CN108424553A - 一种无卤室内电缆原料 - Google Patents

一种无卤室内电缆原料 Download PDF

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CN108424553A
CN108424553A CN201810338256.1A CN201810338256A CN108424553A CN 108424553 A CN108424553 A CN 108424553A CN 201810338256 A CN201810338256 A CN 201810338256A CN 108424553 A CN108424553 A CN 108424553A
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parts
halogen
raw material
house cable
cable
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谢博民
孟相君
王茂刚
辛超
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SHANDONG DILONG CABLES CO Ltd
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SHANDONG DILONG CABLES CO Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/262—Alkali metal carbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/22—Halogen free composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Health & Medical Sciences (AREA)
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Abstract

本发明公开了一种无卤室内电缆原料。所述一种无卤室内电缆原料，由以下重量份的原料制成：顺丁橡胶40‑70份；天然橡胶60‑80份；补强体系3‑7份；硫化剂1‑3份；硫化助剂0.5‑1份；灭菌体系3‑5份；阻燃剂7‑9份。本发明具有以下有益效果：在达到同等性能的技术要求时，同时降低了生产成本，最高比含卤电缆还要低13%，阻燃效果优异，完全满足室内电缆的阻燃需求，同时与含卤电缆对比，部分性能还有超出，抗菌灭菌，能有效防止房内的细菌蔓延，维护人民的健康。

Description

一种无卤室内电缆原料
技术领域
本发明涉及一种无卤电缆，具体说是一种无卤室内电缆原料。
背景技术
低烟无卤电缆，是指不含卤素（F、Cl、Br、I、At）、不含铅镉铬汞等环境物质的胶料制成，燃烧时不会发出有毒烟雾的环保型电缆。
而无卤阻燃助剂的成本极高，使用无卤阻燃剂制作的电缆售价也极高，导致仍有部分人，还在采用含卤电缆，含卤电缆燃烧易产生大量有毒气体，特别是作为室内电缆使用，在电起火时燃烧产生的危害极大。
而且室内电缆多是安置在室内的墙体内，环境阴暗潮湿，细菌易通过外置对接装置，如开关、插孔，侵入细菌，而细菌则会沿电缆线路散布到整个房间，如卫生间或厨房的细菌沿电缆线路散布到卧式等处，维护人民健康。
发明内容
本发明所要解决的技术问题是提供一种低成本的无卤室内电缆原料。
为解决上述技术问题，本发明的技术方案是：一种无卤室内电缆原料，由以下重量份的原料制成：顺丁橡胶40-70份；天然橡胶60-80份；补强体系3-7份；硫化剂1-3份；硫化助剂0.5-1份；灭菌体系3-5份；阻燃剂7-9份。
作为优选的技术方案，所述一种无卤室内电缆原料，由以下重量份原料制成：顺丁橡胶55份；天然橡胶70份；补强体系5份；硫化剂2份；硫化助剂0.75份；灭菌体系4份；阻燃剂8份。
作为优选，所述补强体系为炭黑N330、炭黑N774按照1：1.25的比例配比后混入按照1：0.7的碳酸钠和碳酸钙配比而成。
作为优选，所述硫化剂促进剂CZ，硫化助剂为二硫化四甲基秋兰姆。
作为优选，所述灭菌体系为AgNO3抗菌剂，也可以是Ag或Cu或Zn。
作为优选，所述阻燃剂为氢氧化铝、聚乙烯醇、西米淀粉、抗阻燃纤维。
由于采用了上述技术方案，，由以下重量份原料制成：顺丁橡胶40-70份；天然橡胶60-80份；补强体系3-7份；硫化剂1-3份；硫化助剂0.5-1份；灭菌体系3-5份；阻燃剂7-9份；本发明具有以下有益效果：
1、在达到同等性能的技术要求时，同时降低了生产成本，最高比含卤电缆还要低13%。
2、阻燃效果优异，完全满足室内电缆的阻燃需求，同时与含卤电缆对比，部分性能还有超出。
3、抗菌灭菌，能有效防止房内的细菌蔓延，维护人民的健康。
具体实施方式
下面结合具体实施例对本发明做进一步地说明。
实施例1
一种无卤室内电缆原料，由以下重量份原料制成：顺丁橡胶40份；天然橡胶60份；补强体系3份；硫化剂1份；硫化助剂0.5份；灭菌体系3份；阻燃剂7份。
实施例2
一种无卤室内电缆原料，由以下重量份原料制成：顺丁橡胶70份；天然橡胶80份；补强体系7份；硫化剂3份；硫化助剂1份；灭菌体系5份；阻燃剂9份。
实施例3
一种无卤室内电缆原料，由以下重量份原料制成：顺丁橡胶55份；天然橡胶70份；补强体系5份；硫化剂2份；硫化助剂0.75份；灭菌体系4份；阻燃剂8份。
实验检验：
表1为本技术方案产品和普通含卤电缆的对比检测数据，按照GB/T12706.2-2008标准要求。
以上所述仅为本发明示意性的具体实施方式，并非用以限定本发明的范围。任何本领域的技术人员，在不脱离本发明的构思和原则的前提下所作出的等同变化与修改，均应属于本发明保护的范围。

Claims (6)

1.一种无卤室内电缆原料，其特征在于，由以下重量份的原料制成：顺丁橡胶40-70份；天然橡胶60-80份；补强体系3-7份；硫化剂1-3份；硫化助剂0.5-1份；灭菌体系3-5份；阻燃剂7-9份。
2.如权利要求1所述一种无卤室内电缆原料，其特征在于，由以下重量份的原料制成：顺丁橡胶55份；天然橡胶70份；补强体系5份；硫化剂2份；硫化助剂0.75份；灭菌体系4份；阻燃剂8份。
3.如权利要求1-2所述一种无卤室内电缆原料，其特征在于：所述补强体系为炭黑N330、炭黑N774按照1：1.25的比例配比后混入按照1：0.7的碳酸钠和碳酸钙配比而成。
4.如权利要求1-2所述一种无卤室内电缆原料，其特征在于：所述硫化剂促进剂CZ，硫化助剂为二硫化四甲基秋兰姆。
5.如权利要求1-2所述一种无卤室内电缆原料，其特征在于：所述灭菌体系为AgNO3抗菌剂，也可以是Ag或Cu或Zn。
6.如权利要求1-2所述一种无卤室内电缆原料，其特征在于：所述阻燃剂为氢氧化铝、聚乙烯醇、西米淀粉、抗阻燃纤维。
CN201810338256.1A 2018-04-16 2018-04-16 一种无卤室内电缆原料 Pending CN108424553A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110218370A (zh) * 2019-06-03 2019-09-10 伊斯特密封科技（江苏）有限公司 一种用于电缆密封件的阻燃防爆橡胶材料及其制备方法

Citations (6)

* Cited by examiner, † Cited by third party
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WO2002030194A1 (en) * 2000-10-12 2002-04-18 Duraban Oy Antimicrobial polyalphaolefin composition
CN103183848A (zh) * 2013-04-15 2013-07-03 桂林电子科技大学 一种快速硫化的低烟无卤阻燃橡胶电缆料及制备方法
CN104558716A (zh) * 2015-01-14 2015-04-29 四川大学 一种高效无卤膨胀阻燃橡胶体系及其制备方法
CN107383706A (zh) * 2017-09-14 2017-11-24 安徽天大铜业有限公司 一种pvc电缆护套料及其制备方法
CN107573555A (zh) * 2017-11-01 2018-01-12 安徽美腾特种电缆材料有限公司 一种高性能电缆材料
CN107602946A (zh) * 2017-08-14 2018-01-19 安徽欧耐橡塑工业有限公司 低烟无卤阻燃钢丝绳芯输送带覆盖层弹性体及其制备方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002030194A1 (en) * 2000-10-12 2002-04-18 Duraban Oy Antimicrobial polyalphaolefin composition
CN103183848A (zh) * 2013-04-15 2013-07-03 桂林电子科技大学 一种快速硫化的低烟无卤阻燃橡胶电缆料及制备方法
CN104558716A (zh) * 2015-01-14 2015-04-29 四川大学 一种高效无卤膨胀阻燃橡胶体系及其制备方法
CN107602946A (zh) * 2017-08-14 2018-01-19 安徽欧耐橡塑工业有限公司 低烟无卤阻燃钢丝绳芯输送带覆盖层弹性体及其制备方法
CN107383706A (zh) * 2017-09-14 2017-11-24 安徽天大铜业有限公司 一种pvc电缆护套料及其制备方法
CN107573555A (zh) * 2017-11-01 2018-01-12 安徽美腾特种电缆材料有限公司 一种高性能电缆材料

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110218370A (zh) * 2019-06-03 2019-09-10 伊斯特密封科技（江苏）有限公司 一种用于电缆密封件的阻燃防爆橡胶材料及其制备方法

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Application publication date: 20180821