CN108424677A - A kind of graphene anticorrosive paint - Google Patents
A kind of graphene anticorrosive paint Download PDFInfo
- Publication number
- CN108424677A CN108424677A CN201810310268.3A CN201810310268A CN108424677A CN 108424677 A CN108424677 A CN 108424677A CN 201810310268 A CN201810310268 A CN 201810310268A CN 108424677 A CN108424677 A CN 108424677A
- Authority
- CN
- China
- Prior art keywords
- parts
- graphene
- anticorrosive paint
- acrylic acid
- polyvinyl chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of graphene anticorrosive paints, are made of following parts by weight：10 50 parts of epoxy resin, 4 15 parts of superchlorinated polyvinyl chloride resin, 12 20 parts of graphene, 4 10 parts of acrylic acid, 35 parts of sodium benzoate, 6 12 parts of reactive diluent, 8 10 parts of auxiliary agent, 48 parts of active carbon powder, 35 parts of antioxidant, 2 10 parts of toughener, the present invention is directed to the imperfect problem of anti-corrosion effect of graphene coating, superchlorinated polyvinyl chloride resin is added in the fabrication process, acrylic acid and sodium benzoate, greatly strengthen the antiseptic property of coating, superchlorinated polyvinyl chloride resin therein has good resistance to industrial atmosphere, sea water resistance, it is acidproof, oil resistant, salt spray resistance, it is mould proof, the performances such as anti-burning, but intolerant to phenols, ketone, the corrosion of the organic solvent mediums such as lipid and benzene class.The coating for increasing epoxy resin has good corrosion resistance, especially alkali resistance, and has preferable wearability, and the addition of acrylic acid is so that anticorrosive paint has excellent guarantor's light colour retention and weatherability.
Description
Technical field
The present invention relates to a kind of graphene anticorrosive paints, more particularly, to a kind of graphene anticorrosive paint.
Background technology
Graphene (Graphene) be one kind by carbon atom with sp2Hybridized orbit forms the two dimension that hexangle type is in honeycomb lattice
Carbon nanomaterial.Graphene has excellent optics, electricity, mechanical characteristic, in materialogy, micro-nano technology, the energy, biomedicine
It is with important application prospects with drug delivery etc., it is considered to be a kind of future revolutionary material.[1] Britain Man Chesi
Especially big physicist An Deliegaimu and Constantine's Nuo Woxiao loves are divided with micromechanics stripping method success from graphite
Graphene is separated out, therefore obtains Nobel Prize in physics in 2010 jointly.The method of the common power production of graphene is machinery
Stripping method, oxidation-reduction method, SiC epitaxial growth methods, film production method are chemical vapour deposition technique (CVD).
In recent years, with the continuous development of heavy industry, requirement of the heavy construction to anticorrosive paint is higher and higher.Traditional weight
Anticorrosive paint such as epoxy zinc-enriched paint increasingly can not meet the construction of modern anticorrosive coating because of the limitation in its construction
Technology requirement；Traditional anticorrosive paint, if epoxy zinc-enriched paint by antiseptic property due to being limited, in heavy antisepsis engineering application
In have to three layers of application, i.e., apply priming, intermediate coat, finishing coat respectively, three layers of painting structure of stroke can be only achieved the anti-of design
Rotten effect, short slab is required for certain technique stand-by period after being application period length, every time brushing, when leading to integral construction
Between extend, material cost and construction cost are high, and coating dosage is more, increases the weight of coated article.
Currently, the anti-corrosion effect of existing graphene anticorrosive paint is not good enough, therefore provide new graphene anticorrosive paint.
Invention content
The object of the present invention is to provide a kind of graphene anticorrosive paints, to solve the problems of the prior art.
A kind of graphene anticorrosive paint, is made of following parts by weight：10-50 parts of epoxy resin, superchlorinated polyvinyl chloride resin 4-15
Part, 12-20 parts of graphene, 4-10 parts of acrylic acid, 3-5 parts of sodium benzoate, 6-12 parts of reactive diluent, 8-10 parts of auxiliary agent, activity
4-8 parts of carbon powder, 3-5 parts of antioxidant, 2-10 parts of toughener.
As a preferred technical solution of the present invention, it is made of following parts by weight：30 parts of epoxy resin, Vinylidene Chloride tree
9 parts of fat, 7 parts of acrylic acid, 4 parts of sodium benzoate, 9 parts of reactive diluent, 9 parts of auxiliary agent, 6 parts of active carbon powder, resists 16 parts of graphene
4 parts of oxidant, 6 parts of toughener.
As a preferred technical solution of the present invention, the epoxy resin is modified epoxy, modified E20, is changed
Any one of the E44 of property.
As a preferred technical solution of the present invention, the reactive diluent is acrylate.
As a preferred technical solution of the present invention, the auxiliary agent includes light stabilizer, thickener, dispersant and defoaming
Agent.
As a preferred technical solution of the present invention, the antioxidant is dibutyl hydroxy toluene or tertiary butyl to benzene
Diphenol.
As a preferred technical solution of the present invention, the toughener is dibutyl phthalate or phosphoric acid triphen
Ester.
The beneficial effects of the invention are as follows：The present invention provides a kind of graphene anticorrosive paint, and the present invention is directed to graphene coating
The imperfect problem of anti-corrosion effect, superchlorinated polyvinyl chloride resin, acrylic acid and sodium benzoate are added in the fabrication process, greatly enhances
The antiseptic property of coating, superchlorinated polyvinyl chloride resin therein have good resistance to industrial atmosphere, sea water resistance, acidproof, oil resistant, salt tolerant
The performances such as mist, mould proof, anti-burning, but intolerant to the corrosion of the organic solvent mediums such as phenols, ketone, lipid and benzene class.Increase ring
The coating of oxygen resin has good corrosion resistance, especially alkali resistance, and has preferable wearability, and paint film has good bullet
Property and hardness, shrinking percentage it is relatively low, acrylic acid addition so that anticorrosive paint have excellent guarantor's light colour retention and weatherability.With very
Good physical mechanical property.Paint film fast drying, easy for construction, product of the present invention has no irritating odor, without secondary pollution, construction
It need not protect in the process, the components such as metal will not be corroded, construction cost can be reduced.Practical of the present invention is suitble to promote
It uses.
Specific implementation mode
A kind of graphene anticorrosive paint, is made of following parts by weight：10-50 parts of epoxy resin, superchlorinated polyvinyl chloride resin 4-15
Part, 12-20 parts of graphene, 4-10 parts of acrylic acid, 3-5 parts of sodium benzoate, 6-12 parts of reactive diluent, 8-10 parts of auxiliary agent, activity
4-8 parts of carbon powder, 3-5 parts of antioxidant, 2-10 parts of toughener.
It is made of following parts by weight：30 parts of epoxy resin, 9 parts of superchlorinated polyvinyl chloride resin, 16 parts of graphene, 7 parts of acrylic acid, benzene
4 parts of sodium formate, 9 parts of reactive diluent, 9 parts of auxiliary agent, 6 parts of active carbon powder, 4 parts of antioxidant, 6 parts of toughener.
The epoxy resin be modified epoxy, modified E20, modification any one of E44.
The reactive diluent is acrylate.
The auxiliary agent includes light stabilizer, thickener, dispersant and antifoaming agent.
The antioxidant is dibutyl hydroxy toluene or tert-butylhydroquinone.
The toughener is dibutyl phthalate or triphenyl phosphate.
The present invention is described further with reference to embodiment：
Embodiment 1
A kind of graphene anticorrosive paint, is made of following parts by weight：30 parts of epoxy resin, 9 parts of superchlorinated polyvinyl chloride resin, graphite
16 parts of alkene, 7 parts of acrylic acid, 4 parts of sodium benzoate, 9 parts of reactive diluent, 9 parts of auxiliary agent, 6 parts of active carbon powder, 4 parts of antioxidant,
6 parts of toughener.
The epoxy resin is modified epoxy, modified E44.
The reactive diluent is acrylate.
The auxiliary agent includes light stabilizer, thickener, dispersant and antifoaming agent.
The antioxidant is dibutyl hydroxy toluene.
The toughener is dibutyl phthalate.
A kind of preparation method of graphene anticorrosive paint, includes the following steps：
(1) according to the composition of graphene anticorrosive paint：30 parts of epoxy resin, 9 parts of superchlorinated polyvinyl chloride resin, 16 parts of graphene,
7 parts of acrylic acid, 4 parts of sodium benzoate, 9 parts of reactive diluent, 9 parts of auxiliary agent, 6 parts of active carbon powder, 4 parts of antioxidant, toughener 6
Part, carry out dispensing；
(2) epoxy resin, superchlorinated polyvinyl chloride resin, graphene, sodium benzoate, active powdered carbon are firstly added according to formula ratio
End, grinder ground and mixed 10min, then adds reactive diluent, and 30min is stirred with homogenizer；
(3) acrylic acid, auxiliary agent, antioxidant, toughener are added at 45 DEG C, and stirs 30min, and it is anti-to obtain graphene
Rotten coating.
Embodiment 2
A kind of graphene anticorrosive paint, is made of following parts by weight：40 parts of epoxy resin, 4 parts of superchlorinated polyvinyl chloride resin, graphite
20 parts of alkene, 4 parts of acrylic acid, 5 parts of sodium benzoate, 6 parts of reactive diluent, 10 parts of auxiliary agent, 4 parts of active carbon powder, antioxidant 5
Part, 2 parts of toughener.
The epoxy resin is modified epoxy, modified E20.
The reactive diluent is acrylate.
The auxiliary agent includes light stabilizer, thickener, dispersant and antifoaming agent.
The antioxidant is tert-butylhydroquinone.
The toughener is triphenyl phosphate.
A kind of preparation method of graphene anticorrosive paint, includes the following steps：
(1) according to the composition of graphene anticorrosive paint：40 parts of epoxy resin, 4 parts of superchlorinated polyvinyl chloride resin, 20 parts of graphene,
4 parts of acrylic acid, 5 parts of sodium benzoate, 6 parts of reactive diluent, 10 parts of auxiliary agent, 4 parts of active carbon powder, 5 parts of antioxidant, toughener
2 parts, carry out dispensing；
(2) epoxy resin, superchlorinated polyvinyl chloride resin, graphene, sodium benzoate, active powdered carbon are firstly added according to formula ratio
End, grinder ground and mixed 10min, then adds reactive diluent, and 20min is stirred with homogenizer；
(3) acrylic acid, auxiliary agent, antioxidant, toughener are added at 30 DEG C, and stirs 20min, and it is anti-to obtain graphene
Rotten coating.
Embodiment 3
A kind of graphene anticorrosive paint, is made of following parts by weight：19 parts of epoxy resin, 15 parts of superchlorinated polyvinyl chloride resin, stone
12 parts of black alkene, 10 parts of acrylic acid, 3 parts of sodium benzoate, 12 parts of reactive diluent, 8 parts of auxiliary agent, 8 parts of active carbon powder, antioxidant
3 parts, 10 parts of toughener.
The epoxy resin is modified epoxy, any one of modified E44.
The reactive diluent is acrylate.
The auxiliary agent includes light stabilizer, thickener, dispersant and antifoaming agent.
The antioxidant is dibutyl hydroxy toluene.
The toughener is dibutyl phthalate.
A kind of preparation method of graphene anticorrosive paint, includes the following steps：
(1) according to the composition of graphene anticorrosive paint：30 parts of epoxy resin, 9 parts of superchlorinated polyvinyl chloride resin, 16 parts of graphene,
7 parts of acrylic acid, 4 parts of sodium benzoate, 9 parts of reactive diluent, 9 parts of auxiliary agent, 6 parts of active carbon powder, 4 parts of antioxidant, toughener 6
Part, carry out dispensing；
(2) epoxy resin, superchlorinated polyvinyl chloride resin, graphene, sodium benzoate, active powdered carbon are firstly added according to formula ratio
End, grinder ground and mixed 10min, then adds reactive diluent, and 40min is stirred with homogenizer；
(3) acrylic acid, auxiliary agent, antioxidant, toughener are added at 60 DEG C, and stirs 40min, and it is anti-to obtain graphene
Rotten coating.
The present invention provides a kind of graphene anticorrosive paint, and the present invention imperfect is asked for the anti-corrosion effect of graphene coating
Topic is added superchlorinated polyvinyl chloride resin, acrylic acid and sodium benzoate, greatly strengthens the antiseptic property of coating in the fabrication process,
In superchlorinated polyvinyl chloride resin there are good resistance to industrial atmosphere, sea water resistance, acidproof, oil resistant, salt spray resistance, the property such as mould proof, anti-burning
Can, but intolerant to the corrosion of the organic solvent mediums such as phenols, ketone, lipid and benzene class.The coating of epoxy resin is increased with good
Good corrosion resistance, especially alkali resistance, and have preferable wearability, paint film have good elasticity and hardness, shrinking percentage compared with
Low, the addition of acrylic acid is so that anticorrosive paint has excellent guarantor's light colour retention and weatherability.With good physical mechanical property.
Paint film fast drying, easy for construction, product of the present invention has no irritating odor, and without secondary pollution, need not go bail in work progress
Shield, will not corrode the components such as metal, can reduce construction cost.Practical of the present invention is suitble to promote the use of.
The foregoing is merely one embodiment of the invention, are not intended to limit the present invention, all to use equivalent substitution or equivalent transformation
The technical solution that is obtained of mode, all fall in protection scope of the present invention.
Claims (7)
1. a kind of graphene anticorrosive paint, which is characterized in that be made of following parts by weight：10-50 parts of epoxy resin, Vinylidene Chloride
4-15 parts of resin, 12-20 parts of graphene, 4-10 parts of acrylic acid, 3-5 parts of sodium benzoate, 6-12 parts of reactive diluent, auxiliary agent 8-10
Part, 4-8 parts of active carbon powder, 3-5 parts of antioxidant, 2-10 parts of toughener.
2. a kind of graphene anticorrosive paint according to claim 1, which is characterized in that be made of following parts by weight：Ring
30 parts of oxygen resin, 16 parts of graphene, 7 parts of acrylic acid, 4 parts of sodium benzoate, 9 parts of reactive diluent, helps 9 parts of superchlorinated polyvinyl chloride resin
9 parts of agent, 6 parts of active carbon powder, 4 parts of antioxidant, 6 parts of toughener.
3. a kind of graphene anticorrosive paint according to claim 1, which is characterized in that the epoxy resin is modified ring
Oxygen resin, modified E20, modification any one of E44.
4. a kind of graphene anticorrosive paint according to claims 1-2, which is characterized in that the reactive diluent is third
Olefin(e) acid ester.
5. a kind of graphene anticorrosive paint according to claims 1-2, which is characterized in that the auxiliary agent includes that light is stablized
Agent, thickener, dispersant and antifoaming agent.
6. a kind of graphene anticorrosive paint according to claims 1-2, which is characterized in that the antioxidant is two fourths
Base hydroxy-methylbenzene or tert-butylhydroquinone.
7. a kind of graphene anticorrosive paint according to claims 1-2, which is characterized in that the toughener is adjacent benzene two
Formic acid dibutyl ester or triphenyl phosphate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810310268.3A CN108424677A (en) | 2018-04-03 | 2018-04-03 | A kind of graphene anticorrosive paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810310268.3A CN108424677A (en) | 2018-04-03 | 2018-04-03 | A kind of graphene anticorrosive paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108424677A true CN108424677A (en) | 2018-08-21 |
Family
ID=63160617
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810310268.3A Pending CN108424677A (en) | 2018-04-03 | 2018-04-03 | A kind of graphene anticorrosive paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108424677A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115233158A (en) * | 2022-06-23 | 2022-10-25 | 安徽工业大学 | Composite coating for surface layer of internal combustion engine valve rod piece and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009179700A (en) * | 2008-01-30 | 2009-08-13 | Teijin Ltd | Thermally conductive powder coating composition |
| CN107201139A (en) * | 2017-06-13 | 2017-09-26 | 合肥大麦灯箱器材有限公司 | A kind of anticorrosive paint and preparation method thereof |
-
2018
- 2018-04-03 CN CN201810310268.3A patent/CN108424677A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009179700A (en) * | 2008-01-30 | 2009-08-13 | Teijin Ltd | Thermally conductive powder coating composition |
| CN107201139A (en) * | 2017-06-13 | 2017-09-26 | 合肥大麦灯箱器材有限公司 | A kind of anticorrosive paint and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115233158A (en) * | 2022-06-23 | 2022-10-25 | 安徽工业大学 | Composite coating for surface layer of internal combustion engine valve rod piece and preparation method thereof |
| CN115233158B (en) * | 2022-06-23 | 2023-12-26 | 安徽工业大学 | Composite coating for surface layer of valve rod of internal combustion engine and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106118295A (en) | A kind of aqueous bottom surface unification Corrosion resisting paint without need of cleaning rust and preparation method thereof | |
| CN108084843A (en) | Applied to face composite bed water paint in the bottom in container field and preparation method thereof | |
| CN106280908B (en) | Corrosive protection of aluminium alloy coating, preparation method and application | |
| CN107987680A (en) | Water-base epoxy graphene anticorrosive paint | |
| CN104947029A (en) | Method of preparing MAX phase ceramic coating by using hot spraying | |
| CN106366851A (en) | Epoxy ester dip-coating water based paint and preparation method thereof | |
| CN108373608A (en) | A kind of environment-friendly water-based chromium-free zinc aluminum conductive coating and its preparation method and application | |
| CN103666201A (en) | Long-acting acid-base resistant solvent-free anticorrosive paint as well as preparation method and application thereof | |
| CN107987591A (en) | A kind of waterborne rust conversion primer base and preparation method thereof | |
| CN108129948A (en) | Carbon nanotubes watersoluble plumbago alkene epoxy zinc rich primer applied to container field | |
| CN105219218A (en) | A kind of aqueous phenolic aldehyde epoxy anticorrosive paint and preparation method thereof | |
| CN104725969A (en) | Water-based anti-corrosion floating type aluminium powder paint and preparation method thereof | |
| CN108424677A (en) | A kind of graphene anticorrosive paint | |
| CN104725977B (en) | Double-component aqueous epoxy zinc rich primer of heavy antisepsis and preparation method thereof | |
| CN106046868A (en) | Falling-off-preventing metal coating and preparation method thereof | |
| CN112500764B (en) | Solvent-free epoxy zinc-rich anticorrosive paint and preparation method thereof | |
| CN107674473A (en) | A kind of steel structure surface High-solid anticorrosive paint and its spraying method | |
| CN103923503A (en) | Composite flash rust inhibitor for waterborne epoxy resin coating and preparation method of composite flash rust inhibitor | |
| CN106497343A (en) | A kind of modified carbon nano-tube anticorrosion and antistatic paint | |
| CN108822705A (en) | A kind of one-component salt spray resistance water paint and preparation method thereof | |
| CN105419439A (en) | Aqueous paint printing ink anti-flash-rust agent, preparation method therefor and applications | |
| CN106554662A (en) | A kind of good formulation for coating material of wearability | |
| CN108329807A (en) | A kind of single-component water-based acrylic acid -ol acid graphene anticorrosive paint of quick-drying | |
| CN108047894A (en) | A kind of anti-corrosive paints and application thereof | |
| CN106837027B (en) | One kind is anti-to lose hood support rod |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180821 |