CN108395623A - A kind of instrument board raw material of anti-aging antiultraviolet - Google Patents

A kind of instrument board raw material of anti-aging antiultraviolet Download PDF

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Publication number
CN108395623A
CN108395623A CN201810289527.9A CN201810289527A CN108395623A CN 108395623 A CN108395623 A CN 108395623A CN 201810289527 A CN201810289527 A CN 201810289527A CN 108395623 A CN108395623 A CN 108395623A
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CN
China
Prior art keywords
tempered glass
aging
parts
raw material
antiultraviolet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810289527.9A
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Chinese (zh)
Inventor
张伟
盛杰
霍洪军
严诏文
陆裕苗
廉杰
董朝阳
齐成锦
王雪峰
冯宝龙
吕小刚
徐富恩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANDONG HENG XIN JI PLASTICS Co Ltd
Original Assignee
SHANDONG HENG XIN JI PLASTICS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by SHANDONG HENG XIN JI PLASTICS Co Ltd filed Critical SHANDONG HENG XIN JI PLASTICS Co Ltd
Priority to CN201810289527.9A priority Critical patent/CN108395623A/en
Publication of CN108395623A publication Critical patent/CN108395623A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/40Glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/13Phenols; Phenolates
    • C08K5/134Phenols containing ester groups
    • C08K5/1345Carboxylic esters of phenolcarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432Six-membered rings
    • C08K5/3435Piperidines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3472Five-membered rings
    • C08K5/3475Five-membered rings condensed with carbocyclic rings

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)

Abstract

The invention discloses a kind of instrument board raw materials of anti-aging antiultraviolet, are composed of the following raw materials by weight:100 parts of polypropylene, 20 parts of talcum powder, 0.03~0.05 part of benzotriazole, 0.03~0.05 part of phenyl salicylate are double(1,2,2,6,6 pentamethvl)0.01~0.02 part of sebacate, 0.1~0.2 part of reflective membrane granule.The present invention in such a way that light shielding material is combined, is made additive that can act on polypropylene itself and acts on light shielding material using light absorber, improves reflection and anti-ultraviolet ability, requirement is still met by long-term illumination experiment.

Description

A kind of instrument board raw material of anti-aging antiultraviolet
Technical field
The present invention relates to a kind of instrument board, the instrument board raw material of specifically a kind of anti-aging antiultraviolet.
Background technology
The function of vehicle instrument is exactly to obtain the data needed and shown using suitable mode.Pervious instrument is general It is limited in the display and 4 ~ 5 warning functions that 3 ~ 4 are measured, present new-type instrument, which then reaches, about 15 amount displays and about 40 polices Accuse monitoring function.For different information by different acquisition modes and display mode, current new-type meter information acquisition modes are main There are three types of:It is transmitted by Vehicle Body Bus;It is sampled and is converted by A/D;Changed by I/O state and is obtained.The material of vehicle instrument mostly uses PP plastics are made, and current fascia is anti-oxidant, anti-uv-ray is poor, since vehicle is parked in the external world for a long time, when Between the long aging that can lead to instrument board by sunlight, cause the damage of instrument board, it is serious to use.
Invention content
Technical problem to be solved by the invention is to provide a kind of instrument board raw materials of anti-aging antiultraviolet.
In order to solve the above technical problems, the technical scheme is that:A kind of instrument board raw material of anti-aging antiultraviolet, It is composed of the following raw materials by weight:100 parts of polypropylene, 20 parts of talcum powder, 0.03~0.05 part of benzotriazole, phenyl salicylate It is 0.03~0.05 part, double(1,2,2,6,6- pentamethvl)0.01~0.02 part of sebacate, reflective membrane granule 0.1~0.2 Part.
The preparation method of the reflective membrane granule includes the following steps:
1. first cleaning up the tempered glass that thickness is 0.05 millimeter, tempered glass is made to reach hydrophilic;2. then using chlorination Stannous is sensitized tempered glass, and pure water wash clean is used after the completion of sensitization;3. silver ammino solution is used to add glucose as reducing solution, spray Tempered glass surface is applied, then places 50~55 minutes and is rinsed well with clear water, the tempered glass thin slice that one side is minute surface is made; 4. 3. minute surface tempered glass thin slice that step is obtained crushes, the tempered glass fragment of crushing is first crossed to 100~120 mesh sieve, is gone Except 100~120 tempered glass clasts below, then 100~120 or more tempered glass clast is ground again, and mistake 100~120 mesh sieve, and collect 100~120 tempered glass clasts below, and the tempered glass not sieved by 100~120 mesh is broken Bits continue to grind, and repeat the above steps, and finally obtain the reflective membrane granule of 100~120 mesh sieve size.
Light stabilizer can be divided into photomask agent, ultra-violet absorber, quencher, radical scavenger by mechanism, traditional, Traditional plastics are only simple addition light stabilizers, and anti-aging anti-ultraviolet ability is poor, as a result of above-mentioned technology Scheme, the present invention in such a way that light shielding material is combined, make additive that can act on polypropylene itself using light absorber, Light shielding material can be acted on again, improved reflection and anti-ultraviolet ability, still met and want by long-term illumination experiment It asks.
Specific implementation mode
Example 1
A kind of instrument board raw material of anti-aging antiultraviolet, is composed of the following raw materials by weight:100 parts of polypropylene, talcum powder 20 Part, 0.03 part of benzotriazole, 0.03 part of phenyl salicylate are double(1,2,2,6,6- pentamethvl)Sebacate 0.01, it is reflective 0.1 part of membrane granule.
The preparation method of the reflective membrane granule includes the following steps:
1. first cleaning up the tempered glass that thickness is 0.05 millimeter, tempered glass is made to reach hydrophilic;2. then using chlorination Stannous is sensitized tempered glass, and pure water wash clean is used after the completion of sensitization;3. silver ammino solution is used to add glucose as reducing solution, spray Tempered glass surface is applied, then places 50 minutes and is rinsed well with clear water, the tempered glass thin slice that one side is minute surface is made; ④ 3. minute surface tempered glass thin slice that step is obtained crushes, and the tempered glass fragment of crushing first crossed to 120 mesh sieve, removal 120 with Under tempered glass clast, then 120 or more tempered glass clast is ground again, and cross 120 mesh sieve, collect 120 with Under tempered glass clast, will not by 120 mesh sieve tempered glass clast continue to grind, repeat the above steps, finally Obtain the reflective membrane granule of 120 mesh sieve size.
Example 2
A kind of instrument board raw material of anti-aging antiultraviolet, is composed of the following raw materials by weight:100 parts of polypropylene, talcum powder 20 Part, 0.05 part of benzotriazole, 0.05 part of phenyl salicylate are double(1,2,2,6,6- pentamethvl)0.02 part of sebacate, instead 0.2 part of light membrane granule.
The preparation method of the reflective membrane granule includes the following steps:
1. first cleaning up the tempered glass that thickness is 0.05 millimeter, tempered glass is made to reach hydrophilic;2. then using chlorination Stannous is sensitized tempered glass, and pure water wash clean is used after the completion of sensitization;3. silver ammino solution is used to add glucose as reducing solution, spray Tempered glass surface is applied, then places 50 minutes and is rinsed well with clear water, the tempered glass thin slice that one side is minute surface is made; ④ 3. minute surface tempered glass thin slice that step is obtained crushes, and the tempered glass fragment of crushing first crossed to 120 mesh sieve, removal 120 with Under tempered glass clast, then 120 or more tempered glass clast is ground again, and cross 120 mesh sieve, collect 120 with Under tempered glass clast, will not by 120 mesh sieve tempered glass clast continue to grind, repeat the above steps, finally Obtain the reflective membrane granule of 120 mesh sieve size.
Example 3
A kind of instrument board raw material of anti-aging antiultraviolet, is composed of the following raw materials by weight:100 parts of polypropylene, talcum powder 20 Part, 0.04 part of benzotriazole, 0.04 part of phenyl salicylate are double(1,2,2,6,6- pentamethvl)0.02 part of sebacate, instead 0.1 part of light membrane granule.
The preparation method of the reflective membrane granule includes the following steps:
1. first cleaning up the tempered glass that thickness is 0.05 millimeter, tempered glass is made to reach hydrophilic;2. then using chlorination Stannous is sensitized tempered glass, and pure water wash clean is used after the completion of sensitization;3. silver ammino solution is used to add glucose as reducing solution, spray Tempered glass surface is applied, then places 50 minutes and is rinsed well with clear water, the tempered glass thin slice that one side is minute surface is made; ④ 3. minute surface tempered glass thin slice that step is obtained crushes, and the tempered glass fragment of crushing first crossed to 120 mesh sieve, removal 120 with Under tempered glass clast, then 120 or more tempered glass clast is ground again, and cross 120 mesh sieve, collect 120 with Under tempered glass clast, will not by 120 mesh sieve tempered glass clast continue to grind, repeat the above steps, finally Obtain the reflective membrane granule of 120 mesh sieve size.
Performance parameter such as following table before each embodiment illumination experiment:
Ultraviolet ray ageing is tested:Ultraviolet lamp wavelength 280~315nm, 50W/ ㎡ 500h(GB/T14522-93)
Performance parameter such as following table after each embodiment illumination experiment:
Can be found by the comparison of two groups of test experiments, instrument board raw material of the invention after illumination is irradiated performance almost without generation Variation, therefore there is good anti-aging, anti-uv-ray.
The foregoing is merely the schematical specific implementation modes of the present invention, are not limited to the scope of the present invention.It is any Those skilled in the art, made equivalent variations and modification under the premise of not departing from design and the principle of the present invention, The scope of protection of the invention should be belonged to.

Claims (3)

1. a kind of instrument board raw material of anti-aging antiultraviolet, which is characterized in that be composed of the following raw materials by weight:Polypropylene 100 parts, 20 parts of talcum powder, 0.03~0.05 part of benzotriazole, 0.03~0.05 part of phenyl salicylate is double(1,2,2,6,6- five Methyl piperidine)0.01~0.02 part of sebacate, 0.1~0.2 part of reflective membrane granule.
2. a kind of instrument board raw material of anti-aging antiultraviolet as described in claim 1, it is characterised in that:The reflective membrane The preparation method of grain includes the following steps:
1. first cleaning up the tempered glass that thickness is 0.05 millimeter, tempered glass is made to reach hydrophilic;2. then using chlorination Stannous is sensitized tempered glass, and pure water wash clean is used after the completion of sensitization;3. silver ammino solution is used to add glucose as reducing solution, spray Tempered glass surface is applied, then places 50~55 minutes and is rinsed well with clear water, the tempered glass thin slice that one side is minute surface is made; 4. 3. minute surface tempered glass thin slice that step is obtained crushes, the tempered glass fragment of crushing is first crossed to 100~120 mesh sieve, is gone Except 100~120 tempered glass clasts below, then 100~120 or more tempered glass clast is ground again, and mistake 100~120 mesh sieve, and collect 100~120 tempered glass clasts below, and the tempered glass not sieved by 100~120 mesh is broken Bits continue to grind, and repeat the above steps, and finally obtain the reflective membrane granule of 100~120 mesh sieve size.
3. a kind of instrument board raw material of anti-aging antiultraviolet as described in claim 1, which is characterized in that by following parts by weight Raw material forms:100 parts of polypropylene, 20 parts of talcum powder, 0.04 part of benzotriazole, 0.04 part of phenyl salicylate are double(1,2,2,6,6- Pentamethvl)0.02 part of sebacate, 0.1 part of reflective membrane granule.
CN201810289527.9A 2018-04-03 2018-04-03 A kind of instrument board raw material of anti-aging antiultraviolet Pending CN108395623A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810289527.9A CN108395623A (en) 2018-04-03 2018-04-03 A kind of instrument board raw material of anti-aging antiultraviolet

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Application Number Priority Date Filing Date Title
CN201810289527.9A CN108395623A (en) 2018-04-03 2018-04-03 A kind of instrument board raw material of anti-aging antiultraviolet

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CN108395623A true CN108395623A (en) 2018-08-14

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4985479A (en) * 1986-11-27 1991-01-15 Sumitomo Chemical Company, Ltd. Stabilized polyolefin composition
CN105237886A (en) * 2015-10-30 2016-01-13 永高股份有限公司 Preparation method for polypropylene-toughened impact-resistant tubular product
CN105579503A (en) * 2013-09-27 2016-05-11 巴斯夫欧洲公司 Polyolefin compositions for building materials
CN106118270A (en) * 2016-07-01 2016-11-16 国网山东省电力公司莱芜供电公司 A kind of electric pole reflectorised paint

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4985479A (en) * 1986-11-27 1991-01-15 Sumitomo Chemical Company, Ltd. Stabilized polyolefin composition
CN105579503A (en) * 2013-09-27 2016-05-11 巴斯夫欧洲公司 Polyolefin compositions for building materials
CN105237886A (en) * 2015-10-30 2016-01-13 永高股份有限公司 Preparation method for polypropylene-toughened impact-resistant tubular product
CN106118270A (en) * 2016-07-01 2016-11-16 国网山东省电力公司莱芜供电公司 A kind of electric pole reflectorised paint

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Application publication date: 20180814

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