum, calcium, magnesium, barium or zinc, and 40-70% water. The liquid detergent in question contains mainly 7-11% of higher sodium alkylbenzenesulfonate, in which the higher alkyl contains 12-13 carbon atoms, 1-3% of sodium alkyl polyethoxysulphate, in which the alkyl contains 10-18 carbon atoms and the polyethoxy contains 3-11 ethylene oxide groups, 10-25% soap , selected from the group consisting of alkali metal tripolyphosphate, alkali metal carbonate, alkali metal bicarbonate, alkali metal sesquicarbonate, alkali metal silicate, alkali metal nitrilotriacetate, alkali metal citrate, alkali metal gluconate, borax, zeolite, zeolite and mixtures thereof, 10-15% soap and 50-70% water. The liquid detergents described, which are particularly suitable for hand washing cotton laundry, are high-performance detergents which effectively clean washable garments with both oily and solid stains and at the same time attach to such washed garments sufficient plasticizer to soften them without appreciably softening them. . In addition, the described compositions can be used to pre-treat heavily soiled areas such as collars and cuffs in washable garments.

The detergents used in the detergent compositions in question are mainly synthetic anionic detergents which are water-soluble sulphates and sulphonates, the lipophilic parts of which contain higher alkyl groups. It is preferred to use a mixture of the higher alkyl benzene sulfonate and alkyl polyethoxysulfate. Although these formulations may also contain other water-soluble straight chain higher alkyl benzene sulfonates such as potassium salts and in some cases ammonium or alkanol ammonium salts, where appropriate, it has been found that the sodium salt is definitely preferred, as is the case with alkyl polyethylenes. Alkylbenzenesulfonate has a higher alkyl content of 12 to 15 carbon atoms, primarily 12 or 13 carbon atoms. Although straight chain alkyl benzene sulfonates are preferred, branched alkyl compounds such as alkyl benzene sulfonates in which the alkyl is a propylene tetramer or pentaraer may also be used. Alkyl polyethoxysulfate, which may also be referred to as a higher straight chain alcohol containing a sulfate group or as a condensation product of a higher fatty alcohol and ethylene oxide or polyethylene glycol containing a sulfate group, is one in which alkyl contains 10 to 13 carbon atoms, for example about 12 to 15 carbon atoms, preferably 3-11 ethylene oxide groups, preferably 3-7, most preferably 3-5 and most preferably 3 or about 3 ethylene oxide groups.

Other anionic detergents such as fatty alcohol sulphates, paraffin sulphonates, olefin sulphonates, monoglyceride sulphates, sarcosinates, sulphosuccinates and similar detergents may also be present. replacing them) but often in addition to these detergents. Optional additional detergents are usually either sulfate or sulfonate compounds (usually as sodium salts) and contain long chain (8-20 carbon atoms) straight or fatty alkyl groups. In addition to anionic synthetic organic detergents, nonionic amphoteric agents such as Neodol, sold by Shell Chemical Company and a trademark for condensation products of ethylene oxide and higher fatty alcohols, such as Neodol 23-6.5, which is a condensation product of a higher fatty alcohol having about 12 to 13 carbon atoms and about 6.5 ethylene-72740 4 oxide roles. Amphoteric detergents are also useful, such as Miranols, for example Miranol C2M, which preferably forms only part of the synthetic organic detergent in the product. Further illumination of the various detergents and the categories of detergents mentioned is available from Surface Active Agents, Part II, Schwartz, Perry and Berch (Interscience Publishers, 1958), especially from pages 25-138, the descriptions of which are incorporated herein by reference.

The preferred salt compound of the soap enhancer ingredients of this invention, which has been found to advantageously improve the detergency of a mixture of synthetic anionic organic detergents, provides the desired pH in liquid detergent and wash water and interacts with detergent and bentonite in sodium wash Due to the best method of preparation, easier mixing and good end-use properties, it is preferred that the content of sodium tripolyphosphate be low in the phase I tripolyphosphate. The content of phase I tripolyphosphate is then preferably less than 10% of the tripolyphosphate used. Although in some cases incompletely neutralized tripolyphosphate may be used, the phosphate used may generally be considered to be pentodium tripolyphosphate, Na 2 P 2 O 2. In some cases, such as when potassium salts of molds are present, ion exchange may, of course, result in the formation of salts other than sodium tripolyphosphate in aqueous solution, but for the purpose of this specification, tripolyphosphate used, usually charged to a mixer, is considered to be a liquid detergent. sodium tripolyphosphate as the penta-sodium salt.

Other water-soluble soap enhancer salts that can be used in place of or in addition to sodium tripolyphosphate and sodium carbonate include sodium citrate, potassium sodium 72740 citrate, sodium nitrilotriacetate (NTA) (the corresponding potassium salts can be used in part, tetrosodium , sodium gluconate, borax, sodium silicate and sodium sesquisilicate.

Corresponding water-soluble salts such as other alkali metal salts can also be used. Of course, various mixtures of the salts of said water-soluble soap enhancer ingredients can also be used. However, the described tripolyphosphate-carbonate mixture has been found to be most preferred, although other soap enhancer ingredients and mixtures thereof are useful, albeit usually to a lesser extent. Water-insoluble soap enhancing ingredients that can be used are zeolites such as Zeolite A, usually in the form of their crystalline hydrate, but some amorphous zeolites are also suitable. One aspect of the present invention is that sodium silicate is not required to provide a high performance detergent-softener mixture, although its presence is sometimes desirable, and therefore such silicate is usually omitted from the recipes in question when zeolite or other soap enhancing agent is present. with it.

The bentonite used is colloidal clay (aluminosilicate) containing montmorillonite. The most suitable bentonite nitrogen is known as sodium bentonite (i.e. Wyoming or Western bentonite), which is usually light to cream in color or may be a yellowish-brown fine powder which can form a colloidal suspension in water with strong thixotropic properties. In many cases, potassium bentonite or a mixture of sodium potassium bentonite may be used instead. The expansion capacity of such a clay in water is usually between 3-15 or 20 ml / g, mainly 7-20 ml / g and its viscosity at a concentration of 6% in water is usually 2-30 cP, preferably 6,72740 at 8-30 cP. The preferred expandable bentonites of this type are sold by Benton Clay Company, Georgia,

A subsidiary of Kaolin Co. as industrial bentonites under the trademark Mineral Colloid and the American Colloid Company under the trademark Volclay. Mineral Colloid clays, which are the same as those previously sold under the THIXO-JEL trade mark, are selectively mined and enriched bentonites and those which are considered to be the best are available under the Mineral Colloid No 101 etc. trade mark, corresponding to THIXO-JEL numbers 1, 2 , 3 and 4. The pH values of these materials (at β% concentration in water) are between 8-9.4, their maximum free moisture contents (before addition to the liquid detergent medium) are about 8% and their specific gravity is about 2.6. At a degree of grinding of such materials, at least about 85% passes through a 200 mesh Sieve Series screen. Preferably, all of the bentonite passes through a 200 mesh screen and most preferably No. 325 through a screen so that the equivalent diameter of the bentonite can be considered to be less than 74 and preferably less than 44. Also useful are American Colloid Company General Purpose Bentonite Powder and their Special Purpose Powder (= American Colloid Company bentonite powder for general and special use), such as their Bento rivet designated AEG-325. Western or Wyoming-Bento rivets are preferred as ingredients in the liquid detergent compositions in question, but other bentonites, including synthetic bentonites (those made from Bento rivets with an alternative calcium and / or magnesium treatment with sodium carbonate) may be used and include compositions of the invention. The preferred expandable bentonites of the synthetic type described are sold under the trademarks Laviosa and Winkelman, for example Laviosa AGB and Winkelman G 13. Other clay grades which can often only be used to partially replace other popular and aforementioned bentonites are also sold under the following brands: Brock, Volclay BC; Gel White GP; Ben-A-Gel; Veegum F; Laponite SP and Barasym LIH 200. Typical chemical analyzes of the bento- 7,72740 rivets suitable for the preparation of the liquid detergents in question show that they contain 62-73.0% SiO 2, 14-22% Al 2 O 3, 1.6-2.9 MgO, 0.5-3.1% CaO, 2.3-3.5% Fe 2 O 3, 0.8-2.3% Na 2 O and 0.4-7.0% K 2 O.

The use of bentonite as a softener in the liquid detergents in question has the advantage that the bentonite does not have to be dried, for example in a spray dryer, and therefore avoids the risk that the softening effect of bentonite is lost due to the drying of its plate-like particles.

It is also unnecessary to specifically formulate and treat the detergent composition of such a recipe to promote rapid disintegration of the detergent grains in the wash water to remove bentonite particles, since in a liquid detergent such particles do not agglomerate into a hard mass, which could require additional time to decompose.

The water-insoluble soaps which can be used for the preparation of the products according to the invention contain from 8 to 20 carbon atoms, in particular from 10 or 12 carbon atoms and most preferably from 18 carbon atoms, and are saturated. Such soaps include aluminum, calcium, magnesium, barium and zinc octoates, decanoates, laurates, myristates, palmitates, oleates, (unsaturated) and stearates, and mixtures thereof. Such soaps are usually prepared by either the fusion method or the precipitation method. In the above method, a suitable metal oxide, hydroxide or salt of a weak acid is reacted directly with the selected fatty acid at an elevated temperature. In the precipitation process, a dilute soluble soap solution is prepared by first reacting Caustic soda with a selected fatty acid and then with a separately prepared saline solution of the desired metal, whereupon the metal soap precipitates. The soaps described are usually sufficiently fine to pass almost completely through the No. 200 sieve (U.S. Sieve Series) and in many cases almost all, e.g., 95 or 99%, pass through the No. 325 sieve. However, under suitable conditions, 72740 8 may also use somewhat coarser powders such as those which pass through a No. 100 sieve, but usually a finer powder is better. Such soaps usually contain very small amounts, if any, of water-soluble salts or moisture and are all powdery solids at room temperature. All said soaps are white, so they do not adversely affect the appearance of the detergent composition. In fact, they may in turn enhance the color of bentonite, which may sometimes tend to appear yellowish brown or cream in color, even though it is nominally white. It should be noted that many aluminum soaps may have higher free acid concentrations than calcium, magnesium, barium and zinc soaps with free acid concentrations of about 30%. However, this does not interfere with the effectiveness of such materials in the present compositions and methods of manufacture of the invention. As for aluminum soaps, a di- or tris-salt can be used, for example aluminum distearate, aluminum tristearate, but a mixture of these soaps is preferred and the proportions are 1: 3 to 3: 1, or 1: 1, for example. Incompletely reacted insoluble soaps of the other mentioned metals (and aluminum) and other divalent and polyvalent metals and their perfectly reacted soaps can be used in different proportions and also mixtures of different soaps can be used.

The various said insoluble soaps are described in a bulletin entitled Witco Metallic Stearates, Their Properties and Uses, September 1974, published by Witco Chemical Corporation, New York, New York 10017, which is incorporated herein by reference.

The only other essential ingredient in the liquid detergents in question is water. The degree of hardness of this water is usually less than about 300 ppm CaCl 2 and is primarily less than 150 ppm. It may often be advantageous to use deionized water, although often urban water with a degree of hardness of less than 50 or 100 ppm is almost as suitable. Although harder waters can be used successfully to make the liquid detergents in question, it is more likely that soft waters will not generate harmful substances that would adversely affect the appearance of the liquid detergent or could precipitate unpleasantly during washing.

Liquid detergents may contain various additives such as fluorescent brighteners, perfumes and colorants. Fluorescent brighteners are, for example, well-known stilbene derivatives, both cotton and nylon brighteners, such as those sold under the trademark Tinopal (5BM Conc.). Perfumes commonly used are essential oils, esters, aldehydes and / or alcohols, all of which are known in the art of perfuming. Dyes can be dyes and various types of water-dispersible pigments, such as ultramarine blue. Due to the bleaching effect caused by the presence of bentonite in the liquid detergent, the colors of the product are often pleasantly pastel. Titanium dioxide can be used to further lighten or bleach the color of the product. Inorganic excipient salts such as sodium sulfate and sodium chloride may be present as well as anti-redeposition agents such as sodium carboxymethylcellulose; dispersants such as sodium polyacrylate; enzymes; bleach; bactericides; fungicides; antifoaming agents such as silicones; stain removers such as copolyesters; preservatives such as formalin; foam stabilizers such as laurine-myristic diethanolamide; and co-solvents such as ethanol. The individual proportion of such excipients is usually less than 3 S, often less than 1% and sometimes even less than 0.5%, except for fillers and solvents and additional detergents and soap enhancers, which may sometimes be present in amounts of up to 10 1. The proportion of additives normally does not exceed 20%. % of the product and preferably it is less than 10% of that, _____ .. - - · χτ :: - - 10 72740 even more preferably less than 5% of the product. Of course, the excipients used do not interfere with the washing and softening effect of the liquid detergent and do not cause instability of the product during storage. They also do not annoyingly settle on the surface of the laundry.

The proportions of the various components of the liquid detergent in question are 5-20% detergent, predominantly 7-15% anionic detergent and preferably 9-13% of it, and 5-15 S, predominantly 7-11% and preferably about 9% of the straight chain sodium detergent. alkyl benzene sulfonate and 1-5%, preferably 1-3% and more preferably about 2% sodium alkyl polyethoxysulfate when using such a combination of anionic detergents; 5-35%, preferably 10-25% and preferably about 15% soap enhancer salt; 8-20%, preferably 10-15% and preferably about 12% expandable bentonite; 0.5-10%, preferably 1-5% and preferably about 2% water-insoluble metal soap; and 40-70%, preferably 50-70% and preferably 55-65%, for example 60% water. When the soap enhancer salts are formed from sodium tripolyphosphate and sodium carbonate, their amounts are usually 5-20%, predominantly 15-17% and more preferably about 11% tripolyphosphate; and 1-10%, preferably 2-7% and preferably about 4% sodium carbonate; and the ratio of tripolyphosphate to carbonate is preferably between 2: 1 and 6: 1.

Liquid detergents can be prepared by suitably mixing its various components together, so that bentonite and insoluble soap or a mixture thereof are preferably added towards the end of the process. Thus, for example, the anionic detergent may be mixed with water, after which the polyphosphate and carbonate may be added in finely divided form, usually sufficiently fine to pass through a No. 160 sieve, followed by any of the excipients and benzonite and insoluble salt. But when the liquid detergent is prepared according to this method or other methods in which bentonite is added earlier, the mixture tends to become at least temporarily thicker than 72740 11. When standing, the mixture thins somewhat, but this requires more preparation time. It has been found that if part of the water is omitted and only added later to the rest of the liquid detergent, it will rapidly cause the detergent to thin to the desired apparent viscosity.

The liquid detergent prepared is, apparently due to the combination of bentonite and insoluble soap, thixotropic and uniform. This is somewhat surprising and due to the combination described, as the ingredients appear to interact to form a flowable detergent. The pH of the liquid detergent suspension, which is usually between 8-11.5, mainly 9-10.8, also appears to be helpful in maintaining the fluidity of the product. Aqueous bentonite suspensions at the same concentration as that used in the liquid detergent in question can sometimes form thick gels which cannot be poured, and it is apparent that a mixture of anionic detergent such as straight chain alkyl benzene sulfonate and ethoxy alcohol sulfate swelling of bentonite in aqueous medium too much.

Experience has shown that a suitable amount of water, which is omitted and added only last in the preparation process, is usually 5-20% of the final liquid detergent, mainly 8-12%, for example about 10% of it.

When mixing the various ingredients in an aqueous medium, and especially when adding bentonite and insoluble soap and residual water, it is important to keep the mixture in motion by continuing to mix it. It is preferred that the mixer is never stopped and the process is continuous, usually about 3 to 30 minutes, preferably 5 to 10 minutes per batch. Water may be heated to promote dissolution of the various components of the product therein and to promote dispersion of bentonite and insoluble soap, but is not necessary and room temperature water, e.g., water at 15 ° -30 ° C, such as 20 ° -25 ° C, is useful. .

The following examples illustrate but do not limit the invention. Unless otherwise indicated, all parts are by weight and all temperatures are in degrees Celsius.

Example. 1

Ingredients%

Straight chain sodium tridecylbenzene 9.0 sulfonate

Sodium alkyl polyethoxysulphate 2,2 (alkyl = fatty alkyl having 12 to 15 carbon atoms; polyethoxy = 3 ethoxy groups)

Pentasodium tripolyphosphate (10% or 11.0 less phase 1)

Sodium carbonate (anhydrous) 4.0

Bentonite (Mineral Colloid 101) 12.0

Insoluble soap (aluminum stearate No. 2.0 18 - Witco Chemical Corp.)

Fluorescent brightener (Tinopal 5BM Conc.) 0.3

Perfume 0.3 Dye (ultramarine blue or FD & C dye solution) 0.2

Water (city water with a hardness of about 59.0 to 50 ppm calcium carbonate) 11UU / v 49 parts of water are added to a suitable mixer such as a vertical cylindrical tank equipped with heating and cooling equipment and connected to an outlet pump, synthetic organic detergents are added, mixed (Lig polyphosphate and carbonate enhancer salts (particle sizes passing through a No. 160 sieve), and the phosphate is added first 72740, followed by a fluorescent brightener and dye. Mixing a batch weighing about 500 kg requires about 4 minutes. Insoluble soap and swellable bentonite, both in the form of a fine powder that passes almost entirely through a No. 200 sieve (US Sieve Series) and more than 90% of it passes through a No. 325 sieve, are then combined with the mixture, resulting in an increase in its viscosity. higher than desired. The rest of the water is added and the perfume is mixed in and the product is ready to be pumped out of the mixer and into the final use tanks. During the mixing operation, which requires about 9 minutes, the added substances and the final product are at about 20 ° C. In some cases, due to the faster dissolution and dispersion of the components, the temperature of the charged water can be raised to 40 ° -50 ° C so that the temperature of the final product may be about 30 ° -40 ° C, in which case the mixing time can be reduced to 5-6 minutes. The resulting liquid detergent can be poured at room temperature from a very plastic detergent bottle with a spout of about 2.5 cm. Its pH is about 10.6. It has a pleasant even blue appearance and storage does not cause the material to sink into different layers. After storage, it still needs to be poured, but if for some reason it becomes too thick, it can be obtained by shaking or bending the plastic container (which is polyethylene or polypropylene) to flow again. However, shaking is not necessary to ensure uniformity of composition.

The washing properties of the prepared liquid detergent were tested by hand washing towels pre-stained with clay and tallow stains at a concentration of 3.5 g / l in water with a hardness of about 100 ppm CaCO 2.

The product is an excellent detergent and cleans and whitens stained wipes and removes stains on them. Apparently, no anti-redeposition agent is needed to prevent harmful re-adhesion of the stain and the clay stain was removed well despite the presence of bentonite in the product. This was not surprising in the light of experience 72740 14 obtained from liquid detergents containing bentonite, such as those described in Finnish Patent Application No. 834553.

Surprisingly, however, in a hand wash test in which the towels were washed by hand in cold water (21 ° C) of the order of magnitude of ordinary urban water (100 ppm CaCO 2), it is indeed possible to obtain excellent softening effects with the compositions of this invention. For example, when cotton hand towels were washed in such cold water containing 3.5 g / l of the liquid detergent in question, followed by rinsing with fresh water and dried with string, the expert rated them almost perfect for their softness, giving them a rating of 9 on a scale of 10. Although some compositions containing bentonite have achieved a grade of 8 when used in hand washing, a grade of 9 is very difficult to achieve and is considered to be an unexpected benefit of using insoluble soap with bentonite in the detergent composition in question. Towels washed with a reference recipe lacking both benthic rivet and insoluble soap were rated for softness only on a grade of 1, while similar towels washed with a liquid detergent containing bentonite in which only insoluble soap was replaced with 8 for the same test were graded. .

The reason for the surprising improvement in the emollient effect of the composition in question is not clear. It has been theorized that bentonite is less effective as a softener when used in hand washing of laundry. due to the lack of a "straining" effect (filtering effect) that may occur when the wash water is drained from the laundry in the washing machine, but which is not achieved during hand washing, and therefore not so much bentonite is sucked through the laundry and remains in the laundry. According to this theory, insoluble soap helps to attach bentonite to the fibers of washable textiles, thus increasing the binding of bentonite to textiles and leading to better softening. While this theory appears to be valid, it is to be understood that this invention is not bound by it and is not intended to limit the present invention.

Liquid detergent is also used to pre-treat stained areas of laundry, for which it is used in full strength (although dilutions may also be used). The liquid detergent is rubbed on the stained areas and during rubbing the bentonite apparently helps to remove and remove the dirt and at the same time tends to adhere to the fibers of the laundry material and thus help to soften it better, especially from those areas. Such softening may contribute to the fact that these areas will not become so dirty in the future, especially when the stained areas are the cuffs and collars of the shirt.

the above recipe variations are replaced by an alkyl benzene-sulfonate branched chain a sodium dodecyl bentseenisulfonaatiliä, uripolyfosfaatti replaced by a tetra-potassium pyrophosphate, sodium carbonate is replaced by sodium sesquicarbonate, and aluminum stearate is replaced in turn, either calcium stearate, magnesium stearate, bariumstea-hydrate, zinc stearate, alumiinipalmitaatilla, calcium myristate, bariumlauraatilla and sinkkioleaatilla and 1: 1 mixtures of aluminum stearate and calcium stearate or aluminum hydrogenated tallow soap and calcium coconut oil soap. The products are good "softergents", emollients, and insoluble soaps have a softening effect on bentonite in hand washing, further enhanced by doubling the proportion of such soaps. Also, when the proportion of bentonite is increased to about 15% and the proportion of insoluble soap is doubled to 4%, and the proportion of water is reduced accordingly, even better softening results are obtained when the liquid detergent is used for hand washing of cotton and other textiles. Excellent softening of 72740 16 also results when in any of the mentioned recipes the concentration of the liquid detergent in the hand wash water is between 0.1 and 1% f, mainly 0.3-0.7%. Although the liquid detergents in question are particularly useful for washing laundry in cold water, they are also good detergent softeners (i.e., "softergents") in warm water and water with a hardness of the order of 0-300 ppm.

In other variations of the present recipe, sodium alkyl polyethoxysulfate may be replaced with a higher fatty alcohol polyethylene oxide condensation product such as Neodol 23-6.5, thereby also providing a useful fabric softening liquid detergent.

Example 2

A liquid detergent is prepared as in Example 1, but only 2% sodium carbonate is used in the recipe and the water content is increased accordingly. Although the sodium carbonate content has been reduced, the mixture can still be made into a final product with the desired properties, which can be used as a high-performance detergent for hand washing and softening cotton and synthetic materials, and can also be used for pretreatment of such laundry.

When other variations of the embodiment of the present invention change the proportions of the various components by + 10% or + 20% without departing from the limits given in the specification, stable, easily flowable liquid detergents with good purification and softening effects are present. In some of these products, it may be advantageous to add up to 10 S of Zeolite A or even 5% sodium silicate with a Na 2 O: SiO 2 ratio of about 1: 2.4, although silicate is often avoided and, if zeolite is present, the silicate is omitted to avoid zeolite silicate aggregates. or precipitation of reaction products, If it is desired to dilute the liquid, up to 10% ethanol or isopropanol can be used.

Example 3

A liquid detergent such as Example 1 is formulated using straight chain dodecyl sulfonate instead of straight chain tridecyl benzene sulfonate, sodium alkyl polyethoxysulfate, wherein alkyl contains 12-13 carbon atoms and polyethoxy contains an average of * G, 5 ethoxy groups, 15%, P bentonite, the aforementioned excipients and 53% water. The addition of sodium carbonate improves the mixing of the various components during the manufacturing process and the replacement of detergents does not appear to adversely affect the properties of the product. The product is prepared in substantially the same manner as described above.

A liquid detergent is a run-off liquid having the desired cleaning and softening properties described for the liquid detergent of Example 1, whether used in laundry or hand washing or pretreatment of laundry, but is particularly useful for cleaning and softening laundry in hand washing.

Liquid detergents are prepared in a similar manner by adding 3% sodium lauryl alcohol sulfate, 2 S Neodol 23-6.5 and 0.5% anti-foaming silicone oil to the components of the product of Example 1 (replacing water). Likewise, adding sodium citrate or potassium citrate to replace sodium carbonate (or replacing only a portion of such materials, e.g., 30% of them, with such citrates or trisodium nitrilotriacetate) results in useful liquid detergents having properties similar to those described above.

Instead of using 2% aluminum stearate as in Example 1, aluminum stearate can be prepared in situ using stoichiometric ratios of aluminum chloride and sodium stearate and in some cases sodium stearate may be present in excess. The liquid detergent 72740 18 thus made has similar highly advantageous fabric softening properties when used in hand-washing laundry, especially laundry containing cotton textiles.

As can be seen from the above description and working examples, the fabric softening high performance liquid detergents of this invention are uniform in quality, pleasant in appearance and functional. Despite the presence of a considerable proportion of the gelling agent (bentonite) and insoluble soap in the liquid medium, they do not form harmful gels. Similarly, despite the long storage times during which suspended bentonite and insoluble soap come into close contact with surfactants and inorganic soap builder salts in an aqueous medium, no harmful agglomeration occurs and the laundry softening effect of the product is not lost.

The product retains its physical and chemical properties, which allow it to adhere to the laundry and act as a lubricant with respect to its fibers, thus promoting the softening of such laundry. As also mentioned above, the use of a liquid medium avoids the possibility that the bentonite would be inactivated due to overheating, for example in a spray drying tower.

The liquid detergents in question are not only useful products for machine and hand washing of laundry but also well suited for pre-treatment of stained parts of laundry and in this treatment the concentration of bentonite and insoluble soap is considered to remove stains and soften the stained area (and then used for washing). Thus, from the above description of the features and advantages of the present invention, it can be seen that it represents a significant advance in the field of detergent compositions as it allows the liquid detergent to be used comfortably in both laundry and softening during hand washing (and pretreatment) with excellent anionic synthetic organic detergents, to which it has not been necessary to add unfavorably active, chemically reactive cationic materials such as quaternary ammonium salts. In addition, the oentonites and insoluble aluminum, calcium and magnesium soaps used are not ecologically harmful as quaternary ammonium salts might be and do not cause harmful fat deposits on the laundry surface, which often produces a faded effect in laundry, such as quaternary compounds.

The sodium salts and sodium compounds of the various components of the liquid detergents in question have been described above because they are particularly advantageous and commercially available, but the corresponding potassium compounds can replace them, at least in part, and are therefore also within the scope of the invention. Thus, potassium detergents, potassium salts as soap enhancers, potassium bentonites and potassium salts as excipients can be used and are intended to belong to the "alkali metal compounds" with sodium compounds.

The invention has been described in terms of various embodiments and working examples, but is not intended to be limited thereto, as it is apparent that one skilled in the art will be able to use substitutes and equivalent agents without departing from the scope of the invention.

Claims (2)

72740 A high-performance liquid detergent for softening textiles, characterized in that it contains 5-20% of a synthetic organic detergent which is an anionic detergent, 5-35% of a soap builder salt such as phosphate or mixtures thereof, 8-20% of swellable bentonite, 0.5- 10% water-insoluble higher fatty acid metal soap with a metal of aluminum, calcium, magnesium, barium or zinc, and 40-70% water. Liquid detergent according to Claim 1, characterized in that the water-insoluble soap is aluminum soap. Liquid detergent according to Claim 1, characterized in that it contains 5-15% of an alkali metal higher alkyl benzene sulphonate in which the higher alkyl contains 12 to 15 carbon atoms, 1 to 5% of an alkali metal alkyl polyethoxy sulphate in which the alkyl contains 10 to 18 carbon atoms and the polyethoxy contains 3 -11 ethylene oxide groups, 5-35% total soap enhancers alkali metal tripolyphosphate and alkali metal carbonate, in which the ratio of tripolyphosphate to carbonate is between 2: 1 and 6: 1, 8-20% swellable bentonite, 0.5-10% water-insoluble soap and 40 -70% water. Liquid detergent according to Claim 3, characterized in that the alkali metal is sodium. Detergent according to Claim 4, characterized in that the sodium higher alkyl benzene sulphonate is a straight-chain sodium tridecyl benzene sulphonate, the sodium alkyl polyethoxysulphate is one in which the alkyl contains 12 to 15 carbon atoms and the polyethoxy contains 3 to 7 ethylene oxide groups and a swellable bentonite. 21 72740 Liquid detergent according to Claim 5, characterized in that it contains 7 to 11% of straight-chain sodium tridecylbenzenesulphonate, 1 to 3% of sodium alkyl polyethoxysulphate, in which the alkyl contains 12 to 15 carbon atoms and the polyethoxy has about 3 ethylene oxide groups, 10 to 17% of sodium tripolyphosphate containing less than 10% of phase I tripolyphosphate, 2-7% sodium carbonate, 10-15% sodium bentonite having a particle size of less than 44, 1-5% aluminum soap and 50-70% water. Liquid detergent according to Claim 6, characterized in that it contains about 9% of straight-chain sodium tridecylbenzenesulphonate, about 2% of sodium alkyl polyethoxysulphate, in which the alkyl contains 12 to 15 carbon atoms and the polyethoxy has 3 ethylene oxide groups, about 11% of sodium tripolyphosphate, about 4% of sodium about 12% Wyoraing bentonite, about 2% aluminum stearate, a mixture of distearate and tristearate, and about 60% water. • · · · "Patentkrav \\\ 1. Textile impactors for the manufacture of fly ash, with the addition of 5 to 20% of the synthetic organic compounds, with the addition of anionic feed, 5-35% of the builders with the presence of phosphate or bleaching agents. , 8-20% of Swedish bentonite, 0,5-10% of wattenolöslig metalltväl av en högre fettsyra, stem metal or Aluminum, calcium, magnesium, barium or zinc, and 40-70% wool. 2. Flytande tvättmedel enligt patentkravet 1, känne-: tecknat av att den den vattenolösliga tvälen är aluminiumtväl. 1 A preferred embodiment of claim 1, which comprises 5-15% of alkali metal haloalkyl benzenesulfonate, of which alkyl is alkyl, 12-15 column atoms, 1-5% of alkali metal alkyl polyethoxy sulfate, of which alkylene