CN108374286A - 一种稀土发光纤维的制备方法 - Google Patents
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Abstract
本发明公开了一种稀土发光纤维的制备方法，包括发光粉末的原料选取、发光粉末的制备、稀土纤维与发光粉末的融合处理、稀土发光纤维的稳固性提升和降污染处理：步骤一：发光粉末的原料选取；步骤二：发光粉末的制备；步骤三：稀土纤维与发光粉末的融合处理；步骤四：稀土发光纤维的稳固性提升；步骤五：降污染处理，通过在发光粉末的制备过程中，在发光粉末原材料并放置Sr、Eu的氧化物组成的稀土离子激活的碱土铝酸盐为基质的疫光材料，能够流动固化成膜性能稳定，发光时间长，装饰效果好的热固性发光粉末涂料。
Description
技术领域
本发明涉及稀土发光纤维技术领域，具体为一种稀土发光纤维的制备方法。
背景技术
稀土发光纤维是利用稀土发光材料制成的功能性环保新材料。该纤维是以纺丝原料为基体，采用长余辉稀土铝酸盐发光材料，经特种纺丝制成夜光纤维。夜光纤维吸收可见光10分钟，便能将光能蓄贮于纤维之中，在黑暗状态下持续发光10小时以上。在有光照时，夜光纤维呈现出各种颜色，如红色、黄色、绿色、蓝色等。在黑暗中，夜光纤维发出各种色光，如红光、黄光、蓝光、绿光等。夜光纤维色彩绚丽，且不需染色，是环保高效的高科技产品。
发光颜料是由金属硫化物与金属活化剂、微量重金属经煅烧制得，其效果，由于为固体发光粉来涂料，解决了易涂装，克服涂装影响作业环境和不安全因素等问题，但是由于其发光材料是由金属硫化物构成，其主要不足是化学稳定性差、易分解、发光时间短，因此难于满足工业生产和生活的需求。
稀土发光纤维成品存在污染性问题。
发明内容
本发明的目的在于提供一种稀土发光纤维的制备方法，解决了背景技术中所提出的问题。
为实现上述目的，本发明提供如下技术方案：一种稀土发光纤维的制备方法，包括发光粉末的原料选取、发光粉末的制备、稀土纤维与发光粉末的融合处理、稀土发光纤维的稳固性提升和降污染处理：
步骤一：发光粉末的原料选取；
步骤二：发光粉末的制备；
步骤三：稀土纤维与发光粉末的融合处理；
步骤四：稀土发光纤维的稳固性提升；
步骤五：降污染处理。
作为本发明的一种优选实施方式，所述发光粉末的原料选取，主要构成是由发光材料与油漆配制构成组合物，发光材料前者是由金属硫化物、氯化物和无机盐制成，成分配比按照1:1:1制成，后者是碱土铝硼酸盐为基质及金属活化剂制成，与油漆及配料是用酚醛、硝基、聚酯、环氧及聚氨酯等配料组合，并加入稀释剂制成溶剂型发光涂料。
作为本发明的一种优选实施方式，所述发光粉末的制备，将发光粉末原材料的组成部分依次放入到存放稀释剂制成溶剂型发光涂料的融合炉中，并放置Sr、Eu的氧化物组成的稀土离子激活的碱土铝酸盐为基质的疫光材料，其原料在煅烧前后经过两次偶联剂、硬酯酸活化改性处理的夜光材料与配组材料组合使用，进行搅拌融合，温度控制在200-300摄氏度，搅拌速率控制在300-400转/分钟，搅拌时间控制在5小时，制成发光粉末溶液。
作为本发明的一种优选实施方式，所述稀土纤维与发光粉末的融合处理将稀土纤维放置与发光粉末溶液内，然后放置催化剂，进行加热处理。
作为本发明的一种优选实施方式，所述稀土发光纤维的稳固性提升，对稀土纤维与发光粉末的混合炉中进行搅拌处理，温度控制在100-150摄氏度，搅拌速率控制在200-300转/分钟，搅拌时间控制在4小时，然后浸泡10小时，然后将稀土发光纤维取出通过烘干机进行烘干处理，制成成品。
作为本发明的一种优选实施方式，所述降污染处理将稀土发光纤维通过压力机对稀土发光纤维进行加压处理，然后通过剪毛机对稀土发光纤维对表层的多余纤维进行剔除。
与现有技术相比，本发明的有益效果如下：
1.通过在发光粉末的制备过程中，在发光粉末原材料并放置Sr、Eu的氧化物组成的稀土离子激活的碱土铝酸盐为基质的疫光材料，能够流动固化成膜性能稳定，发光时间长，装饰效果好的热固性发光粉末涂料。
2.在稀土发光纤维的制备方法中设有稀土发光纤维的稳固性提升的步骤，对稀土纤维与发光粉末的混合炉中进行搅拌处理，温度控制在100-150摄氏度，搅拌速率控制在200-300转/分钟，搅拌时间控制在4小时，然后浸泡10小时，可以提高发光粉末和稀土纤维进行搅拌和热加工处理，加热后进行浸泡处理，可以提高稀土纤维和发光粉末的契合度。
具体实施方式
下面将结合本发明实施例中，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
本发明提供一种技术方案：一种稀土发光纤维的制备方法，包括发光粉末的原料选取、发光粉末的制备、稀土纤维与发光粉末的融合处理、稀土发光纤维的稳固性提升和降污染处理：
步骤一：发光粉末的原料选取；
步骤二：发光粉末的制备；
步骤三：稀土纤维与发光粉末的融合处理；
步骤四：稀土发光纤维的稳固性提升；
步骤五：降污染处理。
所述发光粉末的原料选取，主要构成是由发光材料与油漆配制构成组合物，发光材料前者是由金属硫化物、氯化物和无机盐制成，成分配比按照1:1:1制成，后者是碱土铝硼酸盐为基质及金属活化剂制成，与油漆及配料是用酚醛、硝基、聚酯、环氧及聚氨酯等配料组合，并加入稀释剂制成溶剂型发光涂料。
所述发光粉末的制备，将发光粉末原材料的组成部分依次放入到存放稀释剂制成溶剂型发光涂料的融合炉中，并放置Sr、Eu的氧化物组成的稀土离子激活的碱土铝酸盐为基质的疫光材料，其原料在煅烧前后经过两次偶联剂、硬酯酸活化改性处理的夜光材料与配组材料组合使用，进行搅拌融合，温度控制在200-300摄氏度，搅拌速率控制在300-400转/分钟，搅拌时间控制在5小时，制成发光粉末溶液。
所述稀土纤维与发光粉末的融合处理将稀土纤维放置与发光粉末溶液内，然后放置催化剂，进行加热处理。
所述稀土发光纤维的稳固性提升，对稀土纤维与发光粉末的混合炉中进行搅拌处理，温度控制在100-150摄氏度，搅拌速率控制在200-300转/分钟，搅拌时间控制在4小时，然后浸泡10小时，然后将稀土发光纤维取出通过烘干机进行烘干处理，制成成品。
所述降污染处理将稀土发光纤维通过压力机对稀土发光纤维进行加压处理，然后通过剪毛机对稀土发光纤维对表层的多余纤维进行剔除，通过在发光粉末的制备过程中，在发光粉末原材料并放置Sr、Eu的氧化物组成的稀土离子激活的碱土铝酸盐为基质的疫光材料，能够流动固化成膜性能稳定，发光时间长，装饰效果好的热固性发光粉末涂料，在稀土发光纤维的制备方法中设有稀土发光纤维的稳固性提升的步骤，对稀土纤维与发光粉末的混合炉中进行搅拌处理，温度控制在100-150摄氏度，搅拌速率控制在200-300转/分钟，搅拌时间控制在4小时，然后浸泡10小时，可以提高发光粉末和稀土纤维进行搅拌和热加工处理，加热后进行浸泡处理，可以提高稀土纤维和发光粉末的契合度。
工作原理：通过在发光粉末的制备过程中，在发光粉末原材料并放置Sr、Eu的氧化物组成的稀土离子激活的碱土铝酸盐为基质的疫光材料，能够流动固化成膜性能稳定，发光时间长，装饰效果好的热固性发光粉末涂料，在稀土发光纤维的制备方法中设有稀土发光纤维的稳固性提升的步骤，对稀土纤维与发光粉末的混合炉中进行搅拌处理，温度控制在100-150摄氏度，搅拌速率控制在200-300转/分钟，搅拌时间控制在4小时，然后浸泡10小时，可以提高发光粉末和稀土纤维进行搅拌和热加工处理，加热后进行浸泡处理，可以提高稀土纤维和发光粉末的契合度。
最后应说明的是：以上所述仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照前述实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。
Claims (6)
1.一种稀土发光纤维的制备方法，包括发光粉末的原料选取、发光粉末的制备、稀土纤维与发光粉末的融合处理、稀土发光纤维的稳固性提升和降污染处理，其特征在于：
步骤一：发光粉末的原料选取；
步骤二：发光粉末的制备；
步骤三：稀土纤维与发光粉末的融合处理；
步骤四：稀土发光纤维的稳固性提升；
步骤五：降污染处理。
2.根据权利要求1所述的一种稀土发光纤维的制备方法，其特征在于：所述发光粉末的原料选取，主要构成是由发光材料与油漆配制构成组合物，发光材料前者是由金属硫化物、氯化物和无机盐制成，成分配比按照1:1:1制成，后者是碱土铝硼酸盐为基质及金属活化剂制成，与油漆及配料是用酚醛、硝基、聚酯、环氧及聚氨酯等配料组合，并加入稀释剂制成溶剂型发光涂料。
3.根据权利要求1所述的一种稀土发光纤维的制备方法，其特征在于：所述发光粉末的制备，将发光粉末原材料的组成部分依次放入到存放稀释剂制成溶剂型发光涂料的融合炉中，并放置Sr、Eu的氧化物组成的稀土离子激活的碱土铝酸盐为基质的疫光材料，其原料在煅烧前后经过两次偶联剂、硬酯酸活化改性处理的夜光材料与配组材料组合使用，进行搅拌融合，温度控制在200-300摄氏度，搅拌速率控制在300-400转/分钟，搅拌时间控制在5小时，制成发光粉末溶液。
4.根据权利要求1所述的一种稀土发光纤维的制备方法，其特征在于：所述稀土纤维与发光粉末的融合处理将稀土纤维放置与发光粉末溶液内，然后放置催化剂，进行加热处理。
5.根据权利要求1所述的一种稀土发光纤维的制备方法，其特征在于：所述稀土发光纤维的稳固性提升，对稀土纤维与发光粉末的混合炉中进行搅拌处理，温度控制在100-150摄氏度，搅拌速率控制在200-300转/分钟，搅拌时间控制在4小时，然后浸泡10小时，然后将稀土发光纤维取出通过烘干机进行烘干处理，制成成品。
6.根据权利要求1所述的一种稀土发光纤维的制备方法，其特征在于：所述降污染处理将稀土发光纤维通过压力机对稀土发光纤维进行加压处理，然后通过剪毛机对稀土发光纤维对表层的多余纤维进行剔除。
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