CN108395787A - A kind of aqueous industrial artistic coating and preparation method thereof - Google Patents
A kind of aqueous industrial artistic coating and preparation method thereof Download PDFInfo
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- CN108395787A CN108395787A CN201810335198.7A CN201810335198A CN108395787A CN 108395787 A CN108395787 A CN 108395787A CN 201810335198 A CN201810335198 A CN 201810335198A CN 108395787 A CN108395787 A CN 108395787A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/327—Aluminium phosphate
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of aqueous industrial artistic coatings and preparation method thereof.The coating includes water, dispersant, GN 90, wetting agent, neutralizer, thixotroping resin, titanium dioxide, filling powder, water-based acrylic resin lotion, aqueous epoxy resin emulsion, thickener, antifoaming agent, film forming agent and aqueous color paste etc..The aqueous industrial artistic coating of the present invention has extremely low VOC content, is free of benzene and free heavy metal, and production, processing, is stored without fire safety evaluating hidden danger at transport.Solid content height is matched in the present invention, unit coating area is big, and unit cost is low.In addition the advantages that coating also has high rigidity, and damage resistant, fast drying is easy to operate, and dosage is few, efficient, and surface detail is firm, and protected decoration works well, has filled up the blank of aqueous industrial artistic coating.
Description
Technical field
The present invention relates to industrial coating field, more particularly to a kind of aqueous industrial artistic coating and preparation method thereof.
Background technology
In production, it needs to carry out application to surfaces such as mechanical equipment, galvanized sheet, woodenware and fiberglass, at present using most
Generally high volatile organic compound (VOC), benzene and content of beary metal are high, the big and seriously polluted solvent type production of dosage
Product not only would seriously pollute the environment, and can also cause most directly to injure to the body of production operation personnel.
Invention content
The present invention provides a kind of aqueous industrial artistic coatings, do film forming matter using water-based lotion, can solve
State one or more of prior art problem.
According to an aspect of the invention, there is provided a kind of aqueous industrial artistic coating, includes the component of following mass ratio,
Water, 12-28 parts；
Dispersant, 0.1-2 parts；Pigment and filler dispersion are effectively facilitated, guarantee system is stablized；
GN-90,10-20 parts, GN-90 is a kind of Ludox, can play the role of the anti-sticking infiltration ground of hardening；
Wetting agent, using wetting agent 270, can significantly reduce system and the surface tension of substrate interface by 0.1-0.4 parts,
Prevent shrinkage cavity cissing phenomenon；
Neutralizer, adjusts pH value by 0.1-0.4 parts；
Thixotroping resin, 0.1-5 parts, guarantee system is stablized；
Titanium dioxide, 45-65 parts；Pigment coloration power and covering power are provided；
Powder is filled, 8-30 parts, filling powder is functional material, and because of ground difference, two kinds to six kinds additions may be selected,
Finished weight, enhancing paint film toughness, inertia and chemical resistance can be increased；
Water-based acrylic resin lotion, 40-65 parts, water-based acrylic resin emulsion content is 46%, model AC1211；
Main film forming substance provides paint adhesion；
Aqueous epoxy resin emulsion, 20-40 parts, aqueous epoxy resin emulsion content is 53%, model 1053；It is secondary at
Membrane substance enhances anticorrosion and cohesive force；
Thickener, 0.15-0.8 parts；Adjusting coating viscosity, convenient for constructing and ensureing coating bin stability；
Antifoaming agent, reduces and inhibits the foam in coating by 0.2-2 parts；
Film forming agent, is a kind of ethers slow drying solvent using film forming agent DPnB, can adjust product in not equality of temperature by 0.3-1 parts
Service efficiency under degree and humidity environment；With,
Aqueous color paste, 0.1-4 parts, for modulating various required specific colors.
The invention has the advantages that the aqueous industrial artistic coating of the present invention has extremely low VOC content, benzene and trip are free of
From heavy metal, production, processing, is stored without fire safety evaluating hidden danger at transport.It is high that solid content is matched in the present invention, unit coating surface
Product is big, and unit cost is low.In addition the coating also has high rigidity, and damage resistant, fast drying is easy to operate, and dosage is few, efficient,
The advantages that surfacecti proteon decorative effect is good.The blank of domestic aqueous industrial art coating is filled up.
In some embodiments, dispersant includes：
Dispersant 1080,0.1-0.8 parts；
Dispersant 136,0.1-0.8 parts.
In some embodiments, filling powder includes talcum powder, blanc fixe, water aluminum-silver slurry, silicon powder, oxidation
Two kinds to six kinds in iron, pearlescent pigment, aluminium triphosphate and zinc oxide.
In some embodiments, filling powder includes：
5-15 parts of the talcum powder of 800-2000 mesh；With,
10-15 parts of the silicon powder of 1250 mesh.
Advantage is that the filling powder is used for aqueous woodware paint, aqueous artwork paint and aqueous glass steel part paint.
In some embodiments, filling powder includes：
10-15 parts of the talcum powder of 1250 mesh；
8-10 parts of the silicon powder of 1250 mesh；
10-12 parts of the iron oxide of 325 mesh；
1250 5-8 parts of mesh aluminium triphosphates；
2-5 parts of zinc oxide；
5-10 parts of water aluminum-silver slurry；
8-10 parts of pearlescent pigment.
Advantage is that the filling powder is used for aqueous metallic paint, including aqueous mechanized equipment paint.
In some embodiments, filling powder includes：
5-10 parts of water aluminum-silver slurry；With,
8-10 parts of pearlescent pigment.
Advantage is that water aluminum-silver slurry and pearlescent pigment preferably individually add in aqueous metallic paint, in aqueous metallic paint
When color matching less plus or acid pigment should be not added with to prevent demulsification as far as possible.
In some embodiments, antifoaming agent includes：
Antifoaming agent A3210,0.2-1.2 part；With,
Antifoaming agent 240,0.2-0.8 parts.
Advantage is that aqueous defoamer A3210 is the mineral oil synthesis antifoaming agent of nontoxic easily biological-degradable, is played fast
Speed eliminates the effect of foam；Aqueous defoamer R240 is the mineral oil antifoam agent of nontoxic easily biological-degradable, plays inhibition system bubble
The effect that foam generates.
In some embodiments, neutralizer is amine neutralizer AMP96 or ethylenediamine.
In some embodiments, thixotroping resin is thixotroping Resin A Q600 or bentonite.
According to another aspect of the present invention, a kind of preparation method of aqueous industrial artistic coating is provided, step includes：
Container is added by required amount of 80% in water, starts blender, rotating speed turns for 200-400, sequentially adds dispersion
Agent 1080, dispersant 136, wetting agent 270, neutralizer AMP96 disperse 1 minute；
Thixotroping Resin A Q600 is added at 1000 turns to disperse 5-10 minutes；
Titanium dioxide is added and turns dispersion 45-60 minutes in 1200-1500；
Be added content be 50% antifoaming agent A3210 800 turns 10-15 minutes；
Be added content be 50% antifoaming agent 240 500 turns 10-15 minutes；
It is used as semi-finished product S spare above；
It weighs the water-based acrylic resin lotion that enough contents are 46% to be put into special container, 800 turns of 3-5 points of stirrings
Clock is added the aqueous epoxy resin emulsion that content is 53% and continues stirring 3-5 minutes；
GN-90 is added and turns stirring 5-10 minutes in 500-600；
Film forming agent DPnB is added and turns stirring 5-10 minutes in 500-600；
Filling powder is added and turns stirring 15-30 minutes in 800-1200；
Semi-finished product S is added, turns stirring 20-30 minutes in 800-1000；
Antifoaming agent A3210 is added, turns stirring 3-5 minutes in 400-600；
Antifoaming agent 240 is added, turns stirring 3-5 minutes in 400-600；
Thickener TT615 is added and turns stirring 5-10 minutes in 500-600；
Mill base is added, stirring is modulated into required color in 10-15 minutes；
Using remaining 20% water cleaning container, water for cleaning is added in coating and is used.
The aqueous industrial artistic coating of the method production of the present invention is equipped with using preferred environment-friendly water-based lotion as film forming matter
High thixotropic resin and high performance adjuvant solve the existing flowing of water paint for a long time soon, and levelling is poor, and hardness is low, attachment
Power is bad, not damage resistant, easy sagging, can only book apply, can not disposably form the problem of beautiful decorative pattern and smooth paint film.Film is dry
After can ensure that surface is smooth, decorative pattern is firm for a long time, it is beautiful in colour, filled up the disposable fine arts industry of domestic aqueous high-performance
The blank of application.The present invention, which need not dilute, can be used, and reduces technical difficulty of operation, greatly improves working efficiency.Follow-up cleaning
It can be reused with water, secondary pollution will not be caused, be effectively improved work and living environment.
Specific implementation mode
The present invention is described in further detail below.
The present invention be one kind in galvanized part, tinplate, aluminum products, glass fiber reinforced plastics product, woodwork and cement components etc. are more
The aqueous industrial artistic coating of protected decoration effect is played on type surface, and the present invention uses component in table one to be prepared.
The component of one aqueous industrial artistic coating of table is detailed
A kind of preparation method of aqueous industrial artistic coating, step include：
Container is added by required amount of 80% in water, starts blender, rotating speed turns for 200-400, sequentially adds dispersion
Agent 1080, dispersant 136, wetting agent 270, neutralizer AMP96 disperse 1 minute；
Thixotroping Resin A Q600 is added at 1000 turns to disperse 5-10 minutes；
Titanium dioxide is added and turns dispersion 45-60 minutes in 1200-1500；
Be added content be 50% antifoaming agent A3210 800 turns 10-15 minutes；
Be added content be 50% antifoaming agent 240 500 turns 10-15 minutes；
It is used as semi-finished product S spare above；
It weighs the water-based acrylic resin lotion that enough contents are 46% to be put into special container, 800 turns of 3-5 points of stirrings
Clock is added the aqueous epoxy resin emulsion that content is 53% and continues stirring 3-5 minutes；
GN-90 is added and turns stirring 5-10 minutes in 500-600；
Film forming agent DPnB is added and turns stirring 5-10 minutes in 500-600；
Filling powder is added and turns stirring 15-30 minutes in 800-1200；
Semi-finished product S is added, turns stirring 20-30 minutes in 800-1000；
Antifoaming agent A3210 is added, turns stirring 3-5 minutes in 400-600；
Antifoaming agent 240 is added, turns stirring 3-5 minutes in 400-600；
Thickener TT615 is added and turns stirring 5-10 minutes in 500-600；
Mill base is added, stirring is modulated into required color in 10-15 minutes；
Using remaining 20% water cleaning container, water for cleaning is added in coating and is used.
The influence of dispersant, neutralizer, antifoaming agent and thickener to properties of product will not very significantly in the present invention, other classes
The use of the dispersant, neutralizer, antifoaming agent and thickener of type should be covered by the protection scope of the present invention.
Thixotroping resin has general character, bentonitic use that should cover the guarantor in the present invention with swelling great soil group thixotropic agent in the present invention
Within the scope of shield.
The range of choice of titanium dioxide is very wide in the present invention, and different titanium dioxides do not cause essence to the main performance of entire product
Property influence, the use of different titanium dioxides is covered by the protection scope of the present invention.
Aqueous acrylic emulsion and aqueous epoxy resin emulsion have been not excluded for similar product in the present invention, during use
It is covered by the protection scope of the present invention.
The present invention can be used from dry and two kinds of drying modes of drying.From it is dry when adapted 4-16% aqueous amines crosslinking agent or
2-15% water-based isocyanate crosslinking agents
Embodiment 1
Container is added by required amount of 80% in water, starts blender, rotating speed is 200 turns, sequentially adds dispersant
1080, dispersant 136, wetting agent 270, neutralizer AMP96 disperse 1 minute；Thixotroping Resin A Q600 is added and disperses 5 at 1000 turns
Minute；Titanium dioxide is added at 1200 turns to disperse 45 minutes；Be added content be 50% antifoaming agent A3210 800 turns 10 minutes；Add
Enter content be 50% antifoaming agent 240 500 turns 10 minutes, it is spare as semi-finished product S.
Embodiment 2
GN-90 is added to stir 5 minutes at 500 turns；Film forming agent DPnB is added to stir 5 minutes at 500 turns；Filling powder is added
It is stirred 15 minutes at 800 turns；The semi-finished product S in embodiment 1 is added, is stirred 20 minutes at 800 turns；Remaining antifoaming agent is added
A3210 is stirred 5 minutes at 400 turns；Remaining antifoaming agent 240 is added, is stirred 3-5 minutes at 400 turns；Thickener TT615 is added to exist
500 turns are stirred 5 minutes；Mill base is added, stirring is modulated into required color in 10 minutes；Using remaining 20% water cleaning container,
Water for cleaning is added in coating and is used.
Aqueous industrial artistic coating made of the embodiment of the present invention can reach the technical indicator of table two.
Two aqueous industrial artistic coating performance indicator of table
Above-described is only some embodiments of the present invention.For those of ordinary skill in the art, not
Under the premise of being detached from the invention design, various modifications and improvements can be made, these belong to the protection model of the present invention
It encloses.
Claims (10)
1. a kind of aqueous industrial artistic coating, wherein include the component of following mass ratio,
Water, 12-28 parts；
Dispersant, 0.1-2 parts；
GN-90,10-20 parts；
Wetting agent, 0.1-0.4 parts；
Neutralizer, 0.1-0.4 parts；
Thixotroping resin, 0.1-5 parts；
Titanium dioxide, 45-65 parts；
Filling powder, 8-30 parts；
Water-based acrylic resin lotion, 40-65 parts；
Aqueous epoxy resin emulsion, 20-40 parts；
Thickener, 0.15-0.8 parts；
Antifoaming agent, 0.2-2 parts；
Film forming agent, 0.3-1 parts；
Aqueous color paste, O.1-4 part.
2. aqueous industrial artistic coating according to claim 1, wherein dispersant includes：
Dispersant 1080,0.1-0.8 parts；With
Dispersant 136,0.1-0.8 parts.
3. aqueous industrial artistic coating according to claim 1, wherein filling powder includes talcum powder, blanc fixe, water
Two kinds to six kinds in property aluminum paste, silicon powder, iron oxide, pearlescent pigment, aluminium triphosphate and zinc oxide.
4. aqueous industrial artistic coating according to claim 1 and preparation method thereof, wherein filling powder includes：
5-15 parts of the talcum powder of 800-2000 mesh；
10-15 parts of the silicon powder of 1250 mesh.
5. aqueous industrial artistic coating according to claim 1, wherein filling powder includes：
10-15 parts of the talcum powder of 1250 mesh；
8-10 parts of the silicon powder of 1250 mesh；
10-12 parts of the iron oxide of 325 mesh；
1250 5-8 parts of mesh aluminium triphosphates；
2-5 parts of zinc oxide；
5-10 parts of water aluminum-silver slurry；
8-10 parts of pearlescent pigment.
6. aqueous industrial artistic coating according to claim 1, wherein filling powder includes：
5-10 parts of water aluminum-silver slurry；Or
8-10 parts of pearlescent pigment.
7. aqueous industrial artistic coating according to claim 1, wherein antifoaming agent includes：
Antifoaming agent A3210,0.2-1.2 part；With,
Antifoaming agent 240,0.2-0.8 parts.
8. aqueous industrial artistic coating according to claim 1, wherein neutralizer is amine neutralizer AMP96 or second two
Amine.
9. aqueous industrial artistic coating according to claim 1, wherein thixotropic agent is thixotroping Resin A Q600 or swelling
Soil.
10. such as the preparation method of claim 1-9 any one of them aqueous industrial artistic coatings, wherein step includes：
Container is added by required amount of 80% in water, starts blender, rotating speed turns for 200-400, sequentially adds dispersant
1080, dispersant 136, wetting agent 270, neutralizer AMP96 disperse 1 minute；
Thixotroping Resin A Q600 is added at 1000 turns to disperse 5-10 minutes；
Titanium dioxide is added and turns dispersion 45-60 minutes in 1200-1500；
Be added content be 50% antifoaming agent A3210 800 turns 10-15 minutes；
Be added content be 50% antifoaming agent 240 500 turns 10-15 minutes；
It is used as semi-finished product S spare above；
It weighs the water-based acrylic resin lotion that enough contents are 46% to be put into special container, 800 turns are stirred 3-5 minutes, are added
Enter the aqueous epoxy resin emulsion that content is 53% and continues stirring 3-5 minutes；
GN-90 is added and turns stirring 5-10 minutes in 500-600；
Film forming agent DPnB is added and turns stirring 5-10 minutes in 500-600；
Filling powder is added and turns stirring 15-30 minutes in 800-1200；
Semi-finished product S is added, turns stirring 20-30 minutes in 800-1000；
Remaining antifoaming agent A3210 is added, turns stirring 3-5 minutes in 400-600；
Remaining antifoaming agent 240 is added, turns stirring 3-5 minutes in 400-600；
Thickener TT615 is added and turns stirring 5-10 minutes in 500-600；
Mill base is added, stirring is modulated into required color in 10-15 minutes；
With remaining water cleaning means and container and it is added among coating.
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| CN201810335198.7A CN108395787A (en) | 2018-04-13 | 2018-04-13 | A kind of aqueous industrial artistic coating and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109913018A (en) * | 2019-02-13 | 2019-06-21 | 临沂大学 | A kind of fine arts environmental protection coating material and preparation method thereof and ager |
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| CN1927968A (en) * | 2006-09-05 | 2007-03-14 | 英志祥 | Water industrial paint based on organosilicon acrylic acid epoxy ester water dispersion and preparation method thereof |
| CN101045843A (en) * | 2007-04-18 | 2007-10-03 | 邹磊 | Water industrial antirust paint and preparation method thereof |
| CN101747692A (en) * | 2008-12-22 | 2010-06-23 | 怀懋企业有限公司 | Components of waterborne paint |
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2018
- 2018-04-13 CN CN201810335198.7A patent/CN108395787A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1709994A (en) * | 2005-07-05 | 2005-12-21 | 北京国科京彪新材料科技有限公司 | Anticorrosive waterproof nano industrial coating and its preparing method |
| CN1927968A (en) * | 2006-09-05 | 2007-03-14 | 英志祥 | Water industrial paint based on organosilicon acrylic acid epoxy ester water dispersion and preparation method thereof |
| CN101045843A (en) * | 2007-04-18 | 2007-10-03 | 邹磊 | Water industrial antirust paint and preparation method thereof |
| CN101747692A (en) * | 2008-12-22 | 2010-06-23 | 怀懋企业有限公司 | Components of waterborne paint |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109913018A (en) * | 2019-02-13 | 2019-06-21 | 临沂大学 | A kind of fine arts environmental protection coating material and preparation method thereof and ager |
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Application publication date: 20180814 |