CN108424692A - A kind of antibacterial metal antirust glue - Google Patents
A kind of antibacterial metal antirust glue Download PDFInfo
- Publication number
- CN108424692A CN108424692A CN201810279349.1A CN201810279349A CN108424692A CN 108424692 A CN108424692 A CN 108424692A CN 201810279349 A CN201810279349 A CN 201810279349A CN 108424692 A CN108424692 A CN 108424692A
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- CN
- China
- Prior art keywords
- parts
- antibacterial metal
- acetic acid
- metal antirust
- antirust glue
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of antibacterial metal antirust glue, raw material includes：Acrylic resin, epoxy resin, phthaloylamino acetic acid hydramine cerium, acetyl triethyl citrate, four amylalcohol ester of tetrabutyl acetic acid season, antiseptic, antifoaming agent, surfactant, thickener, curing agent.The present invention significantly improves the anti-microbial property of protective film, antirust glue good film-forming property of the invention, strong adhesive force are efficient to the anticorrosion of metal, environmentally protective using N dodecyls bi-quaternary ammonium salt, methylisothiazolinone as antiseptic.
Description
Technical field
The present invention relates to technical field of rust prevention more particularly to a kind of antibacterial metal antirust glue.
Background technology
Chemistry, electrochemistry or physical action occur between metal and surrounding medium residing for it, cause the rotten of metal and
It degenerates, referred to as metal erosion.Two class of dry corrosion and wet corrosion can be divided into according to the environment of corrosion, wherein wet corrosion can be divided into certainly again
The corrosion etc. in corrosion and industrial environment under right environment.For example, the corrosion such as steamer, aircraft carrier, bridge, metallic conduit, rotten
Erosion can cause irreversible destruction and loss to the shape of metal, gloss and mechanical performance, to cause the waste of resource, simultaneously
Also the life security of the mankind is endangered.
Currently, common antirust glue prevents and slow down the generation speed of metal erosion, metal is protected.With society development and
The progress of production, various equipment are higher and higher to corrosion-resistant requirement, not only have good antiseptic property, while also having anti-
Bacterium, heat-resisting, high other performances, traditional antirust glue such as hard, wear-resisting have been unable to meet people's demand.
Invention content
Technical problems based on background technology, the present invention propose a kind of antibacterial metal antirust glue, and film forming is fine and close, attached
Put forth effort by force, anticorrosion is efficient, anti-microbial property is good.
The present invention proposes that a kind of antibacterial metal antirust glue, raw material include by weight：40-60 parts of acrylic resin, ring
20-30 parts of oxygen resin, 12-20 parts of phthaloylamino acetic acid hydramine cerium, 10-18 parts of acetyl triethyl citrate, the tetrabutyl
Acetic acid season 7-14 parts of four amylalcohol ester, 0.5-1.0 parts of antiseptic, 0.5-1 parts of antifoaming agent, 0.4-1 parts of surfactant, thickener
0.5-2 parts, 1-3 parts of curing agent.
Preferably, raw material includes by weight：45-55 parts of polyurethane resin, 24-28 parts of epoxy resin, O-phthalic
14-18 parts of acylamino- acetic acid hydramine cerium, 12-16 parts of acetyl triethyl citrate, the tetrabutyl acetic acid season 9-12 parts of four amylalcohol ester, resist
0.6-0.8 parts of microbial inoculum, 0.7-0.9 parts of antifoaming agent, 0.6-0.8 parts of surfactant, 1-1.5 parts of thickener, curing agent 1.5-2.5
Part.
Preferably, phthaloylamino acetic acid hydramine cerium, acetyl triethyl citrate, four amylalcohol ester of tetrabutyl acetic acid season
Weight ratio be 8：7：5.
Preferably, antiseptic is N- dodecyls bi-quaternary ammonium salt and/or methylisothiazolinone.
Preferably, acrylic resin is water-based acrylic resin.
Preferably, the solid content of water-based acrylic resin is 40-60%.
Preferably, antifoaming agent is polyoxyethylene polyoxypropylene pentaerythrite ether and/or dimethyl silicone polymer.
Preferably, surfactant is fatty glyceride and/or stearic acid.
Preferably, thickener is cellulose ether.
Preferably, curing agent is polyether diamine and/or 2-ethyl-4-methylimidazole.
Phthaloylamino acetic acid hydramine cerium, acetyl triethyl citrate, four amylalcohol of tetrabutyl acetic acid season in the present invention
The high rust resistance of ester, three, which cooperates, forms the antirust system of metal, and adsorbing metal surface forms protective film, prevents water
Divide erosion surface, significantly improves the antiseptic property of metal, and acrylic resin and epoxy resin are as synergistic preservative and dispersion
Medium, film forming height, strong adhesive force, can improve the film forming thickness and compactness of protective film, improve rust-proof effect；The present invention with
N- dodecyls bi-quaternary ammonium salt, methylisothiazolinone are antiseptic, significantly improve the anti-microbial property of protective film；Add in the present invention
Enter suitable antifoaming agent, surfactant, thickener, reduce bubble, increase absorption and the wetting effect of antirust glue and metal, adjusts
The viscosity of whole antirust glue increases system stability.
Specific implementation mode
In the following, technical scheme of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of antibacterial metal antirust glue, raw material include by weight：The water-based acrylic resin 40 that solid content is 40%
Part, 20 parts of epoxy resin, 12 parts of phthaloylamino acetic acid hydramine cerium, 10 parts of acetyl triethyl citrate, tetrabutyl acetic acid
Season 7 parts of four amylalcohol ester, 0.5 part of N- dodecyls bi-quaternary ammonium salt, 0.5 part of polyoxyethylene polyoxypropylene pentaerythrite ether, aliphatic acid
0.4 part of glyceride, 0.5 part of cellulose ether, 1 part of polyether diamine.
Embodiment 2
A kind of antibacterial metal antirust glue, raw material include by weight：The water-based acrylic resin 60 that solid content is 60%
Part, 30 parts of epoxy resin, 20 parts of phthaloylamino acetic acid hydramine cerium, 18 parts of acetyl triethyl citrate, tetrabutyl acetic acid
Season 14 parts of four amylalcohol ester, 1.0 parts of methylisothiazolinone, 1 part of dimethyl silicone polymer, 1 part of stearic acid, 2 parts of cellulose ether, 2-
3 parts of ethyl -4-methylimidazole.
Embodiment 3
A kind of antibacterial metal antirust glue, raw material include by weight：The water-based acrylic resin 50 that solid content is 50%
Part, 25 parts of epoxy resin, 16 parts of phthaloylamino acetic acid hydramine cerium, 14 parts of acetyl triethyl citrate, tetrabutyl acetic acid
Season 10 parts of four amylalcohol ester, 0.8 part of N- dodecyls bi-quaternary ammonium salt, 0.8 part of polyoxyethylene polyoxypropylene pentaerythrite ether, aliphatic acid
0.7 part of glyceride, 1.3 parts of cellulose ether, 2 parts of polyether diamine.
Embodiment 4
A kind of antibacterial metal antirust glue, raw material include by weight：The water-based acrylic resin 45 that solid content is 45%
Part, 24 parts of epoxy resin, 14 parts of phthaloylamino acetic acid hydramine cerium, 12 parts of acetyl triethyl citrate, tetrabutyl acetic acid
Season 9 parts of four amylalcohol ester, 0.7 part of methylisothiazolinone, 0.7 part of dimethyl silicone polymer, 0.6 part of stearic acid, cellulose ether 1.0
Part, 1.5 parts of 2-ethyl-4-methylimidazole.
Embodiment 5
A kind of antibacterial metal antirust glue, raw material include by weight：The water-based acrylic resin 55 that solid content is 55%
Part, 28 parts of epoxy resin, 18 parts of phthaloylamino acetic acid hydramine cerium, 16 parts of acetyl triethyl citrate, tetrabutyl acetic acid
Season 12 parts of four amylalcohol ester, 0.9 part of N- dodecyls bi-quaternary ammonium salt, 0.9 part of polyoxyethylene polyoxypropylene pentaerythrite ether, aliphatic acid
0.8 part of glyceride, 1.7 parts of cellulose ether, 2.5 parts of polyether diamine.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (9)
1. a kind of antibacterial metal antirust glue, which is characterized in that its raw material includes by weight：40-60 parts of acrylic resin, epoxy
20-30 parts of resin, 12-20 parts of phthaloylamino acetic acid hydramine cerium, 10-18 parts of acetyl triethyl citrate, tetrabutyl second
Sour season 7-14 parts of four amylalcohol ester, 0.5-1.0 parts of antiseptic, 0.5-1 parts of antifoaming agent, 0.4-1 parts of surfactant, thickener 0.5-
2 parts, 1-3 parts of curing agent.
2. antibacterial metal antirust glue according to claim 1, which is characterized in that its raw material includes by weight：Polyurethane tree
45-55 parts of fat, 24-28 parts of epoxy resin, 14-18 parts of phthaloylamino acetic acid hydramine cerium, acetyl triethyl citrate 12-
16 parts, the tetrabutyl acetic acid season 9-12 parts of four amylalcohol ester, 0.6-0.8 parts of antiseptic, 0.7-0.9 parts of antifoaming agent, surfactant
0.6-0.8 parts, 1-1.5 parts of thickener, 1.5-2.5 parts of curing agent.
3. antibacterial metal antirust glue according to claim 1 or claim 2, which is characterized in that phthaloylamino acetic acid hydramine cerium,
Acetyl triethyl citrate, the weight ratio of four amylalcohol ester of tetrabutyl acetic acid season are 8：7：5.
4. according to any one of the claim 1-3 antibacterial metal antirust glue, which is characterized in that antiseptic is that N- dodecyls are double
Quaternary ammonium salt and/or methylisothiazolinone.
5. according to any one of the claim 1-4 antibacterial metal antirust glue, which is characterized in that acrylic resin is aqueous acrylamide
Acid resin；Preferably, the solid content of water-based acrylic resin is 40-60%.
6. according to any one of the claim 1-5 antibacterial metal antirust glue, which is characterized in that antifoaming agent is polyoxyethylene polyoxy
Propylene pentaerythrite ether and/or dimethyl silicone polymer.
7. according to any one of the claim 1-6 antibacterial metal antirust glue, which is characterized in that surfactant is that aliphatic acid is sweet
Grease and/or stearic acid.
8. according to any one of the claim 1-7 antibacterial metal antirust glue, which is characterized in that thickener is cellulose ether.
9. according to any one of the claim 1-8 antibacterial metal antirust glue, which is characterized in that curing agent be polyether diamine and/
Or 2-ethyl-4-methylimidazole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810279349.1A CN108424692A (en) | 2018-03-30 | 2018-03-30 | A kind of antibacterial metal antirust glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810279349.1A CN108424692A (en) | 2018-03-30 | 2018-03-30 | A kind of antibacterial metal antirust glue |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108424692A true CN108424692A (en) | 2018-08-21 |
Family
ID=63159713
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810279349.1A Withdrawn CN108424692A (en) | 2018-03-30 | 2018-03-30 | A kind of antibacterial metal antirust glue |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108424692A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113462450A (en) * | 2021-06-18 | 2021-10-01 | 浙江盛杰联合股份有限公司 | Environment-friendly seal coat anti-rust oil |
| CN117510558A (en) * | 2022-09-29 | 2024-02-06 | 范斌磊 | Preparation method of marine machinery antirust agent |
-
2018
- 2018-03-30 CN CN201810279349.1A patent/CN108424692A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113462450A (en) * | 2021-06-18 | 2021-10-01 | 浙江盛杰联合股份有限公司 | Environment-friendly seal coat anti-rust oil |
| CN117510558A (en) * | 2022-09-29 | 2024-02-06 | 范斌磊 | Preparation method of marine machinery antirust agent |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180821 |