CN106118270A - A kind of electric pole reflectorised paint - Google Patents
A kind of electric pole reflectorised paint Download PDFInfo
- Publication number
- CN106118270A CN106118270A CN201610510199.1A CN201610510199A CN106118270A CN 106118270 A CN106118270 A CN 106118270A CN 201610510199 A CN201610510199 A CN 201610510199A CN 106118270 A CN106118270 A CN 106118270A
- Authority
- CN
- China
- Prior art keywords
- safety glass
- electric pole
- reflectorised paint
- revs
- reflective particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of electric pole reflectorised paint, it is made up of the raw material of following weight portion: luminescent powder granule 10, fluorescent powder grain 10, TEGO Dispers wetting dispersing agent 1.5, smooth dose 0.6, aqueous film-forming resin 50, polyisocyanates 10～12, acryl polyol 20, organic solvent 20～30, anti-settling agent 0.5～1.5, plasticizer 0.3～0.5, safety glass reflective particles 20, styrene-acrylic emulsion 50～60, modified adhesive 30～34, methyl hydroxyethylcellulose 2～5, glycerol 2～3, sodium carboxymethyl cellulose 2～4, methyl-silicone oil 0.2～0.3, deionized water 20～40.The electric pole reflectorised paint of the present invention is applied to electric pole surface; even if also can be high-visible during distance 120 meters in the thick fog of visibility 100 meters, when night, after light-illuminating, safety glass reflective particles can also be by former for part light return; it is easy to driver discover, plays preferably warning and reflection action.
Description
Technical field
The present invention relates to a kind of paint, specifically a kind of electric pole reflectorised paint.
Background technology
Electric pole is one of infrastructure that China is important in early days.Various electric poles in early days, all start to walk from rod,
Even include that electric pressure is not the highest high-voltage line electric pole.Later along with iron and steel and the development of armored concrete, and requirement
Improve constantly, concrete iron and steel combination electric pole instead of major part rod.At present, in order to prevent Pedestrians and vehicles etc. from hitting
On electric pole, scribble the reflectorised paint that black Huang is alternate in the bottom of electric pole, or post a circle reflective sheeting, warning can be played and make
With, again can be reflective, it is simple to pedestrian and vehicle find to dodge in time, reflective sheeting is more preferable relative to reflectorised paint reflecting effect, and paper using is made
Being more easy to adhere to reflectorized material for carrier, but reflective sheeting has the biggest defect, reflective sheeting is the most damaged, and badly broken just may result in
Circle reflective sheeting drops, and causes the electric pole can not be reflective, is unfavorable for the safety of pedestrians and vehicles, although reflectorised paint can be the most firm
Be attached to electric pole surface, but the reflecting effect of reflectorised paint is not ideal enough, and particularly in the greasy weather, reflecting effect is poor, still
It is difficult to meet safety need.
Summary of the invention
It is an object of the invention to, it is provided that a kind of electric pole reflectorised paint, to achieve these goals, the skill that the present invention uses
Art scheme is as follows:
A kind of electric pole reflectorised paint, is made up of the raw material of following weight portion: luminescent powder granule 10, fluorescent powder grain 10, dispersant 1
～it is 2, smooth dose 0.5～0.6, aqueous film-forming resin 40～60, polyisocyanates 10～12, acryl polyol 20, organic
Solvent 20～30, anti-settling agent 0.5～1.5, plasticizer 0.3～0.5, safety glass reflective particles 20, styrene-acrylic emulsion 50～60, change
Property binding agent 30～34, methyl hydroxyethylcellulose 2～5, glycerol 2～3, sodium carboxymethyl cellulose 2～4, methyl-silicone oil 0.2
～0.3, deionized water 20～40；
Described modified adhesive is made up of the raw material of following weight parts: ethylene～Vinyl Acetate Copolymer Emulsion 100,
Phenolic resin 20, blended emulsifier 15～20, phthalic acid two fourth 3, Pulvis Talci 6, VTES 2～3,
Aluminium hydroxide 3～5, ethanol 6～8, polyvinyl alcohol 6～8；
The preparation method of described silver-plated tempering glass film fragment comprises the following steps:
1) first the safety glass that thickness is 0.1 millimeter is cleaned up, make safety glass reach hydrophilic；2) chlorination is then used
Stannous is to safety glass sensitization, and pure water wash clean is used in sensitization after completing；3) glucose is added as reducing solution, spray with silver ammino solution
It is coated with safety glass surface, then places and rinse well with clear water for 30～40 minutes, make the one side safety glass thin slice for minute surface；
4) minute surface safety glass thin slice step 3) obtained is pulverized, and the safety glass fragment pulverized first is crossed 70～80 mesh sieves, removes
Trickle safety glass chip, then after 45～50 mesh sieves, and collects the safety glass chip under 45～50 mesh sieve sieves, will not
Continue to pulverize by the safety glass chip of 45～50 mesh sieves, and repeat the above steps, finally give 50～70 mesh sieve sizes
Safety glass reflective particles.
The preparation method of said wires bar reflectorised paint, comprises the following steps:
(1) by above-mentioned aqueous film-forming resin, organic solvent, polyisocyanates, acryl polyol, styrene-acrylic emulsion, deionization
Water is mixed to join in dispersion cylinder, 800～1000 revs/min, high speed dispersion 3～5min；
(2) add above-mentioned luminescent powder granule, fluorescent powder grain, safety glass reflective particles, dispersant, smooth dose, 1200～
1600 revs/min, high speed dispersion 20～30min；
(3) adding above-mentioned modified adhesive, anti-settling agent, 200～300 revs/min, low speed disperses 4～6 minutes, adds residue
Each raw material, is uniformly dispersed by 400～600 revs/min, obtains described electric pole reflectorised paint.
The present invention has a luminescent powder granule of noctilucence effect by addition, and have reflection action fluorescent powder grain,
Safety glass reflective particles makes reflectorised paint have good reflection action, and safety glass reflective particles is dispersed in reflectorised paint, steel
The reflective surface changing glass reflecting granule can be towards all directions, it is simple to the light being emitted onto on safety glass reflective particles is anti-
To surrounding, improving the reflecting effect of reflectorised paint, beneficially pedestrian and vehicle finds that electric pole is dodged, by the present invention's in time
Electric pole reflectorised paint is applied to electric pole surface, even if also can be high-visible during distance 120 meters in the thick fog of visibility 100 meters,
Thus increase visibility；When night, after light-illuminating, safety glass reflective particles can also be by former for part light return, it is simple to department
Machine is discovered, and luminescent powder granule accepts light and the light of part safety glass reflective particles reflection, the most beneficially luminescent powder simultaneously
Granule effectively absorbs light, makes full use of light so that it is self fluorescent lifetime is more longlasting, plays preferably warning and reflective work
With.
Detailed description of the invention
A kind of electric pole reflectorised paint, is made up of the raw material of following weight portion: luminescent powder granule 10, fluorescent powder grain 10,
TEGO Dispers wetting dispersing agent 1.5, smooth dose 0.6, aqueous film-forming resin 50, polyisocyanates 11, acrylate polynary
Alcohol 20, organic solvent 25, anti-settling agent 1, plasticizer 0.4, safety glass reflective particles 20, styrene-acrylic emulsion 55, modified adhesive 32,
Methyl hydroxyethylcellulose 4, glycerol 2.5, sodium carboxymethyl cellulose 3, methyl-silicone oil 0.3, deionized water 30；
The preparation method of described silver-plated tempering glass film fragment comprises the following steps:
1) first the safety glass that thickness is 0.1 millimeter is cleaned up, make safety glass reach hydrophilic；2) chlorination is then used
Stannous is to safety glass sensitization, and pure water wash clean is used in sensitization after completing；3) glucose is added as reducing solution, spray with silver ammino solution
It is coated with safety glass surface, then places and rinse well with clear water for 30～40 minutes, make the one side safety glass thin slice for minute surface；
4) minute surface safety glass thin slice step 3) obtained is pulverized, and the safety glass fragment pulverized first is crossed 70～80 mesh sieves, removes
Trickle safety glass chip, then after 45～50 mesh sieves, and collects the safety glass chip under 45～50 mesh sieve sieves, will not
Continue to pulverize by the safety glass chip of 45～50 mesh sieves, and repeat the above steps, finally give 50～70 mesh sieve sizes
Safety glass reflective particles；
Described modified adhesive is made up of the raw material of following weight parts: ethylene～Vinyl Acetate Copolymer Emulsion 100, phenol
Urea formaldehyde 20, blended emulsifier 18, phthalic acid two fourth 3, Pulvis Talci 6, VTES 2.5, hydroxide
Aluminum 4, ethanol 7, polyvinyl alcohol 7；Described modified adhesive prepares by the following method: with the blended emulsifier of formula ratio half with
Pulvis Talci, VTES, aluminium hydroxide mix and blend, low speed 200～300 revs/min stir 5 minutes, are mixed
Mixture A, then surplus stock is mixed with the blended emulsifier of second half formula ratio, 1000～1200 revs/min are stirred 1 point at a high speed
Clock, obtains intermixture B, is finally blended by intermixture A and intermixture B and uniformly obtains modified adhesive；
Described organic solvent is the mixture of benzene, ether, and the weight fraction of benzene, ether is than for 1:2, and described blended emulsifier is
Stearic acid sodium salt, N domiphen, paraoctyl phenol polyoxyethylene ether form according to the weight of 1:1:2, described
Luminescent powder granule, the fineness of fluorescent powder grain are 90～100 mesh.
The preparation method of said wires bar reflectorised paint, comprises the following steps:
(1) by above-mentioned aqueous film-forming resin, organic solvent, polyisocyanates, acryl polyol, styrene-acrylic emulsion, deionization
Water is mixed to join in dispersion cylinder, 800～1000 revs/min, high speed dispersion 3～5min；
(2) add above-mentioned luminescent powder granule, fluorescent powder grain, safety glass reflective particles, dispersant, smooth dose, 1200～
1600 revs/min, high speed dispersion 20～30min；
(3) adding above-mentioned modified adhesive, anti-settling agent, 200～300 revs/min, low speed disperses 4～6 minutes, adds residue
Each raw material, is uniformly dispersed by 400～600 revs/min, obtains described electric pole reflectorised paint.
Performance test:
Paint film appearance has concave-convex sense, surface gloss good；
Abrasion resistance is tested: passing through for 1000 times, paint film is without breakage；
Artificial ageing resistance test: 2000 hours non-foaming, do not peel off, flawless；
Resistance to water: 140h paint film is without breakage；
Alkali resistance: 120h paint film is without breakage.
The foregoing is only the schematic detailed description of the invention of the present invention, be not limited to the scope of the present invention.Any
Those skilled in the art, equivalent variations done on the premise of without departing from the design of the present invention and principle and amendment, all
The scope of protection of the invention should be belonged to.
Claims (7)
1. an electric pole reflectorised paint, it is characterised in that be made up of the raw material of following weight portion: luminescent powder granule 10, fluorescent material
Granule 10, dispersant 1～2, smooth dose 0.5～0.6, aqueous film-forming resin 40～60, polyisocyanates 10～12, acrylate
Polyhydric alcohol 20, organic solvent 20～30, anti-settling agent 0.5～1.5, plasticizer 0.3～0.5, safety glass reflective particles 20, phenylpropyl alcohol
Emulsion 50～60, modified adhesive 30～34, methyl hydroxyethylcellulose 2～5, glycerol 2～3, sodium carboxymethyl cellulose 2～
4, methyl-silicone oil 0.2～0.3, deionized water 20～40；
Described modified adhesive is made up of the raw material of following weight parts: ethylene～Vinyl Acetate Copolymer Emulsion 100, phenol
Urea formaldehyde 20, blended emulsifier 15～20, phthalic acid two fourth 3, Pulvis Talci 6, VTES 2～3, hydrogen
Aluminium oxide 3～5, ethanol 6～8, polyvinyl alcohol 6～8；
The preparation method of described silver-plated tempering glass film fragment comprises the following steps:
1) first the safety glass that thickness is 0.1 millimeter is cleaned up, make safety glass reach hydrophilic；2) chlorination is then used
Stannous is to safety glass sensitization, and pure water wash clean is used in sensitization after completing；3) glucose is added as reducing solution, spray with silver ammino solution
It is coated with safety glass surface, then places and rinse well with clear water for 30～40 minutes, make the one side safety glass thin slice for minute surface；
4) minute surface safety glass thin slice step 3) obtained is pulverized, and the safety glass fragment pulverized first is crossed 70～80 mesh sieves, removes
Trickle safety glass chip, then after 45～50 mesh sieves, and collects the safety glass chip under 45～50 mesh sieve sieves, will not
Continue to pulverize by the safety glass chip of 45～50 mesh sieves, and repeat the above steps, finally give 50～70 mesh sieve sizes
Safety glass reflective particles.
2. a kind of electric pole reflectorised paint as claimed in claim 1, it is characterised in that described modified adhesive is by the following method
Prepare: with the blended emulsifier of formula ratio half and Pulvis Talci, VTES, aluminium hydroxide mix and blend, low
Speed 200～300 revs/min stirs 5 minutes, obtains intermixture A, then is mixed by the blended emulsifier of surplus stock with second half formula ratio
Closing, 1000～1200 revs/min are stirred 1 minute at a high speed, obtain intermixture B, are finally blended uniformly by intermixture A and intermixture B
Obtain modified adhesive.
3. a kind of electric pole reflectorised paint as claimed in claim 1, it is characterised in that: described dispersant is TEGO Dispers profit
Hygroscopic water powder or polyethylene glycol 200.
4. electric pole reflectorised paint as claimed in claim 1 a kind of, it is characterised in that: described organic solvent be benzene, ether mixed
Compound, and the weight fraction of benzene, ether is than for 1:2.
5. a kind of electric pole reflectorised paint as claimed in claim 1, it is characterised in that: described blended emulsifier is sodium stearate
Salt, N domiphen, paraoctyl phenol polyoxyethylene ether form according to the weight of 1:1:2.
6. a kind of electric pole reflectorised paint as claimed in claim 1, it is characterised in that: described luminescent powder granule, fluorescent powder grain
Fineness be 90～100 mesh.
The preparation method of a kind of electric pole reflectorised paint the most as claimed in claim 1, it is characterised in that comprise the following steps:
(1) by above-mentioned aqueous film-forming resin, organic solvent, polyisocyanates, acryl polyol, styrene-acrylic emulsion, deionization
Water is mixed to join in dispersion cylinder, 800～1000 revs/min, high speed dispersion 3～5min；
(2) add above-mentioned luminescent powder granule, fluorescent powder grain, safety glass reflective particles, dispersant, smooth dose, 1200～
1600 revs/min, high speed dispersion 20～30min；
(3) adding above-mentioned modified adhesive, anti-settling agent, 200～300 revs/min, low speed disperses 4～6 minutes, adds residue
Each raw material, is uniformly dispersed by 400～600 revs/min, obtains described electric pole reflectorised paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610510199.1A CN106118270B (en) | 2016-07-01 | 2016-07-01 | A kind of electric pole reflectorised paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610510199.1A CN106118270B (en) | 2016-07-01 | 2016-07-01 | A kind of electric pole reflectorised paint |
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| Publication Number | Publication Date |
|---|---|
| CN106118270A true CN106118270A (en) | 2016-11-16 |
| CN106118270B CN106118270B (en) | 2018-06-01 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610510199.1A Active CN106118270B (en) | 2016-07-01 | 2016-07-01 | A kind of electric pole reflectorised paint |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106977989A (en) * | 2017-03-23 | 2017-07-25 | 合肥仁德电子科技有限公司 | A kind of protective paint in the installation for street lamp |
| CN107236455A (en) * | 2017-07-26 | 2017-10-10 | 合肥华盖光伏科技有限公司 | It is a kind of for anti-aging paint of street lamp and preparation method thereof |
| CN108395623A (en) * | 2018-04-03 | 2018-08-14 | 山东恒信基塑业股份有限公司 | A kind of instrument board raw material of anti-aging antiultraviolet |
| CN115232520A (en) * | 2022-08-23 | 2022-10-25 | 广东嘉宝莉科技材料有限公司 | High-definition projection paint and preparation method thereof |
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| CN1078734A (en) * | 1992-05-11 | 1993-11-24 | 王胜利 | Reflective composite painting |
| EP1138644A2 (en) * | 2000-03-27 | 2001-10-04 | Friedhelm Dörge | Mass and shaped bodies formed thereof , having a surface effect |
| CN101338152A (en) * | 2007-07-20 | 2009-01-07 | 潘东海 | Road reflective marker line coating |
| CN101604032A (en) * | 2008-06-11 | 2009-12-16 | 梁晓斌 | Spotlight display high-brightness reflection optical lens protecting adhesive film |
| CN103351713A (en) * | 2013-07-08 | 2013-10-16 | 苏州凹凸彩印厂 | Luminous printing ink for printing outdoor advertisements |
| CN105331171A (en) * | 2015-12-08 | 2016-02-17 | 安徽中益新材料科技有限公司 | Retro-reflection energy-storing luminous paint and preparing method thereof |
-
2016
- 2016-07-01 CN CN201610510199.1A patent/CN106118270B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1078734A (en) * | 1992-05-11 | 1993-11-24 | 王胜利 | Reflective composite painting |
| EP1138644A2 (en) * | 2000-03-27 | 2001-10-04 | Friedhelm Dörge | Mass and shaped bodies formed thereof , having a surface effect |
| CN101338152A (en) * | 2007-07-20 | 2009-01-07 | 潘东海 | Road reflective marker line coating |
| CN101604032A (en) * | 2008-06-11 | 2009-12-16 | 梁晓斌 | Spotlight display high-brightness reflection optical lens protecting adhesive film |
| CN103351713A (en) * | 2013-07-08 | 2013-10-16 | 苏州凹凸彩印厂 | Luminous printing ink for printing outdoor advertisements |
| CN105331171A (en) * | 2015-12-08 | 2016-02-17 | 安徽中益新材料科技有限公司 | Retro-reflection energy-storing luminous paint and preparing method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106977989A (en) * | 2017-03-23 | 2017-07-25 | 合肥仁德电子科技有限公司 | A kind of protective paint in the installation for street lamp |
| CN107236455A (en) * | 2017-07-26 | 2017-10-10 | 合肥华盖光伏科技有限公司 | It is a kind of for anti-aging paint of street lamp and preparation method thereof |
| CN108395623A (en) * | 2018-04-03 | 2018-08-14 | 山东恒信基塑业股份有限公司 | A kind of instrument board raw material of anti-aging antiultraviolet |
| CN115232520A (en) * | 2022-08-23 | 2022-10-25 | 广东嘉宝莉科技材料有限公司 | High-definition projection paint and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN106118270B (en) | 2018-06-01 |
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