CN108439551A - A kind of de- bitter sewage treatment equipment of semen armeniacae amarae and its processing method - Google Patents

A kind of de- bitter sewage treatment equipment of semen armeniacae amarae and its processing method Download PDF

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Publication number
CN108439551A
CN108439551A CN201810336495.3A CN201810336495A CN108439551A CN 108439551 A CN108439551 A CN 108439551A CN 201810336495 A CN201810336495 A CN 201810336495A CN 108439551 A CN108439551 A CN 108439551A
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CN
China
Prior art keywords
sink
bitter
semen armeniacae
armeniacae amarae
reaction tower
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810336495.3A
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Chinese (zh)
Inventor
彭艳芳
李洁
李明华
刘晓光
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Hebei Normal University for Nationalities
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Hebei Normal University for Nationalities
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Priority to CN201810336495.3A priority Critical patent/CN108439551A/en
Publication of CN108439551A publication Critical patent/CN108439551A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/20Removal of unwanted matter, e.g. deodorisation or detoxification
    • A23L5/27Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/20Removal of unwanted matter, e.g. deodorisation or detoxification
    • A23L5/27Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption
    • A23L5/276Treatment with inorganic compounds
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/57Chemical peeling or cleaning of harvested fruits, vegetables or other foodstuffs
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23NMACHINES OR APPARATUS FOR TREATING HARVESTED FRUIT, VEGETABLES OR FLOWER BULBS IN BULK, NOT OTHERWISE PROVIDED FOR; PEELING VEGETABLES OR FRUIT IN BULK; APPARATUS FOR PREPARING ANIMAL FEEDING- STUFFS
    • A23N5/00Machines for hulling, husking or cracking nuts
    • A23N5/002Machines for hulling, husking or cracking nuts for skinning nut kernels
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • C02F2101/18Cyanides

Abstract

The invention discloses a kind of de- bitter sewage treatment equipments of semen armeniacae amarae, including scourer, straight line reciprocating sieve, sink one, sink two, sink three and Inner electrolysis reaction tower, the scourer, straight line reciprocating sieve, sink one, sink two, sink three and Inner electrolysis reaction tower are sequentially connected and form an integrated apparatus, the bottom of the sink three is equipped with water pump, and it is provided with discharge outlet on sink three, the invention also discloses a kind of de- bitter wastewater treatment methods of semen armeniacae amarae, include the following steps:S4, S1, decladding, S2, screening, S3, peeling go hardship, S5, waste material filtering, S6, Inner electrolysis reaction tower handle waste water.The semen armeniacae amarae takes off bitter sewage treatment equipment and its processing method, quickly can take off hardship for present semen armeniacae amarae, and can effectively purify the waste water after de- hardship, and different de- bitter modes can be selected according to amygdalate two states, increases practicability, suitable to promote.

Description

A kind of de- bitter sewage treatment equipment of semen armeniacae amarae and its processing method
Technical field
The present invention relates to bitterness from almond and its technical field of waste water processing, the de- bitter wastewater treatment of specially a kind of semen armeniacae amarae is set Standby and its processing method.
Background technology
Semen armeniacae amarae is the seed of apricot, and curing mainly function has sending down abnormally ascending relieving cough and asthma, relaxes bowel, originate in the Inner Mongol, Liaoning, The cities such as Jilin;
Amarogentin is one of amygdalate main functional component, is the main source of semen armeniacae amarae bitter taste, and hydrogen cyanide It is the ingredient in semen armeniacae amarae, but unlike amarogentin, hydrogen cyanide is not only harmful to human body, and largely take in hydrogen cyanogen Acid may lead to death, therefore the de- bitter and its subsequent wastewater treatment of semen armeniacae amarae has become the key in semen armeniacae amarae process Technology.
The de- bitter sewage treatment equipment of traditional semen armeniacae amarae and method de- bitter time are long, and cannot effectively extract in waste water Substance, therefore it is proposed that a kind of semen armeniacae amarae takes off bitter sewage treatment equipment and its processing method, to solve the above problems.
Invention content
It is above-mentioned to solve the purpose of the present invention is to provide a kind of de- bitter sewage treatment equipment of semen armeniacae amarae and its processing method The de- bitter sewage treatment equipment of traditional semen armeniacae amarae and method de- bitter time proposed in background technology is long, and cannot effectively extract The problem of substance in waste water.
To achieve the above object, the present invention provides the following technical solutions:A kind of de- bitter sewage treatment equipment of semen armeniacae amarae, including Scourer, straight line reciprocating sieve, sink one, sink two, sink three and Inner electrolysis reaction tower, the scourer, straight line reciprocating sieve, water Slot one, sink two, sink three and Inner electrolysis reaction tower are sequentially connected and are formed an integrated apparatus, and the inside of the sink one is set Be equipped with crushing bar, the sink two is internally provided with stirring rod, the water outlet of the sink one and sink two with sink three It is connected, and the inside of sink three is equipped with Inner electrolysis reaction tower, the bottom of the sink three is equipped with water pump, and on sink three It is provided with discharge outlet.
Preferably, the inside of the sink one and sink two is mounted on heating rod.
Preferably, the bottom of one end connection Inner electrolysis reaction tower of the water pump, and in the other end of water pump and sink three Portion is connected.
The present invention also provides a kind of de- bitter wastewater treatment methods of semen armeniacae amarae, include the following steps:S1, decladding, S2, screening, S4, S3, peeling go hardship, S5, waste material filtering, S6, Inner electrolysis reaction tower handle waste water.
Preferably, the peeling condition in the step S3 is the lye of the addition 1.2% in the case where being heated to 90 DEG C, and Continue 10-20 minutes to remove the peel.
Preferably, the condition in the step S4 is the NaCl that 9% is added at 70 DEG C and under conditions of crushing, 0.1% Citric acid and Na2SO3, liquid ratio 10:1, heating time is 5 hours, or in 90 DEG C and the stirring condition of rotating speed 2r/s Under, 9% NaCl, 0.1% citric acid and Na is added2SO3, liquid ratio 10:1, heating time is 10 hours.
Preferably, in the Inner electrolysis reaction tower of the step S6, the fillers such as iron filings and coke need to be added.
Preferably, in the Inner electrolysis reaction tower of the step S6, internal iron filings need to be added 4% before addition After NaOH, 1h, 1.2% H is added2SO4Impregnate 25min.
Compared with prior art, the beneficial effects of the invention are as follows:The de- bitter sewage treatment equipment of the semen armeniacae amarae and its processing side Method, relative to the de- bitter sewage treatment equipment of traditional semen armeniacae amarae and method, the present invention can realize de- hardship faster, and can have Waste water after the purification of effect is de- bitter, and the present invention can according to amygdalate two states (complete semen armeniacae amarae and pulpous state Semen armeniacae amarae) select different de- bitter modes, practicability is increased, is suitble to promote.
Description of the drawings
Fig. 1 is the de- bitter and sewage treatment equipment structural schematic diagram of the present invention;
Fig. 2 is the process flow chart of wastewater treatment under pulverization conditions of the present invention;
Fig. 3 is the process flow chart of wastewater treatment under stirring condition of the present invention.
In figure:1, scourer;2, straight line reciprocating sieve;3, sink one;4, sink two;5, bar is crushed;6, stirring rod;7, it heats Stick;8, sink three;9, water pump;10, Inner electrolysis reaction tower;11, discharge outlet.
Specific implementation mode
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation describes, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
- 3 are please referred to Fig.1, the present invention provides a kind of technical solution:A kind of de- bitter sewage treatment equipment of semen armeniacae amarae, including go Shell machine 1, sink 1, sink 24, crushes bar 5, stirring rod 6, heating rod 7, sink 38, water pump 9, interior electricity at straight line reciprocating sieve 2 Solve reaction tower 10 and discharge outlet 11, scourer 1, straight line reciprocating sieve 2, sink 1, sink 24, sink 38 and Inner electrolysis reaction Tower 10 is sequentially connected and is formed an integrated apparatus, and the inside of sink 1 and sink 24 is mounted on heating rod 7, passes through heating Stick 7 can adjust the temperature inside sink 1 and sink 24 so that semen armeniacae amarae may be implemented quickly de- hardship, sink 1 it is interior Portion, which is provided with, crushes bar 5, and sink 24 is internally provided with stirring rod 6, the water outlet of sink 1 and sink 24 with sink three 8 are connected, and the inside of sink 38 is equipped with Inner electrolysis reaction tower 10, and the bottom of sink 38 is equipped with water pump 9, and sink three Discharge outlet 11, the bottom of one end connection Inner electrolysis reaction tower 10 of water pump 9, and the other end of water pump 9 and sink three are provided on 8 It is connected inside 8, when waste water enters in screw clamp 38, it is anti-waste water can be endlessly pumped into Inner electrolysis using water pump 9 Answer in tower 10, in the way of electrolysis, by cyanide, SS and COD compounds condense into it is cotton-shaped, it is convenient to pass through Inner electrolysis reaction tower 10 discharges, realize the effect of purification waste water, and can be recycled to these compounds.
The present invention also provides a kind of de- bitter wastewater treatment methods of semen armeniacae amarae, include the following steps:S1, decladding, S2, screening, S3, peeling, the peeling condition in step S3 are 1.2% lye to be added in the case where being heated to 90 DEG C, and continue 10-20 points Clock is removed the peel, and is used as decorticating agent using lye so that and the semen armeniacae amarae after decortication can more quickly remove amarogentin, S4, go hardship, the condition in step S4 be 70 DEG C and crush under conditions of, be added 9% NaCl, 0.1% citric acid and Na2SO3, liquid ratio 10:1, heating time is 5 hours, which implements for complete semen armeniacae amarae, is testing In, this kind of method can quickly remove the amarogentin in complete semen armeniacae amarae, realize amygdalate de- hardship, S5, waste material It filters, S6, the processing waste water of Inner electrolysis reaction tower 10, in the Inner electrolysis reaction tower 10 of step S6, iron filings and coke etc. need to be added and fill out Fill object, using two kinds of Different electrodes conductive metal and it is nonmetallic be used as electrode, in electrolyte solution, will produce electric field, And it reacts in electrode appearance, the cyanide in final waste water can form floccule and be removed, and realize toxic in waste water The purification and extraction of substance, in the Inner electrolysis reaction tower 10 of step S6, internal iron filings need to be added 4% before addition After NaOH, 1h, 1.2% H is added2SO425min is impregnated, is made a return journey the greasy dirt above scrap iron removing using 4% NaOH, avoids greasy dirt It can influence electrode reaction, and 1.2% H2SO4For removing the oxidation film on scrap iron removing surface so that electrode reaction can carry out.
The present invention also has another process in the de- hardships of step S4, under 90 DEG C and rotating speed 2r/s of stirring conditions, 9% NaCl, 0.1% citric acid and Na is added2SO3, liquid ratio 10:1, heating time is 10 hours, which is needle Complete semen armeniacae amarae is implemented, in an experiment, this kind of method can be quickly by the amarogentin in complete semen armeniacae amarae Amygdalate de- hardship is realized in removal.
Operation principle:When using the de- bitter sewage treatment equipment of the semen armeniacae amarae and its processing method, scourer 1 can be utilized Decladding in scourer 1 first is put into the almond after drying, then utilizes straight line reciprocating sieve 2 by apricot shell, broken almond and complete Almond screened, then complete almond is put into sink 24 as needed, is heated using heating rod 7 and using stirring It mixes bar 6 to stir under conditions of rotating speed is 2r/s, is subsequently added into 9% NaCl, 0.1% citric acid and Na2SO3, liquid ratio is 10:1, heated at constant temperature is kept, in experiment, after heating 10 hours, the amarogentin in complete semen armeniacae amarae can be removed, then Waste water is discharged into sink 38, waste liquid is pumped into Inner electrolysis reaction tower 10 using water pump 9, at this time in Inner electrolysis reaction tower 10 Iron filings and coke cooperation Inner electrolysis reaction tower 10 in electrolyte, can realize cell reaction, allow cyanide etc. in waste liquid Harmful substance forms floccule, and is discharged from discharge outlet 11, and harmful substance is net in the final de- bitter and its waste water of realization semen armeniacae amarae Change and extraction is recycled, also have a kind of mode of operation in the present embodiment, screw clamp 1 is added in broken almond and complete almond In, then utilize heating rod 7 heat and using crush bar 5 crush, be subsequently added into 9% NaCl, 0.1% citric acid and Na2SO3, liquid ratio 10:1, heated at constant temperature is kept, in experiment, after heating 5 hours, in the semen armeniacae amarae that pulpous state can be removed Amarogentin realizes the de- hardship of semen armeniacae amarae under different conditions.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace And modification, the scope of the present invention is defined by the appended.

Claims (8)

1. a kind of de- bitter sewage treatment equipment of semen armeniacae amarae, including scourer (1), straight line reciprocating sieve (2), sink one (3), sink two (4), sink three (8) and Inner electrolysis reaction tower (10), it is characterised in that:The scourer (1), straight line reciprocating sieve (2), sink one (3), sink two (4), sink three (8) and Inner electrolysis reaction tower (10) are sequentially connected and are formed an integrated apparatus, the sink Being internally provided with for one (3) crushes bar (5), and the sink two (4) is internally provided with stirring rod (6), the sink one (3) and The water outlet of sink two (4) is connected with sink three (8), and the inside of sink three (8) is equipped with Inner electrolysis reaction tower (10), The bottom of the sink three (8) is equipped with water pump (9), and discharge outlet (11) is provided on sink three (8).
2. a kind of de- bitter sewage treatment equipment of semen armeniacae amarae according to claim 1 and its processing method, it is characterised in that:Institute The inside for stating sink one (3) and sink two (4) is mounted on heating rod (7).
3. a kind of de- bitter sewage treatment equipment of semen armeniacae amarae according to claim 1 and its processing method, it is characterised in that:Institute State the bottom of one end connection Inner electrolysis reaction tower (10) of water pump (9), and the other end of water pump (9) and the internal phase of sink three (8) Connection.
4. a kind of de- bitter wastewater treatment method of semen armeniacae amarae, it is characterised in that:Include the following steps:S1, decladding, S2, screening, S3, S4, peeling goes hardship, S5, waste material filtering, S6, Inner electrolysis reaction tower handle waste water.
5. a kind of de- bitter wastewater treatment method of semen armeniacae amarae according to claim 4, it is characterised in that:In the step S3 Peeling condition is 1.2% lye to be added in the case where being heated to 90 DEG C, and continue 10-20 minutes to remove the peel.
6. a kind of de- bitter wastewater treatment method of semen armeniacae amarae according to claim 4, it is characterised in that:In the step S4 Condition is that 9% NaCl, 0.1% citric acid and Na is added at 70 DEG C and under conditions of crushing2SO3, liquid ratio 10:1, Heating time is 5 hours, or under 90 DEG C and rotating speed 2r/s of stirring condition, 9% NaCl, 0.1% citric acid is added And Na2SO3, liquid ratio 10:1, heating time is 10 hours.
7. a kind of de- bitter wastewater treatment method of semen armeniacae amarae according to claim 4, it is characterised in that:The step S6's is interior In cell reaction tower, the fillers such as iron filings and coke need to be added.
8. a kind of de- bitter wastewater treatment method of semen armeniacae amarae according to claim 7, it is characterised in that:The step S6's is interior In cell reaction tower, internal iron filings need to be added before addition 4% NaOH, and after 1h, 1.2% H is added2SO4It impregnates 25min。
CN201810336495.3A 2018-04-13 2018-04-13 A kind of de- bitter sewage treatment equipment of semen armeniacae amarae and its processing method Pending CN108439551A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113754707A (en) * 2021-10-12 2021-12-07 承德亚欧果仁有限公司 Method for recovering amygdalin from almond debitterized water through MVR concentrator

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113754707A (en) * 2021-10-12 2021-12-07 承德亚欧果仁有限公司 Method for recovering amygdalin from almond debitterized water through MVR concentrator

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