CN108385380A - A kind of solid-state silk impregnating agent and preparation method thereof - Google Patents
A kind of solid-state silk impregnating agent and preparation method thereof Download PDFInfo
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- CN108385380A CN108385380A CN201810183865.4A CN201810183865A CN108385380A CN 108385380 A CN108385380 A CN 108385380A CN 201810183865 A CN201810183865 A CN 201810183865A CN 108385380 A CN108385380 A CN 108385380A
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- silk impregnating
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- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 69
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 17
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 12
- 229960000583 acetic acid Drugs 0.000 claims abstract description 12
- 235000019441 ethanol Nutrition 0.000 claims abstract description 12
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 12
- 239000012362 glacial acetic acid Substances 0.000 claims abstract description 12
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 12
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000012188 paraffin wax Substances 0.000 claims abstract description 12
- 229920002545 silicone oil Polymers 0.000 claims abstract description 12
- 239000008117 stearic acid Substances 0.000 claims abstract description 12
- 150000002148 esters Chemical class 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 11
- 150000003512 tertiary amines Chemical class 0.000 claims abstract description 10
- 239000001993 wax Substances 0.000 claims description 11
- 241000238631 Hexapoda Species 0.000 claims description 8
- 235000013871 bee wax Nutrition 0.000 claims description 8
- 239000012166 beeswax Substances 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 5
- 238000003860 storage Methods 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 239000003822 epoxy resin Substances 0.000 claims description 4
- 229920000647 polyepoxide Polymers 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 3
- 235000013312 flour Nutrition 0.000 claims description 3
- 238000003801 milling Methods 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000004806 packaging method and process Methods 0.000 claims description 2
- -1 dimethyl tertiary amine Chemical class 0.000 claims 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract description 9
- 239000000243 solution Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 238000013016 damping Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- BVPWJMCABCPUQY-UHFFFAOYSA-N 4-amino-5-chloro-2-methoxy-N-[1-(phenylmethyl)-4-piperidinyl]benzamide Chemical compound COC1=CC(N)=C(Cl)C=C1C(=O)NC1CCN(CC=2C=CC=CC=2)CC1 BVPWJMCABCPUQY-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000736192 Ostrya virginiana Species 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 230000005621 ferroelectricity Effects 0.000 description 1
- 239000013056 hazardous product Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 239000012178 vegetable wax Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/328—Amines the amino group being bound to an acyclic or cycloaliphatic carbon atom
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of solid-state silk impregnating agent and preparation method thereof, which includes following parts by weight of component：20 ~ 30 parts of paraffin；20 ~ 30 parts of octadecyldimethyl tertiary amine；5 ~ 10 parts of stearic acid；1.5 ~ 3 parts of fatty alcohol polyoxyethylene ether；5 ~ 9 parts of glacial acetic acid；18 ~ 22 parts of silicone oil；3 ~ 10 parts of ethyl alcohol；1 ~ 2 part of ester cerotin；8 ~ 10 parts of water.The present invention mainly replaces traditional liquid state silk impregnating agent by preparing solid-state like silk impregnating agent, improves convenient transport degree and conevying efficiency；Secondly, it is easy to be not in leakage situation in transportational process, eliminates some potential safety problems.
Description
Technical field
The present invention relates to silk thread inorganic agent technology, more particularly to a kind of solid-state silk impregnating agent and preparation method thereof.
Background technology
The silk impregnating agent comparison of ingredients of early stage is single, hophornbeam loom period, and requirements of weaving process is substantially based on flexibility, such as
Suds are exactly a kind of most simple most simple silk impregnating agent.Later with the improvement of silk loom, start to compare using speed of throwing a spear
Fast full ferroelectricity power loom, silk impregnating agent just have the requirement of flatness, to reduce the friction coefficient that quick picking motion generates, subtract
Few latitude and longitude end breakage rate, the silk impregnating agent in this period have hydrophilic white oil, a kind of emulsified component of turkey red oil and white oil.To previous generation
It records the end of the seventies, with the progress of science and technology and to product quality requirements at the higher level, the ingredient of silk impregnating agent starts to multi-functional comprehensive
Conjunction property direction is developed, and has gradually so that silk is smooth, soft and weather-proof etc. characteristics.
But silk impregnating agent is liquid state at present, the content of silk impregnating agent only has 20 percent left side in liquid state silk impregnating agent
The right side, therefore during barreled, actual needs barrelage amount is high, and occupied space is unfavorable for transporting greatly；And it is easy in transportational process
It leaks, there is some potential safety problems.
Invention content
The first object of the present invention is to provide a kind of solid-state silk impregnating agent, mainly replaces passing by preparing solid-state like silk impregnating agent
The liquid state silk impregnating agent of system, improves convenient transport degree and conevying efficiency.
The present invention above-mentioned technical purpose technical scheme is that：A kind of solid-state silk impregnating agent, mainly
It include following parts by weight of component：20~30 parts of paraffin；20~30 parts of octadecyldimethyl tertiary amine；5~10 parts of stearic acid；Fat
1.5~3 parts of fat alcohol polyoxyethylene ether；5~9 parts of glacial acetic acid；18~22 parts of silicone oil；3~10 parts of ethyl alcohol；1~2 part of ester cerotin；Water 8
~10 parts.
Through the above technical solutions, the paraffin and stearic acid in formula have the function of lubricating silk thread；18 in formula
Alkyl dimethyl uncle and each component dissolving are more abundant；Glacial acetic acid in formula is as neutralizer, for adjusting in the component ratio
Ph values under example, ideal Ph values are 6 or so；Silicone oil in formula is can to handle silk thread as softening agent, make its quality
Softness improves the effect for touching sense；Ethyl alcohol can promote to dissolve each other between water and organic phase as solvent, between promotion recipe ingredient
It is quickly compatible, it can promote quick fatty alcohol polyoxyethylene ether as emulsifier to a certain extent, there is emulsification, it can
So that formula dispersion.
The present invention is further：It in terms of parts by weight of component, also comprises the following components, 2~4 parts of beeswax；2~4 parts of insect wax.
Through the above technical solutions, beeswax and insect wax all have the effect of stable emulsifying first, component is further promoted
Between dissolve each other, furthermore, it is aobvious and easy higher than room temperature because the fusing point of beeswax and insect wax is respectively 70 DEG C or so and 80 DEG C or so
See, therefore during normal storage, silk impregnating agent fusing connection after storage condition heating can be avoided blocking, so being conducive to
The integrality for maintaining silk impregnating agent reaches the quality in follow-up use and remains preferable；Third, since beeswax and insect wax belong to environment-friendly type
Wax belongs to pollution-free non-hazardous product to a certain extent, not only environmentally friendly, but also in thawing, it will be carried out staff
Before silk damping, silk impregnating agent directly is touched also without influence with hand, safety is higher.
The present invention is further：It also include 0.2~0.5 part of fatty acid methyl in terms of parts by weight of component, in said components
Ester sodium sulfonate.
Through the above technical solutions, methyl sodiosul foaliphatate is a kind of anion surface active derived from natural oil
Agent, the addition of methyl sodiosul foaliphatate can improve the emulsibility of fatty alcohol polyoxyethylene ether, while aliphatic alcohol polyethenoxy
Ether can improve the dissolubility of methyl sodiosul foaliphatate again, and the two complements each other, to promote in formula between component mutually
Dissolving, improves the quality of product；In addition, the degradability of methyl sodiosul foaliphatate is good, degradability is good in addition, can
Edaphon is promoted to decompose, it is not easy to soil can be jeopardized, it is environmentally friendly；Moreover, using the two as surfactant,
There are having certain cleaning function in the aqueous solution of preparation, it is mainly reflected in later stage water and solid-like silk impregnating agent by a certain percentage
When dissolving carries out silk damping, silk thread can be cleaned.
The present invention is further：Further include double 1~2 part of A types epoxy resin in terms of parts by weight of component, in said components；Ring
0.2~0.5 part of oxygen resin curing agent.
Through the above technical solutions, after dissolving each other between improving mobility and component of the component during stirring and evenly mixing
Caking property, so during later stage dicing, will not be similar to wax, generate a large amount of clasts, facilitate slice processing
Step.
The present invention is further：Further include alkyl polyoxyethylene ether in terms of parts by weight of component, in said components.
Through the above technical solutions, alkyl polyoxyethylene ether is as a kind of detergent, and for detergent, the later stage is soaking
In silk damping line process decontamination cleaning can be carried out to wire surface.
The second object of the present invention is to provide a kind of preparation method, and the solid-state silk impregnating agent being prepared can replace traditional
Liquid state silk impregnating agent improves convenient transport degree and conevying efficiency.
The present invention above-mentioned technical purpose technical scheme is that：A kind of preparation of solid-state silk impregnating agent
Method includes the following steps：Step a, melt, by the paraffin of formula ratio, octadecyldimethyl tertiary amine, stearic acid and fatty alcohol
Polyoxyethylene ether puts into reaction vessel processing of dissolving each other and obtains raw material；Step b, stir, by the glacial acetic acid of formula ratio, silicone oil,
Ethyl alcohol and ester cerotin are put into reactor, and dissolving is stirred；Step c, water-soluble, the water of formula ratio is added to reaction vessel
It is middle to carry out the mixed liquor water-soluble, wherein water temperature is 75 DEG C~85 DEG C；Product in reaction vessel is cooled to 40 by step d, cooling
℃；Step e, solid-state like silk impregnating agent is prepared；Step f, packaging and storage.
Through the above technical solutions, the water-soluble rear immersion silk thread of solid-state silk impregnating agent is prepared, have the function of lubricating silk thread；
Can also be played to silk thread makes its soft texture improve the effect for touching sense.
The present invention is further：In the step e, described the step of preparing solid-state like silk impregnating agent, is：Step e1, using cutting
Cooling in step d is obtained solid block silk impregnating agent and is cut into sheet by piece machine；Step e2, sheet silk impregnating agent is crushed using pulverizer
Preparing granular smashes it through the pharmacopeia sieve of 20 mesh；Step e3, using flour mill by granular silk impregnating agent powder crushing process end shape, after milling
Pipeline is carried out using air blower, is then packed.
Pass through above-mentioned technical proposal：Sheet, granular and powdered silk impregnating agent can be prepared, the various of product is improved
Property.
In summary：The present invention has the advantages that lower：Mainly by preparing sheet, granular and powdered silk impregnating agent replacement biography
The liquid state silk impregnating agent of system, the content of silk impregnating agent only has 20 or so percent in liquid state silk impregnating agent, therefore in barreled process
In, actual needs barrelage amount is high, and occupied space is big, and uses solid-state silk impregnating agent packed parallel, and silk damping agent content is high, occupied space
It is small, improve convenient transport degree and conevying efficiency；Moreover, it is easy to be not in leakage situation in transportational process, eliminate
Some potential safety problems.
Specific implementation mode
Invention is further described in detail below.
Operation specific as follows：
Embodiment 1
The component and its parts by weight of a kind of 1 solid-state silk impregnating agent of table
| Component | Number (part) | Component | Number (part) |
| Paraffin | 20 | Glacial acetic acid | 9 |
| Octadecyldimethyl tertiary amine | 30 | Silicone oil | 18 |
| Stearic acid | 5 | Ethyl alcohol | 10 |
| Fatty alcohol polyoxyethylene ether | 3 | Ester cerotin | 2 |
| Water | 8 |
Embodiment 2
The component and its parts by weight of a kind of 2 solid-state silk impregnating agent of table
Embodiment 3
The component and its parts by weight of a kind of 3 solid-state silk impregnating agent of table
| Component | Number (part) | Component | Number (part) |
| Paraffin | 25 | Glacial acetic acid | 6 |
| Octadecyldimethyl tertiary amine | 25 | Silicone oil | 19 |
| Stearic acid | 7 | Ethyl alcohol | 7 |
| Fatty alcohol polyoxyethylene ether | 2 | Ester cerotin | 1.5 |
| Water | 9 | Beeswax | 4 |
| Insect wax | 3 | Methyl sodiosul foaliphatate | 0.3 |
Embodiment 4
The component and its parts by weight of a kind of 4 solid-state silk impregnating agent of table
| Component | Number (part) | Component | Number (part) |
| Paraffin | 26 | Glacial acetic acid | 8 |
| Octadecyldimethyl tertiary amine | 27 | Silicone oil | 20 |
| Stearic acid | 8 | Ethyl alcohol | 9 |
| Fatty alcohol polyoxyethylene ether | 3 | Ester cerotin | 1 |
| Water | 10 | Beeswax | 3 |
| Insect wax | 4 | Methyl sodiosul foaliphatate | 0.2 |
| Double A types epoxy resin | 2 | Epoxy curing agent | 0.4 |
Embodiment 5
The component and its parts by weight of a kind of 5 solid-state silk impregnating agent of table
Comparative example 1
The component and its parts by weight of a kind of 6 solid-state silk impregnating agent of table
| Component | Number (part) | Component | Number (part) |
| Paraffin | 20 | Glacial acetic acid | 8 |
| Two tertiary amines | 30 | Silicone oil | 18 |
| Stearic acid | 6 | Water | 8 |
| Fatty alcohol polyoxyethylene ether | 2 |
Comparative example 2
The component and its parts by weight of a kind of 7 solid-state silk impregnating agent of table
| Component | Number (part) | Component | Number (part) |
| Paraffin | 22 | Glacial acetic acid | 8 |
| Octadecyldimethyl tertiary amine | 28 | Silicone oil | 18 |
| Stearic acid | 6 | Ethyl alcohol | 8 |
| Fatty alcohol polyoxyethylene ether | 2 | Ester cerotin | 2 |
| Water | 8 | Vegetable wax | 5 |
Examples 1 to 5 and comparative example 1 and 2 are prepared with the following method：Include the following steps：Step a, melt, by formula ratio
Paraffin, octadecyldimethyl tertiary amine, stearic acid and fatty alcohol polyoxyethylene ether put into dissolve each other in reaction vessel and handle
To raw material；Step b, it stirs, by the glacial acetic acid of formula ratio, silicone oil, ethyl alcohol and ester cerotin and or beeswax and insect wax or aliphatic acid
Methyl ester sulfonate or double A types epoxy resin or epoxy curing agent or alkyl polyoxyethylene ether are put into reactor, are carried out
Stirring and dissolving；Step c, water-soluble, the water of formula ratio is added in reaction vessel and carries out the mixing water-soluble, wherein water temperature is 80 DEG C
Liquid；Product in reaction vessel is cooled to 40 DEG C by step d, cooling；Step e, solid-state like silk impregnating agent is prepared；Step f, it packs
Storage.
In the wherein described step e, described the step of preparing solid-state like silk impregnating agent, is：Step e1, using slicer by step d
Middle cooling obtains solid block silk impregnating agent and is cut into sheet；Step e2, sheet silk impregnating agent is crushed by preparing granular using pulverizer, crushed
The pharmacopeia sieve of 20 mesh is crossed afterwards；Step e3, using flour mill by granular silk impregnating agent powder crushing process end shape, after milling using air blower into
Row pipeline, is then packed.
Product property characterization one：The high temperature resistant melting of testing example 1~5 and comparative example 1 and 2 under pulverulence, respectively
Group weighs 20g powder, is then placed in beaker, first wind turbine is used to dry up 5 minutes, and the humidity for avoiding starting test specimens is different, drop
Otherness between low each group is then placed in baking oven 10 minutes, controlled at 80 DEG C, pours out in beaker liquid to test tube
In, volume is read, and data result is recorded in table 8.
Product property characterization two：Testing example 1~5 and comparative example 1 and 2 be sliced under pulverulence after it is complete
Property, each group is made and cuts 10cm*10cm*10cm solid-state silk impregnating agents, then use wax slicer carry out and cut growth 2cm,
Then the thin slice of wide 1cm and thickness 0.3cm sort out the weight that thin slice removal clast weighs each group thin slice again, then calculating and block
Result is recorded in table 8 by weight difference when shape.
Table 8：The performance parameter of silk impregnating agent
This specific embodiment is only explanation of the invention, is not limitation of the present invention, and those skilled in the art exist
Can as needed the present embodiment be made the modification of not creative contribution after this specification by reading, but as long as in the present invention
Right in all protected by Patent Law.
Claims (7)
1. a kind of solid-state silk impregnating agent, which is characterized in that include mainly following parts by weight of component：20 ~ 30 parts of paraffin；Octadecyl
20 ~ 30 parts of dimethyl tertiary amine；5 ~ 10 parts of stearic acid；1.5 ~ 3 parts of fatty alcohol polyoxyethylene ether；5 ~ 9 parts of glacial acetic acid；Silicone oil 18 ~ 22
Part；3 ~ 10 parts of ethyl alcohol；1 ~ 2 part of ester cerotin；8 ~ 10 parts of water.
2. a kind of solid-state silk impregnating agent according to claim 1, which is characterized in that further include as follows in terms of parts by weight of component
Component, 2 ~ 4 parts of beeswax；2 ~ 4 parts of insect wax.
3. a kind of solid-state silk impregnating agent according to claim 2, which is characterized in that in terms of parts by weight of component, in said components
It also include 0.2 ~ 0.5 part of methyl sodiosul foaliphatate.
4. a kind of solid-state silk impregnating agent according to claim 3, which is characterized in that in terms of parts by weight of component, in said components
Further include double 1 ~ 2 part of A types epoxy resin；0.2 ~ 0.5 part of epoxy curing agent.
5. a kind of solid-state silk impregnating agent according to claim 1, which is characterized in that in terms of parts by weight of component, in said components
It further include alkyl polyoxyethylene ether.
6. a kind of preparation method of solid-state silk impregnating agent according to claim 1, which is characterized in that include the following steps：Step
Rapid a, melt, the paraffin of formula ratio, octadecyldimethyl tertiary amine, stearic acid and fatty alcohol polyoxyethylene ether are put into reaction
Processing of dissolving each other in container obtains raw material；Step b, it stirs, the glacial acetic acid of formula ratio, silicone oil, ethyl alcohol and ester cerotin is put into instead
It answers in device, is stirred dissolving；Step c, water-soluble, the water of formula ratio is added in reaction vessel and carries out water-soluble, wherein water temperature
For 75 DEG C ~ 85 DEG C of mixed liquor；Product in reaction vessel is cooled to 40 DEG C by step d, cooling；Step e, it prepares solid-state like
Silk impregnating agent；Step f, packaging and storage.
7. a kind of preparation method of solid-state silk impregnating agent according to claim 6, which is characterized in that described in the step e
The step of preparing solid-state like silk impregnating agent be：Step e1, cooling in step d solid block silk impregnating agent is obtained using slicer to be cut into
Sheet；Step e2, sheet silk impregnating agent is crushed by preparing granular using pulverizer, smashes it through the pharmacopeia sieve of 20 mesh；Step e3, it uses
Granular silk impregnating agent powder crushing process end shape is carried out pipeline using air blower after milling, is then packed by flour mill.
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Cited By (1)
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| CN112376270A (en) * | 2020-11-17 | 2021-02-19 | 安徽宏祥丝绸织造有限公司 | Formula of high-efficiency softening sericin silk soaking agent |
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