CN108385242B - A kind of antistatic, radiation protection, fire-retardant, high permeability fabric and preparation method thereof - Google Patents
A kind of antistatic, radiation protection, fire-retardant, high permeability fabric and preparation method thereof Download PDFInfo
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- CN108385242B CN108385242B CN201810292882.1A CN201810292882A CN108385242B CN 108385242 B CN108385242 B CN 108385242B CN 201810292882 A CN201810292882 A CN 201810292882A CN 108385242 B CN108385242 B CN 108385242B
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/242—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads inorganic, e.g. basalt
- D03D15/25—Metal
- D03D15/258—Noble metal
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/593—Stiff materials, e.g. cane or slat
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
- D06M2101/28—Acrylonitrile; Methacrylonitrile
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2101/00—Inorganic fibres
- D10B2101/10—Inorganic fibres based on non-oxides other than metals
- D10B2101/12—Carbon; Pitch
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/10—Bamboo
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/10—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
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- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a kind of antistatics, radiation protection, fire-retardant, high permeability fabric and preparation method thereof, fabric alternately clamps porous core by warp cluster and weft cluster and constitutes, in which: warp cluster is made of 1-3 root calcium alginate fire resistance fibre 1 and 3-5 root silver fiber 2,1-2 root polyester fiber；Weft cluster is made of the fire-retardant acrylic fiber 4 of 2-4 root and 1-3 root stainless steel fiber, 1-2 root polyester fiber；Porous core is made of 2-4 root bamboo fibre or carbon fiber or bamboo fibre with carbon fiber；Antistatic agent is coated at the warp cluster of porous core two sides and the intersection seam of weft cluster.The fabric meets antistatic, radiation protection, fire-retardant and high permeability requirement, while reaching the Functional Requirement of fabric, has preferable comfort.And ensure that the stability of the antistatic agent on fabric, there is preferable radiation protection, antistatic, fire-retardant and wear-resisting and permeability, ensure that it has preferable comfort property on the whole.
Description
Technical field
The present invention relates to composite textile technical field, more particularly to a kind of antistatic, radiation protection, fire-retardant, high
Property fabric and preparation method thereof.
Background technique
Current garment material mainly uses the yarn weavings such as cotton, hair, chemical fibre to form, and the mutual friction of clothes phase can generate quiet
Electricity, therefore be always the focus of this field for the research of the antistatic property of garment material.In daily life, we
Clothing can rub simultaneously with family's textile fabric, such as when being sitting on sofa seat, more compared with the contact of sofa fabric, existing
Sofa fabric antistatic effect it is poor, lean against on sofa, under the action of electrostatic, hair is easily attracted on sofa,
When standing up, cause hair style in disorder, furthermore the moulding of the electrostatic influence clothing between clothing, it is inconvenient and awkward to be easy to cause.
Therefore family's textile fabric used in sofa is also required to improve its antistatic property.
Chinese patent CN201320187689.4 discloses a kind of anti-static function fabric, in the upper and lower surface of fabric base layer
Antistatic coating and lower antistatic coating is respectively coated, so that fabric be made to have antistatic effect.Due to antistatic coating
Be by antistatic finishing agent coating be formed by, therefore antistatic effect be not it is permanent, which wears no resistance,
If sofa fabric use, than very fast, antistatic effect is easy gradually to weaken for the abrasion of antistatic coating, until losing completely
Effect, furthermore the fabric has a single function, and is unable to satisfy the modern life to the multi-functional requirement of family's textile fabric.
Anti-static fabric mostly uses greatly polyester cotton, and there is apparent defects in polyester fiber performance: feel is poor,
Pilling wears sultry, poor air permeability.Therefore, by the change on the physical and chemical performance of polyester fiber, improve fabric
Wearability becomes the target of people's exploration.In recent years, the tencel developed by the modification to polyester fiber --- it inhales
Wet perspiration fibre becomes the renewal product of polyester fiber.What international at present, domestic production hygroscopic fibre used
It is common PET slice, changes the cross sectional shape of its fiber simply by physical means, increase some specific surface areas and groove to change
Kind taking can not guarantee and its function after various other fiber blends without fundamentally solving the essence of ordinary polyester fiber
The validity of energy does not overcome its first defect led and later period adsorption capacity is poor with functionality.Novel moisture absorption perspiration fibre is
A kind of denatured product of polyester fiber has fiber inside and outside perforative micro- during the spinning process by chemically and physically means
Pore structure can quickly absorb water, is hydrophobic, spreading and volatilizing, and so as to improve the physical property of fiber, have fabric good
Moisture absorbing and sweat releasing characteristic.Simultaneously as polyester fiber wet yield modulus with higher, it will not be as cotton fibre under moisture state
Dimension lodges like that, can remain the comfort conditions between fabric and skin, improve the wearing comfort of fiber.Novel moisture absorption
Perspiration fibre is that a have good flexibility, anti-fluffing and anti-pilling, hydroscopic fast-drying, low temperature dyeing and other functions to roll into one
Multifunctional fibre, and can be with various fiber blends after, still can guarantee the validity of its performance, being really achieved makes its function
Permanently, the feature of environmental protection, the popularity and the fabulous requirement for taking safety that use.
For the microorganism of nature, the skin of people is a kind of good Nutrient medium.Under normal circumstances, fell
Some resident strains play a part of protecting the skin from pathogenic bacteria harm on skin, once but the flora imbalance in microorganism, it
In a small amount of pathogenic bacteria will mass propagation, and human body is caused by skin, respiratory tract, alimentary canal and genital tract mucosa
Harm.Textile can stain many sweat, sebum and various other human secretions in human body wearing process, while also can
It is stained by the pollution in environment, in the breeding and transmittance process of pathogenic bacteria, becomes an important medium.So Ren Menxu
It wants that antibacterial textile can be supported to meet the requirement to health, and anion (antibacterial) polyester staple fiber is antibacterial fabric
Desirable feedstock.Silver ion (antibacterial) polyester staple fiber fuses into anti-biotic material among spinning melt, is process through spinning
A kind of permanent type functional fibre is compared with the method for anti-bacterial finish, have broad-spectrum antiseptic, antibiotic rate height, durable antibacterial effect,
Harmless, applied widely advantage safe to the human body.
Currently, the patent document in terms of multifunctional fabric also has many reports.Such as: 1, application No. is
200710070548.3, the application for a patent for invention of entitled " moisture permeable anti-ultraviolet multifunctional antibiotic facing material and its processing technology ".
2, application No. is a kind of 201010265716.6, applications for a patent for invention of entitled " multifunctional fabric ".3, application No. is
201310436630.9, the application for a patent for invention of entitled " a kind of shell fabric with health care function ".But these fabrics are not able to satisfy
In high radiation, the requirement of high temperature applicationss, so the application specially provide with radiation protection, wear-resisting, fire-retardant, radiation protection,
The fabric of gas permeability and anti-static function.
Summary of the invention
In order to overcome the above-mentioned deficiencies of the prior art, the present invention provides one kind with calcium alginate fire resistance fibre, silver fiber,
Bamboo fibre or carbon fiber braiding are enclosed for interior armful when polyester fiber, fire-retardant acrylic fiber, stainless steel fiber braiding, and saturating being located at
Be coated at the warp cluster of gaseous core two sides and the intersection seam of weft cluster antistatic agent braiding made of fabric, thus meet fabric prevent it is quiet
Electricity, radiation protection, fire-retardant and high permeability requirement, while reaching the Functional Requirement of fabric, consideration that can be appropriate its relax
Adaptive.
The technical scheme adopted by the invention is that: a kind of antistatic, radiation protection, fire-retardant, high permeability fabric, by warp cluster and
The interconnection of weft cluster clamps porous core composition simultaneously, in which:
Warp cluster is made of 1-3 root calcium alginate fire resistance fibre 1 and 3-5 root silver fiber 2,1-2 root polyester fiber；
Weft cluster is made of the fire-retardant acrylic fiber of 2-4 root and 1-3 root stainless steel fiber, 1-2 root polyester fiber；
Porous core is made of 2-4 root bamboo fibre or carbon fiber or bamboo fibre with carbon fiber；
Antistatic agent is coated at the warp cluster of porous core two sides and the intersection seam of weft cluster；
In specific textile fabric, a weaving unit is carried out in accordance with the following steps and weaves fabric, three to four braidings are single
After member braiding is completed, carries out starting hot-air seasoning or ultraviolet light dries this three to four weaving units:
A. warp cluster and weft cluster are alternately fed using two shuttle machines；
B. spray antistatic agent, using automatic spray apparatus clamping electrostatic spinning machine alignment porous core two sides warp cluster and
Antistatic agent is sprayed at the intersection seam of weft cluster；
C. porous core is fed；
D. shuttle machine cross feed warp cluster and weft cluster are then used；
E. spray antistatic agent, using automatic spray apparatus clamping electrostatic spinning machine alignment porous core two sides warp cluster and
Antistatic agent is sprayed at the intersection seam of weft cluster, completes the circulation of a textile fabric；
After the completion of above-mentioned fabric is tentatively weaved, following process: fire retardant spraying, secondary drying, Wear-resistant Treatment is successively carried out
And stentering forming；In fire retardant spraying, the outer surface of fabric is only sprayed, and the flame retardant formulations are according to weight percent packet
Following component is included to prepare: 13 parts of sodium hydroxide, 55 parts -65 parts of fire retardant ATP, 1 part -3 parts of anion-permeable membrane agent, 3 parts
Catalyst, remaining is water.
Further, secondary drying technique is dried using independent drying equipment, and drying equipment includes being sequentially connected
Drying unit and its drive apparatus, anti-wear agent spraying and its drive apparatus and wrap-up, wherein drying unit and its transmission
Equipment carries out secondary drying to fabric and automatically delivers, and anti-wear agent spraying and its drive apparatus are used for spraying abrasion-proof agent, simultaneously
Cloth is transmitted, and wrap-up is for winding fabric.
Further, the formula of antistatic agent, the ingredient including following parts by weight:
Potassium acetate: 16 parts, technical white oil: 8~12 parts, polypropylene: 11~13 parts, dimethylbenzene: 25 parts, p-methyl benzenesulfonic acid:
15 parts, triethanolamine: 13 parts, acetone: 6~8 parts, dimethyl terephthalate (DMT): 21 parts, surfactant: 32 parts, initiator: 4
Part, ethyl alcohol: 19 parts, deionized water: 82 parts.
Further, the antistatic agent is in production, by surfactant, potassium acetate, technical white oil, polypropylene, two
Toluene, p-methyl benzenesulfonic acid, triethanolamine and 50wt% deionized water sequence blender is added, stir half an hour at 45 DEG C,
150~200 revs/min of mixing speed；Then acetone, dimethyl terephthalate (DMT), initiator, ethyl alcohol and remaining deionized water are added
Enter blender, be warming up to 60-63 DEG C, stir 1.5 hours, be cooled to room temperature under 200~300 revs/min of revolving speed, after filtering i.e.
It can be used.
Further, fire retardant spraying equipment includes being sequentially connected preheating device, spray equipment and ultraviolet curing dress
It sets, and is continuously driven by drive apparatus between these equipment, while being additionally provided with seal closure on the outside of spray equipment, sealed
Cover in connect vaccum-pumping equipment, guarantee fire retardant spraying when environmental pressure be 0.5-0.6Mpa, have more uniformly spray
Pressure.
Further, sealing device, and ultraviolet curing device and fire retardant also are provided on the outside of ultraviolet curing device
Spraying equipment connection, it is whole to guarantee that working environment pressure is 0.5-0.6Mpa.
Further, fabric sprays antistatic agent using automatic spray apparatus clamping electrostatic spinning machine in fabrication processes
When, automatic spray apparatus is arranged on the track of shuttle machine weaving direction, while automatic spray apparatus by servo motor drive into
Braiding fabric synchronous with shuttle machine on that track is connected to sliding block.
Further, electrostatic spinning machine nozzle is the flat structure after loudspeaker flatten, and spray area is larger when spinneret.
A kind of antistatic, radiation protection, fire-retardant, high permeability fabric preparation method, including it is several functional fiber lines are first
First it is twisted warp cluster and weft cluster, and the method for porous core being wrapped up in warp cluster and weft cluster in weaving, in which:
In specific textile fabric, a weaving unit is carried out in accordance with the following steps and weaves fabric, three to four braidings are single
After member braiding is completed, carries out starting hot-air seasoning or ultraviolet light dries this three to four weaving units:
A. warp cluster and weft cluster are alternately fed using two shuttle machines；
B. spray antistatic agent, using automatic spray apparatus clamping electrostatic spinning machine alignment porous core two sides warp cluster and
Antistatic agent is sprayed at the intersection seam of weft cluster；
C. porous core is fed；
D. shuttle machine cross feed warp cluster and weft cluster are then used,
E. spray antistatic agent, using automatic spray apparatus clamping electrostatic spinning machine alignment porous core two sides warp cluster and
Antistatic agent is sprayed at the intersection seam of weft cluster, completes the circulation of a textile fabric；
After the completion of above-mentioned fabric is tentatively weaved, following process: fire retardant spraying, secondary drying, Wear-resistant Treatment is successively carried out
And stentering forming；In fire retardant spraying, the outer surface of fabric is only sprayed, and the flame retardant formulations are according to weight percent packet
Following component is included to prepare: 13 parts of sodium hydroxide, 55 parts -65 parts of fire retardant ATP, 1 part -3 parts of anion-permeable membrane agent, 3 parts
Catalyst, remaining is water.
Further, secondary drying technique is dried using independent drying equipment, and drying equipment includes being sequentially connected
Drying unit and its drive apparatus, anti-wear agent spraying and its drive apparatus and wrap-up, wherein drying unit and its transmission
Equipment carries out secondary drying to fabric and automatically delivers, and anti-wear agent spraying and its drive apparatus are used for spraying abrasion-proof agent, simultaneously
Cloth is transmitted, and wrap-up is for winding fabric；When manufacturing the fabric, it should also meet following requirement:
Antistatic agent production when, by surfactant, potassium acetate, technical white oil, polypropylene, dimethylbenzene, to toluene sulphur
Blender is added in the deionized water sequence of acid, triethanolamine and 50wt%, stirs half an hour at 45 DEG C, and mixing speed 150~
200 revs/min；Blender, heating then is added in acetone, dimethyl terephthalate (DMT), initiator, ethyl alcohol and remaining deionized water
It to 60-63 DEG C, stirs 1.5 hours, is cooled to room temperature under 200~300 revs/min of revolving speed, can be used after filtering；
Fire retardant spraying equipment includes being sequentially connected preheating device, spray equipment and ultraviolet curing device, and this
It is continuously driven by drive apparatus between a little equipment, while being additionally provided with seal closure on the outside of spray equipment, connection in seal closure
Vaccum-pumping equipment, guarantee fire retardant spraying when environmental pressure be 0.5-0.6Mpa, have more uniformly spray pressure；It is ultraviolet
Sealing device, and ultraviolet curing device and fire retardant spraying equipment connection also are provided on the outside of line solidification equipment, it is whole to guarantee
Working environment pressure is 0.5-0.6Mpa.
Compared with prior art, the beneficial effects of the present invention are: fabric one kind of the invention with calcium alginate fire resistance fibre,
Bamboo fibre or carbon fiber braiding are enclosed for interior armful when silver fiber, polyester fiber, fire-retardant acrylic fiber, stainless steel fiber braiding, and
Fabric made of antistatic agent braiding is coated at the intersection seam of the warp cluster and weft cluster that are located at porous core two sides, to meet
Fabric antistatic, radiation protection, fire-retardant and high permeability requirement can be appropriate while reaching the Functional Requirement of fabric
Consider its comfort.
In addition, the antistatic, radiation protection, fire-retardant, high permeability fabric, one of unit in the fabrication process is knitted
Make process are as follows: use shuttle machine cross feed warp cluster and weft cluster, then carry out antistatic agent spraying, feeding porous core, it
Cross feed warp cluster and weft cluster afterwards, spray antistatic agent again, the weaving process in fabric manufacturing process fully
Antistatic agent has been smeared, and has then almost been synchronously carried out hot-air seasoning or ultraviolet light, ensure that the stabilization of antistatic agent
Property, so the application fills on the whole, there is preferable radiation protection, antistatic, fire-retardant and wear-resisting and permeability, guarantee
It has a preferable comfort property on the whole.
Detailed description of the invention
Fig. 1 be a kind of antistatic, radiation protection, fire-retardant, high permeability fabric a weaving unit one embodiment knot
Composition；
Fig. 2 be weaving antistatic, radiation protection, the automatic spray apparatus of fire-retardant, high permeability fabric and electrostatic spinning machine with
The position assumption diagram of shuttle machine connection；
The knot for the drying equipment that Fig. 3 is used when being the secondary drying of weaving antistatic, radiation protection, fire-retardant, high permeability fabric
Structure schematic diagram；
Fig. 4 be weave antistatic, radiation protection, fire-retardant, high permeability fabric fire retardant spraying equipment structural schematic diagram.
Specific embodiment
In order to deepen the understanding of the present invention, present invention will be further explained below with reference to the attached drawings and examples, the implementation
Example for explaining only the invention, does not constitute protection scope of the present invention and limits.
Embodiment 1
A kind of antistatic, radiation protection, fire-retardant, high permeability fabric, as shown in Figure 1, by warp cluster 3 and weft cluster interconnection
The composition of porous core 5 is clamped simultaneously, in which:
Warp cluster 3 is made of 1-3 root calcium alginate fire resistance fibre 1 and 3-5 root silver fiber 2,1-2 root polyester fiber, is protected
Flame retardant property, electric conductivity i.e. antistatic property and wear-resisting property with higher after fabric is made are demonstrate,proved；
Weft cluster 4 is made of the fire-retardant acrylic fiber of 2-4 root and 1-3 root stainless steel fiber, 1-2 root polyester fiber, is protected
Having demonstrate,proved has preferable shielding property and wear-resisting property after fabric is made；
Porous core 5 is made of 2-4 root bamboo fibre or carbon fiber or bamboo fibre with carbon fiber, has preferable electric conductivity
And permeability；
It is coated with antistatic agent at the warp cluster of 5 two sides of porous core and the intersection seam of weft cluster, antistatic effect is more preferably；
In specific textile fabric, a weaving unit is carried out in accordance with the following steps and weaves fabric, three to four braidings are single
After member braiding is completed, carries out starting hot-air seasoning or ultraviolet light dries this three to four weaving units:
A. warp cluster and weft cluster are alternately fed using two shuttle machines；
B. spray antistatic agent, using automatic spray apparatus clamping electrostatic spinning machine alignment porous core two sides warp cluster and
Antistatic agent is sprayed at the intersection seam of weft cluster；
C. porous core is fed；
D. warp cluster and weft cluster then are alternately fed using shuttle machine,
E. spray antistatic agent, using automatic spray apparatus clamping electrostatic spinning machine alignment porous core two sides warp cluster and
Antistatic agent is sprayed at the intersection seam of weft cluster, completes the circulation of a textile fabric；
After the completion of above-mentioned fabric is tentatively weaved, following process: fire retardant spraying, secondary drying, Wear-resistant Treatment is successively carried out
And stentering forming；In fire retardant spraying, the outer surface of fabric is only sprayed, and the flame retardant formulations are according to weight percent packet
Following component is included to prepare: 13 parts of sodium hydroxide, 55 parts -65 parts of fire retardant ATP, 1 part -3 parts of anion-permeable membrane agent, 3 parts
Catalyst, remaining is water.The above-mentioned antistatic completed using above-mentioned method for weaving and technique, radiation protection, fire-retardant, high permeability
Fabric ensure that the stability of antistatic agent, so the application fills on the whole, have preferable radiation protection, antistatic, resistance
Combustion and wear-resisting and permeability, ensure that it has preferable comfort property on the whole.More preferably flame retardant formulations according to
Weight percent includes that following component is prepared: 13 parts of sodium hydroxide, 62 parts of fire retardant ATP, 2 parts of anion-permeable membrane agent, and 3
The catalyst of part, remaining is water, using the fire retardant of the formula, is sprayed on fabric, and whole flame retardant property effect is preferable, and
It can guarantee that influence is not received in other radiation protections in fabric component, antistatic property, and can guarantee certain permeability.
Embodiment 2
With embodiment 1 the difference is that secondary drying technique is dried using independent drying equipment, drying equipment packet
Sequentially connected drying unit and its drive apparatus, anti-wear agent spraying and its drive apparatus and wrap-up are included, wherein drying dress
It sets and its drive apparatus carries out secondary drying to fabric and automatically delivers, anti-wear agent spraying and its drive apparatus are resistance to for spraying
Grinding agent, while cloth is transmitted, and wrap-up is for winding fabric.Fabric total quality obtained is preferable.
Embodiment 3
With Examples 1 and 2 the difference is that in the present embodiment, the formula of antistatic agent, including following parts by weight at
Point:
Potassium acetate: 16 parts, technical white oil: 8 or 11 or 12 parts, polypropylene: 11 or 12 or 13 parts, dimethylbenzene: 25 parts, to first
Benzene sulfonic acid: 15 parts, triethanolamine: 13 parts, acetone: 6 or 7 or 8 parts, dimethyl terephthalate (DMT): 21 parts, surfactant: 32
Part, initiator: 4 parts, ethyl alcohol: 19 parts, deionized water: 82 parts.Cooperate above-mentioned Weaving method using the antistatic agent of this proportion
With fabric made from preparation method, have the effect of when in use more environmentally friendly and durable.
More preferably embodiment is the antistatic agent in production, by surfactant, potassium acetate, technical white oil, is gathered
Propylene, dimethylbenzene, p-methyl benzenesulfonic acid, triethanolamine and 50wt% deionized water sequence blender is added, stirred at 45 DEG C
Half an hour, 150~200 revs/min of mixing speed；Then acetone, dimethyl terephthalate (DMT), initiator, ethyl alcohol and residue are gone
Blender is added in ionized water, is warming up to 60-63 DEG C, stirs 1.5 hours, be cooled to room temperature under 200~300 revs/min of revolving speed,
It can be used after filtering.Use antistatic agent made from the preparation method, Environment-friendlywear-resistant wear-resistant.
Embodiment 4
With embodiment 1 the difference is that fire retardant spraying equipment includes being sequentially connected preheating device, spray equipment and purple
Outside line solidification equipment, and be continuously driven by drive apparatus between these equipment, while being additionally provided on the outside of spray equipment
Seal closure connects vaccum-pumping equipment in seal closure, guarantees when fire retardant spraying in environmental pressure to be 0.5-0.6Mpa, have more
Uniformly spray pressure.More preferably embodiment is also to be provided with sealing device, and ultraviolet curing on the outside of ultraviolet curing device
Device and fire retardant spraying equipment connection, it is whole to guarantee that working environment pressure is 0.5-0.6Mpa.When the fabric is fire-retardant by this
When spraying equipment is sprayed, painting environments pressure is uniform, and has certain atmospheric pressure, and spraying effect is preferable.
Embodiment 5
The embodiments different from embodiment 1 are that fabric is in fabrication processes, as shown in Fig. 2, using automatic spraying dress
When setting 6 clamping electrostatic spinning machines 10 spraying antistatic agent, automatic spray apparatus 6 is arranged on the track 7 of shuttle machine weaving direction, together
When automatic spray apparatus by the driving feeding connection of sliding block 9 of servo motor 8 braiding fabric synchronous with shuttle machine on that track, spray
Automatic performance it is good, and can be fed with 11 synchronous coordination of shuttle machine, weaving efficiency is high.And electrostatic spinning machine nozzle is loudspeaker
Flat structure after flattening, spray area is larger when spinneret.
Embodiment 6
A kind of antistatic, radiation protection, fire-retardant, high permeability fabric preparation method, including it is several functional fiber lines are first
It is first twisted warp cluster and weft cluster, and wraps up the method for porous core in warp cluster and weft cluster in weaving, in which:
In specific textile fabric, a weaving unit is carried out in accordance with the following steps and weaves fabric, wherein being as shown in Figure 1
The structural schematic diagram of one weaving unit carries out starting hot-air seasoning or purple after three to four weaving unit braidings are completed
This three to four weaving units are dried in outside line:
A. warp cluster and weft cluster are alternately fed using two shuttle machines；
B. antistatic agent is sprayed, the warp c. cluster of automatic spray apparatus clamping electrostatic spinning machine alignment porous core two sides is used
With spraying antistatic agent at the intersection seam of weft cluster；
D. porous core is fed；
E. warp cluster and weft cluster are alternately then fed using shuttle machine,
F. spray antistatic agent, using automatic spray apparatus clamping electrostatic spinning machine alignment porous core two sides warp cluster and
Antistatic agent is sprayed at the intersection seam of weft cluster, completes the circulation of a textile fabric；
After the completion of above-mentioned fabric is tentatively weaved, following process: fire retardant spraying, secondary drying, Wear-resistant Treatment is successively carried out
And stentering forming；In fire retardant spraying, the outer surface of fabric is only sprayed, and the flame retardant formulations are according to weight percent packet
Following component is included to prepare: 13 parts of sodium hydroxide, 55 parts -65 parts of fire retardant ATP, 1 part -3 parts of anion-permeable membrane agent, 3 parts
Catalyst, remaining is water.The above-mentioned antistatic completed using above-mentioned method for weaving and technique, radiation protection, fire-retardant, high permeability
Fabric ensure that the stability of antistatic agent, so the application fills on the whole, have preferable radiation protection, antistatic, resistance
Combustion and wear-resisting and permeability, ensure that it has preferable comfort property on the whole.
Embodiment 7
With embodiment 5 the difference is that as shown in figure 3, secondary drying technique is dried using independent drying equipment,
Drying equipment includes sequentially connected drying unit and its drive apparatus 12, anti-wear agent spraying and its drive apparatus 13 and winding dress
14 are set, wherein drying unit and its drive apparatus carry out secondary drying to fabric and automatically deliver, anti-wear agent spraying and its biography
Dynamic equipment is used for spraying abrasion-proof agent, while transmitting cloth, and wrap-up is for winding fabric；When manufacturing the fabric, also
Following requirement should be met:
Antistatic agent production when, by surfactant, potassium acetate, technical white oil, polypropylene, dimethylbenzene, to toluene sulphur
Blender is added in the deionized water sequence of acid, triethanolamine and 50wt%, stirs half an hour at 45 DEG C, and mixing speed 150~
200 revs/min；Blender, heating then is added in acetone, dimethyl terephthalate (DMT), initiator, ethyl alcohol and remaining deionized water
It to 60-63 DEG C, stirs 1.5 hours, is cooled to room temperature under 200~300 revs/min of revolving speed, can be used after filtering；
As shown in figure 4, fire retardant spraying equipment 15 includes being sequentially connected preheating device 16, spray equipment 17 and ultraviolet light
Solidification equipment 18, and be continuously driven by drive apparatus between these equipment, while being additionally provided on the outside of spray equipment close
Sealing cover 19 connects vaccum-pumping equipment 20 in seal closure, guarantees when fire retardant spraying in environmental pressure to be 0.5-0.6Mpa, have compared with
To uniformly spray pressure；Sealing device, and ultraviolet curing device and fire retardant also are provided on the outside of ultraviolet curing device
Spraying equipment connection, it is whole to guarantee that working environment pressure is 0.5-0.6Mpa.When the fabric is carried out by the fire-retarding spray coating equipment
When spraying, painting environments pressure is uniform, and has certain atmospheric pressure, and spraying effect is preferable.
What the embodiment of the present invention was announced is preferred embodiment, and however, it is not limited to this, the ordinary skill people of this field
Member, easily according to above-described embodiment, understands spirit of the invention, and make different amplification and variation, but as long as not departing from this
The spirit of invention, all within the scope of the present invention.
Claims (10)
1. a kind of antistatic, radiation protection, fire-retardant, high permeability fabric, which is characterized in that intersected by warp cluster (3) and weft cluster and connected
It connects while clamping porous core (5) composition, in which:
Warp cluster (3) is made of 1-3 root calcium alginate fire resistance fibre (1) and 3-5 root silver fiber (2), 1-2 root polyester fiber；
Weft cluster (4) is made of the fire-retardant acrylic fiber of 2-4 root (4) and 1-3 root stainless steel fiber, 1-2 root polyester fiber；
Porous core (5) is made of 2-4 root bamboo fibre or carbon fiber or bamboo fibre with carbon fiber；
Antistatic agent is coated at the warp cluster of porous core (5) two sides and the intersection seam of weft cluster；
In specific textile fabric, a weaving unit is carried out in accordance with the following steps and weaves fabric, three to four weaving units are compiled
It casts off into later, carries out starting hot-air seasoning or ultraviolet light dries this three to four weaving units:
Warp cluster and weft cluster are alternately fed using two shuttle machines；
Antistatic agent is sprayed, the warp cluster and weft cluster of automatic spray apparatus clamping electrostatic spinning machine alignment porous core two sides are used
Intersection seam at spray antistatic agent；
Feed porous core；
Warp cluster and weft cluster then are alternately fed using shuttle machine,
Antistatic agent is sprayed, the warp cluster and weft cluster of automatic spray apparatus clamping electrostatic spinning machine alignment porous core two sides are used
Intersection seam at spray antistatic agent, complete the circulation of a textile fabric；
After the completion of above-mentioned fabric is tentatively weaved, following process: fire retardant spraying, secondary drying, Wear-resistant Treatment and drawing is successively carried out
Width sizing；In fire retardant spraying, the outer surface of fabric is only sprayed, and the flame retardant formulations include such as according to weight percent
Lower component is prepared: 13 parts of sodium hydroxide, 55 parts -65 parts of fire retardant ATP, 1 part -3 parts of anion-permeable membrane agent, and 3 parts are urged
Agent, remaining is water.
2. a kind of antistatic according to claim 1, radiation protection, fire-retardant, high permeability fabric, which is characterized in that secondary baking
Dry technique is dried using independent drying equipment, drying equipment include sequentially connected drying unit and its drive apparatus,
Anti-wear agent spraying and its drive apparatus and wrap-up, wherein drying unit and its drive apparatus to fabric carry out secondary drying with
And automatically deliver, anti-wear agent spraying and its drive apparatus are used for spraying abrasion-proof agent, while transmitting cloth, and wrap-up is used for
Wind fabric.
3. a kind of antistatic according to claim 1 or 2, radiation protection, fire-retardant, high permeability fabric, which is characterized in that resist quiet
The formula of electric agent, the ingredient including following parts by weight:
Potassium acetate: 16 parts, technical white oil: 8~12 parts, polypropylene: 11~13 parts, dimethylbenzene: 25 parts, p-methyl benzenesulfonic acid: 15 parts,
Triethanolamine: 13 parts, acetone: 6~8 parts, dimethyl terephthalate (DMT): 21 parts, surfactant: 32 parts, initiator: 4 parts, second
Alcohol: 19 parts, deionized water: 82 parts.
4. a kind of antistatic according to claim 3, radiation protection, fire-retardant, high permeability fabric, which is characterized in that described anti-
Electrostatic agent is in production, by surfactant, potassium acetate, technical white oil, polypropylene, dimethylbenzene, p-methyl benzenesulfonic acid, triethanolamine
And blender is added in the deionized water sequence of 50wt%, stirs half an hour at 45 DEG C, 150~200 revs/min of mixing speed；With
Blender is added in acetone, dimethyl terephthalate (DMT), initiator, ethyl alcohol and remaining deionized water afterwards, is warming up to 60-63 DEG C,
It stirs 1.5 hours, is cooled to room temperature under 200~300 revs/min of revolving speed, can be used after filtering.
5. a kind of antistatic according to claim 1 or 2, radiation protection, fire-retardant, high permeability fabric, which is characterized in that fire-retardant
Agent spraying equipment is equal including being sequentially connected preheating device, spray equipment and ultraviolet curing device, and between these equipment
It is continuously driven by drive apparatus, while being additionally provided with seal closure on the outside of spray equipment, vaccum-pumping equipment is connected in seal closure, protected
Demonstrate,prove fire retardant spraying when environmental pressure be 0.5-0.6Mpa, have more uniformly spray pressure.
6. a kind of antistatic according to claim 5, radiation protection, fire-retardant, high permeability fabric, which is characterized in that ultraviolet light
Sealing device, and ultraviolet curing device and fire retardant spraying equipment connection also are provided on the outside of solidification equipment, it is whole to guarantee work
Making environmental pressure is 0.5-0.6Mpa.
7. a kind of antistatic according to claim 1, radiation protection, fire-retardant, high permeability fabric, which is characterized in that fabric exists
In fabrication processes, when using automatic spray apparatus clamping electrostatic spinning machine spraying antistatic agent, automatic spray apparatus is arranged in shuttle
On the track of machine weaving direction, at the same automatic spray apparatus by servo motor drive feeding sliding block connection on that track with shuttle
The synchronous braiding fabric of machine.
8. a kind of antistatic according to claim 1 or claim 7, radiation protection, fire-retardant, high permeability fabric, which is characterized in that electrostatic
Spinning instrument nozzle is the flat structure after loudspeaker flatten, and spray area is larger when spinneret.
9. a kind of antistatic, radiation protection, fire-retardant, high permeability fabric preparation method, be used for manufacturing claims 1-8 any one
The antistatic, radiation protection, fire-retardant, high permeability fabric, which is characterized in that including being twisted several functional fiber lines first
Warp cluster and weft cluster, and weaving when in warp cluster and weft cluster wrap up porous core method, in which:
In specific textile fabric, a weaving unit is carried out in accordance with the following steps and weaves fabric, three to four weaving units are compiled
It casts off into later, carries out starting hot-air seasoning or ultraviolet light dries this three to four weaving units:
A. warp cluster and weft cluster are alternately fed using two shuttle machines；
B. antistatic agent is sprayed, the warp cluster and weft of automatic spray apparatus clamping electrostatic spinning machine alignment porous core two sides are used
Antistatic agent is sprayed at the intersection seam of cluster；
C. porous core is fed；
D. warp cluster and weft cluster are alternately then fed using shuttle machine,
E. antistatic agent is sprayed, the warp cluster and weft of automatic spray apparatus clamping electrostatic spinning machine alignment porous core two sides are used
Antistatic agent is sprayed at the intersection seam of cluster, completes the circulation of a textile fabric；
After the completion of above-mentioned fabric is tentatively weaved, following process: fire retardant spraying, secondary drying, Wear-resistant Treatment and drawing is successively carried out
Width sizing；In fire retardant spraying, the outer surface of fabric is only sprayed, and the flame retardant formulations include such as according to weight percent
Lower component is prepared: 13 parts of sodium hydroxide, 55 parts -65 parts of fire retardant ATP, 1 part -3 parts of anion-permeable membrane agent, and 3 parts are urged
Agent, remaining is water.
10. the preparation method of fabric according to claim 9, which is characterized in that secondary drying technique uses independent baking
Dry equipment is dried, and drying equipment includes sequentially connected drying unit and its drive apparatus, anti-wear agent spraying and its transmission
Equipment and wrap-up, wherein drying unit and its drive apparatus carry out secondary drying to fabric and automatically deliver, anti-wear agent
Spraying and its drive apparatus are used for spraying abrasion-proof agent, while transmitting cloth, and wrap-up is for winding fabric；It is somebody's turn to do in manufacture
When fabric, should also meet following requirement: antistatic agent in production, by surfactant, potassium acetate, technical white oil, polypropylene,
Dimethylbenzene, p-methyl benzenesulfonic acid, triethanolamine and 50wt% deionized water sequence blender is added, it is small that half is stirred at 45 DEG C
When, 150~200 revs/min of mixing speed；Then by acetone, dimethyl terephthalate (DMT), initiator, ethyl alcohol and remaining deionization
Blender is added in water, is warming up to 60-63 DEG C, stirs 1.5 hours, be cooled to room temperature under 200~300 revs/min of revolving speed, filters
It can be used afterwards；
Fire retardant spraying equipment includes being sequentially connected preheating device, spray equipment and ultraviolet curing device, and these set
It is continuously driven by drive apparatus between standby, while being additionally provided with seal closure on the outside of spray equipment, connection is taken out true in seal closure
Null device, guarantee fire retardant spraying when environmental pressure be 0.5-0.6Mpa, have more uniformly spray pressure；Ultraviolet light is solid
Makeup sets outside and also is provided with sealing device, and ultraviolet curing device and fire retardant spraying equipment connection, whole to guarantee work
Environmental pressure is 0.5-0.6Mpa.
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| CN110029425A (en) * | 2019-04-15 | 2019-07-19 | 中山市仕春纺织印染实业有限公司 | A kind of Composite anti-radiation material garment material |
| CN111778615B (en) * | 2019-07-18 | 2021-10-22 | 深圳市健力达纺织品有限公司 | Preparation method of antistatic woven fabric capable of absorbing sweat and removing dirt |
| CN111424361A (en) * | 2020-03-31 | 2020-07-17 | 江西服装学院 | Flame-retardant fabric and preparation method thereof |
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| US20130118635A1 (en) * | 2009-12-14 | 2013-05-16 | International Global Trading Usa, Inc. | Flame, Heat and Electric Arc Protective Yarn and Fabric |
| CN104372488A (en) * | 2014-11-20 | 2015-02-25 | 常熟市创裕印染有限公司 | Preparing method of multifunctional shielding fabric |
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