CN108570272A - A kind of antifriction metal (AFM) antirust agent - Google Patents
A kind of antifriction metal (AFM) antirust agent Download PDFInfo
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- CN108570272A CN108570272A CN201810293667.3A CN201810293667A CN108570272A CN 108570272 A CN108570272 A CN 108570272A CN 201810293667 A CN201810293667 A CN 201810293667A CN 108570272 A CN108570272 A CN 108570272A
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- afm
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- antirust agent
- acetic acid
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a kind of antifriction metal (AFM) antirust agent, raw material includes：Polyurethane resin, epoxy resin, phthaloylamino acetic acid hydramine cerium, acetyl triethyl citrate, four amylalcohol ester of tetrabutyl acetic acid season, boron carbide, antifoaming agent, surfactant, thickener, curing agent, water.Boron carbide cooperation phthaloylamino acetic acid hydramine cerium and curing agent, can improve resin film-strength, improve the wear-resisting property of antirust agent, antirust agent good film-forming property of the invention, strong adhesive force, anticorrosion are efficient, environmentally protective in the present invention.
Description
Technical field
The present invention relates to technical field of rust prevention more particularly to a kind of antifriction metal (AFM) antirust agent.
Background technology
Metal erosion be chemistry or electrochemical action occur between metal and surrounding medium and cause rotten or
Person destroys.For example, steamer, aircraft, aircraft carrier, cable, metallic conduit etc., corrosion not only endangers mankind's property safety, simultaneously
Also the life security of the mankind is endangered.According to the Track character that corrosion occurs, metal erosion can be divided into chemical attack, electrochemistry
Corrosion and physics corrosion, wherein chemical attack refer to that with non-electrolyte corrosion phenomenon caused by chemical reaction occurs for metal,
Feature is that with non-electrolyte reduction reaction occurs for the atom in metal, and the transmission of electronics directly carries out therebetween.
Currently, common antirust agent prevents and slows down the generation speed of metal erosion, to achieve the purpose that protect metal.With
The progress of the development and production of society, various equipment are higher and higher to corrosion-resistant requirement, not only have good antiseptic property, together
When also there is heat-resisting, high other performances, traditional antirust agent such as hard, wear-resisting to have been unable to meet people's demand.
Invention content
Technical problems based on background technology, the present invention propose a kind of antifriction metal (AFM) antirust agent, and film forming is fine and close, attached
Put forth effort by force, anticorrosion is efficient, wear-resisting property is good, and environmentally protective, cost is relatively low.
The present invention proposes that a kind of antifriction metal (AFM) antirust agent, raw material include by weight：20-30 parts of polyurethane resin, ring
20-30 parts of oxygen resin, 12-20 parts of phthaloylamino acetic acid hydramine cerium, 10-18 parts of acetyl triethyl citrate, the tetrabutyl
Acetic acid season 7-14 parts of four amylalcohol ester, 5-10 parts of boron carbide, 0.5-1 parts of antifoaming agent, 0.4-1 parts of surfactant, thickener 0.5-2
Part, 1-3 parts of curing agent, 40-60 parts of water.
Preferably, raw material includes by weight：22-26 parts of polyurethane resin, 24-28 parts of epoxy resin, O-phthalic
14-18 parts of acylamino- acetic acid hydramine cerium, 12-16 parts of acetyl triethyl citrate, the tetrabutyl acetic acid season 9-12 parts of four amylalcohol ester, carbon
7-8 parts of boron of change, 0.7-0.9 parts of antifoaming agent, 0.6-0.8 parts of surfactant, 1-1.5 parts of thickener, 1.5-2.5 parts of curing agent,
45-55 parts of water.
Preferably, phthaloylamino acetic acid hydramine cerium, acetyl triethyl citrate, four amylalcohol ester of tetrabutyl acetic acid season
Weight ratio be 8：7：5.
Preferably, the weight ratio of polyurethane resin, boron carbide and curing agent is 25：8：2.
Preferably, polyurethane resin is waterborne polyurethane resin；Preferably, the solid content of waterborne polyurethane resin is 40-
60%.
Preferably, antifoaming agent is polyoxyethylene polyoxypropylene pentaerythrite ether and/or dimethyl silicone polymer.
Preferably, surfactant is fatty glyceride and/or stearic acid.
Preferably, thickener is cellulose ether.
Preferably, curing agent is polyether diamine and/or 2-ethyl-4-methylimidazole.
Phthaloylamino acetic acid hydramine cerium, acetyl triethyl citrate, four amylalcohol of tetrabutyl acetic acid season in the present invention
The high rust resistance of ester, three, which cooperates, forms the antirust system of metal, and adsorbing metal surface forms protective film, prevents water
Divide erosion surface, significantly improves the antiseptic property of metal, and the film forming of polyurethane resin and epoxy resin is high, strong adhesive force,
The film forming thickness and compactness of protective film can be improved, rust-proof effect is improved；Boron carbide coordinates phthalyl ammonia in the present invention
Guanidine-acetic acid hydramine cerium and curing agent can improve resin film-strength, improve the wear-resisting property of antirust agent；It is added in the present invention appropriate
Antifoaming agent, surfactant, thickener, reduce bubble, increase antirust agent and metal absorption and wetting effect, adjust antirust
The viscosity of agent increases system stability.
Specific implementation mode
In the following, technical scheme of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of antifriction metal (AFM) antirust agent, raw material include by weight：Gu containing 20 parts of the waterborne polyurethane resin for 40%,
20 parts of epoxy resin, 12 parts of phthaloylamino acetic acid hydramine cerium, 10 parts of acetyl triethyl citrate, tetrabutyl acetic acid Ji Si
7 parts of amylalcohol ester, 5 parts of boron carbide, 0.5 part of polyoxyethylene polyoxypropylene pentaerythrite ether, 0.4 part of fatty glyceride, cellulose
0.5 part of ether, 1 part of polyether diamine, 40 parts of water.
Embodiment 2
A kind of antifriction metal (AFM) antirust agent, raw material include by weight：Gu containing 30 parts of the waterborne polyurethane resin for 60%,
30 parts of epoxy resin, 20 parts of phthaloylamino acetic acid hydramine cerium, 18 parts of acetyl triethyl citrate, tetrabutyl acetic acid Ji Si
14 parts of amylalcohol ester, 10 parts of boron carbide, 1 part of dimethyl silicone polymer, 1 part of stearic acid, 2 parts of cellulose ether, 2- ethyl -4- methyl miaows
3 parts of azoles, 60 parts of water.
Embodiment 3
A kind of antifriction metal (AFM) antirust agent, raw material include by weight：Gu containing 25 parts of the waterborne polyurethane resin for 50%,
25 parts of epoxy resin, 16 parts of phthaloylamino acetic acid hydramine cerium, 14 parts of acetyl triethyl citrate, tetrabutyl acetic acid Ji Si
10 parts of amylalcohol ester, 8 parts of boron carbide, 0.8 part of polyoxyethylene polyoxypropylene pentaerythrite ether, 0.7 part of fatty glyceride, cellulose
1.3 parts of ether, 2 parts of polyether diamine, 50 parts of water.
Embodiment 4
A kind of antifriction metal (AFM) antirust agent, raw material include by weight：Gu containing 22 parts of the waterborne polyurethane resin for 45%,
24 parts of epoxy resin, 14 parts of phthaloylamino acetic acid hydramine cerium, 14 parts of acetyl triethyl citrate, tetrabutyl acetic acid Ji Si
9 parts of amylalcohol ester, 7 parts of boron carbide, 0.7 part of dimethyl silicone polymer, 0.6 part of stearic acid, 1 part of cellulose ether, 2- ethyl -4- methyl
1.5 parts of imidazoles, 45 parts of water.
Embodiment 5
A kind of antifriction metal (AFM) antirust agent, raw material include by weight：Gu containing 26 parts of the waterborne polyurethane resin for 55%,
28 parts of epoxy resin, 18 parts of phthaloylamino acetic acid hydramine cerium, 16 parts of acetyl triethyl citrate, tetrabutyl acetic acid Ji Si
12 parts of amylalcohol ester, 9 parts of boron carbide, 0.9 part of polyoxyethylene polyoxypropylene pentaerythrite ether, 0.8 part of fatty glyceride, cellulose
1.5 parts of ether, 2.5 parts of polyether diamine, 55 parts of water.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (9)
1. a kind of antifriction metal (AFM) antirust agent, which is characterized in that its raw material includes by weight：20-30 parts of polyurethane resin, epoxy
20-30 parts of resin, 12-20 parts of phthaloylamino acetic acid hydramine cerium, 10-18 parts of acetyl triethyl citrate, tetrabutyl second
Sour season 7-14 parts of four amylalcohol ester, 5-10 parts of boron carbide, 0.5-1 parts of antifoaming agent, 0.4-1 parts of surfactant, thickener 0.5-2
Part, 1-3 parts of curing agent, 40-60 parts of water.
2. antifriction metal (AFM) antirust agent according to claim 1, which is characterized in that its raw material includes by weight：Polyurethane tree
22-26 parts of fat, 24-28 parts of epoxy resin, 14-18 parts of phthaloylamino acetic acid hydramine cerium, acetyl triethyl citrate 12-
16 parts, the tetrabutyl acetic acid season 9-12 parts of four amylalcohol ester, 7-8 parts of boron carbide, 0.7-0.9 parts of antifoaming agent, surfactant 0.6-0.8
Part, 1-1.5 parts of thickener, 1.5-2.5 parts of curing agent, 45-55 parts of water.
3. antifriction metal (AFM) antirust agent according to claim 1 or claim 2, which is characterized in that phthaloylamino acetic acid hydramine cerium,
Acetyl triethyl citrate, the weight ratio of four amylalcohol ester of tetrabutyl acetic acid season are 8：7：5.
4. according to any one of the claim 1-3 antifriction metal (AFM) antirust agent, which is characterized in that polyurethane resin, boron carbide and
The weight ratio of curing agent is 25：8：2.
5. according to any one of the claim 1-4 antifriction metal (AFM) antirust agent, which is characterized in that polyurethane resin is aqueous poly- ammonia
Ester resin；Preferably, the solid content of waterborne polyurethane resin is 40-60%.
6. according to any one of the claim 1-5 antifriction metal (AFM) antirust agent, which is characterized in that antifoaming agent is polyoxyethylene polyoxy
Propylene pentaerythrite ether and/or dimethyl silicone polymer.
7. according to any one of the claim 1-6 antifriction metal (AFM) antirust agent, which is characterized in that surfactant is that aliphatic acid is sweet
Grease and/or stearic acid.
8. according to any one of the claim 1-7 antifriction metal (AFM) antirust agent, which is characterized in that thickener is cellulose ether.
9. according to any one of the claim 1-8 antifriction metal (AFM) antirust agent, which is characterized in that curing agent be polyether diamine and/
Or 2-ethyl-4-methylimidazole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810293667.3A CN108570272A (en) | 2018-03-30 | 2018-03-30 | A kind of antifriction metal (AFM) antirust agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810293667.3A CN108570272A (en) | 2018-03-30 | 2018-03-30 | A kind of antifriction metal (AFM) antirust agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108570272A true CN108570272A (en) | 2018-09-25 |
Family
ID=63574474
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810293667.3A Withdrawn CN108570272A (en) | 2018-03-30 | 2018-03-30 | A kind of antifriction metal (AFM) antirust agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108570272A (en) |
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2018
- 2018-03-30 CN CN201810293667.3A patent/CN108570272A/en not_active Withdrawn
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180925 |
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| WW01 | Invention patent application withdrawn after publication |