CN108411516A - Acetate fiber crimps pretreatment unit, pretreatment fluid and preprocess method - Google Patents

Acetate fiber crimps pretreatment unit, pretreatment fluid and preprocess method Download PDF

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Publication number
CN108411516A
CN108411516A CN201810289825.8A CN201810289825A CN108411516A CN 108411516 A CN108411516 A CN 108411516A CN 201810289825 A CN201810289825 A CN 201810289825A CN 108411516 A CN108411516 A CN 108411516A
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China
Prior art keywords
spraying
pretreatment
acetate fiber
acetate
curling
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Granted
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CN201810289825.8A
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Chinese (zh)
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CN108411516B (en
Inventor
叶兆清
胡志钢
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Hubei Xinyang Special Fiber Co Ltd
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Hubei Xinyang Special Fiber Co Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B1/00Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
    • D06B1/02Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by spraying or projecting
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B23/00Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
    • D06B23/20Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration, distillation
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B23/00Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
    • D06B23/20Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration, distillation
    • D06B23/22Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration, distillation for heating
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/12Aldehydes; Ketones
    • D06M13/127Mono-aldehydes, e.g. formaldehyde; Monoketones
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic

Abstract

The invention discloses acetate fiber curling pretreatment unit, pretreatment fluid and preprocess methods, pass through the acetate silk preprocess method to match with fiber crimp technique, tow reduction when receiving technology itself is set to crimp modulus, improve fibrous fracture elongation percentage, mitigate curling damage, enhances curling, shaping effect.The pretreatment includes spraying device, temperature control system, micrometeor control unit, atomization gas circulator, enters uniform and stable spraying before crimping machine to obtain silk ribbon.Pretreatment fluid provided by the invention coordinates spraying system, can for technology there are the problem of, various additives are purposefully added, achieve the effect that conventional vapor spraying is unable to reach, such as increases lubrication, adjust outer oil content, improve cluster performance, prevent vitrifying tendency, reduce curling damage.

Description

Acetate fiber crimps pretreatment unit, pretreatment fluid and preprocess method
Technical field
The present invention relates to acetate fiber spinning fields, and in particular to acetate fiber crimp pretreatment unit, pretreatment fluid and Preprocess method.
Background technology
Acetate fiber curly course is particularly significant, has vital influence to its performance and application.On the one hand, it crimps Acetate fiber is set to obtain more bigger serface, better Adsorption Filtration Properties, higher filtering rod;On the other hand, it crimps again So that fiber surface is formed curling damage by strong friction and shearing, negative shadow is generated to its physical property and subsequent use It rings;Importantly, for the acetate silk higher to single-strand, imappropriate pretreatment, technology almost without Method is implemented.Tart flavour and to go mouldy be the phenomenon that acetate fiber another kind is easy to happen, although can be added such as in spinning oil The bacteriostatic agent of hydrogen peroxide etc, but tend not to thorough solve the problems, such as.Diacetate fiber slice itself carries certain tart flavour, certain A little sharp-nosed people dislike this taste.If tow tart flavour can be removed, user welcomes very much.In addition the vinegar after crimping Sour fibre bundle needs by technical process, the adjustings of tow cluster performance such as drying, pendulum wire, packings to help that silk ribbon is overcome to transport The problems such as diverging that row generates in the process, curling round the roll, silk ribbon be wide, electrostatic.Silk ribbon pretreatment appropriate, can help to solve or change The above many disadvantages of kind acetate fiber, are a kind of novel technical finesse means.
The usually used technology of dry spinning process is fairly simple, and the upper silk ribbon for crossing finish is sent into crimping machine and completes work Skill route, for the strand specification that certain curling modulus are larger, this simple way is inappropriate, and such curling is unstable Fixed, rebound is big, and curling wave is not secured enough, and tow specific surface area is not big enough, silk ribbon poor appearance, and technique, which is not achieved, in crimp energy wants It asks.It, completely can be to avoid the above problem by appropriately pre-processing.On the other hand, we attempt and compare other reduction curlings The method of modulus, if steam sprays, steam sprays or is also easy to produce condensation water slug because steam flow is small, causes spray vapour uneven It is even, or because of steam flow generation overtemperature bigger than normal, to cause tow quality unstable.
Invention content
A kind of acetate fiber curling pretreatment unit of present invention offer, pretreatment fluid and preprocess method, acid is removed to obtain Taste reduces curling modulus, softening tow, reduces curling damage, antibacterial and mouldproof, adjusts the multipurposes such as silk ribbon cluster performance.
The present invention is realized using such technical solution:A kind of acetate fiber curling pretreatment unit, including pretreatment Flow container, bottom are connected to spraying system by pipeline through flowmeter, and spraying system includes that spraying babinet and nozzle, nozzle are also connected with There is compressed air pipe;Pending acetate silk is through spraying babinet;It is additionally provided with temperature sensor in pretreatment flow container And electric heating tube, temperature sensor and electric heating tube are all connected to temperature controller.
Further, it is set in spray tank body there are two nozzle, is mounted on spraying babinet acetate silk approaching side, position In acetate silk upper and lower.
Further, compressed air pipe is equipped with pressure regulator valve.
Further, the pretreatment flow container is located at a high position, and spray tank body is located at low level.
Further, it is equipped with ball-cock assembly above pretreatment flow container.
The invention further relates to acetate fibers to crimp pretreatment fluid, based on mass concentration, wherein selective plasticization agent as needed For in 2-5%, spinning oil 1-3%, alkali 10-50ppm, oil film reinforcing agent 100-500ppm, bacteriostatic agent 50-500ppm one kind or Person is several, remaining is deionized water.
Water itself has cooling and lubrication function, can effectively prevent tow vitrifying in curling;Other additives can To need to accept or reject according to different, can also use simultaneously;For example:When producing the higher tow of single fiber line density, it can add Plasticizer;When the free acid of raw material is higher, alkali can be added;When needing to be improved an appearance or coherent, spinning can be added Finish and oil film reinforcing agent;Tow sells to high temperature and humidity at area or across plum rain season storage period, can add bacteriostatic agent.
Further, the plasticizer is acetone, and alkali is food-grade sodium carbonate, and oil film reinforcing agent is alkyl-blocked random Polyethers, bacteriostatic agent are Nepal's gold esters food grade additives.
The invention further relates to acetate fibers to crimp preprocess method, before acetate fiber curling, by atomization system, by vinegar Sour fiber crimp pretreatment fluid atomization, is injected on acetate fiber, is fully soaked before so that acetate fiber is entered crimping machine.
Further, the spray particle diameter of the atomization system is 100 μm, and the temperature of spraying liquid is controlled at 35-65 DEG C.
Further, the atomization system is processed into stable haze, atomization quantity 10-60ml/ by pretreatment fluid is crimped min。
It is controlled and stablize to form temperature, granularity and spray amount by atomization system for pretreatment unit in the present invention Atomization air flow is accurately injected on acetate fiber, and haze is formed around tow, before so that acetate fiber is entered crimping machine fully Wetting, possesses appropriate curling modulus, the temperature of stronger coiling-resistant toughness and uniform spinning oil coating and stabilization.
Plasticizer is added in pretreatment fluid, curling modulus can be reduced;Alkali is added can also mitigate for adjusting pH value Tart flavour, the softening tow of acetate silk;Oil film reinforcing agent is added, curling damage can be mitigated;And bacteriostatic agent is added, it can be with It prevents from going mouldy;Spinning oil is added, cluster performance can be adjusted, particularly with the addition of the spinning oil in patent 201610151069.3 Agent.In preferred scheme, select acetone as plasticizer in pretreatment fluid, since acetone is the solvent of acetate fiber spinning, energy Cellulose acetate is dissolved, the present invention, by tow surface slightly soluble, makes tow acquisition preferably crimp tough using the acetone of concentration 2-5% Property, and when reducing tow crimping surface chap.
The invention has the advantages that:
1)Acetate fiber crimps modulus and reduces, and crimping difficult kind curling quality originally improves;
2)Acetate fiber appearance enhancement after curling:Curling, shaping is good, and curling wave is uniform, and curling, shaping is secured;
3)Acetate fiber tart flavour is reduced;
4)Acetate fiber curling damage reduces;
5)Acetate fiber anti-mildew ability enhancing for a long time.
Description of the drawings
Fig. 1 is the structural schematic diagram of pretreatment unit provided by the invention.
Specific implementation mode
The present invention is described in more detail with reference to embodiment.
Embodiment 1:As shown in Figure 1, a kind of acetate fiber crimps pretreatment unit, including pretreatment flow container 1, bottom passes through Pipeline is connected to spraying system through flowmeter 6, can accurately control nozzle flow, and spraying system includes spraying babinet 8 and spray Mouth 9, nozzle 9 are also associated with compressed air pipe;Pending acetate silk 10 is through spraying babinet 8;Pre-process flow container 1 It is inside additionally provided with temperature sensor 4 and electric heating tube 3, temperature sensor 4 and electric heating tube 3 are all connected to temperature controller 5, can be accurate Ground controls the temperature of pretreatment fluid.
In preferred embodiment, set in babinet 8 of spraying there are two nozzle 9, be mounted on spraying 8 acetate silk 10 of babinet into Enter side, is located at 10 upper and lower of acetate silk.Dichlorodiphenyl Acetate fibre bundle is synchronized by upper and lower position to be handled, injection effect Fruit is good.The especially use of spraying babinet 8, contributes to pretreatment fluid atomization air mass formed therein that, Dichlorodiphenyl Acetate fibre bundle Processing is more uniformly distributed.
Further, compressed air pipe is equipped with pressure regulator valve 7.The pressure that compressed air can accurately be controlled, to adjust Whole nozzle grain size.
Further, the pretreatment flow container 1 is located at a high position, and spraying babinet 8 is located at low level.The input of pump can be reduced.
Further, 1 top of pretreatment flow container is equipped with ball-cock assembly 2.
Embodiment 2:
A kind of acetate fiber curling pretreatment fluid, predominantly deionized water, wherein bacteriostatic agent are 100ppm.The pretreatment fluid is used for Conventional products, other process conditions are constant, and after spraying, the crimp energy of tow is constant, and fracture strength increases 2N/ktex:If adjusted Whole crimping machine maintains fracture strength constant, then crimp energy increases 20g.cm/cm or so.Wherein " crimp energy " and " fracture strength " be The quality index of tow.
Embodiment 3:
A kind of acetate fiber curling pretreatment fluid, based on mass concentration, wherein spinning oil 3%, oil film reinforcing agent are 100ppm, Alkali is 40ppm, remaining is water.The formula be suitable for conventional products, raw material vinegar sheet free miserable scholar when 70 ppm, adjust pH Value, to dispel tart flavour.
Embodiment 4:
A kind of acetate fiber curling pretreatment fluid, based on mass concentration, wherein plasticizer is 5%, spinning oil 1%, and bacteriostatic agent is 100ppm;Remaining is water.The formula for produce single fiber line density it is higher, under the conditions of common process not fertile part silk Beam product.
Such as the product of single fiber line density 6.67dtex, under common process, " fracture strength " and " crimp energy " is difficult same When reach defined requirement, after the pretreatment fluid processing of embodiment 4, so that it may raw not change other common process The product of output qualification.
Embodiment 5:
A kind of acetate fiber curling pretreatment fluid, based on mass concentration, wherein plasticizer is 3%, spinning oil 2%, and alkali is 40ppm, oil film reinforcing agent are 350ppm, remaining is water.
Embodiment 6:A kind of acetate fiber curling preprocess method, before acetate fiber curling, by atomization system, by vinegar Sour fiber crimp pretreatment fluid atomization, is injected on acetate fiber, is fully soaked before so that acetate fiber is entered crimping machine.
Further, the spray particle diameter of the atomization system is less than 100 μ, and the temperature of spraying liquid is controlled at 35-65 DEG C It is interior selected.
Further, the atomization system is processed into stable haze, atomization quantity 10-60ml/ by pretreatment fluid is crimped min。
The above embodiments are only the preferred technical solution of the present invention, and are not construed as the limitation for the present invention, this hair Technical characteristic in the technical solution that bright protection domain should be recorded with claim, including the technical solution of claim record Equivalents are protection domain.Equivalent replacement i.e. within this range is improved, also within protection scope of the present invention.

Claims (10)

1. acetate fiber crimps pretreatment unit, which is characterized in that including pre-processing flow container(1), bottom is by pipeline through stream Gauge(6)It is connected to spraying system, spraying system includes spraying babinet(8)And nozzle(9), nozzle(9)It is empty to be also associated with compression Feed channel;Pending acetate silk(10)Through spraying babinet(8);Pre-process flow container(1)Inside it is additionally provided with temperature sensing Device(4)And electric heating tube(3), temperature sensor(4)And electric heating tube(3)It is all connected to temperature controller(5).
2. the apparatus according to claim 1, it is characterised in that:Spraying babinet(8)Nozzle there are two inside setting(9), installation In spraying babinet(8)Acetate silk(10)Approaching side is located at acetate silk(10)Upper and lower.
3. the apparatus according to claim 1, it is characterised in that:Compressed air pipe is equipped with pressure regulator valve(7).
4. the apparatus according to claim 1, it is characterised in that:The pretreatment flow container(1)Positioned at a high position, babinet of spraying (8)Positioned at low level.
5. the apparatus according to claim 1, it is characterised in that:Pre-process flow container(1)Top is equipped with ball-cock assembly(2).
6. acetate fiber crimps pretreatment fluid, which is characterized in that based on mass concentration, wherein selective plasticization agent as needed is 2- 5%, a kind of or several in spinning oil 1-3%, alkali 10-50ppm, oil film reinforcing agent 100-500ppm, bacteriostatic agent 50-500ppm Kind, remaining is deionized water.
7. pretreatment fluid according to claim 6, it is characterised in that:The plasticizer is acetone, and alkali is food-grade carbon Sour sodium, oil film reinforcing agent are alkyl-blocked atactic polyether, and bacteriostatic agent is Nepal's gold esters food grade additives.
8. acetate fiber crimps preprocess method, it is characterised in that:Before acetate fiber curling, by atomization system, by acetic acid Fiber crimp pretreatment fluid is atomized, and is injected on acetate fiber, is fully soaked before so that acetate fiber is entered crimping machine.
9. preprocess method according to claim 8, it is characterised in that:The spray particle diameter of the atomization system is 10-100 μm, the temperature of spraying liquid is controlled at 35-65 DEG C.
10. preprocess method according to claim 8, it is characterised in that:The atomization system will crimp pretreatment fluid It is processed into stable haze, atomization quantity 10-60ml/min.
CN201810289825.8A 2018-04-03 2018-04-03 Acetate fiber crimps pretreatment unit, pretreatment fluid and preprocess method Active CN108411516B (en)

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CN108796886A (en) * 2018-08-30 2018-11-13 张家港市利佳纺织有限公司 A kind of coating spandex additive treating system
CN110052355A (en) * 2019-05-10 2019-07-26 汉硕高新材料(天津)有限公司 A kind of novel carbon fiber prepreg system and preparation method thereof
CN112831870A (en) * 2020-12-31 2021-05-25 广东源辉环保纤维有限公司 Regenerated fiber post-spinning device and using method thereof

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Publication number Priority date Publication date Assignee Title
CN108796886A (en) * 2018-08-30 2018-11-13 张家港市利佳纺织有限公司 A kind of coating spandex additive treating system
CN110052355A (en) * 2019-05-10 2019-07-26 汉硕高新材料(天津)有限公司 A kind of novel carbon fiber prepreg system and preparation method thereof
CN110052355B (en) * 2019-05-10 2024-02-20 汉硕高新材料(天津)有限公司 Carbon fiber prepreg system and manufacturing method thereof
CN112831870A (en) * 2020-12-31 2021-05-25 广东源辉环保纤维有限公司 Regenerated fiber post-spinning device and using method thereof
CN112831870B (en) * 2020-12-31 2022-03-25 广东源辉环保纤维有限公司 Regenerated fiber post-spinning device and using method thereof

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