CN108385380B - Solid silk soaking agent and preparation method thereof - Google Patents
Solid silk soaking agent and preparation method thereof Download PDFInfo
- Publication number
- CN108385380B CN108385380B CN201810183865.4A CN201810183865A CN108385380B CN 108385380 B CN108385380 B CN 108385380B CN 201810183865 A CN201810183865 A CN 201810183865A CN 108385380 B CN108385380 B CN 108385380B
- Authority
- CN
- China
- Prior art keywords
- parts
- silk
- soaking agent
- solid
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000002791 soaking Methods 0.000 title claims abstract description 62
- 239000007787 solid Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 66
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000001993 wax Substances 0.000 claims abstract description 23
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 20
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 20
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 12
- 229960000583 acetic acid Drugs 0.000 claims abstract description 12
- 239000012362 glacial acetic acid Substances 0.000 claims abstract description 12
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 12
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000012188 paraffin wax Substances 0.000 claims abstract description 12
- 229920002545 silicone oil Polymers 0.000 claims abstract description 12
- 239000008117 stearic acid Substances 0.000 claims abstract description 12
- -1 octadecyl dimethyl tertiary amine Chemical class 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims description 13
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 11
- 239000003822 epoxy resin Substances 0.000 claims description 11
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 11
- 229920000647 polyepoxide Polymers 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- 239000011734 sodium Substances 0.000 claims description 11
- 241000238631 Hexapoda Species 0.000 claims description 9
- 235000013871 bee wax Nutrition 0.000 claims description 9
- 239000012166 beeswax Substances 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- 238000002844 melting Methods 0.000 claims description 6
- 230000008018 melting Effects 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 238000005520 cutting process Methods 0.000 claims description 4
- 238000004090 dissolution Methods 0.000 claims description 4
- 239000006260 foam Substances 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 238000004806 packaging method and process Methods 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 238000007873 sieving Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 11
- 239000007788 liquid Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 150000002191 fatty alcohols Chemical class 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- 238000009941 weaving Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000007766 cera flava Substances 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 235000010931 Mesua ferrea Nutrition 0.000 description 1
- 235000005704 Olneya tesota Nutrition 0.000 description 1
- 240000007909 Prosopis juliflora Species 0.000 description 1
- 235000008198 Prosopis juliflora Nutrition 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000013101 initial test Methods 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 239000012165 plant wax Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/328—Amines the amino group being bound to an acyclic or cycloaliphatic carbon atom
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a solid silk soaking agent and a preparation method thereof, wherein the silk soaking agent comprises the following components in parts by weight: 20-30 parts of paraffin; 20-30 parts of octadecyl dimethyl tertiary amine; 5-10 parts of stearic acid; 1.5-3 parts of fatty alcohol-polyoxyethylene ether; 5-9 parts of glacial acetic acid; 18-22 parts of silicone oil; 3-10 parts of ethanol; 1-2 parts of fatty wax alcohol; 8-10 parts of water. The method has the advantages that the traditional liquid-state thread soaking agent is replaced by the solid-state thread soaking agent, so that the transportation convenience and the transportation efficiency are improved; secondly, the leakage situation can not appear easily in the transportation process, has eliminated certain potential safety hazard.
Description
Technical Field
The invention relates to a silk thread treating agent technology, in particular to a solid silk soaking agent and a preparation method thereof.
Background
The components of the early silk soaking agent are single, and the weaving requirement is mainly based on softness in the period of a ironwood weaving machine, for example, soapy water is the simplest silk soaking agent. Later, with the improvement of a silk weaving machine, an all-iron electric weaving machine with a higher picking speed is started to be applied, the silk soaking agent has the requirement on smoothness so as to reduce the friction coefficient generated by the quick picking motion and reduce the broken ends of warps and wefts, and the silk soaking agent in the period has hydrated white oil, an emulsified component of antique oil and white oil. By the end of the last 70 th century, with the progress of science and technology and higher requirements on product quality, the components of the silk soaking agent begin to develop towards multifunctional comprehensiveness, and the silk soaking agent gradually has the characteristics of smoothness, softness, weather resistance and the like.
However, the silk soaking agent is in a liquid state at present, and the content of the silk soaking agent in the liquid state silk soaking agent is only about twenty percent, so that the actually required barrels are high in quantity in the barreling process, and large occupied space is not beneficial to transportation; and leakage is easy to occur in the transportation process, so that certain potential safety hazard is realized.
Disclosure of Invention
The invention aims to provide a solid silk soaking agent, which is mainly used for replacing the traditional liquid silk soaking agent by preparing the solid silk soaking agent, so that the transportation convenience and the transportation efficiency are improved.
The technical purpose of the invention is realized by the following technical scheme: a solid silk soaking agent mainly comprises the following components in parts by weight: 20-30 parts of paraffin; 20-30 parts of octadecyl dimethyl tertiary amine; 5-10 parts of stearic acid; 1.5-3 parts of fatty alcohol-polyoxyethylene ether; 5-9 parts of glacial acetic acid; 18-22 parts of silicone oil; 3-10 parts of ethanol; 1-2 parts of fatty wax alcohol; 8-10 parts of water.
By the technical scheme, the paraffin and the stearic acid in the formula have the function of lubricating the silk threads; octadecyl dimethyl tertiary and all components in the formula are dissolved more fully; glacial acetic acid in the formula is used as a neutralizer for adjusting the pH value under the component proportion, and the ideal pH value is about 6; the silicone oil in the formula is used as a softening agent, and can treat the silk threads, so that the texture of the silk threads is soft, and the touch feeling effect is improved; the ethanol is used as a solvent to promote mutual solubility between water and an organic phase, promote rapid compatibility between formula components, promote rapid fatty alcohol-polyoxyethylene ether to be used as an emulsifier to a certain extent, have an emulsifying effect, and disperse the formula.
The invention further comprises the following steps: the composition further comprises 2-4 parts by weight of beeswax; 2-4 parts of insect wax.
According to the technical scheme, firstly, the beeswax and the insect wax have the emulsification stabilizing effect, so that mutual solubility of the components is further promoted, and moreover, as the melting points of the beeswax and the insect wax are about 70 ℃ and about 80 ℃, which are obviously higher than the normal temperature, the silk soaking agent can be prevented from being melted and connected into blocks after the temperature of a storage environment is raised in a normal storage process, so that the completeness of the silk soaking agent is favorably maintained, and the better quality maintenance in subsequent use is achieved; thirdly, as the beeswax and the insect wax belong to environment-friendly wax, and belong to pollution-free and harmless products to a certain extent, the environment-friendly wax is not only environment-friendly, but also the worker directly touches the silk soaking agent with hands before melting the silk to be soaked, and the safety is higher.
The invention further comprises the following steps: the components also comprise 0.2-0.5 part by weight of sodium fatty acid methyl ester sulfonate.
According to the technical scheme, the fatty acid methyl ester sodium sulfonate is an anionic surfactant derived from natural oil, the addition of the fatty acid methyl ester sodium sulfonate can improve the emulsifying property of fatty alcohol-polyoxyethylene ether, and meanwhile, the fatty alcohol-polyoxyethylene ether can improve the solubility of the fatty acid methyl ester sodium sulfonate, and the fatty acid methyl ester sodium sulfonate and the fatty alcohol-polyoxyethylene ether are complementary, so that the mutual dissolution of components in a formula is promoted, and the quality of a product is improved; in addition, the sodium fatty acid methyl ester sulfonate has good degradability, in addition, the decomposition of soil microorganisms can be promoted, the soil is not easy to be damaged, and the environment is protected; however, both of them are surfactants, and the aqueous solution prepared by the surfactant has a certain washing effect, and mainly shows that the silk threads can be washed when the later water and the solid silk-soaking agent are dissolved in a certain ratio for silk soaking.
The invention further comprises the following steps: the epoxy resin composition comprises, by weight, 1-2 parts of a double A type epoxy resin; 0.2-0.5 part of epoxy resin curing agent.
Through above-mentioned technical scheme, improve the mobility of component in the stirring mixing in-process to and the cohesiveness after mutually dissolving between the component, so at the in-process of cutting the piece in later stage, can not be similar to wax, produce a large amount of pieces, made things convenient for the section processing step.
The invention further comprises the following steps: the components also comprise alkyl polyoxyethylene ether in parts by weight.
According to the technical scheme, the alkyl polyoxyethylene ether is used as a detergent and is also used for cleaning, and the surface of the silk thread can be cleaned in a decontamination mode in the process of soaking the silk thread in the later period.
The second purpose of the invention is to provide a preparation method, and the prepared solid-state thread soaking agent can replace the traditional liquid-state thread soaking agent, so that the transportation convenience and the transportation efficiency are improved.
The technical purpose of the invention is realized by the following technical scheme: a preparation method of a solid silk soaking agent comprises the following steps: melting, namely putting the paraffin, the octadecyl dimethyl tertiary amine, the stearic acid and the fatty alcohol-polyoxyethylene ether in a formula ratio into a reaction vessel for mutual dissolution treatment to obtain a raw material; b, stirring, namely putting glacial acetic acid, silicone oil, ethanol and fatty wax alcohol in a formula ratio into a reactor, and stirring for dissolving; c, dissolving in water, namely adding water with the formula amount into a reaction container for dissolving in water, wherein the water temperature is mixed solution at 75-85 ℃; step d, cooling, namely cooling the product in the reaction container to 40 ℃; step e, preparing a solid-state silk soaking agent; and f, packaging and warehousing.
By adopting the technical scheme, the prepared solid silk soaking agent is dissolved in water and then is used for soaking silk threads, and has the function of lubricating the silk threads; the yarn can be softened and have an effect of improving the touch feeling.
The invention further comprises the following steps: in the step e, the step of preparing the solid-state thread-soaking agent comprises the following steps: step e1, cutting the solid blocky silk soaking agent obtained in the step d into sheets by adopting a slicing machine; step e2, crushing the flaky soaking silk agent into particles by adopting a crusher, and sieving the particles by a 20-mesh pharmacopeia sieve after crushing; and e3, crushing the granular silk soaking agent into powder by using a pulverizer, conveying the powder by using a pipeline of an air blower after the powder is ground, and then bagging.
Through the technical scheme: can be used for preparing sheet, granular and powdery silk soaking agents, and improves the diversity of products.
In summary, the following steps: the invention has the following advantages: the traditional liquid silk soaking agent is replaced by the sheet, granular and powdery silk soaking agent, and the content of the silk soaking agent in the liquid silk soaking agent is only about twenty percent, so that in the barreling process, the number of actually required barrels is high, the occupied space is large, and the solid silk soaking agent is bagged in parallel, so that the content of the silk soaking agent is high, the occupied space is small, and the transportation convenience and the transportation efficiency are improved; not only does this, the leakage situation can not appear easily in the transportation process, has eliminated certain potential safety hazard.
Detailed Description
The present invention will be described in further detail below.
The method comprises the following specific operations:
example 1
Table 1 shows components and parts by weight of solid silk soaking agent
| Components | Parts (1) | Components | Parts (1) |
| Paraffin wax | 20 | Glacial acetic acid | 9 |
| Octadecyl dimethyl Tertiary amine | 30 | Silicone oil | 18 |
| Stearic acid | 5 | Ethanol | 10 |
| Fatty alcohol polyoxyethylene ether | 3 | Fatty wax alcohol | 2 |
| Water (W) | 8 |
Example 2
Table 2 components and parts by weight of solid silk soaking agent
Example 3
TABLE 3 ingredients and parts by weight of solid silk-soaking agent
| Components | Parts (1) | Components | Parts (1) |
| Paraffin wax | 25 | Glacial acetic acid | 6 |
| Octadecyl dimethyl Tertiary amine | 25 | Silicone oil | 19 |
| Stearic acid | 7 | Ethanol | 7 |
| Fatty alcohol polyoxyethylene ether | 2 | Fatty wax alcohol | 1.5 |
| Water (W) | 9 | Beeswax (Cera flava) | 4 |
| Insect wax | 3 | Sodium fatty acid methyl ester sulfonate | 0.3 |
Example 4
Table 4 components and parts by weight of solid silk soaking agent
| Components | Parts (1) | Components | Parts (1) |
| Paraffin wax | 26 | Glacial acetic acid | 8 |
| Octadecyl dimethyl Tertiary amine | 27 | Silicone oil | 20 |
| Stearic acid | 8 | Ethanol | 9 |
| Fatty alcohol polyoxyethylene ether | 3 | Fatty wax alcohol | 1 |
| Water (W) | 10 | Beeswax (Cera flava) | 3 |
| Insect wax | 4 | Sodium fatty acid methyl ester sulfonate | 0.2 |
| bis-A-type epoxy resin | 2 | Epoxy resin curing agent | 0.4 |
Example 5
TABLE 5 solid silk soaking agent composition and its weight parts
Comparative example 1
TABLE 6 solid silk soaking agent composition and its weight parts
| Components | Parts (1) | Components | Parts (1) |
| Paraffin wax | 20 | Glacial acetic acid | 8 |
| Di-tertiary amine | 30 | Silicone oil | 18 |
| Stearic acid | 6 | Water (W) | 8 |
| Fatty alcohol polyoxyethylene ether | 2 |
Comparative example 2
Table 7 shows components and parts by weight of solid silk soaking agent
| Components | Parts (1) | Components | Parts (1) |
| Paraffin wax | 22 | Glacial acetic acid | 8 |
| Octadecyl dimethyl Tertiary amine | 28 | Silicone oil | 18 |
| Stearic acid | 6 | Ethanol | 8 |
| Fatty alcohol polyoxyethylene ether | 2 | Fatty wax alcohol | 2 |
| Water (W) | 8 | Plant wax | 5 |
Examples 1-5 and comparative examples 1 and 2 were prepared as follows: comprises the following steps: melting, namely putting the paraffin, the octadecyl dimethyl tertiary amine, the stearic acid and the fatty alcohol-polyoxyethylene ether in a formula ratio into a reaction vessel for mutual dissolution treatment to obtain a raw material; b, stirring, namely putting the glacial acetic acid, the silicone oil, the ethanol, the fatty wax alcohol, or the beeswax and the insect wax or the sodium fatty acid methyl ester sulfonate, or the double A-type epoxy resin or the epoxy resin curing agent or the alkyl polyoxyethylene ether into a reactor according to the formula ratio, and stirring for dissolving; c, dissolving in water, namely adding water with the formula amount into a reaction container for dissolving in water, wherein the water temperature is mixed solution at 80 ℃; step d, cooling, namely cooling the product in the reaction container to 40 ℃; step e, preparing a solid-state silk soaking agent; and f, packaging and warehousing.
In the step e, the step of preparing the solid-state thread-soaking agent comprises the following steps: step e1, cutting the solid blocky silk soaking agent obtained in the step d into sheets by adopting a slicing machine; step e2, crushing the flaky soaking silk agent into particles by adopting a crusher, and sieving the particles by a 20-mesh pharmacopeia sieve after crushing; and e3, crushing the granular silk soaking agent into powder by using a pulverizer, conveying the powder by using a pipeline of an air blower after the powder is ground, and then bagging.
Product performance characterization one: testing the high-temperature melting resistance of the powder of the examples 1-5 and the comparative examples 1 and 2, weighing 20g of powder of each group, placing the powder into a beaker, blowing the powder for 5 minutes by using a fan, avoiding the difference of the humidity of the initial test samples, reducing the difference among the groups, placing the beaker into an oven for 10 minutes, controlling the temperature to be 80 ℃, pouring the liquid in the beaker into a test tube, reading the volume, and recording the data result in a table 8.
Product performance characterization two: the integrity of the powder-state slices of examples 1 to 5 and comparative examples 1 and 2 was tested, and 10cm x 10cm solid state filament foam was prepared and cut from each group, and then cut into 2cm long, 1cm wide and 0.3cm thick slices using a wax slicer, then the weight of each group of slices was weighed after picking up the slices to remove debris, and then the difference in weight from the block was calculated, and the results were recorded in table 8.
Table 8: performance parameters of the yarn-soaking agent
The present embodiment is only for explaining the present invention, and it is not limited to the present invention, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present invention.
Claims (2)
1. The solid silk soaking agent is characterized by mainly comprising the following components in parts by weight: 20-30 parts of paraffin; 20-30 parts of octadecyl dimethyl tertiary amine; 5-10 parts of stearic acid; 1.5-3 parts of fatty alcohol-polyoxyethylene ether; 5-9 parts of glacial acetic acid; 18-22 parts of silicone oil; 3-10 parts of ethanol; 1-2 parts of fatty wax alcohol; 8-10 parts of water and 2-4 parts of beeswax; 2-4 parts of insect wax and 1-2 parts of double A type epoxy resin; 0.2-0.5 part of epoxy resin curing agent, 0.2-0.5 part of alkyl polyoxyethylene ether and 0.2-0.5 part of sodium fatty acid methyl ester sulfonate; the preparation of the solid silk soaking agent comprises the following steps: melting, namely putting the paraffin, the octadecyl dimethyl tertiary amine, the stearic acid and the fatty alcohol-polyoxyethylene ether in a formula ratio into a reaction vessel for mutual dissolution treatment to obtain a raw material; b, stirring, namely putting glacial acetic acid, silicone oil, ethanol, fatty wax alcohol, beeswax, insect wax, double A type epoxy resin, an epoxy resin curing agent, alkyl polyoxyethylene ether and sodium fatty acid methyl ester sulfonate into a reactor according to the formula ratio, and stirring for dissolving; c, dissolving in water, namely adding water with the formula amount into a reaction container for dissolving in water, wherein the water temperature is mixed solution at 75-85 ℃; step d, cooling, namely cooling the product in the reaction container to 40 ℃; step e, preparing a solid-state silk soaking agent; and f, packaging and warehousing.
2. The solid silk foam agent of claim 1, wherein in the step e, the step of preparing the solid silk foam agent is: step e1, cutting the solid blocky silk soaking agent obtained in the step d into sheets by adopting a slicing machine; step e2, crushing the flaky soaking silk agent into particles by adopting a crusher, and sieving the particles by a 20-mesh pharmacopeia sieve after crushing; and e3, crushing the granular silk soaking agent into powder by using a pulverizer, conveying the powder by using a pipeline of an air blower after the powder is ground, and then bagging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810183865.4A CN108385380B (en) | 2018-03-06 | 2018-03-06 | Solid silk soaking agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810183865.4A CN108385380B (en) | 2018-03-06 | 2018-03-06 | Solid silk soaking agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108385380A CN108385380A (en) | 2018-08-10 |
| CN108385380B true CN108385380B (en) | 2021-04-09 |
Family
ID=63066523
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810183865.4A Expired - Fee Related CN108385380B (en) | 2018-03-06 | 2018-03-06 | Solid silk soaking agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108385380B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112376270A (en) * | 2020-11-17 | 2021-02-19 | 安徽宏祥丝绸织造有限公司 | Formula of high-efficiency softening sericin silk soaking agent |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103194069A (en) * | 2013-04-15 | 2013-07-10 | 山东大学 | Paraffin-based composite material and preparation method thereof |
| CN106223033A (en) * | 2016-07-18 | 2016-12-14 | 上林县中兴丝业有限公司 | A kind of automatic silk reeling production and application silk impregnating agent |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3925242A (en) * | 1970-06-17 | 1975-12-09 | Rhone Poulenc Sa | Process for reducing foaming of liquids susceptible to foaming |
| CN1174141C (en) * | 2000-12-14 | 2004-11-03 | 中国科学院长春应用化学研究所 | Dipping oil for increasing strength of raw silk |
| CN103466966A (en) * | 2012-06-07 | 2013-12-25 | 天津市硅酸盐研究所 | Impregnating compound for enhancing quartz fiber tensile strength |
| CN104088149B (en) * | 2014-06-17 | 2016-04-27 | 黄山蓝天方园实业有限公司 | A kind of silk damping technique |
-
2018
- 2018-03-06 CN CN201810183865.4A patent/CN108385380B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103194069A (en) * | 2013-04-15 | 2013-07-10 | 山东大学 | Paraffin-based composite material and preparation method thereof |
| CN106223033A (en) * | 2016-07-18 | 2016-12-14 | 上林县中兴丝业有限公司 | A kind of automatic silk reeling production and application silk impregnating agent |
Non-Patent Citations (1)
| Title |
|---|
| 经纬通用型泡丝剂TWS的性能及应用;张洪曲等;《四川丝绸》;19941231(第4期);30-33 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108385380A (en) | 2018-08-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6821827B2 (en) | Fabric softener composition | |
| CN1219863C (en) | Method of stabilising fabric softening compositions | |
| KR19990064005A (en) | Scalping and Cleaning Composition Containing Cellulose Microfibers | |
| KR101791840B1 (en) | Non-hydrous Bio cellulous powder, Manufacturing method thereof and Cosmetic by using therof | |
| CN108385380B (en) | Solid silk soaking agent and preparation method thereof | |
| CN105441202B (en) | A kind of leather cleaning nursing nano emulsion composition and preparation method thereof | |
| EP0051983A1 (en) | A fabric softening composition and a process for preparing it | |
| EP3167034B1 (en) | Polyalkoxylated polyamines in laundry methods | |
| CN104059783A (en) | Preparation method of surfactant for detergents and detergent composition | |
| WO2021203555A1 (en) | Preparation method for fatty alcohol emulsion defoaming agent | |
| Keshwani et al. | Natural polymer based detergents for stain removal | |
| CN105623895B (en) | A kind of LED substrate substrate dewaxing cleaning agent | |
| KR101703709B1 (en) | Envelope type detergent | |
| KR101400887B1 (en) | Novel cation surfactant derived from modified natural oil, preparation method thereof and fabric softner using the same | |
| CN112537895B (en) | Preparation and application method of oily sludge biological treatment agent | |
| EP3555256B1 (en) | Cleaning compositions and methods of cleaning equipment | |
| CN111205940B (en) | Wax removal cleaning agent and preparation method and application thereof | |
| CN111893798A (en) | Synthetic alcohol ester papermaking stripping agent and preparation method thereof | |
| CN105838133B (en) | Emulsion detergent for ink and preparation method thereof | |
| CN109112020B (en) | Instant soap flakes and preparation method thereof | |
| CN104232366A (en) | Stainless steel cleaning bright aerosol | |
| CN115353936B (en) | Detergent composition with oil stain dispersing effect and preparation method of laundry gel beads thereof | |
| CN110483956A (en) | One kind is containing the modified polyadipate/butylene terephthalate composite material and preparation method of banana bast fiber | |
| DE102012202043A1 (en) | Washing or cleaning agent with cellulose or a cellulose derivative | |
| CN115387126B (en) | Preparation method of high-stability low-solvent softening agent for cotton |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20210409 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |