CN108368813A - Method and fuel injector for manufacturing the valve member for being used for fuel injector - Google Patents
Method and fuel injector for manufacturing the valve member for being used for fuel injector Download PDFInfo
- Publication number
- CN108368813A CN108368813A CN201680071613.1A CN201680071613A CN108368813A CN 108368813 A CN108368813 A CN 108368813A CN 201680071613 A CN201680071613 A CN 201680071613A CN 108368813 A CN108368813 A CN 108368813A
- Authority
- CN
- China
- Prior art keywords
- valve member
- basic material
- hardness
- support layer
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M47/00—Fuel-injection apparatus operated cyclically with fuel-injection valves actuated by fluid pressure
- F02M47/02—Fuel-injection apparatus operated cyclically with fuel-injection valves actuated by fluid pressure of accumulator-injector type, i.e. having fuel pressure of accumulator tending to open, and fuel pressure in other chamber tending to close, injection valves and having means for periodically releasing that closing pressure
- F02M47/027—Electrically actuated valves draining the chamber to release the closing pressure
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/04—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings of inorganic non-metallic material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/60—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes
- C23C8/62—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes only one element being applied
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/80—After-treatment
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M63/00—Other fuel-injection apparatus having pertinent characteristics not provided for in groups F02M39/00 - F02M57/00 or F02M67/00; Details, component parts, or accessories of fuel-injection apparatus, not provided for in, or of interest apart from, the apparatus of groups F02M39/00 - F02M61/00 or F02M67/00; Combination of fuel pump with other devices, e.g. lubricating oil pump
- F02M63/0012—Valves
- F02M63/007—Details not provided for in, or of interest apart from, the apparatus of the groups F02M63/0014 - F02M63/0059
- F02M63/0077—Valve seat details
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M2200/00—Details of fuel-injection apparatus, not otherwise provided for
- F02M2200/90—Selection of particular materials
- F02M2200/9038—Coatings
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M2200/00—Details of fuel-injection apparatus, not otherwise provided for
- F02M2200/90—Selection of particular materials
- F02M2200/9046—Multi-layered materials
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M2200/00—Details of fuel-injection apparatus, not otherwise provided for
- F02M2200/90—Selection of particular materials
- F02M2200/9053—Metals
- F02M2200/9061—Special treatments for modifying the properties of metals used for fuel injection apparatus, e.g. modifying mechanical or electromagnetic properties
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Inorganic Chemistry (AREA)
- Fuel-Injection Apparatus (AREA)
Abstract
The present invention relates to a kind of methods for manufacturing the valve member (108) for fuel injector (100), the injector has the region for constituting valve seat (115) on the valve member (108), wherein, the valve member (108) is by preferably hardening or quenched steel is formed as basic material (119), the surface of the basic material is coated with carbon-coating (130) in the range of constituting the region of the valve seat (115), and the carbon-coating has the hardness bigger than the material of the basic material (119).It is arranged according to the present invention, support layer (120) is configured between the basic material (119) and the carbon-coating (130), wherein, the hardness of the support layer (120) is at least big as the hardness of the basic material (119).
Description
Technical field
The present invention relates to it is a kind of according to claim 1 preamble, for manufacturing the valve member for being used for fuel injector
Method.In addition, the present invention relates to a kind of fuel injectors with valve member of the present invention.
Background technology
Such as the component part of fuel injector is known for use as by 10 2,013 225 387 A1 of document DE of applicant
This valve member have valve seat, the valve seat with for example in be formed from steel hardening valve ball form closure member collective effect.It is logical
Fuel can be controlled to the discharge in the area of low pressure of fuel injector, so as to so as to open or close nozzle by crossing valve seat
Needle.Due to wear reason it is known that the basic material of this valve member being made of steel is coated with carbon-coating, so as to larger
Hardness equip valve member on valve seat with the coefficient region of valve components.This carbon-coating is usually had by technique several micro- with determining
Rice, typically about 2 microns of layer thickness.This layer thickness is used enough in the case where particle size is small, however in particle size
It can be bumped against on their boundary in the case of larger.Therefore, this is caused in the case where there are larger particles in the carbon from valve member
Layer generates the surface stress improved when being transitioned into basic material, because due to larger particle elastic-plastic can occur for basic material
Deformation, and carbon-coating largely keeps rigidity.This may lead to the local shedding of carbon-coating, this may result in channel simultaneously again
And insecure pressure at valve seat is caused to be vacillated blow-by in other words.
Invention content
From the prior art shown, the task that the present invention is based on is, extension is according to claim 1 preamble in this way
Method partial, for manufacturing the valve member for being used for fuel injector so that the especially valve member in the case where there are larger particles
Wearability with raising.In particular, carbon-coating should be avoided from valve member local shedding.
According to the present invention, in method with claim 1 feature, for manufacturing the valve member for being used for fuel injector
In the case of solve the task.
The design that the present invention is based on is, can by the support layer being arranged between the basic material of valve member and carbon-coating
The firmness change process evenly on valve member is achieved so that hardness from basic material to carbon coating direction be not prominent
So increase.In the ideal case, this support layer causes to increase from basic material to the substantially continuous hardness in carbon coating direction.
As a result, in the transitional region between the support layer of valve member and basic material under the action of bulky grain in basic material region
The surface stress for causing carbon-coating or support layer to loosen or fall off is not generated.
The advantageous expansion of the method for the present invention for manufacturing the valve member for being used for fuel injector is enumerated in the dependent claims
Exhibition scheme.
It is arranged in the preferred configuration of support layer, the hardness of support layer is more than the hardness of basic material.As a result, particularly well
And it is effectively protected basic material to avoid being plastically deformed caused by particle.
Especially such effect can be realized when the hardness of additionally support layer is less than the hardness of carbon-coating, that is, construct at least
Three firmness zones, their hardness are improved upwards in the side in the region for constituting valve seat:It is the region of basic material, the area first
Domain has minimum hardness.What is be connected with the region is the region of support layer, and the region of the support layer has than basic material
Material is big however the hardness smaller than carbon coating, is finally carbon coating, which is most suitable for occurring since hardness is maximum
Valve seat is avoided to deform when grain.
It has determined in test:Advantageously, the layer thickness of support layer is between 100 microns and 500 microns, preferably
Between 100 microns and 300 microns.As a result experiment certainly is for example achieved in:In the case of nitridation in connectionless layer,
Support layer has the layer thickness between 160 microns to 190 microns and the hardness between 1000HV and 1200HV.This support layer structure
It makes on the basic material being tempered of valve member being made of X40CrMoV5-1, wherein ground related with heat treatment method, basis
Material has the hardness of about 490HV.
It is hardened and is carried out on the above-mentioned basic material being made of X40CrMoV5-1 high by vacuum surface in support layer
In the case of pressing gas quenching to generate, the further experiment with certainty result is realized.Here, the layer thickness of support layer is about
It it is 200 microns, and the hardness of support layer is between 800HV and 900HV.
However, the present invention should not be limited to this vacuum surface method for curing or nitriding method of basic material.But one
As property this support layer can be generated by method of diffusion.
However, not only the nitridation of connectionless layer but also the vacuum surface hardening with high pressure quenching all provide it is special excellent
Point, i.e., introduce residual stress in the basic material region by near surface, and the carbon-coating and then applied is thus additionally protected to keep away
Exempt from harmful tensile stress.On the whole, by being diffused method to valve member basic material in valve seat area, can promote to improve
The marginal layer hardness of valve seat and to construct the present invention support layer.And then it is supported the carbon coating of layer, the carbon coating
Since its high rigidity can prevent particle from invading in surface.
The present invention also includes the fuel injector for having valve member, and the valve member is manufactured according to above-mentioned the method for the present invention.
Even if in the case where there are larger particles, this fuel injector especially from the aspect of service life on its valve seat have compared with
Therefore small abrasion simultaneously has small blow-by.
Description of the drawings
Further advantage, feature and the details of the present invention is by being described below and obtaining with reference to the accompanying drawings to preferred embodiment.
Attached drawing is shown:
The longitudinal section of the fuel injector of Fig. 1 self-igniting internal combustion engines and
Valve seat areas of the Fig. 2 in the fuel injector according to Fig. 1 on there is different size of particle valve member
Simplified illustration.
Similar elements or the identical element of function are provided with identical figure numbers in the accompanying drawings.
Specific implementation mode
Fuel injector 100 shown in FIG. 1 have elongated construction case of sprayer 101, as discharge or
The nozzle needle 102 of the closing injection component that unshowned injection is open in Fig. 1 can longitudinally be arranged in this up and down
In case of sprayer.The manipulation of nozzle needle 102 with it is known per se and therefore do not describe (because for the present invention nor weight
Want) mode carried out by magnetic actuator 105, which controls fuel from the discharge in control room 106, nozzle
Needle 102 is sunk to its end in the control room.The construction of control room 106, should in the valve member 108 substantially in sleeve shaped
Valve member is arranged in the stepped hole 109 in case of sprayer 101.Valve member 108 locally sinks to high pressure with its outer periphery
In chamber 110, which flows into take over 111 by fuel and is connect with unshowned high-voltage power supply (rail), wherein high-voltage power supply provides system
System pressure.It is disposed with the basic high-pressure channel 112 with circular cross section for this purpose, being flowed into take over 111 in fuel, the high pressure is logical
Road passes through the connecting hole 113 equally with circular and smaller than high-pressure channel 112 cross section on the side towards high pressure chest 110
It is connect with high pressure chest 110.
Valve member 108 has through hole 114 on the side towards magnetic actuator 105, and the through hole is to fuel injector 100
Area of low pressure direction be transitioned into conical valve seat 115.Valve seat 115 and the ball-shaped closure element 116 being for example made of hardened steel
Collective effect, the closure member can be manipulated by magnetic actuator 105 and be supported on valve seat 115 with position state shown in FIG. 1
On, to avoid fuel from being discharged in the area of low pressure of fuel injector 100 by through hole 114 from control room 106.
Section in the region of the strong valve seat 115 for simplifiedly showing valve member 108 in fig. 2.Valve member 108 is away from valve seat
115 side is made of the basic material 119 made of steel, especially X40CrMoV5-1.On the basic material 119 of valve member 108
It is applied with the support layer 120 of the present invention.The thickness d of support layer 120 be between 100 microns and 500 microns, preferably 100 microns
Between 300 microns.Support layer 120 is constructed by method of diffusion, wherein depending on manufacturing method, the hardness of support layer 120
For instance between 800HV and 1200HV.In contrast, the hardness for the basic material of valve member 108 hardened in advance is e.g., about
490HV。
Carbon-coating 130 is applied on support layer 120, the hardness of the carbon-coating is more than the hardness of support layer 120 again.Carbon-coating 130
E.g., about 2 microns of thickness D.
In addition, being shown in FIG. 2 in 115 region of valve seat in the case where there is particle 1a, 1b when for example in closure member
When part 116 is closed this support layer 120 of these particles when being entrapped between the closure member 116 of valve member 108 and valve seat 115 or
The performance of carbon-coating 130.Particle 1a has smaller particle size, and particle 1b has relatively large particle size.Especially may be used
See, particle 1a is only partly invaded in carbon-coating 130, and particle 1b makes the material of support layer 120 deform, and support layer exists
This is squeezed into the material of basic material 119.However, avoiding carbon-coating 130 from valve member by the in this regard described support layer 120
The material of 108 basic material 119 falls off.It is desirable that from the material of basic material 119, the hardness edge of the material of valve member 108
The direction of carbon-coating 130 persistently increases or is not especially suddenly to increase.
In this regard the fuel injector 100 or valve member 108 can be carried out modification or be changed in a manner of diversified
Become, without departing from the design of the present invention.The design is, is configured between the basic material and carbon-coating 130 of valve member 108 attached
The support layer 120 added, the support layer prevent carbon-coating 130 from falling off when acting in particle 1a, 1b.
Claims (10)
1. the method for manufacturing the valve member (108) for fuel injector (100), the injector is in the valve member (108)
It is upper with the region for constituting valve seat (115), wherein the valve member (108) is by preferably hardening or quenched steel is as basic material
(119) it forms, the surface of the basic material is coated with carbon-coating in the range of constituting the region of the valve seat (115)
(130), the carbon-coating has the hardness bigger than the material of the basic material (119),
It is characterized in that, being configured with support layer (120) between the basic material (119) and the carbon-coating (130), wherein
The hardness of the support layer (120) is at least big as the hardness of the basic material (119).
2. according to the method described in claim 1, it is characterized in that, the hardness of the support layer (120) is more than the basic material
Expect the hardness of (119).
3. method according to claim 1 or 2, which is characterized in that the hardness of the support layer (120) is less than the carbon-coating
(130) hardness.
4. according to the method in any one of claims 1 to 3, which is characterized in that the layer thickness of the support layer (120)
(d) it is between 100 microns and 500 microns, between preferably 100 microns and 300 microns.
5. method according to claim 1 to 4, which is characterized in that generate the support by method of diffusion
Layer (120).
6. according to the method described in claim 5, it is characterized in that, being hardened by vacuum surface and and then high pressure gas quenching
Or the support layer (120) is generated by the nitridation of the basic material (119) of the valve member (108).
7. method according to claim 5 or 6, which is characterized in that in the basic material (119) by the area of near surface
Residual stress is generated when generating the support layer (120) in domain.
8. method according to any one of claim 1 to 7, which is characterized in that at the thickness (D) of the carbon-coating (130)
Between 1 micron and 3 microns, preferably about 2 microns.
9. method according to any one of claim 1 to 8, which is characterized in that use described in the conduct of X40CrMoV5-1 steel
The basic material of valve member (108).
10. fuel injector (100) has the valve member (108) manufactured according to any one of claim 1 to 9.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102015219353.5A DE102015219353A1 (en) | 2015-10-07 | 2015-10-07 | A method of manufacturing a valve piece for a fuel injector and fuel injector |
DE102015219353.5 | 2015-10-07 | ||
PCT/EP2016/069050 WO2017059990A1 (en) | 2015-10-07 | 2016-08-10 | Method for producing a valve piece for a fuel injector, and fuel injector |
Publications (1)
Publication Number | Publication Date |
---|---|
CN108368813A true CN108368813A (en) | 2018-08-03 |
Family
ID=56979509
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201680071613.1A Pending CN108368813A (en) | 2015-10-07 | 2016-08-10 | Method and fuel injector for manufacturing the valve member for being used for fuel injector |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP3359804A1 (en) |
KR (1) | KR20180059929A (en) |
CN (1) | CN108368813A (en) |
DE (1) | DE102015219353A1 (en) |
WO (1) | WO2017059990A1 (en) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001061182A1 (en) * | 2000-02-15 | 2001-08-23 | Caterpillar Inc. | Thin film coatings for fuel injector components |
EP1310577A1 (en) * | 2001-11-12 | 2003-05-14 | Hitachi, Ltd. | Fuel pump and direct fuel injection engine |
DE102008009030A1 (en) * | 2008-02-14 | 2009-09-03 | Continental Automotive Gmbh | Valve needle for a valve of combustion chambers of internal-combustion engines, comprises seat area with a layer sequence of a first adhesive layer, a first wear-protection layer, a second adhesive layer and a second wear-protection layer |
CN101821425A (en) * | 2007-09-28 | 2010-09-01 | 卡特彼勒公司 | The method of coating fuel system components |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6715693B1 (en) * | 2000-02-15 | 2004-04-06 | Caterpillar Inc | Thin film coating for fuel injector components |
DE102007047074A1 (en) * | 2007-10-01 | 2009-04-02 | Robert Bosch Gmbh | Method of carburizing workpieces and use |
US20100304107A1 (en) * | 2009-05-27 | 2010-12-02 | United Technologies Corporation | Layered coating for erosion protection |
DE102013225387A1 (en) | 2013-12-10 | 2015-06-11 | Robert Bosch Gmbh | Connecting portion between a high pressure passage and a high pressure chamber and fuel injection component with a connection portion |
-
2015
- 2015-10-07 DE DE102015219353.5A patent/DE102015219353A1/en not_active Withdrawn
-
2016
- 2016-08-10 KR KR1020187012583A patent/KR20180059929A/en unknown
- 2016-08-10 EP EP16769867.9A patent/EP3359804A1/en not_active Withdrawn
- 2016-08-10 WO PCT/EP2016/069050 patent/WO2017059990A1/en active Application Filing
- 2016-08-10 CN CN201680071613.1A patent/CN108368813A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001061182A1 (en) * | 2000-02-15 | 2001-08-23 | Caterpillar Inc. | Thin film coatings for fuel injector components |
EP1310577A1 (en) * | 2001-11-12 | 2003-05-14 | Hitachi, Ltd. | Fuel pump and direct fuel injection engine |
CN101821425A (en) * | 2007-09-28 | 2010-09-01 | 卡特彼勒公司 | The method of coating fuel system components |
DE102008009030A1 (en) * | 2008-02-14 | 2009-09-03 | Continental Automotive Gmbh | Valve needle for a valve of combustion chambers of internal-combustion engines, comprises seat area with a layer sequence of a first adhesive layer, a first wear-protection layer, a second adhesive layer and a second wear-protection layer |
Also Published As
Publication number | Publication date |
---|---|
WO2017059990A1 (en) | 2017-04-13 |
EP3359804A1 (en) | 2018-08-15 |
DE102015219353A1 (en) | 2017-04-13 |
KR20180059929A (en) | 2018-06-05 |
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PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
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WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180803 |