CN108441329B - Train outside compartment cleaning agent and preparation method thereof - Google Patents

Train outside compartment cleaning agent and preparation method thereof Download PDF

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Publication number
CN108441329B
CN108441329B CN201810329158.1A CN201810329158A CN108441329B CN 108441329 B CN108441329 B CN 108441329B CN 201810329158 A CN201810329158 A CN 201810329158A CN 108441329 B CN108441329 B CN 108441329B
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cleaning agent
acid
train
outside compartment
cleaning
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CN108441329A (en
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苏卜顺
冯侠
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HUAYANG XINXING TECHNOLOGY (TIANJIN) GROUP CO LTD
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HUAYANG XINXING TECHNOLOGY (TIANJIN) GROUP CO LTD
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/06Phosphates, including polyphosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2079Monocarboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/221Mono, di- or trisaccharides or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/34Organic compounds containing sulfur
    • C11D3/349Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/36Organic compounds containing phosphorus
    • C11D3/361Phosphonates, phosphinates or phosphonites

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a train outside compartment cleaning agent, which comprises the following components in percentage by weight: surfactant (b): 1-3%; organic acid: 0.1-3%; inorganic acid: 0.1-1%; chelating agent: 0.5-3%; the balance being water. The cleaning agent is simple to prepare and easy and convenient to operate, the pH value of the solution is weakly acidic to neutral, the cleaning agent has no damage to a machine body and a vehicle body, no adverse effect on a paint film and metal, no pungent smell, and environment-friendly reagents.

Description

Train outside compartment cleaning agent and preparation method thereof
Technical Field
The invention belongs to the technical field of chemical cleaning agents, and particularly relates to a train outside compartment cleaning agent and a preparation method thereof.
Background
The locomotive outer carriage is used as an important component, along with the vigorous development of urban construction, the requirement on the appearance of the locomotive is higher and higher, and because the locomotive is exposed in the air for a long time and is influenced by adverse factors such as ultraviolet irradiation, rain wash, sand erosion and the like, the brightness and the thickness of the locomotive paint surface are greatly reduced, so that the locomotive paint surface is gradually whitened, blackened and lackluster, an oxide layer is further formed, and the service life of the locomotive is shortened. In addition, the locomotive generates a strong electrostatic layer due to air friction during running, and adsorbs a large amount of dust, oil stain and chemical dust, and a hard traffic film is formed after a long time. If the traffic film cannot be removed in time, the paint surface of the locomotive is easy to oxidize, corrode and peel off. Along with the rapid development of the rail transit industry, the number of running trains is greatly increased, the use amount of products for cleaning and maintaining the outside of the train is also greatly increased, and the market demand is huge. Therefore, the development of a high-quality and high-efficiency cleaning agent product for cleaning and maintaining the appearance of the locomotive is urgently needed.
Through searching, the following two patent publications related to the patent application of the invention are found:
1. the high-efficiency cleaning agent for the hard scale on the surface of the high-speed train, the preparation method and the cleaning method (CN106675879A) comprise the following raw material components in percentage by mass: 0.1-10% of nonionic surfactant, 0.1-5% of essential oil, 0.1-20% of oxygenated solvent, 0.5-15% of alcohol solvent and 50-90% of water. The preparation method comprises the following steps in sequence: a. adding water into a stirring kettle, adding the nonionic surfactant, the oxygen-containing solvent and the alcohol solvent, mixing and stirring uniformly; b. adding the essential oil, and uniformly stirring; the cleaning method comprises machine cleaning or manual cleaning, wherein the machine cleaning is used in a general cleaning machine for trains, 8#10 sections are grouped, the using amount is 5#8 kilograms, and the machine cleaning is used at normal temperature; the manual cleaning is to use tap water to prepare about 5 percent of cleaning solution and use rag, brush or mop to dip the cleaning solution to scrub the surface of the train.
2. The train surface oil stain cleaning agent (CN103436392A) comprises the following components in percentage by mass: 16-19% of eicosane, 7-9% of limonene, 55-65% of decafluoropentane, 6-8% of N-methylpyrrolidone, 3-6% of ethylene glycol monobutyl ether, 0.8-2.6% of NP-8.6, 0.5-1.5% of benzotriazole and 0.5-1.5% of JFC. The cleaning agent is suitable for cleaning various maintenance mark stroke lines of various rail transit trains, sealing paint and oil stains on the surfaces of various hubs, and surface oil stains such as solidified stains on the surfaces of mechanical parts of the hubs, and the like, can not cause damage to the surfaces of train bodies and the mechanical parts of the trains, does not damage human bodies, and has no pollution to the environment.
By contrast, the present patent application is substantially different from the above patent publications.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides the train outside compartment cleaning agent and the preparation method thereof, the cleaning agent is simple to prepare and simple and convenient to operate, the pH value of the solution is from weak acidity to neutral, the cleaning agent has no damage to a train body and a train body, no adverse effect on a paint film and metal, no pungent smell, environment-friendly reagents and environment-friendly.
The technical scheme adopted by the invention for solving the technical problems is as follows:
a cleaning agent for an outer compartment of a train comprises the following components in percentage by weight:
surfactant (b): 1-3%; organic acid: 0.1-3%; inorganic acid: 0.1-1%; chelating agent: 0.5-3%; the balance being water.
Moreover, the surface activity is α -olefin sodium sulfonate, sodium dodecyl benzene sulfonate or fatty alcohol-polyoxyethylene ether sodium sulfate.
And the organic acid is acetic acid, hydroxyethylidene diphosphonic acid or citric acid.
Further, the inorganic acid is tartaric acid, sulfamic acid or tannic acid.
And the chelating agent is ethylene diamine tetraacetic acid, sodium gluconate or sodium pyrophosphate.
Moreover, the pH value of the train outside compartment cleaning agent is from weak acidity to neutrality.
The preparation method of the train outside compartment cleaning agent comprises the following steps:
and respectively adding the surfactant, the organic acid, the inorganic acid, the chelating agent and the water according to the proportion, and uniformly stirring to obtain the train outside compartment cleaning agent.
The invention has the advantages and positive effects that:
1. the cleaning agent is simple to prepare and easy and convenient to operate, the pH value of the solution is weakly acidic to neutral, the cleaning agent has no damage to a machine body and a vehicle body, no adverse effect on a paint film and metal, no pungent smell, and environment-friendly reagents.
2. The cleaning agent is convenient to use, high in cleaning power and obvious in cleaning effect, and can be used for easily cleaning the locomotive trunk by using the cleaning agent with the mass fraction of 3% -10% under the condition of normal temperature, so that the cleaning effect is good.
Detailed Description
The following detailed description of the embodiments of the present invention is provided for the purpose of illustration and not limitation, and should not be construed as limiting the scope of the invention.
The raw materials used in the invention are conventional commercial products unless otherwise specified; the methods used in the present invention are, unless otherwise specified, conventional in the art; the concentrations of the individual substances used according to the invention are the usual concentrations.
Example 1:
a cleaning agent for an outer compartment of a train comprises the following components in percentage by weight:
α -olefin sodium sulfonate 1%;
acetic acid: 2 percent;
tartaric acid: 0.5 percent;
sodium pyrophosphate: 1 percent;
water: 95.5 percent.
The preparation method of the cleaning agent for the outside train compartment comprises the following steps:
α -olefin sodium sulfonate, acetic acid, tartaric acid, sodium pyrophosphate and water are respectively added according to the mixture ratio and evenly stirred to obtain the finished product of the train outside compartment cleaning agent.
Appearance of the finished product: a light yellow transparent liquid; odor: no pungent smell; PH is 4-7; specific gravity (25 ℃): 1.060.
example 2:
a cleaning agent for an outer compartment of a train comprises the following components in percentage by weight:
sodium dodecylbenzenesulfonate: 1 percent;
hydroxyethylidene diphosphonic acid: 2 percent;
sulfamic acid: 0.5 percent;
ethylene diamine tetraacetic acid: 1 percent;
water: 95.5 percent.
The preparation method of the cleaning agent for the outside train compartment comprises the following steps:
adding sodium dodecyl benzene sulfonate, hydroxyl ethylidene diphosphonic acid, sulfamic acid, ethylene diamine tetraacetic acid and water according to the proportion, and stirring uniformly to obtain the finished product of the train outside compartment cleaning agent.
Appearance of the finished product: a light yellow transparent liquid; odor: no pungent smell; PH is 4-7; specific gravity (25 ℃): 1.061.
example 3
A cleaning agent for an outer compartment of a train comprises the following components in percentage by weight:
surfactant (b): 1-3%; organic acid: 0.1-3%; inorganic acid: 0.1-1%; chelating agent: 0.5-3%; the balance being water.
Preferably, the surface activity is α -olefin sodium sulfonate, sodium dodecyl benzene sulfonate or fatty alcohol-polyoxyethylene ether sodium sulfate.
Preferably, the organic acid is acetic acid, hydroxyethylidene diphosphonic acid or citric acid.
Preferably, the inorganic acid is tartaric acid, sulfamic acid or tannic acid.
Preferably, the chelating agent is ethylenediamine tetraacetic acid, sodium gluconate or sodium pyrophosphate.
Preferably, the pH value of the train outside compartment cleaning agent is from weak acidity to neutrality.
The preparation method of the train outside compartment cleaning agent comprises the following steps:
adding surfactant, organic acid, inorganic acid, chelating agent and water according to a certain proportion, and uniformly stirring. And obtaining the cleaning agent for the outer carriage of the train.
Application examples of the invention:
by using the cleaning agent for the train outside compartment, 3-8% of cleaning agent aqueous solution by mass fraction can be used for manually scrubbing or scrubbing local intractable dirt by using high-concentration cleaning solution.
Quality standard:
Figure RE-GDA0001674434020000041

Claims (1)

1. a cleaning agent for an outside compartment of a train is characterized in that: the composite material comprises the following components in percentage by weight:
surfactant (b): 1-3%; organic acid: 0.1-3%; inorganic acid: 0.1-1%; chelating agent: 0.5-3%; the balance of water;
the surface activity is α -olefin sodium sulfonate;
the organic acid is hydroxyethylidene diphosphonic acid or tannic acid;
the inorganic acid is sulfamic acid;
the chelating agent is ethylenediamine tetraacetic acid and sodium gluconate;
the pH value of the train outside compartment cleaning agent is from weak acidity to neutrality;
the preparation method of the train outside compartment cleaning agent comprises the following steps:
and respectively adding the surfactant, the organic acid, the inorganic acid, the chelating agent and the water according to the proportion, and uniformly stirring to obtain the train outside compartment cleaning agent.
CN201810329158.1A 2018-04-13 2018-04-13 Train outside compartment cleaning agent and preparation method thereof Active CN108441329B (en)

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CN108441329B true CN108441329B (en) 2020-05-08

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Publication number Priority date Publication date Assignee Title
CN111979057B (en) * 2019-05-23 2022-05-17 合肥科源应用化工研究所 Neutral cleaning agent for motor train unit and preparation method of neutral cleaning agent
CN111559799B (en) * 2020-05-14 2022-10-28 北京可林维尔化工有限公司 Multipurpose cleaning bactericide and preparation method and use method thereof
CN113736574A (en) * 2021-09-27 2021-12-03 北京中铁富红企业管理有限责任公司 Cleaning agent for cleaning bullet train, preparation method of cleaning agent and bullet train cleaning method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102504975B (en) * 2011-11-23 2013-10-16 上海应用技术学院 Ordinary passenger train outer wagon powdery cleaning agent and preparation method thereof
MX2017016839A (en) * 2015-07-07 2018-08-15 Delaval Holding Ab Acid detergent.
CN107057897A (en) * 2017-03-13 2017-08-18 广州泰成生化科技有限公司 A kind of new situ cleaning agent and preparation method thereof

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