CN106118270B - A kind of electric pole reflectorised paint - Google Patents
A kind of electric pole reflectorised paint Download PDFInfo
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- CN106118270B CN106118270B CN201610510199.1A CN201610510199A CN106118270B CN 106118270 B CN106118270 B CN 106118270B CN 201610510199 A CN201610510199 A CN 201610510199A CN 106118270 B CN106118270 B CN 106118270B
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- tempered glass
- electric pole
- reflectorised paint
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- particles
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of electric pole reflectorised paints, are made of the raw material of following parts by weight：Noctilucence powder particles 10, fluorescent powder grain 10, TEGO Dispers wetting dispersing agents 1.5, flat dose 0.6, aqueous film-forming resin 50, polyisocyanates 10~12, acryl polyol 20, organic solvent 20~30, anti-settling agent 0.5~1.5, plasticizer 0.3~0.5, tempered glass reflective particles 20, styrene-acrylic emulsion 50~60, modified adhesive 30~34, methyl hydroxyethylcellulose 2~5, glycerine 2~3, sodium carboxymethylcellulose 2~4, methyl-silicone oil 0.2~0.3, deionized water 20~40.The electric pole reflectorised paint of the present invention is applied to electric pole surface; also can be high-visible during 120 meters of distance even if in the thick fog of 100 meters of visibility, at night, tempered glass reflective particles can also be returned part light is former after light-illuminating; discover convenient for driver, play preferably warning and reflection action.
Description
Technical field
The present invention relates to a kind of paints, are specifically a kind of electric pole reflectorised paint.
Background technology
Electric pole is one of important infrastructure of early stage China.The various electric poles of early stage are started to walk from rod,
It is not too high high-voltage line electric pole even including voltage class.Later with the development and requirement of steel and armored concrete
Continuous improvement, concrete steel combination electric pole instead of most of rod.At present, Pedestrians and vehicles etc. is hit in order to prevent
Onto electric pole, the alternate reflectorised paint of black Huang is scribbled in the bottom of electric pole or posts a circle reflective sheeting, warning can be played and made
With, and can be reflective, it finds to avoid in time convenient for pedestrian and vehicle, reflective sheeting is more preferable compared with reflectorised paint reflecting effect, with paper is made
Attachment reflectorized material is more easy to for carrier, but reflective sheeting has the defects of very big, and reflective sheeting is easily damaged, and badly broken may result in just
Circle reflective sheeting drops, and causes electric pole reflective, is unfavorable for the safety of pedestrians and vehicles, although reflectorised paint can more securely
Be attached to electric pole surface, but the reflecting effect of reflectorised paint is not ideal enough, and particularly in the greasy weather, reflecting effect is poor, still
It is difficult to meet security needs.
The content of the invention
It is an object of the present invention to provide a kind of electric pole reflectorised paints, to achieve these goals, the skill that the present invention uses
Art scheme is as follows：
A kind of electric pole reflectorised paint, is made of the raw material of following parts by weight：Noctilucence powder particles 10, fluorescent powder grain 10 divide
Powder 1~2, flat dose 0.5~0.6, aqueous film-forming resin 40~60, polyisocyanates 10~12, acryl polyol 20,
Organic solvent 20~30, anti-settling agent 0.5~1.5, plasticizer 0.3~0.5, tempered glass reflective particles 20, styrene-acrylic emulsion 50~
60th, modified adhesive 30~34, methyl hydroxyethylcellulose 2~5, glycerine 2~3, sodium carboxymethylcellulose 2~4, methyl silicon
Oil 0.2~0.3, deionized water 20~40；
The modified adhesive is made of the raw material of following weight parts：Ethylene~Vinyl Acetate Copolymer Emulsion
100th, phenolic resin 20, blended emulsifier 15~20, dibutyl phthalate 3, talcum powder 6, vinyl triethoxyl silicon
Alkane 2~3, aluminium hydroxide 3~5, ethyl alcohol 6~8, polyvinyl alcohol 6~8；
The preparation method of the tempered glass reflective particles comprises the following steps：
1）The tempered glass that thickness is 0.1 millimeter is cleaned up first, tempered glass is made to reach hydrophilic； 2）Then use
Stannous chloride is sensitized tempered glass, and pure water wash clean is used after the completion of sensitization； 3）By the use of silver ammino solution plus glucose as reduction
Then liquid, spraying tempered glass surface are placed 30~40 minutes and are rinsed well with clear water, the tempered glass that one side is minute surface is made
Thin slice； 4）By step 3）Obtained minute surface tempered glass thin slice crushes, and the tempered glass fragment of crushing is first crossed 70~80 mesh
Sieve, removes subtle tempered glass chip, and then after 45~50 mesh sieves, and the tempered glass collected under 45~50 mesh sieves sieve is broken
Bits, the tempered glass chip not by 45~50 mesh sieves is continued to crush, and is repeated the above steps, and finally obtains 50~70 mesh sieves
The tempered glass reflective particles of size.
The preparation method of said wires bar reflectorised paint, comprises the following steps：
（1）By above-mentioned aqueous film-forming resin, organic solvent, polyisocyanates, acryl polyol, styrene-acrylic emulsion, go
Ionized water is mixed to join in dispersion cylinder, 800~1000 revs/min, 3~5min of high speed dispersion；
（2）Add in above-mentioned noctilucence powder particles, fluorescent powder grain, tempered glass reflective particles, dispersant, flat dose, 1200
~1600 revs/min, 20~30min of high speed dispersion；
（3）Above-mentioned modified adhesive, anti-settling agent are added in, 200~300 revs/min, low speed disperses 4~6 minutes, adds
Remaining each raw material, is uniformly dispersed to get the electric pole reflectorised paint by 400~600 revs/min.
The present invention by add in noctilucence effect noctilucence powder particles and have reflection action fluorescent powder grain,
Tempered glass reflective particles make reflectorised paint have good reflection action, and tempered glass reflective particles are dispersed in reflectorised paint, steel
The reflective surface for changing glass reflecting particle can be anti-convenient for the light that is emitted onto on tempered glass reflective particles towards all directions
Around, the reflecting effect of reflectorised paint is improved, is conducive to pedestrian and vehicle and finds that electric pole is avoided in time, by the present invention's
Electric pole reflectorised paint is applied to electric pole surface, also can be high-visible during 120 meters of distance even if in the thick fog of 100 meters of visibility,
So as to increase visibility；At night, tempered glass reflective particles can also return to part light original after light-illuminating, convenient for department
Machine is discovered, while noctilucence powder particles receive light and the light of part tempered glass reflective particles reflection, are so conducive to luminescent powder
Particle effectively absorbs light, makes full use of light, makes its own fluorescent lifetime more longlasting, plays preferably warning and reflective work
With.
Specific embodiment
A kind of electric pole reflectorised paint, is made of the raw material of following parts by weight：Noctilucence powder particles 10, fluorescent powder grain 10,
TEGO Dispers wetting dispersing agents 1.5, flat dose 0.6, aqueous film-forming resin 50, polyisocyanates 11, acrylate it is polynary
Alcohol 20, organic solvent 25, anti-settling agent 1, plasticizer 0.4, tempered glass reflective particles 20, styrene-acrylic emulsion 55, modified adhesive 32,
Methyl hydroxyethylcellulose 4, glycerine 2.5, sodium carboxymethylcellulose 3, methyl-silicone oil 0.3, deionized water 30；
The preparation method of the tempered glass reflective particles comprises the following steps：
1）The tempered glass that thickness is 0.1 millimeter is cleaned up first, tempered glass is made to reach hydrophilic； 2）Then use
Stannous chloride is sensitized tempered glass, and pure water wash clean is used after the completion of sensitization； 3）By the use of silver ammino solution plus glucose as reduction
Then liquid, spraying tempered glass surface are placed 30~40 minutes and are rinsed well with clear water, the tempered glass that one side is minute surface is made
Thin slice； 4）By step 3）Obtained minute surface tempered glass thin slice crushes, and the tempered glass fragment of crushing is first crossed 70~80 mesh
Sieve, removes subtle tempered glass chip, and then after 45~50 mesh sieves, and the tempered glass collected under 45~50 mesh sieves sieve is broken
Bits, the tempered glass chip not by 45~50 mesh sieves is continued to crush, and is repeated the above steps, and finally obtains 50~70 mesh sieves
The tempered glass reflective particles of size；
The modified adhesive is made of the raw material of following weight parts：Ethylene~Vinyl Acetate Copolymer Emulsion
100th, phenolic resin 20, blended emulsifier 18, dibutyl phthalate 3, talcum powder 6, vinyltriethoxysilane
2.5th, aluminium hydroxide 4, ethyl alcohol 7, polyvinyl alcohol 7；The modified adhesive is made by the following method：With mixing for formula ratio half
Co-emulsifier is mixed with talcum powder, vinyltriethoxysilane, aluminium hydroxide, and 200~300 revs/min of low speed stirs 5 points
Clock obtains intermixture A, then surplus stock is mixed with the blended emulsifier of the other half formula ratio, 1000~1200 turns at a high speed/
Divide stirring 1 minute, obtain intermixture B, intermixture A and intermixture B blendings are uniformly finally obtained into modified adhesive；
The organic solvent is benzene, the mixture of ether, and the weight fraction ratio of benzene, ether is 1:2, the mixing and emulsifying
Agent is stearic acid sodium salt, N- domiphens, p-Octylphenol polyoxyethylene ether are according to 1:1:2 weight group
Into the noctilucence powder particles, the fineness of fluorescent powder grain are 90~100 mesh.
The preparation method of said wires bar reflectorised paint, comprises the following steps：
（1）By above-mentioned aqueous film-forming resin, organic solvent, polyisocyanates, acryl polyol, styrene-acrylic emulsion, go
Ionized water is mixed to join in dispersion cylinder, 800~1000 revs/min, 3~5min of high speed dispersion；
（2）Add in above-mentioned noctilucence powder particles, fluorescent powder grain, tempered glass reflective particles, dispersant, flat dose, 1200
~1600 revs/min, 20~30min of high speed dispersion；
（3）Above-mentioned modified adhesive, anti-settling agent are added in, 200~300 revs/min, low speed disperses 4~6 minutes, adds
Remaining each raw material, is uniformly dispersed to get the electric pole reflectorised paint by 400~600 revs/min.
Performance test：
Paint film appearance has concave-convex sense, the surface gloss good；
Abrasion resistance is tested：1000 times by the way that paint film is without breakage；
Artificial ageing resistance is tested：It is 2000 not blistering when small, do not peel off, flawless；
Water resistance：140h paint films are without breakage；
Alkali resistance：120h paint films are without breakage.
The foregoing is merely the schematical specific embodiments of the present invention, are not limited to the scope of the present invention.It is any
Those skilled in the art, made equivalent variations and modification on the premise of the design of the present invention and principle is not departed from,
The scope of protection of the invention should be belonged to.
Claims (7)
1. a kind of electric pole reflectorised paint, which is characterized in that be made of the raw material of following parts by weight：Noctilucence powder particles 10, fluorescent powder
Particle 10, dispersant 1~2, flat dose 0.5~0.6, aqueous film-forming resin 40~60, polyisocyanates 10~12, acrylate
Polyalcohol 20, organic solvent 20~30, anti-settling agent 0.5~1.5, plasticizer 0.3~0.5, tempered glass reflective particles 20, phenylpropyl alcohol
Lotion 50~60, modified adhesive 30~34, methyl hydroxyethylcellulose 2~5, glycerine 2~3, sodium carboxymethylcellulose 2~
4th, methyl-silicone oil 0.2~0.3, deionized water 20~40；
The modified adhesive is made of the raw material of following weight parts：Ethylene~Vinyl Acetate Copolymer Emulsion 100, phenol
Urea formaldehyde 20, blended emulsifier 15~20, dibutyl phthalate 3, talcum powder 6, vinyltriethoxysilane 2~3,
Aluminium hydroxide 3~5, ethyl alcohol 6~8, polyvinyl alcohol 6~8；
The preparation method of the tempered glass reflective particles comprises the following steps：
1）The tempered glass that thickness is 0.1 millimeter is cleaned up first, tempered glass is made to reach hydrophilic； 2）Then chlorination is used
Stannous is sensitized tempered glass, and pure water wash clean is used after the completion of sensitization； 3）By the use of silver ammino solution plus glucose as reducing solution, spray
Tempered glass surface is applied, then places 30~40 minutes and is rinsed well with clear water, the tempered glass thin slice that one side is minute surface is made；
4）By step 3）Obtained minute surface tempered glass thin slice crushes, and the tempered glass fragment of crushing is first crossed 70~80 mesh sieves, removal
Subtle tempered glass chip then after 45~50 mesh sieves, and collects the tempered glass chip under 45~50 mesh sieves sieve, will not
Continue to crush by the tempered glass chip of 45~50 mesh sieves, and repeat the above steps, finally obtain 50~70 mesh sieve sizes
Tempered glass reflective particles.
2. a kind of electric pole reflectorised paint as described in claim 1, which is characterized in that the modified adhesive is by the following method
It is made：It is mixed with the blended emulsifier and talcum powder, vinyltriethoxysilane, aluminium hydroxide of formula ratio half, it is low
200~300 revs/min of speed stirs 5 minutes, obtains intermixture A, then the blended emulsifier of surplus stock and the other half formula ratio is mixed
It closes, stirs 1 minute for 1000~1200 revs/min at a high speed, obtain intermixture B, finally intermixture A and intermixture B is blended uniform
Obtain modified adhesive.
3. a kind of electric pole reflectorised paint as described in claim 1, it is characterised in that：The dispersant moistens for TEGO Dispers
Hygroscopic water powder or polyethylene glycol 200.
4. a kind of electric pole reflectorised paint as described in claim 1, it is characterised in that：The organic solvent is benzene, ether it is mixed
Object is closed, and the weight fraction ratio of benzene, ether is 1:2.
5. a kind of electric pole reflectorised paint as described in claim 1, it is characterised in that：The blended emulsifier is odium stearate
Salt, N- domiphens, p-Octylphenol polyoxyethylene ether are according to 1:1:2 weight composition.
6. a kind of electric pole reflectorised paint as described in claim 1, it is characterised in that：The noctilucence powder particles, fluorescent powder grain
Fineness be 90~100 mesh.
7. a kind of preparation method of electric pole reflectorised paint as described in claim 1, it is characterised in that comprise the following steps：
（1）By above-mentioned aqueous film-forming resin, organic solvent, polyisocyanates, acryl polyol, styrene-acrylic emulsion, deionization
Water is mixed to join in dispersion cylinder, 800~1000 revs/min, 3~5min of high speed dispersion；
（2）Add in above-mentioned noctilucence powder particles, fluorescent powder grain, tempered glass reflective particles, dispersant, flat dose, 1200~
1600 revs/min, 20~30min of high speed dispersion；
（3）Above-mentioned modified adhesive, anti-settling agent are added in, 200~300 revs/min, low speed disperses 4~6 minutes, adds residue
Each raw material, is uniformly dispersed to get the electric pole reflectorised paint by 400~600 revs/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610510199.1A CN106118270B (en) | 2016-07-01 | 2016-07-01 | A kind of electric pole reflectorised paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610510199.1A CN106118270B (en) | 2016-07-01 | 2016-07-01 | A kind of electric pole reflectorised paint |
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| Publication Number | Publication Date |
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| CN106118270A CN106118270A (en) | 2016-11-16 |
| CN106118270B true CN106118270B (en) | 2018-06-01 |
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| CN201610510199.1A Active CN106118270B (en) | 2016-07-01 | 2016-07-01 | A kind of electric pole reflectorised paint |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106977989A (en) * | 2017-03-23 | 2017-07-25 | 合肥仁德电子科技有限公司 | A kind of protective paint in the installation for street lamp |
| CN107236455A (en) * | 2017-07-26 | 2017-10-10 | 合肥华盖光伏科技有限公司 | It is a kind of for anti-aging paint of street lamp and preparation method thereof |
| CN108395623A (en) * | 2018-04-03 | 2018-08-14 | 山东恒信基塑业股份有限公司 | A kind of instrument board raw material of anti-aging antiultraviolet |
| CN115232520B (en) * | 2022-08-23 | 2023-05-23 | 广东嘉宝莉科技材料有限公司 | High-definition projection paint and preparation method thereof |
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|---|---|---|---|---|
| CN1078734A (en) * | 1992-05-11 | 1993-11-24 | 王胜利 | Reflective composite painting |
| EP1138644A2 (en) * | 2000-03-27 | 2001-10-04 | Friedhelm Dörge | Mass and shaped bodies formed thereof , having a surface effect |
| CN101338152A (en) * | 2007-07-20 | 2009-01-07 | 潘东海 | Road reflective marker line coating |
| CN101604032A (en) * | 2008-06-11 | 2009-12-16 | 梁晓斌 | Spotlight display high-brightness reflection optical lens protecting adhesive film |
| CN103351713A (en) * | 2013-07-08 | 2013-10-16 | 苏州凹凸彩印厂 | Luminous printing ink for printing outdoor advertisements |
| CN105331171A (en) * | 2015-12-08 | 2016-02-17 | 安徽中益新材料科技有限公司 | Retro-reflection energy-storing luminous paint and preparing method thereof |
-
2016
- 2016-07-01 CN CN201610510199.1A patent/CN106118270B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1078734A (en) * | 1992-05-11 | 1993-11-24 | 王胜利 | Reflective composite painting |
| EP1138644A2 (en) * | 2000-03-27 | 2001-10-04 | Friedhelm Dörge | Mass and shaped bodies formed thereof , having a surface effect |
| CN101338152A (en) * | 2007-07-20 | 2009-01-07 | 潘东海 | Road reflective marker line coating |
| CN101604032A (en) * | 2008-06-11 | 2009-12-16 | 梁晓斌 | Spotlight display high-brightness reflection optical lens protecting adhesive film |
| CN103351713A (en) * | 2013-07-08 | 2013-10-16 | 苏州凹凸彩印厂 | Luminous printing ink for printing outdoor advertisements |
| CN105331171A (en) * | 2015-12-08 | 2016-02-17 | 安徽中益新材料科技有限公司 | Retro-reflection energy-storing luminous paint and preparing method thereof |
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| CN106118270A (en) | 2016-11-16 |
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