CN108440887A - 一种阻燃型水性丙烯酸树脂 - Google Patents
一种阻燃型水性丙烯酸树脂 Download PDFInfo
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 16
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 14
- 239000004925 Acrylic resin Substances 0.000 title claims abstract description 12
- 229920000178 Acrylic resin Polymers 0.000 title claims abstract description 12
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims abstract description 10
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002253 acid Substances 0.000 claims abstract description 6
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 5
- 229920000388 Polyphosphate Polymers 0.000 claims abstract description 5
- LAUIXFSZFKWUCT-UHFFFAOYSA-N [4-[2-(4-phosphonooxyphenyl)propan-2-yl]phenyl] dihydrogen phosphate Chemical compound C=1C=C(OP(O)(O)=O)C=CC=1C(C)(C)C1=CC=C(OP(O)(O)=O)C=C1 LAUIXFSZFKWUCT-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000010452 phosphate Substances 0.000 claims abstract description 5
- MWFNQNPDUTULBC-UHFFFAOYSA-N phosphono dihydrogen phosphate;piperazine Chemical compound C1CNCCN1.OP(O)(=O)OP(O)(O)=O MWFNQNPDUTULBC-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000001205 polyphosphate Substances 0.000 claims abstract description 5
- 235000011176 polyphosphates Nutrition 0.000 claims abstract description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims abstract description 5
- 235000019394 potassium persulphate Nutrition 0.000 claims abstract description 5
- 239000004094 surface-active agent Substances 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 claims abstract description 4
- UQSHIDHNLKIYGN-UHFFFAOYSA-N diphenoxyphosphoryl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OP(=O)(OC=1C=CC=CC=1)OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 UQSHIDHNLKIYGN-UHFFFAOYSA-N 0.000 claims abstract description 4
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229940117013 triethanolamine oleate Drugs 0.000 claims abstract description 4
- -1 dimethylamino-propyl Chemical group 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims 1
- HVLBHJWRJSDHBW-UHFFFAOYSA-N phosphane;1,3,5-triazine-2,4,6-triamine Chemical compound P.NC1=NC(N)=NC(N)=N1 HVLBHJWRJSDHBW-UHFFFAOYSA-N 0.000 claims 1
- FLCAEMBIQVZWIF-UHFFFAOYSA-N 6-(dimethylamino)-2-methylhex-2-enamide Chemical compound CN(C)CCCC=C(C)C(N)=O FLCAEMBIQVZWIF-UHFFFAOYSA-N 0.000 abstract description 4
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 4
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 abstract description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 150000004702 methyl esters Chemical class 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/5205—Salts of P-acids with N-bases
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明公开了一种阻燃型水性丙烯酸树脂，包括A组分和B组分，其中A组分按重量份计包括：丙烯酸甲酯30~40份、丙烯酸丁酯20~30份、甲基丙烯酸乙酯5~10份、二甲氨基丙基甲基丙烯酰胺1~2份、马来酸二酰肼0.1~0.5份、油酸三乙醇胺1~1.5份、过硫酸钾0.1~0.5份、表面活性剂2~3份、消泡剂0.03~0.1份、水50~60份；B组分按重量份计包括：三聚氰胺磷酸酯10~20份，哌嗪多磷酸酯20~30份，哌嗪焦磷酸酯10~20份，四苯基焦磷酸酯10~20份，卤烷基磷酸酯30~40份，双酚A二磷酸酯10~20份；所述A组分和B组分的重量混合比1:0.5~1。本发明的一种阻燃型水性丙烯酸树脂具有良好的阻燃性，且成膜性能良好。
Description
技术领域
本发明涉及一种阻燃型水性丙烯酸树脂。
背景技术
现有的水性丙烯酸树脂基本无阻燃性，为了达到阻燃性能，就 要加入大量的阻燃剂，大量的阻燃剂加入势必会影响产品性能。加入的阻燃剂量大，成膜树脂的量相对就少了，牢度就差了；而为了提高牢度，就要增加树脂量，阻燃剂量相对减少，阻燃性降低。
发明内容
本发明的目的在于一种阻燃型水性丙烯酸树脂，旨在解决上述问题。
为了实现上述目的，本发明的技术方案是设计一种阻燃型水性丙烯酸树脂，包括A组分和B组分，其中A组分按重量份计包括：丙烯酸甲酯30~40份、丙烯酸丁酯20~30份、甲基丙烯酸乙酯5~10份、二甲氨基丙基甲基丙烯酰胺1~2份、马来酸二酰肼0.1~0.5份、油酸三乙醇胺1~1.5份、过硫酸钾0.1~0.5份、表面活性剂2~3份、消泡剂0.03~0.1份、水50~60份；B组分按重量份计包括：三聚氰胺磷酸酯10~20份，哌嗪多磷酸酯20~30份，哌嗪焦磷酸酯10~20份，四苯基焦磷酸酯10~20份，卤烷基磷酸酯30~40份，双酚A二磷酸酯10~20份；所述A组分和B组分的重量混合比1:0.5~1。
本发明的优点和有益效果在于：本发明的一种阻燃型水性丙烯酸树脂具有良好的阻燃性，且成膜性能良好。
具体实施方式
下面结合实施例，对本发明的具体实施方式作进一步描述。以下实施例仅用于更加清楚地说明本发明的技术方案，而不能以此来限制本发明的保护范围。
实施例1：
一种阻燃型水性丙烯酸树脂，包括A组分和B组分，其中A组分按重量份计包括：丙烯酸甲酯30~40份、丙烯酸丁酯20~30份、甲基丙烯酸乙酯5份、二甲氨基丙基甲基丙烯酰胺1份、马来酸二酰肼0.1份、油酸三乙醇胺1份、过硫酸钾0.1份、表面活性剂2份、消泡剂0.03份、水50份；B组分按重量份计包括：三聚氰胺磷酸酯10份，哌嗪多磷酸酯20份，哌嗪焦磷酸酯10份，四苯基焦磷酸酯10份，卤烷基磷酸酯30份，双酚A二磷酸酯10份；所述A组分和B组分的重量混合比1:0.5。
实施例2：
一种阻燃型水性丙烯酸树脂，包括A组分和B组分，其中A组分按重量份计包括：丙烯酸甲酯40份、丙烯酸丁酯30份、甲基丙烯酸乙酯10份、二甲氨基丙基甲基丙烯酰胺2份、马来酸二酰肼0.5份、油酸三乙醇胺1.5份、过硫酸钾0.5份、表面活性剂3份、消泡剂0.1份、水60份；B组分按重量份计包括：三聚氰胺磷酸酯20份，哌嗪多磷酸酯30份，哌嗪焦磷酸酯20份，四苯基焦磷酸酯20份，卤烷基磷酸酯40份，双酚A二磷酸酯20份；所述A组分和B组分的重量混合比1:1。
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明技术原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。
Claims (1)
1.一种阻燃型水性丙烯酸树脂，其特征在于，包括A组分和B组分，其中A组分按重量份计包括：丙烯酸甲酯30~40份、丙烯酸丁酯20~30份、甲基丙烯酸乙酯5~10份、二甲氨基丙基甲基丙烯酰胺1~2份、马来酸二酰肼0.1~0.5份、油酸三乙醇胺1~1.5份、过硫酸钾0.1~0.5份、表面活性剂2~3份、消泡剂0.03~0.1份、水50~60份；B组分按重量份计包括：三聚氰胺磷酸酯10~20份，哌嗪多磷酸酯20~30份，哌嗪焦磷酸酯10~20份，四苯基焦磷酸酯10~20份，卤烷基磷酸酯30~40份，双酚A二磷酸酯10~20份；所述A组分和B组分的重量混合比1:0.5~1。
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102516446A (zh) * | 2011-12-02 | 2012-06-27 | 佛山市南海高拓包装材料有限公司 | 一种水性丙烯酸树脂及其制备方法和应用 |
| CN103965393A (zh) * | 2014-05-06 | 2014-08-06 | 江门骅弘颜料有限公司 | 一种水性丙烯酸树脂 |
| CN106147319A (zh) * | 2016-08-08 | 2016-11-23 | 丹阳市日月漆业有限公司 | 一种丙烯酸树脂阻燃涂料 |
| CN107075378A (zh) * | 2015-01-08 | 2017-08-18 | 株式会社艾迪科 | 阻燃剂组合物及阻燃性合成树脂组合物 |
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2018
- 2018-03-29 CN CN201810269775.7A patent/CN108440887A/zh active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102516446A (zh) * | 2011-12-02 | 2012-06-27 | 佛山市南海高拓包装材料有限公司 | 一种水性丙烯酸树脂及其制备方法和应用 |
| CN103965393A (zh) * | 2014-05-06 | 2014-08-06 | 江门骅弘颜料有限公司 | 一种水性丙烯酸树脂 |
| CN107075378A (zh) * | 2015-01-08 | 2017-08-18 | 株式会社艾迪科 | 阻燃剂组合物及阻燃性合成树脂组合物 |
| CN106147319A (zh) * | 2016-08-08 | 2016-11-23 | 丹阳市日月漆业有限公司 | 一种丙烯酸树脂阻燃涂料 |
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