CN108441329A - A kind of train enclosure cleaning agent and preparation method thereof - Google Patents

A kind of train enclosure cleaning agent and preparation method thereof Download PDF

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Publication number
CN108441329A
CN108441329A CN201810329158.1A CN201810329158A CN108441329A CN 108441329 A CN108441329 A CN 108441329A CN 201810329158 A CN201810329158 A CN 201810329158A CN 108441329 A CN108441329 A CN 108441329A
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China
Prior art keywords
acid
cleaning agent
train enclosure
train
enclosure cleaning
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CN201810329158.1A
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Chinese (zh)
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CN108441329B (en
Inventor
苏卜顺
冯侠
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Huayang Xinxing Science And Technology (tianjin) Group Co Ltd
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Huayang Xinxing Science And Technology (tianjin) Group Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/06Phosphates, including polyphosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2079Monocarboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/221Mono, di- or trisaccharides or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/34Organic compounds containing sulfur
    • C11D3/349Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/36Organic compounds containing phosphorus
    • C11D3/361Phosphonates, phosphinates or phosphonites

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a kind of train enclosure cleaning agent, constituent component and weight percent are:Surfactant:1~3%;Organic acid:0.1~3%;Inorganic acid:0.1~1%;Chelating agent:0.5~3%;Surplus is water.This cleaning agent is prepared simply, and easy to operate, solution ph is weakly acidic to neutral, not damaged to fuselage and vehicle body, has no adverse effects, has no irritating odor to paint film and metal, agents useful for same environmental protection, environmentally friendly.

Description

A kind of train enclosure cleaning agent and preparation method thereof
Technical field
The invention belongs to chemical technical field, especially a kind of train enclosure cleaning agent and preparation method thereof.
Background technology
Rolling stock enclosure is as important composition part, with flourishing for Process of Urbanization Construction, to locomotive appearance requirement It is higher and higher, due to locomotive for a long time exposure in air, be irradiated with, rain drop erosion, dust storm corrode etc. it is unfavorable because Element influences, and the brightness of locomotive lacquer painting, thickness is caused all to be had a greatly reduced quality, and so that locomotive lacquer painting is slowly whitened, sends out crow, is matt, in turn Oxide layer is formed, locomotive service life is shortened.In addition, locomotive is under steam because windage generates strong electrostatic layer, and A large amount of dusts, greasy dirt and chemical dust are adsorbed, can be formed over time one layer hard " traffic film "." traffic film " is if obtained not It is removed to timely, easily makes the oxidation corrosion of locomotive lacquer painting, peels off.Along with the rapid development of track transportation industry, the row of operation Vehicle quantity is significantly increased, and the usage amount of outside vehicle clean and maintenance product also increases substantially therewith, and market demand is huge.Cause This, there is an urgent need for develop high-quality, efficient rinse product to carry out clean and maintenance to locomotive appearance.
By retrieval, following two and the relevant patent publication us of present patent application are found:
1, the stupid dirty efficient cleaner of high ferro Train surface and preparation method and cleaning method (CN106675879A), raw material group Divide and mass percent is as follows:Nonionic surfactant 0.1~10%, essential oil 0.1~5%, oxo solvent 0.1~20%, Alcohols solvent 0.5~15%, water 50~90%.Preparation method carries out as follows successively:A, water is added in a stirring kettle, The addition of nonionic surfactant, oxo solvent and alcohols solvent is mixed and stirred for uniformly;B, essential oil is added, stirring is equal It is even;Cleaning method, machine washing or artificial cleaning, the machine washing are to be used in train universal cleaning machine, 8#10 section marshallings, dosage 5#8 kilograms, room temperature uses;The artificial cleaning with rag, hairbrush or is dragged to be configured to 5% or so cleaning solution with tap water Cloth dips in cleaning solution and cleans Train surface.
2, Train surface greasy dirt detergent (CN103436392A) is grouped as by following mass ratio group:Icosane hydrocarbon 16- 19%, limonene 7-9%, Decafluoropentane 55-65%, N-Methyl pyrrolidone 6-8%, ethylene glycol monobutyl ether 3-6%, NP- 8.6,0.8-2.6%, benzotriazole 0.5-1.5%, JFC0.5-1.5%.It is suitable for various rail transit trains All kinds of maintenance marking pen scribing line cleanings, all kinds of hub surface sealing paint, greasy dirt cleaning, and its component of machine surface cure The surface and oil contaminants such as spot clean, and will not be damaged to the surface of train body, train component of machine, to human zero damage, It is environmentally safe.
By comparison, there is the difference of essence with above-mentioned patent publication us in present patent application.
Invention content
It is an object of the invention in place of overcome the deficiencies in the prior art, provide a kind of train enclosure cleaning agent and its preparation Method, the cleaning agent are prepared simply, and easy to operate, solution ph is weakly acidic to neutral, not damaged to fuselage and vehicle body, to paint Film and metal have no adverse effects, and have no irritating odor, agents useful for same environmental protection, environmentally friendly.
The technical solution adopted by the present invention to solve the technical problems is:
A kind of train enclosure cleaning agent, constituent component and weight percent are:
Surfactant:1~3%;Organic acid:0.1~3%;Inorganic acid:0.1~1%;Chelating agent:0.5~3%;It is remaining Amount is water.
Moreover, the surface-active is alpha-olefin sodium sulfonate, neopelex or fatty alcohol polyoxyethylene ether sulphur Sour sodium.
Moreover, the organic acid is acetic acid, 1-hydroxy ethylidene-1,1-diphosphonic acid or citric acid.
Moreover, the inorganic acid is tartaric acid, sulfamic acid or tannic acid.
Moreover, the chelating agent is ethylenediamine tetra-acetic acid, sodium gluconate or sodium pyrophosphate.
Moreover, the pH value of the train enclosure cleaning agent is faintly acid to neutrality.
The preparation method of train enclosure cleaning agent as described above, steps are as follows:
It is separately added into surfactant, organic acid, inorganic acid, chelating agent, water according to the ratio, stirs evenly outside to get train Compartment cleaning agent.
The advantages of present invention obtains and good effect are:
1, this cleaning agent is prepared simple, and easy to operate, solution ph is weakly acidic to neutral, lossless to fuselage and vehicle body Wound, has no adverse effects to paint film and metal, has no irritating odor, agents useful for same environmental protection, environmentally friendly.
2, this cleaning agent is easy to use, washing power is high, and cleaning performance is apparent, under conditions of room temperature, use quality score For 3%~10% cleaning agent, you can easily clean up locomotive enclosure, washing effect is good.
Specific implementation mode
The embodiment of the present invention is described in detail below, it should be noted that the present embodiment is narrative, is not limited , protection scope of the present invention cannot be limited with this.
Raw material used in the present invention is unless otherwise specified conventional commercial product;Used in the present invention Method is unless otherwise specified the conventional method of this field;Each material concentration used in the present invention is usually using dense Degree.
Embodiment 1:
A kind of train enclosure cleaning agent, each component and its weight percent are respectively:
Alpha-olefin sodium sulfonate:1%;
Acetic acid:2%;
Tartaric acid:0.5%;
Sodium pyrophosphate:1%;
Water:95.5%.
The preparation method of above-mentioned train enclosure cleaning agent is as follows:
It is separately added into alpha-olefin sodium sulfonate, acetic acid, tartaric acid, sodium pyrophosphate and water according to the ratio, stirs evenly, becomes row Vehicle enclosure cleaning agent finished product.
Finished appearance:Light yellow clear liquid;Smell:It has no irritating odor;PH=4~7;Proportion (25 DEG C):1.060.
Embodiment 2:
A kind of train enclosure cleaning agent, each component and its weight percent are respectively:
Neopelex:1%;
1-hydroxy ethylidene-1,1-diphosphonic acid:2%;
Sulfamic acid:0.5%;
Ethylenediamine tetra-acetic acid:1%;
Water:95.5%.
The preparation method of above-mentioned train enclosure cleaning agent is as follows:
Be separately added into according to the ratio neopelex, 1-hydroxy ethylidene-1,1-diphosphonic acid, sulfamic acid, ethylenediamine tetra-acetic acid and Water stirs evenly, and becomes train enclosure cleaning agent finished product.
Finished appearance:Light yellow clear liquid;Smell:It has no irritating odor;PH=4~7;Proportion (25 DEG C):1.061.
Embodiment 3
A kind of train enclosure cleaning agent, constituent component and weight percent are:
Surfactant:1~3%;Organic acid:0.1~3%;Inorganic acid:0.1~1%;Chelating agent:0.5~3%;It is remaining Amount is water.
More preferably, the surface-active is alpha-olefin sodium sulfonate, neopelex or fatty alcohol polyoxyethylene ether Sodium sulphate.
More preferably, the organic acid is acetic acid, 1-hydroxy ethylidene-1,1-diphosphonic acid or citric acid.
More preferably, the inorganic acid is tartaric acid, sulfamic acid or tannic acid.
More preferably, the chelating agent is ethylenediamine tetra-acetic acid, sodium gluconate or sodium pyrophosphate.
More preferably, the pH value of the train enclosure cleaning agent is faintly acid to neutrality.
The preparation method of train enclosure cleaning agent as described above, steps are as follows:
It is separately added into surfactant, organic acid, inorganic acid, chelating agent, water according to the ratio, stirs evenly.Outside up to train Compartment cleaning agent.
The application example of the present invention:
It is 3~8% cleaning agent aqueous solutions with mass fraction, to local intractable using train enclosure cleaning agent of the present invention Dirt can use high concentration cleaning solution to clean or scrub by hand, you can.
Quality standard:

Claims (7)

1. a kind of train enclosure cleaning agent, it is characterised in that:Its constituent component and weight percent are:
Surfactant:1~3%;Organic acid:0.1~3%;Inorganic acid:0.1~1%;Chelating agent:0.5~3%;Surplus is Water.
2. train enclosure cleaning agent according to claim 1, it is characterised in that:The surface-active is alpha-olefin sulfonic acid Sodium, neopelex or sodium sulfate of polyethenoxy ether of fatty alcohol.
3. train enclosure cleaning agent according to claim 1, it is characterised in that:The organic acid is acetic acid, hydroxy ethylidene Di 2 ethylhexyl phosphonic acid or citric acid.
4. train enclosure cleaning agent according to claim 1, it is characterised in that:The inorganic acid is tartaric acid, amino sulphur Acid or tannic acid.
5. train enclosure cleaning agent according to claim 1, it is characterised in that:The chelating agent be ethylenediamine tetra-acetic acid, Sodium gluconate or sodium pyrophosphate.
6. train enclosure cleaning agent according to any one of claims 1 to 5, it is characterised in that:The train enclosure cleaning The pH value of agent is faintly acid to neutrality.
7. such as the preparation method of claim 1 to 6 any one of them train enclosure cleaning agent, it is characterised in that:Steps are as follows:
It is separately added into surfactant, organic acid, inorganic acid, chelating agent, water according to the ratio, stirs evenly clear to get train enclosure Lotion.
CN201810329158.1A 2018-04-13 2018-04-13 Train outside compartment cleaning agent and preparation method thereof Active CN108441329B (en)

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Application Number Priority Date Filing Date Title
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CN108441329B CN108441329B (en) 2020-05-08

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111559799A (en) * 2020-05-14 2020-08-21 北京可林维尔化工有限公司 Multipurpose cleaning bactericide and preparation method and use method thereof
CN111979057A (en) * 2019-05-23 2020-11-24 合肥科源应用化工研究所 Neutral cleaning agent for motor train unit and preparation method of neutral cleaning agent
CN113736574A (en) * 2021-09-27 2021-12-03 北京中铁富红企业管理有限责任公司 Cleaning agent for cleaning bullet train, preparation method of cleaning agent and bullet train cleaning method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102504975A (en) * 2011-11-23 2012-06-20 上海应用技术学院 Ordinary passenger train outer wagon powdery cleaning agent and preparation method thereof
CN107057897A (en) * 2017-03-13 2017-08-18 广州泰成生化科技有限公司 A kind of new situ cleaning agent and preparation method thereof
CN107849498A (en) * 2015-07-07 2018-03-27 利拉伐控股有限公司 Acid detergent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102504975A (en) * 2011-11-23 2012-06-20 上海应用技术学院 Ordinary passenger train outer wagon powdery cleaning agent and preparation method thereof
CN107849498A (en) * 2015-07-07 2018-03-27 利拉伐控股有限公司 Acid detergent
CN107057897A (en) * 2017-03-13 2017-08-18 广州泰成生化科技有限公司 A kind of new situ cleaning agent and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111979057A (en) * 2019-05-23 2020-11-24 合肥科源应用化工研究所 Neutral cleaning agent for motor train unit and preparation method of neutral cleaning agent
CN111979057B (en) * 2019-05-23 2022-05-17 合肥科源应用化工研究所 Neutral cleaning agent for motor train unit and preparation method of neutral cleaning agent
CN111559799A (en) * 2020-05-14 2020-08-21 北京可林维尔化工有限公司 Multipurpose cleaning bactericide and preparation method and use method thereof
CN113736574A (en) * 2021-09-27 2021-12-03 北京中铁富红企业管理有限责任公司 Cleaning agent for cleaning bullet train, preparation method of cleaning agent and bullet train cleaning method

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