CN108428523A - GIS insulator design methods with the distribution of two-dimentional dielectric constant linear gradient - Google Patents

GIS insulator design methods with the distribution of two-dimentional dielectric constant linear gradient Download PDF

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Publication number
CN108428523A
CN108428523A CN201810217668.XA CN201810217668A CN108428523A CN 108428523 A CN108428523 A CN 108428523A CN 201810217668 A CN201810217668 A CN 201810217668A CN 108428523 A CN108428523 A CN 108428523A
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dielectric constant
epoxy resin
constant linear
linear gradient
distribution
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CN108428523B (en
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杜伯学
王泽华
李进
冉昭玉
梁虎成
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Tianjin University
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Tianjin University
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B19/00Apparatus or processes specially adapted for manufacturing insulators or insulating bodies
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B19/00Apparatus or processes specially adapted for manufacturing insulators or insulating bodies
    • H01B19/04Treating the surfaces, e.g. applying coatings
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02GINSTALLATION OF ELECTRIC CABLES OR LINES, OR OF COMBINED OPTICAL AND ELECTRIC CABLES OR LINES
    • H02G5/00Installations of bus-bars
    • H02G5/06Totally-enclosed installations, e.g. in metal casings
    • H02G5/066Devices for maintaining distance between conductor and enclosure
    • H02G5/068Devices for maintaining distance between conductor and enclosure being part of the junction between two enclosures

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  • Insulating Bodies (AREA)
  • Epoxy Resins (AREA)
  • Organic Insulating Materials (AREA)

Abstract

The present invention discloses a kind of GIS insulator design methods with two-dimentional dielectric constant linear gradient distribution, and key step includes:First prepare epoxide resin material;Secondly staged curing processing;Then, gradient design is carried out to epoxy resin disc insulator:Its surface is divided into five closely coupled annulars from inside to outside, the relative dielectric constant of annular is enabled to be sequentially reduced;Epoxy resin disc insulator is positioned in magnetron sputtering apparatus, sputters different time in different location according to dull distribution gradient, time range is 0min 60min, obtains the disc insulator of two-dimensional gradient distribution.The present invention achievees the purpose that internal field is excessively high and promotes insulation system electric durability energy under alleviation alternating voltage;There are important theory value and engineering significance to improving the operation stability of GIS and the safety of electric system.

Description

GIS insulator design methods with the distribution of two-dimentional dielectric constant linear gradient
Technical field
Modified polymeric material and its preparation field in being manufactured the invention belongs to high voltage installation are related to a kind of with two dimension Jie The GIS insulator design methods of electric constant linear gradient distribution, and in particular to one kind having two-dimentional dielectric constant linear gradient point The GIS epoxy resin insulator design methods of cloth.
Background technology
In recent years, with electric system high voltage, the growth requirement of large capacity transmission, gas-insulated metal enclosed switchgear is set Standby (GIS) and gas-insulated metal closed power transmission line (GIL) are excellent because its transmission capacity is big, floor space is small, reliability is high etc. Point has obtained extensive concern and application.Wherein, disc insulator not only plays the role of mechanical support, but also as electric insulation Body plays conclusive key effect to the safe and stable operation of entire GIS, GIL.However, even if harsh in quality In 1000kV AC extra high voltage engineerings, epoxy casting class insulator remains unchanged Frequent Troubles.
It is generally believed that it is to lead to insulation breakdown, the basic reason of electric durability energy difference that non-uniform electric degree is higher.Not With interface such as metallic conductor, insulator and the SF of medium6At three binding site of gas, due to the change dramatically of dielectric parameter, Make non-uniform electric, internal field's distortion is serious, leads to the generation of shelf depreciation.On the one hand aggravation insulation ag(e)ing, separately On the one hand cause flashover, reduce the electric durability energy of insulation.Currently, in order to promote the electric durability energy of insulation, frequently with optimization electrode Or the method for insulation system shape, it such as adds grading ring, shielding case and improves insulator shape.Although field distribution is changed It is kind, but insulation system is more complicated, and effect is limited.
Functionally graded material (FunctionallyGradedMaterial, the FGM) concept in materialogy field is applied to Electric insulation field carries out the field distribution under exchange by building the insulation system of relative dielectric constant non-uniform Distribution Regulation and control alleviate the excessively high purpose of internal field to promote field distribution uniform.Japan Nagoya university Okubo teaches team Manufacturing technology is centrifuged by inorganic filler, constructs the composite material FGM insulators that contour structures are round platform and dish-type, research hair Maximum field intensity effectively reduces at existing three binding sites, and flashover voltage is significantly improved.However this technological controllability difference and shadow The factor of sound is complicated, it is difficult to high-volume manufacture epoxy insulation.Magnetron sputtering method is applied to epoxy resin primary surface, passes through control Target type, sputtering time, sputtering power etc. construct two dimension FGM insulators, have many advantages, such as easy to operate, easily controllable, are The manufacture of FGM insulators provides completely new approach.
Invention content
It is an object of the invention to overcome the deficiencies of the prior art and provide one kind having two-dimentional dielectric constant linear gradient point The GIS insulator design methods of cloth, by sputtering the two-dimensional gradient that different time forms dielectric constant in epoxy resin primary surface Distribution promotes insulator electric durability energy to regulate and control the distribution of its surface field.
The present invention constructs the insulator with two-dimentional dielectric constant gradient distribution by controlling sputtering time, and then flexibly Regulate and control the field distribution on Spacer Under AC Voltage surface, improves the electric durability energy of GIS insulators.
The present invention is to solve the technical solution that its technical problem proposes to be:With the distribution of two-dimentional dielectric constant linear gradient GIS insulator design methods, this method comprises the following steps:
1) epoxide resin material is prepared:
(1) by epoxy resin-matrix, curing agent and aluminium oxide according to 100:38:330 proportionings are added blending tank and obtain asphalt mixtures modified by epoxy resin Fat mixing material, 130 DEG C of temperature;
(2) motor stirs 0.5 hour, one hour of vacuum outgas under the vacuum degree of -0.1MPa;
(3) step (2) epoxy resin mixing material is poured into preheated treated mold:Preheating temperature 130 DEG C, it is not less than 1 hour;
2) it is handled using staged curing method, solidification process is divided into two steps:
(1) mold is first put into oven and carries out one-step solidification at 130 DEG C 8 hours, then demoulded;
(2) product after demoulding is put into oven and carries out secondary curing at 130 DEG C 8 hours, can be obtained epoxy after cooling Resin disc insulator;
3) gradient design is carried out to epoxy resin disc insulator:
(1) its surface is divided into five closely coupled annulars from inside to outside, the relative dielectric constant of annular is enabled to subtract successively It is small;
(2) epoxy resin disc insulator is positioned in magnetron sputtering apparatus, according to dull distribution gradient in different positions Sputtering different time is set, time range 0min-60min obtains the disc insulator of two-dimensional gradient distribution.
Sputter different time in different location according to dull distribution gradient in (2) step by step in the step 3), by it is interior to Outer sputtering time is respectively 60min, 45min, 30min, 15min, 0min.
Sputter different time in different location according to dull distribution gradient in (2) step by step in the step 3), by it is interior to Outer sputtering time is respectively 40min, 30min, 20min, 10min, 0min.
Sputter different time in different location according to dull distribution gradient in (2) step by step in the step 3), by it is interior to Outer sputtering time is respectively 20min, 15min, 10min, 5min, 0min.
The radio-frequency voltage in (2) in sputtering process is 650V, electric current 120mA step by step in the step 3).
(2) sputter under argon atmosphere and carry out step by step in the step 3), and argon gas flow velocity is 50-60SCCM.
The graceful board CT5531 of the preferred imported from America Hensel of step 1) epoxy resin base.
The preferred HY5533 of curing agent in the step 1).
The preferred TiO of target that magnetron sputtering uses in (2) step by step in the step 3)2
Advantageous effect
The present invention uses for reference the theory of absorption function functionally gradient material (FGM) (FGM), innovatively uses the method for magnetron sputtering will be high Dielectric constant inorganic matter TiO2、BaTiO3Etc. being sputtered onto epoxy resin primary surface, and passes through control and sputter duration and form epoxy resin The two-dimensional gradient of surface dielectric constant is distributed, and builds surface dielectric functionally graded material, and then is reached and alleviated office under alternating voltage Portion's electric field is excessively high and promotes the purpose of insulation system electric durability energy.
The present invention has important theory value and engineering to improving the operation stability of GIS and the safety of electric system Meaning.
Description of the drawings
Fig. 1 is the epoxy resin disc insulator with two-dimentional dielectric constant linear gradient distribution of design of Simulation.
Specific implementation mode
Below by specific embodiments and the drawings, the present invention is further illustrated.The embodiment of the present invention is in order to more So that those skilled in the art is more fully understood the present invention well, any limitation is not made to the present invention.
The mould material for the disc insulator that the present invention uses be the graceful board CT5531 epoxy resin of imported from America Hensel and HY5533 curing agent;The target that the two-dimensional linear gradient distribution of epoxy resin-matrix and magnetron sputtering use is realized by magnetron sputtering method Material includes but not limited to TiO2、BaTiO3, provided by middle promise green wood (Beijing) Science and Technology Ltd.;Magnetron sputtering corollary apparatus is DK-92L types power control cabinet and BILON-T-5001 type sub-cooled circulator;The type of two-dimensional gradient distribution is linear monotonic point Cloth.
Motor of the present invention stirs 0.5 hour, one hour of vacuum outgas under the vacuum degree of -0.1MPa;Preheating temperature is 130 DEG C, it is not less than 1 hour;The one-step solidification time is 8 hours, and the secondary curing time is 8 hours.
Embodiment 1
1) by epoxy resin-matrix, curing agent and aluminium oxide according to 100:38:Blending tank, 130 DEG C of temperature is added in 330 proportionings; Open motor stirring, vacuum outgas;Preheated treated mold is pushed into pouring can, carries out evacuation processing;By what is mixed Epoxy resin mixing material is poured by casting equipment in mold.
2) epoxy resin is handled using staged curing method, and solidification process is divided into two steps:First the mold after vacuum processing is put Enter oven and carry out one-step solidification, then demoulds;It is placed again into oven and carries out secondary curing, can be obtained epoxy resin basin after cooling Formula insulator.
3) design that gradient is carried out to epoxy resin disc insulator, i.e., be divided into five close phases from inside to outside by its surface Annular even enables the relative dielectric constant of annular be sequentially reduced:
Epoxy resin disc insulator is positioned in magnetron sputtering apparatus, is splashed in different location according to dull distribution gradient Different time is penetrated, sputtering time is respectively 60min, 45min, 30min, 15min, 0min from inside to outside, you can obtain two-dimentional ladder Spend the disc insulator of distribution.
Radio-frequency voltage in sputtering process is 650V, electric current 120mA;It sputters under argon atmosphere and carries out, argon gas flow velocity For 50-60SCCM.
Embodiment 2
1) by epoxy resin-matrix, curing agent and aluminium oxide according to 100:38:Blending tank, 130 DEG C of temperature is added in 330 proportionings; Open motor stirring, vacuum outgas;Preheated treated mold is pushed into pouring can, carries out evacuation processing;By what is mixed Epoxy resin mixing material is poured by casting equipment in mold.
2) epoxy resin is handled using staged curing method, and solidification process is divided into two steps, first puts the mold after vacuum processing Enter oven and carry out one-step solidification, then demoulds;It is placed again into oven and carries out secondary curing, can be obtained epoxy resin basin after cooling Formula insulator.
3) design that gradient is carried out to epoxy resin disc insulator, i.e., be divided into five close phases from inside to outside by its surface Annular even enables the relative dielectric constant of annular be sequentially reduced:
Epoxy resin disc insulator is positioned in magnetron sputtering apparatus, is splashed in different location according to dull distribution gradient Different time is penetrated, sputtering time is respectively 40min, 30min, 20min, 10min, 0min from inside to outside, you can obtain two-dimentional ladder Spend the disc insulator of distribution.
Radio-frequency voltage in sputtering process is 650V, electric current 120mA;It sputters under argon atmosphere and carries out, argon gas flow velocity For 50-60SCCM.
Embodiment 3
1) by epoxy resin-matrix, curing agent and aluminium oxide according to 100:38:330 proportioning addition blending tanks, 130 DEG C of temperature, Open motor stirring, vacuum outgas;Preheated treated mold is pushed into pouring can, carries out evacuation processing;By what is mixed Epoxy resin mixing material is poured by casting equipment in mold.
2) epoxy resin is handled using staged curing method, and solidification process is divided into two steps:First the mold after vacuum processing is put Enter oven and carry out one-step solidification, then demould, is placed again into oven and carries out secondary curing, can be obtained epoxy resin basin after cooling Formula insulator.
3) design that gradient is carried out to epoxy resin disc insulator, i.e., be divided into five close phases from inside to outside by its surface Annular even enables the relative dielectric constant of annular be sequentially reduced:
Epoxy resin disc insulator is positioned in magnetron sputtering apparatus, is splashed in different location according to dull distribution gradient Different time is penetrated, sputtering time is respectively 20min, 15min, 10min, 5min, 0min from inside to outside, you can obtains two-dimensional gradient The disc insulator of distribution.
Radio-frequency voltage in sputtering process is 650V, electric current 120mA;It sputters under argon atmosphere and carries out, argon gas flow velocity For 50-60SCCM.
Fig. 1 is the epoxy resin disc insulator with two-dimentional dielectric constant linear gradient distribution of design of Simulation, by scheming As it can be seen that being successively increased along relative dielectric constant of its surface from ground terminal to high-pressure side, the disc insulator with pure epoxy resin Compare, the design of two-dimensional gradient reduces the field strength at three binding site of high-pressure side so that disc insulator along face field distribution More uniformly, to improve the electric durability energy of insulation system.

Claims (9)

1. the GIS insulator design methods with two-dimentional dielectric constant linear gradient distribution, which is characterized in that this method includes such as Lower step:
1) epoxide resin material is prepared:
(1) by epoxy resin-matrix, curing agent and aluminium oxide according to 100:38:It is mixed that 330 proportioning addition blending tanks obtain epoxy resin Condensation material, 130 DEG C of temperature;
(2) motor stirs 0.5 hour, one hour of vacuum outgas under the vacuum degree of -0.1MPa;
(3) step (2) epoxy resin mixing material is poured into preheated treated mold:Preheating temperature is 130 DEG C, Not less than 1 hour;
2) it is handled using staged curing method, solidification process is divided into two steps:
(1) mold is first put into oven and carries out one-step solidification at 130 DEG C 8 hours, then demoulded;
(2) product after demoulding is put into oven and carries out secondary curing at 130 DEG C 8 hours, can be obtained epoxy resin after cooling Disc insulator;
3) gradient design is carried out to epoxy resin disc insulator:
(1) its surface is divided into five closely coupled annulars from inside to outside, the relative dielectric constant of annular is enabled to be sequentially reduced;
(2) epoxy resin disc insulator is positioned in magnetron sputtering apparatus, is splashed in different location according to dull distribution gradient Different time is penetrated, time range 0min-60min obtains the disc insulator of two-dimensional gradient distribution.
2. the GIS insulator design methods with two-dimentional dielectric constant linear gradient distribution according to claim 1, special Sign is, sputters different time in different location according to dull distribution gradient in (2) step by step in the step 3), from inside to outside Sputtering time is respectively 60min, 45min, 30min, 15min, 0min.
3. the GIS insulator design methods with two-dimentional dielectric constant linear gradient distribution according to claim 1, special Sign is, sputters different time in different location according to dull distribution gradient in (2) step by step in the step 3), from inside to outside Sputtering time is respectively 40min, 30min, 20min, 10min, 0min.
4. the GIS insulator design methods with two-dimentional dielectric constant linear gradient distribution according to claim 1, special Sign is, sputters different time in different location according to dull distribution gradient in (2) step by step in the step 3), from inside to outside Sputtering time is respectively 20min, 15min, 10min, 5min, 0min.
5. the GIS insulator design methods with two-dimentional dielectric constant linear gradient distribution according to claim 1, special Sign is, the radio-frequency voltage in the step 3) step by step in (2) in sputtering process is 650V, electric current 120mA.
6. the GIS insulator design methods with two-dimentional dielectric constant linear gradient distribution according to claim 1, special Sign is, (2) sputter under argon atmosphere and carry out step by step in the step 3), and argon gas flow velocity is 50-60SCCM.
7. the GIS insulator design methods with two-dimentional dielectric constant linear gradient distribution according to claim 1, special Sign is, the graceful board CT5531 of the preferred imported from America Hensel of step 1) epoxy resin base.
8. the GIS insulator design methods with two-dimentional dielectric constant linear gradient distribution according to claim 1, special Sign is, the preferred HY5533 of curing agent in the step 1).
9. the GIS insulator design methods with two-dimentional dielectric constant linear gradient distribution according to claim 1, special Sign is, the preferred TiO of target that magnetron sputtering uses in (2) step by step in the step 3)2
CN201810217668.XA 2018-03-16 2018-03-16 GIS insulator design method with two-dimensional dielectric constant linear gradient distribution Expired - Fee Related CN108428523B (en)

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WO2019174425A1 (en) * 2018-03-16 2019-09-19 天津大学 Method for designing gis insulator having two dimensional dielectric constant linear gradient distribution
CN111599554A (en) * 2020-05-28 2020-08-28 天津大学 Electric field optimization method for post insulator for extra-high voltage alternating current GIL
CN111599548A (en) * 2020-05-28 2020-08-28 天津大学 Manufacturing method of flexible interface functional gradient basin-type insulator for extra-high voltage direct current GIL
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WO2019174425A1 (en) * 2018-03-16 2019-09-19 天津大学 Method for designing gis insulator having two dimensional dielectric constant linear gradient distribution
CN109830348A (en) * 2019-01-29 2019-05-31 天津大学 A kind of high voltage direct current disc insulator fast industrialization surface conductivity processing method
CN111599554A (en) * 2020-05-28 2020-08-28 天津大学 Electric field optimization method for post insulator for extra-high voltage alternating current GIL
CN111599548A (en) * 2020-05-28 2020-08-28 天津大学 Manufacturing method of flexible interface functional gradient basin-type insulator for extra-high voltage direct current GIL
CN111599548B (en) * 2020-05-28 2021-10-22 天津大学 Manufacturing method of flexible interface functional gradient basin-type insulator for extra-high voltage alternating current GIL
CN111916265A (en) * 2020-07-28 2020-11-10 南方电网科学研究院有限责任公司 Insulating part and preparation method thereof
CN113470907A (en) * 2021-06-23 2021-10-01 西安交通大学 Method for inhibiting partial discharge at flange of GIS/GIL supporting insulator
CN113470907B (en) * 2021-06-23 2022-07-12 西安交通大学 Method for inhibiting partial discharge at flange of GIS/GIL supporting insulator
CN114709034A (en) * 2022-03-14 2022-07-05 天津大学 GIS/GIL (gas insulated switchgear/gas insulated switchgear) surface electric field regulation and self-diagnosis method based on functional gradient coating

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