CN108395623A - A kind of instrument board raw material of anti-aging antiultraviolet - Google Patents
A kind of instrument board raw material of anti-aging antiultraviolet Download PDFInfo
- Publication number
- CN108395623A CN108395623A CN201810289527.9A CN201810289527A CN108395623A CN 108395623 A CN108395623 A CN 108395623A CN 201810289527 A CN201810289527 A CN 201810289527A CN 108395623 A CN108395623 A CN 108395623A
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- China
- Prior art keywords
- tempered glass
- aging
- parts
- raw material
- antiultraviolet
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/40—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
- C08K5/1345—Carboxylic esters of phenolcarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Abstract
The invention discloses a kind of instrument board raw materials of anti-aging antiultraviolet, are composed of the following raw materials by weight:100 parts of polypropylene, 20 parts of talcum powder, 0.03~0.05 part of benzotriazole, 0.03~0.05 part of phenyl salicylate are double(1,2,2,6,6 pentamethvl)0.01~0.02 part of sebacate, 0.1~0.2 part of reflective membrane granule.The present invention in such a way that light shielding material is combined, is made additive that can act on polypropylene itself and acts on light shielding material using light absorber, improves reflection and anti-ultraviolet ability, requirement is still met by long-term illumination experiment.
Description
Technical field
The present invention relates to a kind of instrument board, the instrument board raw material of specifically a kind of anti-aging antiultraviolet.
Background technology
The function of vehicle instrument is exactly to obtain the data needed and shown using suitable mode.Pervious instrument is general
It is limited in the display and 4 ~ 5 warning functions that 3 ~ 4 are measured, present new-type instrument, which then reaches, about 15 amount displays and about 40 polices
Accuse monitoring function.For different information by different acquisition modes and display mode, current new-type meter information acquisition modes are main
There are three types of:It is transmitted by Vehicle Body Bus;It is sampled and is converted by A/D;Changed by I/O state and is obtained.The material of vehicle instrument mostly uses
PP plastics are made, and current fascia is anti-oxidant, anti-uv-ray is poor, since vehicle is parked in the external world for a long time, when
Between the long aging that can lead to instrument board by sunlight, cause the damage of instrument board, it is serious to use.
Invention content
Technical problem to be solved by the invention is to provide a kind of instrument board raw materials of anti-aging antiultraviolet.
In order to solve the above technical problems, the technical scheme is that:A kind of instrument board raw material of anti-aging antiultraviolet,
It is composed of the following raw materials by weight:100 parts of polypropylene, 20 parts of talcum powder, 0.03~0.05 part of benzotriazole, phenyl salicylate
It is 0.03~0.05 part, double(1,2,2,6,6- pentamethvl)0.01~0.02 part of sebacate, reflective membrane granule 0.1~0.2
Part.
The preparation method of the reflective membrane granule includes the following steps:
1. first cleaning up the tempered glass that thickness is 0.05 millimeter, tempered glass is made to reach hydrophilic;2. then using chlorination
Stannous is sensitized tempered glass, and pure water wash clean is used after the completion of sensitization;3. silver ammino solution is used to add glucose as reducing solution, spray
Tempered glass surface is applied, then places 50~55 minutes and is rinsed well with clear water, the tempered glass thin slice that one side is minute surface is made;
4. 3. minute surface tempered glass thin slice that step is obtained crushes, the tempered glass fragment of crushing is first crossed to 100~120 mesh sieve, is gone
Except 100~120 tempered glass clasts below, then 100~120 or more tempered glass clast is ground again, and mistake
100~120 mesh sieve, and collect 100~120 tempered glass clasts below, and the tempered glass not sieved by 100~120 mesh is broken
Bits continue to grind, and repeat the above steps, and finally obtain the reflective membrane granule of 100~120 mesh sieve size.
Light stabilizer can be divided into photomask agent, ultra-violet absorber, quencher, radical scavenger by mechanism, traditional,
Traditional plastics are only simple addition light stabilizers, and anti-aging anti-ultraviolet ability is poor, as a result of above-mentioned technology
Scheme, the present invention in such a way that light shielding material is combined, make additive that can act on polypropylene itself using light absorber,
Light shielding material can be acted on again, improved reflection and anti-ultraviolet ability, still met and want by long-term illumination experiment
It asks.
Specific implementation mode
Example 1
A kind of instrument board raw material of anti-aging antiultraviolet, is composed of the following raw materials by weight:100 parts of polypropylene, talcum powder 20
Part, 0.03 part of benzotriazole, 0.03 part of phenyl salicylate are double(1,2,2,6,6- pentamethvl)Sebacate 0.01, it is reflective
0.1 part of membrane granule.
The preparation method of the reflective membrane granule includes the following steps:
1. first cleaning up the tempered glass that thickness is 0.05 millimeter, tempered glass is made to reach hydrophilic;2. then using chlorination
Stannous is sensitized tempered glass, and pure water wash clean is used after the completion of sensitization;3. silver ammino solution is used to add glucose as reducing solution, spray
Tempered glass surface is applied, then places 50 minutes and is rinsed well with clear water, the tempered glass thin slice that one side is minute surface is made; ④
3. minute surface tempered glass thin slice that step is obtained crushes, and the tempered glass fragment of crushing first crossed to 120 mesh sieve, removal 120 with
Under tempered glass clast, then 120 or more tempered glass clast is ground again, and cross 120 mesh sieve, collect 120 with
Under tempered glass clast, will not by 120 mesh sieve tempered glass clast continue to grind, repeat the above steps, finally
Obtain the reflective membrane granule of 120 mesh sieve size.
Example 2
A kind of instrument board raw material of anti-aging antiultraviolet, is composed of the following raw materials by weight:100 parts of polypropylene, talcum powder 20
Part, 0.05 part of benzotriazole, 0.05 part of phenyl salicylate are double(1,2,2,6,6- pentamethvl)0.02 part of sebacate, instead
0.2 part of light membrane granule.
The preparation method of the reflective membrane granule includes the following steps:
1. first cleaning up the tempered glass that thickness is 0.05 millimeter, tempered glass is made to reach hydrophilic;2. then using chlorination
Stannous is sensitized tempered glass, and pure water wash clean is used after the completion of sensitization;3. silver ammino solution is used to add glucose as reducing solution, spray
Tempered glass surface is applied, then places 50 minutes and is rinsed well with clear water, the tempered glass thin slice that one side is minute surface is made; ④
3. minute surface tempered glass thin slice that step is obtained crushes, and the tempered glass fragment of crushing first crossed to 120 mesh sieve, removal 120 with
Under tempered glass clast, then 120 or more tempered glass clast is ground again, and cross 120 mesh sieve, collect 120 with
Under tempered glass clast, will not by 120 mesh sieve tempered glass clast continue to grind, repeat the above steps, finally
Obtain the reflective membrane granule of 120 mesh sieve size.
Example 3
A kind of instrument board raw material of anti-aging antiultraviolet, is composed of the following raw materials by weight:100 parts of polypropylene, talcum powder 20
Part, 0.04 part of benzotriazole, 0.04 part of phenyl salicylate are double(1,2,2,6,6- pentamethvl)0.02 part of sebacate, instead
0.1 part of light membrane granule.
The preparation method of the reflective membrane granule includes the following steps:
1. first cleaning up the tempered glass that thickness is 0.05 millimeter, tempered glass is made to reach hydrophilic;2. then using chlorination
Stannous is sensitized tempered glass, and pure water wash clean is used after the completion of sensitization;3. silver ammino solution is used to add glucose as reducing solution, spray
Tempered glass surface is applied, then places 50 minutes and is rinsed well with clear water, the tempered glass thin slice that one side is minute surface is made; ④
3. minute surface tempered glass thin slice that step is obtained crushes, and the tempered glass fragment of crushing first crossed to 120 mesh sieve, removal 120 with
Under tempered glass clast, then 120 or more tempered glass clast is ground again, and cross 120 mesh sieve, collect 120 with
Under tempered glass clast, will not by 120 mesh sieve tempered glass clast continue to grind, repeat the above steps, finally
Obtain the reflective membrane granule of 120 mesh sieve size.
Performance parameter such as following table before each embodiment illumination experiment:
Ultraviolet ray ageing is tested:Ultraviolet lamp wavelength 280~315nm, 50W/ ㎡ 500h(GB/T14522-93)
Performance parameter such as following table after each embodiment illumination experiment:
Can be found by the comparison of two groups of test experiments, instrument board raw material of the invention after illumination is irradiated performance almost without generation
Variation, therefore there is good anti-aging, anti-uv-ray.
The foregoing is merely the schematical specific implementation modes of the present invention, are not limited to the scope of the present invention.It is any
Those skilled in the art, made equivalent variations and modification under the premise of not departing from design and the principle of the present invention,
The scope of protection of the invention should be belonged to.
Claims (3)
1. a kind of instrument board raw material of anti-aging antiultraviolet, which is characterized in that be composed of the following raw materials by weight:Polypropylene
100 parts, 20 parts of talcum powder, 0.03~0.05 part of benzotriazole, 0.03~0.05 part of phenyl salicylate is double(1,2,2,6,6- five
Methyl piperidine)0.01~0.02 part of sebacate, 0.1~0.2 part of reflective membrane granule.
2. a kind of instrument board raw material of anti-aging antiultraviolet as described in claim 1, it is characterised in that:The reflective membrane
The preparation method of grain includes the following steps:
1. first cleaning up the tempered glass that thickness is 0.05 millimeter, tempered glass is made to reach hydrophilic;2. then using chlorination
Stannous is sensitized tempered glass, and pure water wash clean is used after the completion of sensitization;3. silver ammino solution is used to add glucose as reducing solution, spray
Tempered glass surface is applied, then places 50~55 minutes and is rinsed well with clear water, the tempered glass thin slice that one side is minute surface is made;
4. 3. minute surface tempered glass thin slice that step is obtained crushes, the tempered glass fragment of crushing is first crossed to 100~120 mesh sieve, is gone
Except 100~120 tempered glass clasts below, then 100~120 or more tempered glass clast is ground again, and mistake
100~120 mesh sieve, and collect 100~120 tempered glass clasts below, and the tempered glass not sieved by 100~120 mesh is broken
Bits continue to grind, and repeat the above steps, and finally obtain the reflective membrane granule of 100~120 mesh sieve size.
3. a kind of instrument board raw material of anti-aging antiultraviolet as described in claim 1, which is characterized in that by following parts by weight
Raw material forms:100 parts of polypropylene, 20 parts of talcum powder, 0.04 part of benzotriazole, 0.04 part of phenyl salicylate are double(1,2,2,6,6-
Pentamethvl)0.02 part of sebacate, 0.1 part of reflective membrane granule.
Priority Applications (1)
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CN201810289527.9A CN108395623A (en) | 2018-04-03 | 2018-04-03 | A kind of instrument board raw material of anti-aging antiultraviolet |
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CN201810289527.9A CN108395623A (en) | 2018-04-03 | 2018-04-03 | A kind of instrument board raw material of anti-aging antiultraviolet |
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CN201810289527.9A Pending CN108395623A (en) | 2018-04-03 | 2018-04-03 | A kind of instrument board raw material of anti-aging antiultraviolet |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4985479A (en) * | 1986-11-27 | 1991-01-15 | Sumitomo Chemical Company, Ltd. | Stabilized polyolefin composition |
CN105237886A (en) * | 2015-10-30 | 2016-01-13 | 永高股份有限公司 | Preparation method for polypropylene-toughened impact-resistant tubular product |
CN105579503A (en) * | 2013-09-27 | 2016-05-11 | 巴斯夫欧洲公司 | Polyolefin compositions for building materials |
CN106118270A (en) * | 2016-07-01 | 2016-11-16 | 国网山东省电力公司莱芜供电公司 | A kind of electric pole reflectorised paint |
-
2018
- 2018-04-03 CN CN201810289527.9A patent/CN108395623A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4985479A (en) * | 1986-11-27 | 1991-01-15 | Sumitomo Chemical Company, Ltd. | Stabilized polyolefin composition |
CN105579503A (en) * | 2013-09-27 | 2016-05-11 | 巴斯夫欧洲公司 | Polyolefin compositions for building materials |
CN105237886A (en) * | 2015-10-30 | 2016-01-13 | 永高股份有限公司 | Preparation method for polypropylene-toughened impact-resistant tubular product |
CN106118270A (en) * | 2016-07-01 | 2016-11-16 | 国网山东省电力公司莱芜供电公司 | A kind of electric pole reflectorised paint |
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Application publication date: 20180814 |
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