CN108441297A - 一种用于发动机的中性润滑油 - Google Patents

一种用于发动机的中性润滑油 Download PDF

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CN108441297A
CN108441297A CN201810313507.0A CN201810313507A CN108441297A CN 108441297 A CN108441297 A CN 108441297A CN 201810313507 A CN201810313507 A CN 201810313507A CN 108441297 A CN108441297 A CN 108441297A
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lubricating oil
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孔勇
周忠阳
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Shandong Zero Kilometer Lubrication Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/045Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M163/00Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C10M2205/0285Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066Thiocarbamic type compounds
    • C10M2219/068Thiocarbamate metal salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/25Internal-combustion engines

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

本发明涉及发动机保护剂技术领域,具体涉及一种用于发动机的中性润滑油,所述用于发动机的中性润滑油,包括以下重量份的物质:基础油75~90重量份、降凝剂0.1~0.5重量份、粘指剂3~8重量份、添加剂8~15重量份、有机钼0.1~0.3重量份、高温抗氧剂0.3~0.8重量份、分散剂0.1~0.5重量份、消泡剂0.001~0.003重量份。本发明通过在基础油中加入抗磨剂有机钼和高温抗氧剂,能够提高合成油的油品黏度,能够使润滑油温度较高的情况下依然能形成完整油膜,减少机油的挥发,从而缓解发动机因机械原因引起的烧机油情况。

Description

一种用于发动机的中性润滑油
技术领域
本发明涉及发动机保护剂技术领域,具体涉及一种用于发动机的中性润滑油。
背景技术
在当前润滑油工业取得了很大的发展,特别是随着社会的不断发展和科学技术的不断提高,以及各种新老设备的技术创新,汽车工业的发展更为突出,因此润滑油工业为了使各种机械设备的功效达到更高的设计要求也必须不断的研发,不断的创新,目前因为汽车工业的不断发展,发动机润滑油占据了润滑油一半的市场,因此受到了各润滑油生产企业和科研单位的高度重视,有很多研发成果功效突出,效果理想,但在批量生产后品质下降,其主要原因是追求利益所致。
因此市面上高品质润滑油价格昂贵,而价格理想的润滑油更多的是功效单一,使用效果不理想,换油周期达不到发动机的基本要求。更有一些生产单位为了追求理想的利润,给产品找卖点,而只注重产品的高抗磨,而忽略了润滑油由于挥发造成的机油粘度降低,而给发动机带来损伤。
发明内容
针对现有技术的不足,本发明的主要目的是提供一种用于发动机的中性润滑油,它能够改善发动机因机油粘度降低而对发动机形成的损伤。
本发明的发明人在长期研究过程中发现:车辆因行驶状况恶劣,机油的粘度降低较快、导致机油挥发变快,而产生“烧机油”现象,这就对发动机造成很大的磨损和损伤,车辆动力不足或是发动机噪声大。
为解决上述问题,本发明提供了一种用于发动机的中性润滑油,包括以下重量份的物质:基础油75~90重量份、降凝剂0.1~0.5重量份、粘指剂3~8重量份、添加剂8~15重量份、有机钼0.1~0.3重量份、高温抗氧剂0.3~0.8重量份、分散剂0.1~0.5重量份、消泡剂0.001~0.003重量份。
根据本发明,优选条件下,所述用于发动机的中性润滑油,包括以下重量份的物质:基础油81.24重量份、降凝剂0.3重量份、粘指剂5重量份、添加剂12.6重量份、有机钼0.13重量份、高温抗氧剂0.6重量份、分散剂0.13重量份、消泡剂0.002重量份。
根据本发明,本发明对基础油的种类没有特殊的要求,可以为所述领域技术人员常知的基础油,优选条件下,所述基础油包括合成油PAO 4、脂3970和合成油PAO150中的至少一种。
根据本发明,本发明通过在润滑油中加入有机钼抗磨剂,能够利于在油膜薄的情况下依然能够起到抗磨损效果,形成的油膜起到缓冲的作用和降噪功能,优选条件下,所述有机钼选自MoDDP和/或MoDTC。
根据本发明,降凝剂能够降低润滑油的表观粘度和屈服值冰点,从而达到提高润滑油的低温流动性,有效地细化蜡晶,优选条件下,所述降凝剂为降凝剂1-189。
本发明中通过在润滑油中加入粘指剂,提高润滑油的黏度稳定性,降低发动机温度对润滑油黏度的影响,优选条件下,所述粘指剂为粘指剂SV203。
优选条件下,所述添加剂为添加剂9490。
本发明通过在润滑油中加入高温抗氧剂,能够减少润滑油或发动机在高温条件氧化,一方面减少原材料的损耗,另一方面还能减少发动机内部油泥积碳内的产生量,优选条件下,所述高温抗氧剂选自高温抗氧剂L-135和/或高温抗氧剂L-57。
本发明中,通过在润滑油中加入清净分散剂,能够及时分解形成的油泥积碳,避免油泥积碳的累积,优选条件下,所述清净分散剂为清净分散剂154。
根据本发明,优选条件下,所述消泡剂选自消泡剂2#。
本发明中,所述润滑油的制备方法为:在基础油中加入降凝剂、粘指剂、添加剂、有机钼、高温抗氧剂、分散剂、消泡剂,混合均匀后,即得到用于发动机的中性润滑油。
与现有技术相比,本发明具有以下技术效果:
本发明通过在基础油中加入抗磨剂有机钼和高温抗氧剂,能够提高合成油的油品黏度,能够使润滑油温度较高的情况下依然能形成完整油膜,减少机油的挥发,从而缓解发动机因机械原因引起的烧机油情况。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白,以下实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。
实施例1
一种用于发动机的中性润滑油,由以下物质制成:
实施例2
一种用于发动机的中性润滑油,由以下物质制成:
实施例3
一种用于发动机的中性润滑油,由以下物质制成:
测试:将上述实施例1~3制得的用于发动机的中性润滑油主要物性指标根据相关检测标准测试,实验结果如表1所示。
表1
将本发明实施例1的中性润滑油与现有市场上的润滑油比较,实验结果如表2所示。
表2
上述描述仅是对本发明部分实施例的描述,并非对本发明范围的任何限定,本行业的普通技术人员可根据本发明对上述实施例做出改进或修改,但均属于本发明保护范围。

Claims (10)

1.一种用于发动机的中性润滑油,其特征在于,包括以下重量份的物质:基础油75~90重量份、降凝剂0.1~0.5重量份、粘指剂3~8重量份、添加剂8~15重量份、有机钼0.1~0.3重量份、高温抗氧剂0.3~0.8重量份、分散剂0.1~0.5重量份、消泡剂0.001~0.003重量份。
2.根据权利要求1所述的用于发动机的中性润滑油,其特征在于,包括以下重量份的物质:基础油81.24重量份、降凝剂0.3重量份、粘指剂5重量份、添加剂12.6重量份、有机钼0.13重量份、高温抗氧剂0.6重量份、分散剂0.13重量份、消泡剂0.002重量份。
3.根据权利要求2所述的用于发动机的中性润滑油,其特征在于,所述基础油包括合成油PAO 4、脂3970和合成油PAO150中的至少一种。
4.根据权利要求2所述的用于发动机的中性润滑油,其特征在于,所述有机钼选自MoDDP和/或MoDTC。
5.根据权利要求2所述的用于发动机的中性润滑油,其特征在于,所述降凝剂为降凝剂1-189。
6.根据权利要求2所述的用于发动机的中性润滑油,其特征在于,所述粘指剂为粘指剂SV203。
7.根据权利要求2所述的用于发动机的中性润滑油,其特征在于,所述添加剂为添加剂9490。
8.根据权利要求2所述的用于发动机的中性润滑油,其特征在于,所述高温抗氧剂选自高温抗氧剂L-135和/或高温抗氧剂L-57。
9.根据权利要求2所述的用于发动机的中性润滑油,其特征在于,所述清净分散剂清净分散剂154。
10.根据权利要求2所述的用于发动机的中性润滑油,其特征在于,所述消泡剂为消泡剂2#。
CN201810313507.0A 2018-04-10 2018-04-10 一种用于发动机的中性润滑油 Pending CN108441297A (zh)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1981020A (zh) * 2004-07-08 2007-06-13 国际壳牌研究有限公司 润滑油组合物
CN103087806A (zh) * 2013-02-01 2013-05-08 大庆海力石油化工有限公司 一种柴油、天然气双燃料发动机用润滑油组合物
CN105733783A (zh) * 2016-03-30 2016-07-06 河北和甘灵生物科技有限公司 酯类合成柴油内燃机润滑油及其制备工艺
CN106883911A (zh) * 2017-01-23 2017-06-23 浙江吉利控股集团有限公司 一种耐高温氧化甲醇机油及其制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1981020A (zh) * 2004-07-08 2007-06-13 国际壳牌研究有限公司 润滑油组合物
CN103087806A (zh) * 2013-02-01 2013-05-08 大庆海力石油化工有限公司 一种柴油、天然气双燃料发动机用润滑油组合物
CN105733783A (zh) * 2016-03-30 2016-07-06 河北和甘灵生物科技有限公司 酯类合成柴油内燃机润滑油及其制备工艺
CN106883911A (zh) * 2017-01-23 2017-06-23 浙江吉利控股集团有限公司 一种耐高温氧化甲醇机油及其制备方法

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