CN108440887A - 一种阻燃型水性丙烯酸树脂 - Google Patents

一种阻燃型水性丙烯酸树脂 Download PDF

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CN108440887A
CN108440887A CN201810269775.7A CN201810269775A CN108440887A CN 108440887 A CN108440887 A CN 108440887A CN 201810269775 A CN201810269775 A CN 201810269775A CN 108440887 A CN108440887 A CN 108440887A
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parts
component
weight
flame
acrylic resin
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李光明
关琳琳
易晓洪
钟文军
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Suzhou Bolaite New Material Co ltd
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Suzhou Bolaite New Material Co ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/5205—Salts of P-acids with N-bases
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了一种阻燃型水性丙烯酸树脂，包括A组分和B组分，其中A组分按重量份计包括：丙烯酸甲酯30~40份、丙烯酸丁酯20~30份、甲基丙烯酸乙酯5~10份、二甲氨基丙基甲基丙烯酰胺1~2份、马来酸二酰肼0.1~0.5份、油酸三乙醇胺1~1.5份、过硫酸钾0.1~0.5份、表面活性剂2~3份、消泡剂0.03~0.1份、水50~60份；B组分按重量份计包括：三聚氰胺磷酸酯10~20份，哌嗪多磷酸酯20~30份，哌嗪焦磷酸酯10~20份，四苯基焦磷酸酯10~20份，卤烷基磷酸酯30~40份，双酚A二磷酸酯10~20份；所述A组分和B组分的重量混合比1:0.5~1。本发明的一种阻燃型水性丙烯酸树脂具有良好的阻燃性，且成膜性能良好。

Description

一种阻燃型水性丙烯酸树脂
技术领域
本发明涉及一种阻燃型水性丙烯酸树脂。
背景技术
现有的水性丙烯酸树脂基本无阻燃性，为了达到阻燃性能，就 要加入大量的阻燃剂，大量的阻燃剂加入势必会影响产品性能。加入的阻燃剂量大，成膜树脂的量相对就少了，牢度就差了；而为了提高牢度，就要增加树脂量，阻燃剂量相对减少，阻燃性降低。
发明内容
本发明的目的在于一种阻燃型水性丙烯酸树脂，旨在解决上述问题。
为了实现上述目的，本发明的技术方案是设计一种阻燃型水性丙烯酸树脂，包括A组分和B组分，其中A组分按重量份计包括：丙烯酸甲酯30~40份、丙烯酸丁酯20~30份、甲基丙烯酸乙酯5~10份、二甲氨基丙基甲基丙烯酰胺1~2份、马来酸二酰肼0.1~0.5份、油酸三乙醇胺1~1.5份、过硫酸钾0.1~0.5份、表面活性剂2~3份、消泡剂0.03~0.1份、水50~60份；B组分按重量份计包括：三聚氰胺磷酸酯10~20份，哌嗪多磷酸酯20~30份，哌嗪焦磷酸酯10~20份，四苯基焦磷酸酯10~20份，卤烷基磷酸酯30~40份，双酚A二磷酸酯10~20份；所述A组分和B组分的重量混合比1:0.5~1。
本发明的优点和有益效果在于：本发明的一种阻燃型水性丙烯酸树脂具有良好的阻燃性，且成膜性能良好。
具体实施方式
下面结合实施例，对本发明的具体实施方式作进一步描述。以下实施例仅用于更加清楚地说明本发明的技术方案，而不能以此来限制本发明的保护范围。
实施例1：
一种阻燃型水性丙烯酸树脂，包括A组分和B组分，其中A组分按重量份计包括：丙烯酸甲酯30~40份、丙烯酸丁酯20~30份、甲基丙烯酸乙酯5份、二甲氨基丙基甲基丙烯酰胺1份、马来酸二酰肼0.1份、油酸三乙醇胺1份、过硫酸钾0.1份、表面活性剂2份、消泡剂0.03份、水50份；B组分按重量份计包括：三聚氰胺磷酸酯10份，哌嗪多磷酸酯20份，哌嗪焦磷酸酯10份，四苯基焦磷酸酯10份，卤烷基磷酸酯30份，双酚A二磷酸酯10份；所述A组分和B组分的重量混合比1:0.5。
实施例2：
一种阻燃型水性丙烯酸树脂，包括A组分和B组分，其中A组分按重量份计包括：丙烯酸甲酯40份、丙烯酸丁酯30份、甲基丙烯酸乙酯10份、二甲氨基丙基甲基丙烯酰胺2份、马来酸二酰肼0.5份、油酸三乙醇胺1.5份、过硫酸钾0.5份、表面活性剂3份、消泡剂0.1份、水60份；B组分按重量份计包括：三聚氰胺磷酸酯20份，哌嗪多磷酸酯30份，哌嗪焦磷酸酯20份，四苯基焦磷酸酯20份，卤烷基磷酸酯40份，双酚A二磷酸酯20份；所述A组分和B组分的重量混合比1:1。
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明技术原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。

Claims (1)

1.一种阻燃型水性丙烯酸树脂，其特征在于，包括A组分和B组分，其中A组分按重量份计包括：丙烯酸甲酯30~40份、丙烯酸丁酯20~30份、甲基丙烯酸乙酯5~10份、二甲氨基丙基甲基丙烯酰胺1~2份、马来酸二酰肼0.1~0.5份、油酸三乙醇胺1~1.5份、过硫酸钾0.1~0.5份、表面活性剂2~3份、消泡剂0.03~0.1份、水50~60份；B组分按重量份计包括：三聚氰胺磷酸酯10~20份，哌嗪多磷酸酯20~30份，哌嗪焦磷酸酯10~20份，四苯基焦磷酸酯10~20份，卤烷基磷酸酯30~40份，双酚A二磷酸酯10~20份；所述A组分和B组分的重量混合比1:0.5~1。
CN201810269775.7A 2018-03-29 2018-03-29 一种阻燃型水性丙烯酸树脂 Pending CN108440887A (zh)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102516446A (zh) * 2011-12-02 2012-06-27 佛山市南海高拓包装材料有限公司 一种水性丙烯酸树脂及其制备方法和应用
CN103965393A (zh) * 2014-05-06 2014-08-06 江门骅弘颜料有限公司 一种水性丙烯酸树脂
CN106147319A (zh) * 2016-08-08 2016-11-23 丹阳市日月漆业有限公司 一种丙烯酸树脂阻燃涂料
CN107075378A (zh) * 2015-01-08 2017-08-18 株式会社艾迪科 阻燃剂组合物及阻燃性合成树脂组合物

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102516446A (zh) * 2011-12-02 2012-06-27 佛山市南海高拓包装材料有限公司 一种水性丙烯酸树脂及其制备方法和应用
CN103965393A (zh) * 2014-05-06 2014-08-06 江门骅弘颜料有限公司 一种水性丙烯酸树脂
CN107075378A (zh) * 2015-01-08 2017-08-18 株式会社艾迪科 阻燃剂组合物及阻燃性合成树脂组合物
CN106147319A (zh) * 2016-08-08 2016-11-23 丹阳市日月漆业有限公司 一种丙烯酸树脂阻燃涂料

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