CN108395809A - A kind of indoor wall environment-friendly waterproof paint and preparation method thereof - Google Patents
A kind of indoor wall environment-friendly waterproof paint and preparation method thereof Download PDFInfo
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- CN108395809A CN108395809A CN201810233878.8A CN201810233878A CN108395809A CN 108395809 A CN108395809 A CN 108395809A CN 201810233878 A CN201810233878 A CN 201810233878A CN 108395809 A CN108395809 A CN 108395809A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 239000003973 paint Substances 0.000 title claims abstract 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 64
- 239000002994 raw material Substances 0.000 claims abstract description 46
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000003349 gelling agent Substances 0.000 claims abstract description 34
- 238000000576 coating method Methods 0.000 claims abstract description 27
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 19
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 16
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 13
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 13
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims abstract description 10
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 10
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000839 emulsion Substances 0.000 claims abstract description 10
- 239000003822 epoxy resin Substances 0.000 claims abstract description 10
- 239000005038 ethylene vinyl acetate Substances 0.000 claims abstract description 10
- 239000004816 latex Substances 0.000 claims abstract description 10
- 229920000126 latex Polymers 0.000 claims abstract description 10
- 239000012188 paraffin wax Substances 0.000 claims abstract description 10
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims abstract description 10
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 10
- 235000019795 sodium metasilicate Nutrition 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 33
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 claims description 28
- 239000011248 coating agent Substances 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 25
- 235000012239 silicon dioxide Nutrition 0.000 claims description 23
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 22
- 239000000843 powder Substances 0.000 claims description 21
- 239000002318 adhesion promoter Substances 0.000 claims description 20
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 claims description 20
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 17
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 16
- 238000001035 drying Methods 0.000 claims description 15
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 14
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 14
- FAPWYRCQGJNNSJ-UBKPKTQASA-L calcium D-pantothenic acid Chemical compound [Ca+2].OCC(C)(C)[C@@H](O)C(=O)NCCC([O-])=O.OCC(C)(C)[C@@H](O)C(=O)NCCC([O-])=O FAPWYRCQGJNNSJ-UBKPKTQASA-L 0.000 claims description 14
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 claims description 14
- 239000001354 calcium citrate Substances 0.000 claims description 14
- 229960002079 calcium pantothenate Drugs 0.000 claims description 14
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 14
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 14
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 14
- 229960000969 phenyl salicylate Drugs 0.000 claims description 14
- 239000004302 potassium sorbate Substances 0.000 claims description 14
- 235000010241 potassium sorbate Nutrition 0.000 claims description 14
- 229940069338 potassium sorbate Drugs 0.000 claims description 14
- 235000013337 tricalcium citrate Nutrition 0.000 claims description 14
- -1 dimethyl glycidyl Chemical group 0.000 claims description 13
- 230000000149 penetrating effect Effects 0.000 claims description 13
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 12
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 11
- 239000000292 calcium oxide Substances 0.000 claims description 11
- 235000012255 calcium oxide Nutrition 0.000 claims description 11
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 10
- 239000002174 Styrene-butadiene Substances 0.000 claims description 9
- 239000010453 quartz Substances 0.000 claims description 9
- 239000011115 styrene butadiene Substances 0.000 claims description 9
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 9
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 claims description 8
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 8
- 239000005543 nano-size silicon particle Substances 0.000 claims description 8
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 8
- 229940048086 sodium pyrophosphate Drugs 0.000 claims description 8
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims description 8
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 8
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 claims description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 6
- 239000005977 Ethylene Substances 0.000 claims description 6
- 108010010803 Gelatin Proteins 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 claims description 6
- 229920002472 Starch Polymers 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 6
- 241000779819 Syncarpia glomulifera Species 0.000 claims description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 6
- 239000000440 bentonite Substances 0.000 claims description 6
- 229910000278 bentonite Inorganic materials 0.000 claims description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 6
- 229910021538 borax Inorganic materials 0.000 claims description 6
- 229940044172 calcium formate Drugs 0.000 claims description 6
- 235000019255 calcium formate Nutrition 0.000 claims description 6
- 239000004281 calcium formate Substances 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 6
- 229920001971 elastomer Polymers 0.000 claims description 6
- 229920000159 gelatin Polymers 0.000 claims description 6
- 239000008273 gelatin Substances 0.000 claims description 6
- 235000019322 gelatine Nutrition 0.000 claims description 6
- 235000011852 gelatine desserts Nutrition 0.000 claims description 6
- 239000000395 magnesium oxide Substances 0.000 claims description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 6
- 239000001739 pinus spp. Substances 0.000 claims description 6
- 239000005060 rubber Substances 0.000 claims description 6
- 239000004328 sodium tetraborate Substances 0.000 claims description 6
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 6
- 239000008107 starch Substances 0.000 claims description 6
- 235000019698 starch Nutrition 0.000 claims description 6
- 239000008117 stearic acid Substances 0.000 claims description 6
- 229940036248 turpentine Drugs 0.000 claims description 6
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 5
- 229960004256 calcium citrate Drugs 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 229960000355 copper sulfate Drugs 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 5
- 229910052808 lithium carbonate Inorganic materials 0.000 claims description 5
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 claims description 5
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 5
- 239000000725 suspension Substances 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- 239000011787 zinc oxide Substances 0.000 claims description 5
- 239000004111 Potassium silicate Substances 0.000 claims description 4
- 229910052913 potassium silicate Inorganic materials 0.000 claims description 4
- 235000019353 potassium silicate Nutrition 0.000 claims description 4
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims description 4
- XYRAEZLPSATLHH-UHFFFAOYSA-N trisodium methoxy(trioxido)silane Chemical compound [Na+].[Na+].[Na+].CO[Si]([O-])([O-])[O-] XYRAEZLPSATLHH-UHFFFAOYSA-N 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 abstract description 7
- 230000001070 adhesive effect Effects 0.000 abstract description 7
- 230000001681 protective effect Effects 0.000 abstract description 4
- 235000013312 flour Nutrition 0.000 abstract 1
- 230000008595 infiltration Effects 0.000 abstract 1
- 238000001764 infiltration Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Paints Or Removers (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
The invention discloses a kind of indoor wall environment-friendly waterproof paints and preparation method thereof, are related to technical field of coatings, include the raw material of following part meter：The raw materials such as 55 ~ 75 parts of epoxy resin, 35 ~ 55 parts of ethylene vinyl acetate copolymer emulsion, 25 ~ 35 parts of butadiene-styrene latex, 25 ~ 30 parts of silica flour, 10 ~ 18 parts of chlorinated paraffin, 10 ~ 18 parts of gelling agent of infiltration, 10 ~ 18 parts of improved silica, 5 ~ 10 parts of triethanolamine, 5 ~ 10 parts of sodium metasilicate, 5 ~ 10 parts of tricresyl phosphate, 2 ~ 6 parts of blanc fixe.The present invention forms fine and close protective film in surface of wall, and cohesive force and adhesive force are high, and water resistance is excellent.
Description
Technical Field
The invention relates to the technical field of coatings, and particularly relates to an indoor wall surface environment-friendly waterproof coating and a preparation method thereof.
Background
The existing inner wall coating materials and technologies are more, and the coating coated on the surface of the concrete outer wall also has the problems of poor waterproofness and heat insulation performance and the like.
Disclosure of Invention
The invention aims to provide an indoor wall surface environment-friendly waterproof coating and a preparation method thereof, which can form a compact protective film on the surface of a wall body, and has high adhesive force and adhesion and excellent waterproof performance.
The invention provides the following technical scheme: an indoor wall surface environment-friendly waterproof coating comprises the following raw materials in parts by weight: 55-75 parts of epoxy resin, 35-55 parts of ethylene-vinyl acetate copolymer emulsion, 25-35 parts of styrene-butadiene latex, 25-30 parts of quartz powder, 10-18 parts of chlorinated paraffin, 10-18 parts of a permeable gelling agent, 10-18 parts of modified silica, 5-10 parts of triethanolamine, 5-10 parts of sodium silicate, 5-10 parts of tricresyl phosphate, 2-6 parts of precipitated barium sulfate, 2-6 parts of 2, 2-dimethylolpropionic acid, 2-6 parts of ethylenediamine, 2-6 parts of sodium pyrophosphate, 2-6 parts of dimethyl glycidyl ether and 75-85 parts of water;
the penetrating gelling agent comprises the following raw materials in parts by weight: 10-15 parts of a crystallizing agent, 14-16 parts of an adhesion promoter, 9-11 parts of potassium sorbate, 9-11 parts of nano zirconium dioxide, 5-8 parts of an accelerating agent, 5-8 parts of calcium pantothenate, 1-4 parts of copper sulfate, 1-4 parts of phenyl salicylate and 1-4 parts of calcium citrate.
The composite material comprises the following raw materials in parts by weight: 60-70 parts of epoxy resin, 40-50 parts of ethylene-vinyl acetate copolymer emulsion, 28-32 parts of styrene-butadiene latex, 26-28 parts of quartz powder, 12-14 parts of chlorinated paraffin, 12-14 parts of a permeable gelling agent, 12-14 parts of modified silica, 7-9 parts of triethanolamine, 7-9 parts of sodium silicate, 7-9 parts of tricresyl phosphate, 3-5 parts of precipitated barium sulfate, 3-5 parts of 2, 2-dimethylolpropionic acid, 3-5 parts of ethylenediamine, 3-5 parts of sodium pyrophosphate, 3-5 parts of dimethyl glycidyl ether and 78-82 parts of water;
the penetrating gelling agent comprises the following raw materials in parts by weight: 11-14 parts of a crystallizing agent, 14-15 parts of an adhesion promoter, 9-10 parts of potassium sorbate, 9-10 parts of nano zirconium dioxide, 6-7 parts of an accelerating agent, 6-7 parts of calcium pantothenate, 2-3 parts of copper sulfate, 2-3 parts of phenyl salicylate and 2-3 parts of calcium citrate.
The accelerator comprises the following raw materials in parts by weight: 2-3 parts of lithium carbonate, 1-2 parts of sodium aluminate, 0.8-1.2 parts of zinc oxide and 0.4-0.6 part of ethanol solution.
Wherein the adhesion promoter comprises the following raw materials in parts by weight: 4-5 parts of vinyl acetate and ethylene copolymerized rubber powder, 3-4 parts of active magnesium oxide, 2-3 parts of bentonite, 2-3 parts of calcium formate, 1-2 parts of monohydrogen phosphate, 0.8-1.2 parts of borax, 0.8-1.2 parts of starch ether, 0.4-0.6 part of gelatin powder and 0.4-0.6 part of ammonium persulfate.
Wherein the crystallizing agent is at least one of sodium methyl silicate, sodium metasilicate and potassium silicate.
Wherein the modified silicon dioxide comprises the following raw materials in parts by weight: 15-20 parts of silicon dioxide, 4-5 parts of nano silicon nitride, 4-5 parts of quick lime, 1-2 parts of stearic acid, 1-2 parts of turpentine, 0.8-1.2 parts of diaminodiphenylmethane, 0.5-0.9 part of sodium tripolyphosphate, 0.3-0.5 part of polyoxyethylene lauryl ether, 0.3-0.5 part of diisobutyl phthalate and 16-20 parts of deionized water.
The preparation method of the modified silicon dioxide comprises the following steps: adding silicon dioxide, quicklime, nano-scale silicon nitride and sodium tripolyphosphate into deionized water according to a ratio, uniformly stirring and dispersing to obtain a suspension, drying at 50-65 ℃ until the water content is lower than 5%, adding diaminodiphenylmethane and diisobutyl phthalate, heating to 130-150 ℃, mixing and stirring for 40-60 min, cooling to room temperature, adding the rest raw materials, stirring at the rotating speed of 700-800 r/min for 3-4 h, drying at 60-70 ℃, and grinding to obtain the nano-silicon dioxide/sodium tripolyphosphate composite material.
The invention provides a preparation method of an indoor wall surface environment-friendly waterproof coating, which comprises the following steps:
(1) preparation of penetrating gelling agent
Mixing a crystallizing agent, an adhesion promoter, potassium sorbate, nano zirconium dioxide, an accelerating agent, calcium pantothenate, copper sulfate, phenyl salicylate and calcium citrate according to a ratio to obtain a mixture A, adding the mixture A into 10-15 times of water by weight, stirring and uniformly dispersing at 55-65 ℃, and drying to obtain a permeable gelling agent;
(2) and (2) weighing the rest raw materials and the permeable gelling agent obtained in the step (1) according to the proportion, adding the weighed materials into water, and stirring and dispersing the materials uniformly at the temperature of 45-55 ℃ to obtain a finished product.
The invention has the beneficial effects that: a compact protective film is formed on the surface of the wall body, so that the adhesive force and the adhesive force are high, and the waterproof performance is excellent, and the adhesive force are as follows:
(1) according to the invention, epoxy resin, ethylene-vinyl acetate copolymer emulsion and styrene-butadiene latex are adopted as main raw materials, quartz powder, chlorinated paraffin, permeable gelling agent, modified silicon dioxide, triethanolamine, sodium silicate, tricresyl phosphate, precipitated barium sulfate and the like are adopted as auxiliary materials, and the indoor wall surface environment-friendly waterproof coating obtained by a reasonable proportion and a preparation method forms a compact protective film on the surface of a wall body, has high cohesive force and adhesive force and excellent waterproof performance, and has good effects of preventing mildew and inhibiting mildew when used as a wall body skin layer;
(2) the invention adopts the crystallizing agent, the adhesion promoter, the potassium sorbate, the nano zirconium dioxide, the accelerating agent, the calcium pantothenate, the copper sulfate, the phenyl salicylate and the calcium citrate to prepare the permeable gelling agent, has good permeability and gelling property, can permeate into wall cracks and can tightly combine other raw materials with wall cement, can prevent a coating from falling off, and simultaneously can prevent the wall from generating water seepage due to the temperature difference between the inside and the outside, thereby playing the roles of water prevention and mildew prevention;
(3) the modified silicon dioxide is prepared from raw materials such as silicon dioxide, quicklime, nano-silicon nitride, stearic acid, turpentine, diaminodiphenylmethane, sodium tripolyphosphate and the like, and the obtained modified silicon dioxide has stronger adsorbability and dispersibility, improves the stability and the ageing resistance of a coating, and is toughened and reinforced;
(4) the adhesion promoter is prepared from vinyl acetate and ethylene copolymerized rubber powder, active magnesium oxide, bentonite, calcium formate, monohydrogen phosphate, borax, starch ether, gelatin powder and ammonium persulfate, and can improve the adhesive force of the coating, prevent the coating from falling off to cause water penetration, and promote the waterproof and heat-insulating effects.
Detailed Description
The invention will be further illustrated with reference to the following specific examples. These examples are intended to illustrate the invention and are not intended to limit the scope of the invention.
Example 1
An indoor wall surface environment-friendly waterproof coating comprises the following raw materials in parts by weight: 55 parts of epoxy resin, 35 parts of ethylene-vinyl acetate copolymer emulsion, 25 parts of styrene-butadiene latex, 25 parts of quartz powder, 10 parts of chlorinated paraffin, 10 parts of permeable gelling agent, 10 parts of modified silicon dioxide, 5 parts of triethanolamine, 5 parts of sodium silicate, 5 parts of tricresyl phosphate, 2 parts of precipitated barium sulfate, 2 parts of 2, 2-dimethylolpropionic acid, 2 parts of ethylenediamine, 2 parts of sodium pyrophosphate, 2 parts of dimethyl glycidyl ether and 75 parts of water;
the penetrating gelling agent comprises the following raw materials in parts by weight: 10 parts of crystallizing agent, 14 parts of adhesion promoter, 9 parts of potassium sorbate, 9 parts of nano zirconium dioxide, 5 parts of accelerating agent, 5 parts of calcium pantothenate, 1 part of copper sulfate, 1-part of phenyl salicylate and 1 part of calcium citrate.
Wherein,
the accelerator comprises the following raw materials in parts by weight: 2 parts of lithium carbonate, 1 part of sodium aluminate, 0.8 part of zinc oxide and 0.4 part of ethanol solution.
The adhesion promoter comprises the following raw materials in parts by weight: 4 parts of vinyl acetate and ethylene copolymerized rubber powder, 3 parts of active magnesium oxide, 2 parts of bentonite, 2 parts of calcium formate, 1 part of monohydrogen phosphate, 0.8 part of borax, 0.8 part of starch ether, 0.4 part of gelatin powder and 0.4 part of ammonium persulfate.
The crystallizing agent is sodium methyl silicate.
Wherein,
the modified silicon dioxide comprises the following raw materials in parts by weight: 15 parts of silicon dioxide, 4 parts of nano silicon nitride, 4 parts of quick lime, 1 part of stearic acid, 1 part of turpentine, 0.8 part of diaminodiphenylmethane, 0.5 part of sodium tripolyphosphate, 0.3 part of polyoxyethylene lauryl ether, 0.3 part of diisobutyl phthalate and 16 parts of deionized water.
The preparation method of the modified silicon dioxide comprises the following steps: adding silicon dioxide, quicklime, nano-scale silicon nitride and sodium tripolyphosphate into deionized water according to a ratio, uniformly stirring and dispersing to obtain a suspension, drying at 50 ℃ until the water content is lower than 5%, adding diaminodiphenylmethane and diisobutyl phthalate, heating to 130 ℃, mixing and stirring for 40min, cooling to room temperature, adding the rest raw materials, stirring at a rotating speed of 700r/min for 3h, drying at 60 ℃, and grinding to obtain the nano-scale silicon dioxide/sodium tripolyphosphate composite material.
The embodiment provides a preparation method of an indoor wall surface environment-friendly waterproof coating, which comprises the following steps:
(1) preparation of penetrating gelling agent
Mixing a crystallizing agent, an adhesion promoter, potassium sorbate, nano zirconium dioxide, an accelerating agent, calcium pantothenate, copper sulfate, phenyl salicylate and calcium citrate according to a ratio to obtain a mixture A, adding the mixture A into 10 times of water by weight, stirring and dispersing uniformly at the temperature of 55-65 ℃, and drying to obtain a permeable gelling agent;
(2) and (2) weighing the rest raw materials and the permeable gelling agent obtained in the step (1) according to the proportion, adding the weighed materials into water, and stirring and dispersing the materials uniformly at the temperature of 45 ℃ to obtain a finished product.
Example 2
An indoor wall surface environment-friendly waterproof coating comprises the following raw materials in parts by weight: 75 parts of epoxy resin, 55 parts of ethylene-vinyl acetate copolymer emulsion, 35 parts of styrene-butadiene latex, 30 parts of quartz powder, 18 parts of chlorinated paraffin, 18 parts of permeable gelling agent, 18 parts of modified silicon dioxide, 10 parts of triethanolamine, 10 parts of sodium silicate, 10 parts of tricresyl phosphate, 6 parts of precipitated barium sulfate, 6 parts of 2, 2-dimethylolpropionic acid, 6 parts of ethylenediamine, 6 parts of sodium pyrophosphate, 6 parts of dimethyl glycidyl ether and 85 parts of water;
the penetrating gelling agent comprises the following raw materials in parts by weight: 15 parts of crystallizing agent, 16 parts of adhesion promoter, 11 parts of potassium sorbate, 11 parts of nano zirconium dioxide, 8 parts of accelerating agent, 8 parts of calcium pantothenate, 4 parts of copper sulfate, 4 parts of phenyl salicylate and 4 parts of calcium citrate.
Wherein,
the accelerator comprises the following raw materials in parts by weight: 3 parts of lithium carbonate, 2 parts of sodium aluminate, 1.2 parts of zinc oxide and 0.6 part of ethanol solution.
The adhesion promoter comprises the following raw materials in parts by weight: 5 parts of vinyl acetate and ethylene copolymerized rubber powder, 4 parts of active magnesium oxide, 3 parts of bentonite, 3 parts of calcium formate, 2 parts of monohydrogen phosphate, 1.2 parts of borax, 1.2 parts of starch ether, 0.6 part of gelatin powder and 0.6 part of ammonium persulfate.
The crystallizing agents are sodium metasilicate and potassium silicate.
Wherein,
the modified silicon dioxide comprises the following raw materials in parts by weight: 20 parts of silicon dioxide, 5 parts of nano silicon nitride, 5 parts of quick lime, 2 parts of stearic acid, 2 parts of turpentine, 1.2 parts of diaminodiphenylmethane, 0.9 part of sodium tripolyphosphate, 0.5 part of polyoxyethylene lauryl ether, 0.5 part of diisobutyl phthalate and 20 parts of deionized water.
The preparation method of the modified silicon dioxide comprises the following steps: adding silicon dioxide, quicklime, nano-scale silicon nitride and sodium tripolyphosphate into deionized water according to a ratio, uniformly stirring and dispersing to obtain a suspension, drying at 65 ℃ until the water content is lower than 5%, adding diaminodiphenylmethane and diisobutyl phthalate, heating to 150 ℃, mixing and stirring for 60min, cooling to room temperature, adding the rest raw materials, stirring at the rotating speed of 800r/min for 4h, drying at 70 ℃, and grinding to obtain the nano-scale silicon dioxide/sodium tripolyphosphate composite material.
The embodiment of the invention provides a preparation method of an indoor wall surface environment-friendly waterproof coating, which comprises the following steps:
(1) preparation of penetrating gelling agent
Mixing a crystallizing agent, an adhesion promoter, potassium sorbate, nano zirconium dioxide, an accelerating agent, calcium pantothenate, copper sulfate, phenyl salicylate and calcium citrate according to a ratio to obtain a mixture A, adding the mixture A into 15 times of water by weight, stirring and uniformly dispersing at 65 ℃, and drying to obtain a permeable gelling agent;
(2) and (2) weighing the rest raw materials and the permeable gelling agent obtained in the step (1) according to the proportion, adding the weighed materials into water, and stirring and dispersing the materials uniformly at the temperature of 55 ℃ to obtain a finished product.
Example 3
An indoor wall surface environment-friendly waterproof coating comprises the following raw materials in parts by weight: 65 parts of epoxy resin, 45 parts of ethylene-vinyl acetate copolymer emulsion, 30 parts of styrene-butadiene latex, 27.5 parts of quartz powder, 14 parts of chlorinated paraffin, 14 parts of permeable gelling agent, 14 parts of modified silicon dioxide, 7.5 parts of triethanolamine, 7.5 parts of sodium silicate, 7.5 parts of tricresyl phosphate, 4 parts of precipitated barium sulfate, 4 parts of 2, 2-dimethylolpropionic acid, 4 parts of ethylenediamine, 4 parts of sodium pyrophosphate, 4 parts of dimethyl glycidyl ether and 80 parts of water;
the penetrating gelling agent comprises the following raw materials in parts by weight: 12.5 parts of crystallizing agent, 15 parts of adhesion promoter, 10 parts of potassium sorbate, 10 parts of nano zirconium dioxide, 6.5 parts of accelerating agent, 6.5 parts of calcium pantothenate, 2.5 parts of copper sulfate, 2.5 parts of phenyl salicylate and 2.5 parts of calcium citrate.
Wherein,
the accelerator comprises the following raw materials in parts by weight: 2.5 parts of lithium carbonate, 1.5 parts of sodium aluminate, 1 part of zinc oxide and 0.5 part of ethanol solution.
The adhesion promoter comprises the following raw materials in parts by weight: 4.5 parts of vinyl acetate and ethylene copolymerized rubber powder, 3.5 parts of active magnesium oxide, 2.5 parts of bentonite, 2.5 parts of calcium formate, 1.5 parts of monohydrogen phosphate, 1 part of borax, 1 part of starch ether, 0.5 part of gelatin powder and 0.5 part of ammonium persulfate.
The crystallizing agent is potassium silicate.
Wherein the modified silicon dioxide comprises the following raw materials in parts by weight: 17.5 parts of silicon dioxide, 4.5 parts of nano silicon nitride, 4.5 parts of quick lime, 1.5 parts of stearic acid, 1.5 parts of turpentine, 1 part of diaminodiphenylmethane, 0.7 part of sodium tripolyphosphate, 0.34 part of polyoxyethylene lauryl ether, 0.4 part of diisobutyl phthalate and 18 parts of deionized water.
The preparation method of the modified silicon dioxide comprises the following steps: adding silicon dioxide, quicklime, nano-scale silicon nitride and sodium tripolyphosphate into deionized water according to a ratio, uniformly stirring and dispersing to obtain a suspension, drying at 55 ℃ until the water content is lower than 5%, adding diaminodiphenylmethane and diisobutyl phthalate, heating to 140 ℃, mixing and stirring for 50min, cooling to room temperature, adding the rest raw materials, stirring at a rotating speed of 750r/min for 3.5h, drying at 65 ℃, and grinding to obtain the nano-scale silicon dioxide/sodium tripolyphosphate composite material.
The embodiment provides a preparation method of an indoor wall surface environment-friendly waterproof coating, which comprises the following steps:
(1) preparation of penetrating gelling agent
Mixing a crystallizing agent, an adhesion promoter, potassium sorbate, nano zirconium dioxide, an accelerating agent, calcium pantothenate, copper sulfate, phenyl salicylate and calcium citrate according to a ratio to obtain a mixture A, adding the mixture A into 13 times of water by weight, stirring and uniformly dispersing at 60 ℃, and drying to obtain a permeable gelling agent;
(2) and (2) weighing the rest raw materials and the permeable gelling agent obtained in the step (1) according to the proportion, adding the weighed materials into water, and stirring and dispersing the materials uniformly at 50 ℃ to obtain a finished product.
While the invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that various changes can be made and equivalents can be substituted for elements thereof. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (9)
1. The environment-friendly waterproof coating for indoor wall surfaces is characterized by comprising the following raw materials in parts by weight: 55-75 parts of epoxy resin, 35-55 parts of ethylene-vinyl acetate copolymer emulsion, 25-35 parts of styrene-butadiene latex, 25-30 parts of quartz powder, 10-18 parts of chlorinated paraffin, 10-18 parts of a permeable gelling agent, 10-18 parts of modified silica, 5-10 parts of triethanolamine, 5-10 parts of sodium silicate, 5-10 parts of tricresyl phosphate, 2-6 parts of precipitated barium sulfate, 2-6 parts of 2, 2-dimethylolpropionic acid, 2-6 parts of ethylenediamine, 2-6 parts of sodium pyrophosphate, 2-6 parts of dimethyl glycidyl ether and 75-85 parts of water;
the penetrating gelling agent comprises the following raw materials in parts by weight: 10-15 parts of a crystallizing agent, 14-16 parts of an adhesion promoter, 9-11 parts of potassium sorbate, 9-11 parts of nano zirconium dioxide, 5-8 parts of an accelerating agent, 5-8 parts of calcium pantothenate, 1-4 parts of copper sulfate, 1-4 parts of phenyl salicylate and 1-4 parts of calcium citrate.
2. The indoor wall surface environment-friendly waterproof paint according to claim 1, which is characterized by comprising the following raw materials in parts by weight: 60-70 parts of epoxy resin, 40-50 parts of ethylene-vinyl acetate copolymer emulsion, 28-32 parts of styrene-butadiene latex, 26-28 parts of quartz powder, 12-14 parts of chlorinated paraffin, 12-14 parts of a permeable gelling agent, 12-14 parts of modified silica, 7-9 parts of triethanolamine, 7-9 parts of sodium silicate, 7-9 parts of tricresyl phosphate, 3-5 parts of precipitated barium sulfate, 3-5 parts of 2, 2-dimethylolpropionic acid, 3-5 parts of ethylenediamine, 3-5 parts of sodium pyrophosphate, 3-5 parts of dimethyl glycidyl ether and 78-82 parts of water;
the penetrating gelling agent comprises the following raw materials in parts by weight: 11-14 parts of a crystallizing agent, 14-15 parts of an adhesion promoter, 9-10 parts of potassium sorbate, 9-10 parts of nano zirconium dioxide, 6-7 parts of an accelerating agent, 6-7 parts of calcium pantothenate, 2-3 parts of copper sulfate, 2-3 parts of phenyl salicylate and 2-3 parts of calcium citrate.
3. The indoor wall surface environment-friendly waterproof paint according to claim 1, which is characterized by comprising the following raw materials in parts by weight: 65 parts of epoxy resin, 45 parts of ethylene-vinyl acetate copolymer emulsion, 30 parts of styrene-butadiene latex, 27.5 parts of quartz powder, 14 parts of chlorinated paraffin, 14 parts of permeable gelling agent, 14 parts of modified silicon dioxide, 7.5 parts of triethanolamine, 7.5 parts of sodium silicate, 7.5 parts of tricresyl phosphate, 4 parts of precipitated barium sulfate, 4 parts of 2, 2-dimethylolpropionic acid, 4 parts of ethylenediamine, 4 parts of sodium pyrophosphate, 4 parts of dimethyl glycidyl ether and 80 parts of water;
the penetrating gelling agent comprises the following raw materials in parts by weight: 12.5 parts of crystallizing agent, 15 parts of adhesion promoter, 10 parts of potassium sorbate, 10 parts of nano zirconium dioxide, 6.5 parts of accelerating agent, 6.5 parts of calcium pantothenate, 2.5 parts of copper sulfate, 2.5 parts of phenyl salicylate and 2.5 parts of calcium citrate.
4. The indoor wall surface environment-friendly waterproof coating material as claimed in claim 1, wherein the accelerator comprises the following raw materials in parts by weight: 2-3 parts of lithium carbonate, 1-2 parts of sodium aluminate, 0.8-1.2 parts of zinc oxide and 0.4-0.6 part of ethanol solution.
5. The indoor wall surface environment-friendly waterproof coating material as claimed in claim 1, wherein the adhesion promoter comprises the following raw materials in parts by weight: 4-5 parts of vinyl acetate and ethylene copolymerized rubber powder, 3-4 parts of active magnesium oxide, 2-3 parts of bentonite, 2-3 parts of calcium formate, 1-2 parts of monohydrogen phosphate, 0.8-1.2 parts of borax, 0.8-1.2 parts of starch ether, 0.4-0.6 part of gelatin powder and 0.4-0.6 part of ammonium persulfate.
6. The environmentally friendly waterproof indoor wall coating material of claim 1, wherein the crystallizing agent is at least one of sodium methyl silicate, sodium metasilicate and potassium silicate.
7. The indoor wall surface environment-friendly waterproof coating material as claimed in claim 1, wherein the modified silica comprises the following raw materials in parts by weight: 15-20 parts of silicon dioxide, 4-5 parts of nano silicon nitride, 4-5 parts of quick lime, 1-2 parts of stearic acid, 1-2 parts of turpentine, 0.8-1.2 parts of diaminodiphenylmethane, 0.5-0.9 part of sodium tripolyphosphate, 0.3-0.5 part of polyoxyethylene lauryl ether, 0.3-0.5 part of diisobutyl phthalate and 16-20 parts of deionized water.
8. The high temperature resistant coating for solar device according to claim 7, wherein the modified silica is prepared by the following steps: adding silicon dioxide, quicklime, nano-scale silicon nitride and sodium tripolyphosphate into deionized water according to a ratio, uniformly stirring and dispersing to obtain a suspension, drying at 50-65 ℃ until the water content is lower than 5%, adding diaminodiphenylmethane and diisobutyl phthalate, heating to 130-150 ℃, mixing and stirring for 40-60 min, cooling to room temperature, adding the rest raw materials, stirring at the rotating speed of 700-800 r/min for 3-4 h, drying at 60-70 ℃, and grinding to obtain the nano-silicon dioxide/sodium tripolyphosphate composite material.
9. The preparation method of the indoor wall surface environment-friendly waterproof coating material as claimed in any one of claims 1 to 8, characterized by comprising the following steps:
(1) preparation of penetrating gelling agent
Mixing a crystallizing agent, an adhesion promoter, potassium sorbate, nano zirconium dioxide, an accelerating agent, calcium pantothenate, copper sulfate, phenyl salicylate and calcium citrate according to a ratio to obtain a mixture A, adding the mixture A into 10-15 times of water by weight, stirring and uniformly dispersing at 55-65 ℃, and drying to obtain a permeable gelling agent;
(2) and (2) weighing the rest raw materials and the permeable gelling agent obtained in the step (1) according to the proportion, adding the weighed materials into water, and stirring and dispersing the materials uniformly at the temperature of 45-55 ℃ to obtain a finished product.
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