CN108432795A - A kind of Pesticidal combination containing betacyfluthrin - Google Patents
A kind of Pesticidal combination containing betacyfluthrin Download PDFInfo
- Publication number
- CN108432795A CN108432795A CN201810287438.0A CN201810287438A CN108432795A CN 108432795 A CN108432795 A CN 108432795A CN 201810287438 A CN201810287438 A CN 201810287438A CN 108432795 A CN108432795 A CN 108432795A
- Authority
- CN
- China
- Prior art keywords
- betacyfluthrin
- compound
- pesticidal combination
- weight ratio
- oxadiazoles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
Abstract
The present invention relates to one kind containing (E) 2 (ethylmercapto group) 5 (4 fluorostyryl) 1,3,4 oxadiazoles and betacyfluthrin for ground insect-pest exterminating composition and its application under vegetable field, effective active composition includes (E) 2 (ethylmercapto group) 5 (4 fluorostyryl) 1,3, the weight ratio of 4 oxadiazoles and betacyfluthrin, the first active constituent and the second active constituent is 1:20‑40:In 1 range, preferably 1:10‑20:1, further preferably 1:5‑10:1, more preferable 1:2.5‑5:1 has excellent collaboration preventive effect.This composition can be configured to the dosage forms such as the granule agriculturally allowed, suspending agent, water dispersible granules, aqueous emulsion or wettable powder.Instant component is reasonable, desinsection control effect is good, and it is not the active simple superposition of each component that it, which kills nematode and the activity of diamondback moth, compared with existing single formulation, in addition to significant insecticidal effect, also there is significant synergistic effect, it is good to crop safety, tomato and wild cabbage yield are obviously improved.
Description
Technical field
The 1,3,4- oxadiazoles thio-ether type compounds that this application involves a kind of containing styryl and betacyfluthrin
The purposes of Pesticidal combination and the Pesticidal combination in terms of prevention Meloidogyne incognita and wild cabbage diamondback moth.
Background technology
Compound (E) -2- (ethylmercapto group) -5- (4- fluorostyryls) -1,3,4- oxadiazoles, structural formula are as followsIt is the nematicide developed by Guizhou University.The prior art have its prevent citrus nematode and
The report of southern root nematode.Whether there is no literature reported on it at present has killing activity to other pests.
Betacyfluthrin, English name:Beta-cyfluthrin, other titles:It protects, chemical name:Cyano-
(the fluoro- 3- benzyloxy phenoxies bases of 4-)-methyl-(2,2- dichloroethylene) -2,2- dimethyl cyclopropane carboxylic acid's esters, tool tag, stomach toxicity and
The prevention effect of ingesting.Insecticidal spectrum is wide, applicable crops:Cotton, wheat, corn, vegetables, tomato, apple, citrus, grape, rape,
Soybean etc..
Through applicant test find compound (E) -2- (ethylmercapto group) -5- (4- fluorostyryls) -1,3,4- oxadiazoles with
Both betacyfluthrins are used in compounding has unexpected collaboration preventive effect to Meloidogyne incognita and wild cabbage diamondback moth.Shen
Ask someone by retrieval, the prior art has no compound (E) -2- (ethylmercapto group) -5- (4- fluorostyryls) -1,3,4- oxadiazoles with
The report that betacyfluthrin is applied in combination.For this purpose, applicant proposes the application, i.e., by compound (E) -2- (ethylmercapto group) -
5- (4- fluorostyryls) -1,3,4- oxadiazoles and betacyfluthrin compound, and by verification experimental verification its to southern root
The compounding of the control effect of tie lines worm and wild cabbage diamondback moth, both test result displays has unexpected insecticidal activity.
Invention content
The purpose of the present invention is to provide a kind of Pesticidal combinations that can prevent the pest on vegetables, including compound
(E) -2- (ethylmercapto group) -5- (4- fluorostyryls) -1,3,4- oxadiazoles (calling compound 1 in the following text) and betacyfluthrin.Two
The weight ratio of person is 1:20-40:In 1 range, preferably 1:10-20:1, further preferably 1:5-10:1, more preferable 1:2.5-
5:1。
A kind of Pesticidal combination containing compound 1 and betacyfluthrin of the present invention is according to the art skill
The dosage form that method well known to art personnel can be prepared is granule, suspending agent, water dispersible granules, aqueous emulsion, wettable powder
Equal regular dosage forms.
To granule, workable auxiliary agent includes:Carrier such as clay, kaolin, talcum, calcium carbonate, cornstarch, silicic acid
It is one or more in aluminium;It is one or more in dispersant such as polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate;Profit
It is one or more in humectant such as alkyl sulfate, alkylsulfonate, naphthalene sulfonate;Adhesive such as polyvinyl alcohol, dextrin, poly- second
It is one or more in alkene pyrrolidone.
To suspending agent, workable auxiliary agent includes:Dispersant for example polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate,
It is one or more in TERSPERSE 2020 (Huntsman Corporation of U.S. product);Emulsifier such as Nongru-700 # (common names:Alkyl phenol
Formaldehyde resin polyoxyethylene ether), agriculture breast 2201, this (common name of disk -60:Span60), Tween-60 it is (general
Name:Polyoxyethylene sorbitan stearate), agriculture breast 1601# (common names:Triphenoethyl benzene phenol polyoxyethylene polyoxypropylene
Block polymer), it is one or more in TERSPERSE 4894 (Huntsman Corporation of U.S. product);Wetting agent such as alkyl phenol is poly-
Oxyethylene group ether formaldehyde condensation products sulfate, alkylphenol-polyethenoxy base ether phosphate, phenethyl phenol polyoxyethylene groups ether phosphoric acid
In ester, alkyl sulfate, alkylsulfonate, naphthalene sulfonate, TERSPERSE 2500 (Huntsman Corporation of U.S. product) it is a kind of or
It is a variety of;It is one or more in thickener such as xanthans, polyvinyl alcohol, bentonite, aluminium-magnesium silicate;Preservative for example formaldehyde, benzoic acid,
It is one or more in sodium benzoate;It is one or more in stabilizer such as epoxidized soybean oil, epoxychloropropane, triphenyl phosphate;Disappear
Infusion such as organic silicon antifoaming agent;In antifreezing agent such as ethylene glycol, propylene glycol, glycerine, urea, inorganic salts such as sodium chloride it is a kind of or
It is a variety of;Water is deionized water.
To water dispersible granules, workable auxiliary agent includes:Dispersant such as polycarboxylate (TERSPERSE 2700), lignin
It is one or more in sulfonate, alkylnaphthalene sulfonate;In wetting agent such as alkyl sulfate, alkylsulfonate, naphthalene sulfonate
It is one or more;It is disintegrant such as ammonium sulfate, sodium sulphate, polyvinylpyrrolidone, starch and its derivative (such as modified starch), swollen
It is one or more in profit soil;Binder such as starch, glucose, polyvinyl alcohol, polyethylene glycol, sodium carboxymethylcellulose, sucrose
In it is one or more;In filler such as diatomite, kaolin, white carbon, precipitated calcium carbonate, talcum powder, attapulgite, clay
It is one or more.
To aqueous emulsion, workable auxiliary agent includes:Emulsifier such as Nonyl pheno (EO=10) ether phosphate, triphen
Ethyl -phenol polyoxyethylene ether phosphate, Nongru-700 # (common names:Alkyl phenol formaldehyde resin polyoxyethylene ether), agriculture breast 2201#,
This disk -60# (common names:Span60), Tween-60 # (common names:Polyoxyethylene sorbitan stearic acid
Ester), TX-10 (common names:Octylphenol polyethylene ethylene oxide (10) ether), 1601 (common name of agriculture breast:Triphenoethyl benzene phenol polyoxypropylene is poly-
Ethylene oxide block polymer), it is agriculture breast 600#, one or more in agriculture breast 400#;Solvent such as dimethylbenzene, toluene, cyclohexanone, solvent
Oily (the trade mark:S-150, S-180, S-200) it is one or more;Stabilizer such as triphenyl phosphite, epoxychloropropane, epoxy soybean
It is one or more in oil;Antifreezing agent:It is one or more in ethylene glycol, propylene glycol, glycerine, urea, inorganic salts such as sodium chloride;Increase
It is one or more in thick dose such as xanthans, polyvinyl alcohol, bentonite, aluminium-magnesium silicate;Preservative such as formaldehyde, benzoic acid, benzoic acid
One or more in sodium, water is deionized water.
To wettable powder, workable auxiliary agent includes:Dispersant such as polycarboxylic acid salt (TERSPERSE 2700, T36,
GY-D06 etc.), lignin sulfonate (Ufoxane 3A, Borresperse NA, Borresperse CA-SA etc.), naphthalene and
Alkyl naphthalene formaldehyde condensate sulfonate class (NNO, MF, Morwet D-425, Tamol NN, TERSPERSE2020 etc.), pull open powder
BX (nekal), EO-PO block polyethers class, alkylphenol-polyethenoxy base ether phosphate, alkylphenol-polyethenoxy base
Ether formaldehyde condensation products sulfate (SOPA), in it is one or more;Wetting agent such as Sulfates (K-12), Sulfonates (ABS-Na,
BX, Terwet 1004 etc.), it is one or more in compound wetting agent (Morwet EFW);Filler such as diatomite, kaolin, light
Calcium, talcum powder, white carbon, attapulgite, clay, ammonium sulfate, urea, sucrose, glucose, cornstarch, sodium sulphate, poly phosphorus
Sour sodium etc. is one or more.
Applicant's premenstruum (premenstrua) tests discovery, the composition of the present invention containing compound 1 and betacyfluthrin,
It is notable to Meloidogyne incognita and wild cabbage diamondback moth preventive effect, it is good to vegetable safeties such as tomato, wild cabbage, rapes without poisoning, meet
The security requirement of pesticidal preparations.It is limited by length, specifiable embodiment is as follows, but is not restricted to this.
Specific implementation mode
(1) Toxicity Determination is tested
It is small to Meloidogyne incognita and wild cabbage by Toxicity Determination research compound 1 and betacyfluthrin compounding
The control effect of diamond-back moth.
1, for the Toxicity Determination of Meloidogyne incognita.
Experiment uses Meloidogyne incognita (Meloidogyne spp.) for test object, high with compound 1 and efficient fluorine
It imitates cyfloxylate compounding and carries out Toxicity Determination.Test method:With reference to《NY/T1833.1-2009 pesticide indoor biologicals are surveyed
Determine test rule nematicide part 1 and inhibits plant pathogeny line insect experiment dip method》.
According to survey data, the death rate and corrected mortality of each processing are calculated, unit is percentage (%), according to formula
Calculate the death rate and corrected mortality.According to drug concentration logarithm and the probability of the corrected mortality of corresponding target
Value does regression analysis, calculates the LC of each medicament50, evaluate after two kinds of composite reagents to the activity of nematode.Simultaneously according to Sun Yunpei's Method
Co-toxicity coefficient method (CTC) evaluate the synergistic effect of pharmacy mix, i.e. CTC≤80, composition shows as antagonism, when 80
<CTC<120, composition shows as summation action, and when CTC >=120, composition shows as synergistic effect.
1 compound 1 of table combines the The Toxicity Determination result to Meloidogyne incognita with efficient fluorine betacyfluthrin
The Toxicity Determination result shows:Compound 1 is with efficient fluorine betacyfluthrin in weight ratio 1:20-40:1 model
Enclose interior compounding has preferable virulence to Meloidogyne incognita, with weight ratio 1:5-10:The synergy that compounding obtains in 1 range is more
To be notable, especially weight ratio is 1:1-5:In 1 range, synergy is the most notable.
2, for the Toxicity Determination of wild cabbage diamondback moth.
Controlling object:Wild cabbage diamondback moth (Plutellaxylostella (L.)), test method:With reference to《The Chinese people are total
With state agricultural industry criteria NY/T1154.2-2006》.
First by single dose and each Mixed Pharmacy be arranged 5 various concentration gradients (on the basis of pilot study result, wild cabbage
The diamondback moth death rate is set in the range of 5%~90% by geometric progression).Test worm is the diamondback moth of indoor raising, is being tested
Age uniform diamondback moth is selected in room, 4~8 hours hungry, is beaten with 1 centimetre of card punch of diameter and takes leaf dish, is put into culture
Ware, and pay attention to moisturizing.With capillary dropper since low concentration, drip the 1 μ L liquids of μ L~2 per leaf dish point, waits for that solvent volatilizees
The malicious leaf dish of folder is made in the leaf dish pairing for being coated with gelatinized corn starch with another afterwards, and making, which finishes, to be put in the hole of 12 hole tissue culturing plates.
4 repetitions are often handled, often repeat the malicious leaf dish of no less than 12 folders, and set the processing conduct of the corresponding organic solvent without medicament
Control.1 test worm is inscribed in each hole of tissue culturing plate, is placed under normal condition and cultivates.After connecing worm 2~4 hours, test worm feeding is waited for
After complete drug containing leaf dish, clean feeds are added in cultivation plate hole and continue raising to investigating, eliminates and has not eaten complete leaf dish
Test worm checks dead borer population for 48 hours, calculates the death rate.It is for statistical analysis with DPS data processor softwares, calculate each medicament
LC50The co-toxicity coefficient (CTC) of value and mixture evaluates activity of the reagent agent to test worm with this.
2 compound 1 of table combines the The Toxicity Determination result to wild cabbage diamondback moth with betacyfluthrin
The Toxicity Determination result shows:Compound 1 is with betacyfluthrin in weight ratio 1:20-40:It is multiple in 1 range
Pairing wild cabbage diamondback moth has preferable virulence, with weight ratio 1:10-10:The synergy that compounding obtains in 1 range is more notable.
(2) example of formulations
Percentage in formula is weight percentage.
1. example of formulations 1
Weigh 15% compound 1,2% betacyfluthrin, 7% Negel, 4% sodium naphthalene sulfonate, 5% paste
Essence, talcum powder add to 100% parts by weight.Above-mentioned raw materials are uniformly mixed in a stirring kettle, by extruding, granulation, drying, and through sieve
17% compound, 1 betacyfluthrin granule is made step by step.
2. example of formulations 2
Weigh 12% compound 1,3% betacyfluthrin, 5.5% sodium lignin sulfonate, 3% sodium alkyl sulfonate, 2%
Polyvinylpyrrolidone, kaolin add to 100% parts by weight.Above-mentioned raw materials are uniformly mixed in a stirring kettle, by squeezing, making
Grain, drying, and 15% compound, 1 betacyfluthrin granule is made in screened step.
3. example of formulations 3
Weigh 5% compound 1,5% betacyfluthrin, 3% agriculture breast 2201,3% phenethyl phenol polyoxyethylene ether
Phosphate, 3% sodium lignin sulfonate, 3% bentonite, 1.5% xanthans, 1.5% urea, 1.2% benzoic acid, 1% organosilicon
Antifoaming agent, deionized water add to 100%.Above-mentioned raw materials disperse 30min through mixing, high speed shear, are made after being sanded with sand mill
10% compound, 1 betacyfluthrin suspending agent.
4. example of formulations 4
Weigh 10% compound 1,3% betacyfluthrin, 4% alkylphenol-polyethenoxy base ether sulfonic acid calcium, 3% alkyl
Naphthalenesulfonate formaldehyde condensation compound, 3% Negel, talcum powder are filled up to 100%.Above-mentioned raw materials are through mixing, ultra micro air-flow
It crushes, hybrid technique step is prepared into 13% compound, 1 betacyfluthrin wettable powder.
5. example of formulations 5
Weigh 8% compound 1,5% betacyfluthrin, 7% polycarboxylate (GY-D06, Huntsman Corporation of the U.S.),
2% sodium lignin sulfonate, 1% lauryl sodium sulfate, 3% alkylsulfonate sodium, talcum powder add to 100%.Above-mentioned raw materials pass through
The method that routine produces water dispersible granules mixes, ultra micro air-flow crushing, mixing, that granulation step produces 13% compound 1 is high
Imitate cyfloxylate water dispersible granules.
6. example of formulations 6
Weigh 6% compound 1,6% betacyfluthrin, 5% Nonyl pheno (EO=10) ether phosphate,
1% Nongru-700 #, 2% agriculture breast 1601,3% Tween-60 #, 1.5% epoxidized soybean oil, 2.5% glycerine, 3% cyclohexanone, 0.5%
Bentonite, 0.3% sodium benzoate, deionized water add to 100%.Through mixing, high speed shearing emulsification is made 12% and changes above-mentioned raw materials
Close 1 betacyfluthrin aqueous emulsion of object.
(3) field control effectiveness test
1, to Meloidogyne incognita field control effectiveness test
Inventor has carried out (17% compound, the 1 efficient cyfluthrin of example of formulations 1 in 2017 in Shouguang City of Shandong Province
Pyrethroids granule), example of formulations 2 (15% compound, 1 betacyfluthrin granule) prevention Meloidogyne incognita field
Between the test of pesticide effectiveness, demonstrate control effect of the medicament to Meloidogyne incognita and the safety to tomato.
Trial crops are tomato, and controlling object is root-knot nematode, experimental field flat, and nematode worm amount is big.Experiment using mispickel/
Native broadcast application, each processing are repeated 4 times, cell random alignment, per cell 15m2, totally 32 cells.
Investigation method:Aggrieved suspicious diseased plant is found, is sampled for 5 points using diagonal line, every 2 plants of investigation, calculating incidence,
Disease index and control effect.
Diseased plant stage division:
0 grade:Root system is without insect gall;
1 grade:Root system has a small amount of small insect gall;
3 grades:2/3rds root systems are covered with small insect gall;
5 grades:Root system is covered with small insect gall and has secondary insect gall;
7 grades:Root system forms fibrous root group.
Table 3 prevents the field test results of Meloidogyne incognita
Table of field test results are bright, example of formulations 1 (17% compound, 1 betacyfluthrin granule) and preparation
Embodiment 2 (15% compound, 1 betacyfluthrin granule) has a good control effect to Meloidogyne incognita, after medicine
15 days preventive effects are higher than 70%, hence it is evident that are better than 10% compound, 1 granule and 2.5% betacyfluthrin missible oil.Experiment institute
There is processing without obvious harmful effects to the growth of tomato, tomato fruit and yield are normal.
2, to the field efficiency test of wild cabbage diamondback moth.
Inventor has carried out prevention wild cabbage diamondback moth field control effectiveness test in 2017 in Shouguang City of Shandong Province, demonstrates this
Medicament is to the control effect of wild cabbage diamondback moth and to (13% compound, the 1 betacyfluthrin water-dispersible grain of sweet formulation examples 5
Agent), the safety of example of formulations 6 (12% compound, 1 betacyfluthrin aqueous emulsion) indigo plant.
Trial crops are wild cabbage, and controlling object is diamondback moth.Experimental field soil be sandy loam, middle fertility, each cell
Cultivation condition, water and fertilizer management uniformity.Test medicine and dosage refer to table 4.It it is 40L/ mus with liquid volume, using hand spray
Device uniformly sprays, it is desirable that each cell cabbage leaves uniformly medicine.Blank control separately is set, often handles 4 repetitions, per plot area 28
㎡, totally 32 cells, random district's groups arrange.Insect population is investigated before dispenser, investigates survival insect population number, root respectively within 7,15 days after medicine
Control effect is calculated according to following formula.
Insect population × 100 before Revision insect recluced rate (%)=(borer population living after insect population-medicine before medicine)/medicine
Control effect (%)=(treatment region Revision insect recluced rate-clear area Revision insect recluced rate)/(clear areas 100- insect population declines
Rate) × 100
Table 4 prevents wild cabbage diamondback moth field test results
Table of field test results are bright, formulation examples 5 (13% compound, 1 betacyfluthrin water dispersible granules), system
Agent embodiment 6 (12% compound, 1 betacyfluthrin aqueous emulsion) has a good control effect to wild cabbage diamondback moth, after medicine
15 days preventive effects are above 90%, hence it is evident that are better than 10% compound, 1 granule and 2.5% betacyfluthrin missible oil.To sweet
Blue security survey is observed daily after spray, and wild cabbage occurs without poisoning phenomenon for each test process.Compared with check plot, place
It manages region wild cabbage yield and is higher than control zone.
In conclusion the composition of the present invention is to use two kinds of active components compound scheme, insecticidal activity is not each group
Active simple superposition is divided other than there is significant insecticidal effect, more to there is significant synergy compared with existing single formulation
Effect, safety is good to making, and meets the security requirement of pesticidal preparations.
Claims (9)
1. a kind of Pesticidal combination including efficient fluorine betacyfluthrin, it is characterised in that:The composition includes following formula
Shown in styryl 1,3,4- oxadiazoles thio-ether type compounds 1
With efficient fluorine betacyfluthrin.
2. Pesticidal combination as described in claim 1, it is characterised in that:The weight ratio of compound 1 and betacyfluthrin
Range is 1:20-40:1.
3. Pesticidal combination as described in claim 1, it is characterised in that:The weight ratio of compound 1 and betacyfluthrin
Range is 1:10-20:1.
4. Pesticidal combination as described in claim 1, it is characterised in that:The weight ratio of compound 1 and betacyfluthrin
Range is preferably 1:5-10:1, more preferable 1:2.5-5:1.
5. a kind of Pesticidal combination preparation comprising betacyfluthrin, it is characterised in that:Including any one of claim 1-4
The Pesticidal combination and agriculturally acceptable auxiliary agent.
6. preparation as claimed in claim 5, it is characterised in that:The dosage form of the preparation is selected from granule, suspending agent, water and milk
Agent, wettable powder or water dispersible granules.
7. purposes of the claim 1-4 any one of them Pesticidal combination in terms of preventing vegetables underground and aboveground pest.
8. use of the claim 5-6 any one of them Pesticidal combination preparations in terms of preventing vegetables underground and aboveground pest
On the way.
9. purposes as claimed in claim 7 or 8, it is characterised in that the pest includes nematode and diamondback moth.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810287438.0A CN108432795A (en) | 2018-04-02 | 2018-04-02 | A kind of Pesticidal combination containing betacyfluthrin |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810287438.0A CN108432795A (en) | 2018-04-02 | 2018-04-02 | A kind of Pesticidal combination containing betacyfluthrin |
Publications (1)
Publication Number | Publication Date |
---|---|
CN108432795A true CN108432795A (en) | 2018-08-24 |
Family
ID=63198951
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810287438.0A Pending CN108432795A (en) | 2018-04-02 | 2018-04-02 | A kind of Pesticidal combination containing betacyfluthrin |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN108432795A (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106674147A (en) * | 2016-12-28 | 2017-05-17 | 贵州大学 | Styryl-containing 1,3,4-oxadiazole thioether compound, as well as preparation method and application thereof |
-
2018
- 2018-04-02 CN CN201810287438.0A patent/CN108432795A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106674147A (en) * | 2016-12-28 | 2017-05-17 | 贵州大学 | Styryl-containing 1,3,4-oxadiazole thioether compound, as well as preparation method and application thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101297649B (en) | Insecticidal composition containing pymetrozine | |
CN103548879B (en) | Insecticidal composition containing pyriminostrobin | |
CN102771510B (en) | Insecticidal composition containing fosthiazate | |
CN102228038A (en) | Insecticidal sterilizing corn seed coating agent containing fipronil | |
CN102487952A (en) | Insecticidal composition containing cycloxaprid and biological insecticide | |
CN105724389A (en) | Dispersible oil suspension containing chlorantraniliprole | |
CN102763664B (en) | Insecticide composite containing spirodiclofen and bifenazate | |
CN101743981A (en) | Insecticidal composite with paichongding and ethofenprox | |
CN103493831A (en) | Insecticide composition with insecticides of pyriminostrobin and tetronic acid | |
CN103283770B (en) | Insecticidal composition containing cycolxylidin and metaflumizone | |
CN109221230A (en) | A kind of insecticide composition containing double third ring worm esters and imidaclothiz | |
CN101642107B (en) | Insect-killing composition containing pymetrozine and etofenprox | |
CN101473828B (en) | Agricultural chemical composition for disinsection and use thereof | |
CN108432795A (en) | A kind of Pesticidal combination containing betacyfluthrin | |
CN104814031B (en) | A kind of Pesticidal combination containing butene-fipronil and clothianidin | |
CN102696603A (en) | Insecticidal composition containing spinetoram | |
CN108432794A (en) | Composition for vegetables underground and aboveground insect-pest exterminating | |
CN102657189B (en) | Pesticide composition containing cycloxaprid | |
CN102771512B (en) | Insecticidal composition containing fosthiazate and pyridaben | |
CN101779663A (en) | Disinfestation composition containing paichongding (IPP) and chlorpyrifos | |
CN108323522A (en) | A kind of novel Pesticidal combination | |
CN101755773B (en) | Pesticidal combination containing IPP and buprofezin | |
CN101632384B (en) | Insecticidal composition containing bifenthrin and triazophos | |
CN108576023A (en) | The composition of Bao Han oxadiazole thio-ether type compounds | |
CN105613562B (en) | A kind of agricultural pesticide composition and application thereof containing sulphur insect amide and dinotefuran |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180824 |
|
RJ01 | Rejection of invention patent application after publication |