CN108354850A - A kind of makeup remover and preparation method thereof - Google Patents

Abstract

The invention discloses a kind of makeup removers, by weight, including following component：50 80 parts of grease；10 35 parts of nonionic surfactant；5 10 parts of silylated silica；15 parts of water；0.1 4 parts of skin conditioning agent；Anti-oxidant 0.01 0.5 parts；0.01 0.2 parts of plant extraction liquid.The present invention is added to by the silylated silica of certain content in the nonionic surfactant of certain content and the grease of certain content, and it is aided with water, antioxidant, skin conditioning agent, the plant extraction liquid of certain content, pass through the coordinated of each component, the makeup remover being prepared has good makeup removing effect, the light removal heavy make-up of energy, and skin allergy and stimulation will not be caused, it is easy to use；Preparation method is easily achieved, can be with scale volume production.

Description

A kind of makeup remover and preparation method thereof

Technical field

The present invention relates to daily cosmetics technical field, more particularly to a kind of makeup remover and preparation method thereof.

Background technology

Makeup has been an essential part in the modern life, the important ring removed ornaments and formal dress as cleaning skin after makeup Section, also increasingly by the extensive concern of consumer.Consumer does not require nothing more than outstanding makeup removing effect, while pursuing outside product See beautiful, easy to use, safe and non-stimulating, makeup removing while the mood for bringing light pleasure.

Makeup remover can dissolve rapidly various color make-up greasy dirts, then by makeup remover by the makeup removing principle of " with the molten oil of oil " Oil-water emulsifiers, meet water massage can spontaneous emulsification poling oil-in-water emulsion soluble easily in water, as clear water takes away skin together Dirt on skin reaches makeup removing and clean effect, and makeup remover currently on the market is all the strong fluid oil of mobility, when use It is easy drippage, cause to stain clothes and causes to be lost.For ease of use, certain viscosity need to be increased, if using general Polymer-thickened, product transparency and stability can be affected, and therefore, research and develop a kind of collection and remove ornaments and formal dress, is transparent and have certain viscosity Makeup remover, be related field technical problem urgently to be resolved hurrily.

Invention content

Appearance is clear, makeup remover with certain viscosity the present invention is directed to providing, and is a kind of easy to use, mild and remove ornaments and formal dress The strong makeup removal products of ability.

Makeup remover of the present invention, by weight, including following component：

50-80 parts of grease；

10-35 parts of nonionic surfactant；

Silylated silica 5-10 parts；

1-5 parts of water；

0.1-4 parts of skin conditioning agent；

It is 0.01-0.5 parts anti-oxidant；

0.01-0.2 parts of plant extraction liquid.

Preferably, the makeup remover, by weight, including following component：

55-75 parts of grease；

20-30 parts of nonionic surfactant；

Silylated silica 5.5-8.5 parts；

2-4 parts of water；

0.1-2.5 parts of skin conditioning agent；

It is 0.1-0.3 parts anti-oxidant；

0.01-0.2 parts of plant extraction liquid.

Wherein, the grease is oil-soluble grease, selected from hydro carbons, fatty alcohol, aliphatic acid, aliphatic ester, glyceride type, silicon One or more of oil, silicon wax；Preferably cetostearyl alcohol ethylhexoate, rice chaff oil, caprylic/capric triglyceride, angle Shepherd's purse is saved at shark alkane, octyl dodecanol, seed oil of Moringa oleigera, deep-sea two（CRAMBE ABYSSINICA）Seed oil, wineberry（VACCINIUM MYRTILLUS）One or more of seed oil.

Wherein, it is different hard to be selected from PEG-20 iso stearic acid of glycerine ester, PEG-20 glycerine three for the nonionic surfactant Resin acid ester, PEG-12 diisopstearates, the smooth isostearate of sorb, polysorbate -85, four oleic acid of sorbeth -30 One kind in ester, four oleate of sorbeth -60, -2 diisopstearate of polyglycereol, PEG-8 iso stearic acid of glycerine ester Or it is several；The preferably smooth isostearate of PEG-20 iso stearic acid of glycerine ester, PEG-20 glyceryl triisostearates, sorb three The compounding of person, and the weight compounding of three is than being 16-18：5-9：1-5.

Wherein, the antioxidant is in butylated hydroxytoluene, tert-butyl hydroquinone, vitamin E, tocopherol acetate One or more, preferably tocopherol acetate；The skin conditioning agent is selected from glycerine, propylene glycol, butanediol, pentanediol, different One or more of pentanediol.

Wherein, the plant extraction liquid is selected from marrubium（MARRUBIUM VULGARE）Extract, citrus（CITRUS RETICULATA）Pericarp extract, Thymus serpyllum（THYMUS SERPILLUM）Extract, purslane（PORTULACA OLERACEA）Extract, ginkgo (GINKGO BILOBA) leaf extract, tea (CAMELLIA SINENSIS) leaf extract, dog Tooth rose (ROSA CANINA) berry extract, hamamelis（HAMAMELIS VIRGINIANA）Extract, centella （CENTELLA ASIATICA）Extract, glycyrrhiza glabra（GLYCYRRHIZA GLABRA）Root extract, Cnidium officinale Makino （CNIDIUM OFFICINALE）Root extract, Japanese elm（ULMUS DAVIDIANA）Root extract, white willow（SALIX ALBA）Tree Bark extract, cork tree（PHELLODENDRON AMURENSE）Bark extract, aloe barbadensis Miller（ALOE BARBADENSIS） Leaf extract, fragrant citrus（CITRUS JUNOS）Berry extract, ginger（ZINGIBER OFFICINALE）Root extract, bladder-wrack （FUCUS VESICULOSUS）Extract, lichee（LITCHI CHINENSIS）Pericarp extract, rice（ORYZA SATIVA）Embryo Bud extract, Mi Luomu（MYROTHAMNUS FLABELLIFOLIA）Leaf/stem extraction, hydrolysis monkey-bread tree（ADANSONIA DIGITATA）Extract, Wild soybean（GLYCINE SOJA）Seed extract, Tokyo oriental cherry（PRUNUS YEDOENSIS）Leaf extracts Object, purple perilla（PERILLA OCYMOIDES）Leaf extract, grape（VITIS VINIFERA）Seed extract, edelweiss （LEONTOPODIUM ALPINUM）Extract, wing seed Moringa（MORINGA PTERYGOSPERMA）Seed extract, sweet almond （PRUNUS AMYGDALUS DULCIS）One or more of seed extract.

The invention also discloses the preparation methods of above-mentioned makeup remover, include the following steps：

（1）Grease, nonionic surfactant are weighed according to proportioning, mixing is heated to 70-75 DEG C, and first is added at a slow speed in stirring Silylation silica, low speed homogeneous 3-5 minutes is to being completely dispersed uniformly；

（2）Stirring is cooled to 45-40 DEG C, and water, antioxidant, skin conditioning agent, the plant extraction liquid weighed according to proportioning is added, To homogeneous transparent, discharging is filling to get makeup remover within 5-10 minutes for stirring.

Compared with prior art, the present invention has following excellent effect：

The present invention is added to the nonionic surfactant of certain content and specific by the silylated silica of certain content In the grease of content, and it is aided with water, antioxidant, skin conditioning agent, the plant extraction liquid of certain content, passes through the association of each component With cooperation, the makeup remover being prepared has good makeup removing effect, can light removal heavy make-up, and will not cause skin allergy and Stimulation, it is easy to use；Preparation method is easily achieved, can be with scale volume production.

Specific implementation mode

It is further illustrated the present invention below by specific implementation mode, following embodiment is the preferable embodiment party of the present invention Formula, but embodiments of the present invention are not limited by following embodiments.

The raw material such as table 1 that the embodiment of the present invention and comparative example use, but it is not limited only to these raw materials：

Table 1

Embodiment 1-9 and comparative example 1-6：The preparation of makeup remover

Grease, nonionic surfactant are weighed according to the proportioning of table 2, mixing is heated to 70-75 DEG C, and stirring is added at a slow speed Silylated silica, low speed homogeneous 3-5 minutes is to being completely dispersed uniformly；Stirring is cooled to 45-40 DEG C, and addition is weighed according to table 2 Water, antioxidant, skin conditioning agent, plant extraction liquid, stirring discharges filling to get makeup remover to homogeneous transparent for 5-10 minute.

The each group distribution ratio of table 2 embodiment 1-9 and comparative example 1-6（Parts by weight）

Continued 2

Appearance transparence stability test, viscosity test, preservation challenge are carried out to the makeup remover of embodiment 1-9 and comparative example 1-6 Test, sensitive skin test：

One, appearance transparence stability test and viscosity test are done to the makeup remover of embodiment 1-9 and comparative example 1-6：

1）Appearance transparence stability test method：To the makeup remover of embodiment 1-9 and comparative example 1-6, it is placed in 40 DEG C and stores 1 The moon, 25 DEG C of room temperature store 1 month, the storage 1 month of 4 DEG C of low temperature, restore to room temperature to observe appearance transparence, test result such as table Shown in 2.

2）Viscosity determining procedure：To the makeup remover of embodiment 1-9 and comparative example 1-6, it is placed in 25 DEG C of room temperature 24 hours, into Row viscosity test：

Use instrument：NDJ-1 type viscosimeters

Test condition：It is read and is stablized after starting 1 minute using regulation by viscosimeter in the rotating speed of 20rpm using No. 3 rotors Viscosity data, test result is as shown in table 2.Two, preservation challenge test is done to the makeup remover of embodiment 1-9 and comparative example 1-6： The requirements of USP 32 are satisfied by, product has good anti-corrosion effect.

Three, sensitive skin is done to the makeup remover of embodiment 1-9 and comparative example 1-6 to test：

1）Test method and number：Cutaneous safety assessment is carried out using the test method of normal individual trial, tests 40 people of number.Its Septum reset sensitivity skin quality people is more than 30 people.

2）Subject selects：Healthy women subject of the age at 18-35 Sui；

3）Product application method and pot life：According to product operation instruction, the dry hand of this product, wet hand all can be used, dry hand shape It is better under state.

Take appropriate makeup remover in the centre of the palm；

Makeup remover is uniformly applied to face etc. and needs position of removing ornaments and formal dress, is softly massaged with finger pulp about 60 seconds, makeup remover is made fully to dissolve Color make-up；

Both hands are bedewed with clear water, continue massage about 30 seconds, until makeup remover emulsification completely is milky emulsion；

It is rinsed well again with a large amount of clear water；

It with cotton pads Qing Shigan faces moisture, and checks color make-up dirt whether removal is clean, be not necessarily to secondary cleaning.

4）Observing time：

It observes 4 weeks altogether.Subject is before being included in research（0th day）, the 14th day and face the 7th day after Clinical practice, after Clinical practice The 28th day after bed use, 4 follow-ups are carried out altogether.

5）Sensibility skin quality selection criteria

Subjective assessment：Head examines day doctor to subject's recipient site to weather（It is cold and dry）, skin care product, detergent, The sensibility of textile and abrasive articles scores respectively：

0 point is insensitive；1 point is sometimes sensitive；2 points are sensitivity；

5 item ratings are added, it is sensitive that total score, which is more than 4 points of persons,.

Such as：Patient's A readmes are insensitive to weather（0 point）, it is sometimes sensitive to skin care product（1 point）, it is quick to detergent Sense（2 points）, it is sometimes sensitive to textile（1 point）, it is sometimes sensitive to abrasive articles（1 point）；Five additions：0+1+2+1+1=5 point, Therefore, it is determined that being sensitive.

Lactic acid irritant test：

Selection semar technique is tested, and 10% lactic acid is applied to nasolabial groove and any one side face cheek at room temperature, respectively 2.5 And 5 minutes sensitivity responses to subject carry out 4 grades of evaluations, then will score addition twice, and it is sensibility skin that score value, which is more than 3, Skin.

0 point is no shouting pain；1 point is slight shouting pain；2 points are moderate shouting pain；3 points are severe shouting pain

Subjective assessment is more than 4 points or lactic acid irritant test is positive, all can determine that as sensitive.

6）Safety evaluation：

Test products are observed to human skin safety, especially to face skin sensitive subjects by normal individual trial experiment.By When examination person pays a return visit, any adverse events that subject is occurred during using trial target are carefully inquired, check and record, including The performances of adverse events, time of origin, treatment measures and lapse to, and to adverse events with made and sentencing using the relationship of product It is disconnected.

Adverse events severity is judged by following grade III Standard：

Slightly-subject can endure, and be not required to especially handle, do not influence the normal life of subject；

Moderate-subject is difficult to endure, and needs to deactivate product or does specially treated, influences the normal life of subject；

Severe-obstruction normal life need to deactivate product immediately or do emergent management.

Skin adverse reaction is classified the versions in 2015 issued according to the Ministry of Public Health《Cosmetics safety technical specification》Specified in Normal individual trial tests skin adverse reaction grade scale to judge：

0 grade（Dermoanergy）；

1 grade（There is faint erythema in skin）；

2 grades（There is erythema, infiltration and papule in skin）；

3 grades（There is erythema, oedema, papule and blister in skin）；

4 grades（There is erythema, oedema and bleb in skin）

The interpretation standard of adverse events and test products relationship：

A is certainly reasonable using test products and reaction generation event sequence, stops using test products reaction to stop, or subtract rapidly Light or improvement reuses test products reaction and reproduces, while documents and materials are proved, and has removed the influence of other Confounding Factors；

B is reasonable most likely with test products and reacting generating time sequence, stops using test products reaction to stop, or rapid Mitigate or improve, other factors influence can be excluded substantially；

C may use test products and reacting generating time in close relations, but cause the product more than one of adverse reaction, or have Other factors can not be excluded；

D unrelated may be occurred using test products and adverse reaction, far, reaction performance and the known makeup of time The adverse reaction of product is misfitted；

E data to be evaluated is not complete, is revalued after waiting for updates or causality is difficult to come to a conclusion, and lacks documents and materials evidence；

F can not evaluate that lacuna is too many, and causality is difficult to come to a conclusion, and data can not supplement.

7）Test result：

Subject's ordinary circumstance：The age of selected subject between 22 years old to 34 years old, is selected in 40 subjects, wherein women altogether 40 people, 0 people of male, average age 25.78 years old, complete cost study.In selected subject, it is sensibility skin to have 30 people, Wherein 3 persons of dividing of lactic acid irritant test score value ＞ are 30 people, and 11 people someone have using cosmetic allergic contact dermatitis history, and 10 people produce daily washing Product are sensitive, and 6 people are sensitive to climate change or solarization, and 5 people are to containing wool, and cotton, the clothings such as terylene are sensitive, and 3 people are quick to abrasive articles Sense, 0 people are sensitive to metal objects.

Safety evaluation：40 subjects（Wherein sensitive 30 people of skin person）Normal individual trial experimental study in 4 weeks, without it is any not Good reaction has preferable safety, even if also showing that preferable safety to the people of sensitive skin, is suitable for sensitive flesh Skin.

Claims (7)

1. a kind of makeup remover, which is characterized in that by weight, including following component：

50-80 parts of grease；

10-35 parts of nonionic surfactant；

Silylated silica 5-10 parts；

1-5 parts of water；

0.1-4 parts of skin conditioning agent；

It is 0.01-0.5 parts anti-oxidant；

0.01-0.2 parts of plant extraction liquid.

2. makeup remover according to claim 1, which is characterized in that the makeup remover, by weight, including such as the following group Point：

55-75 parts of grease；

20-30 parts of nonionic surfactant；

Silylated silica 5.5-8.5 parts；

2-4 parts of water；

0.1-2.5 parts of skin conditioning agent；

It is 0.1-0.3 parts anti-oxidant；

0.01-0.2 parts of plant extraction liquid.

3. according to claim 1-3 any one of them makeup removers, which is characterized in that the grease is oil-soluble grease, is selected from One or more of hydro carbons, fatty alcohol, aliphatic acid, aliphatic ester, glyceride type, silicone oil, silicon wax；Preferably cetostearyl alcohol Shepherd's purse is saved at ethylhexoate, rice chaff oil, caprylic/capric triglyceride, saualane, octyl dodecanol, seed oil of Moringa oleigera, deep-sea two （CRAMBE ABYSSINICA）Seed oil, wineberry（VACCINIUM MYRTILLUS）One or more of seed oil.

4. according to claim 1-3 any one of them makeup removers, which is characterized in that the nonionic surfactant is selected from The smooth different tristearin of PEG-20 iso stearic acid of glycerine ester, PEG-20 glyceryl triisostearates, PEG-12 diisopstearates, sorb Acid esters, polysorbate -85, four oleate of sorbeth -30, four oleate of sorbeth -60, polyglycereol -2 two One or more of isostearate, PEG-8 iso stearic acid of glycerine ester；Preferably PEG-20 iso stearic acid of glycerine ester, The compounding of the smooth isostearate three of PEG-20 glyceryl triisostearates, sorb, and the weight compounding of three is than being 16-18： 5-9：1-5.

5. according to claim 1-3 any one of them makeup removers, which is characterized in that the antioxidant is selected from butylhydroxy first One or more of benzene, tert-butyl hydroquinone, vitamin E, tocopherol acetate, preferably tocopherol acetate；The skin Conditioner is selected from one or more of glycerine, propylene glycol, butanediol, pentanediol, isoprene.

6. according to claim 1-3 any one of them makeup removers, which is characterized in that the plant extraction liquid is selected from marrubium （MARRUBIUM VULGARE）Extract, citrus（CITRUS RETICULATA）Pericarp extract, Thymus serpyllum（THYMUS SERPILLUM）Extract, purslane（PORTULACA OLERACEA）Extract, the extraction of ginkgo (GINKGO BILOBA) leaf Object, tea (CAMELLIA SINENSIS) leaf extract, dog rose (ROSA CANINA) berry extract, hamamelis （HAMAMELIS VIRGINIANA）Extract, centella（CENTELLA ASIATICA）Extract, glycyrrhiza glabra （GLYCYRRHIZA GLABRA）Root extract, Cnidium officinale Makino（CNIDIUM OFFICINALE）Root extract, Japanese elm（ULMUS DAVIDIANA）Root extract, white willow（SALIX ALBA）Bark extract, cork tree（PHELLODENDRON AMURENSE）Tree Bark extract, aloe barbadensis Miller（ALOE BARBADENSIS）Leaf extract, fragrant citrus（CITRUS JUNOS）Berry extract, ginger （ZINGIBER OFFICINALE）Root extract, bladder-wrack（FUCUS VESICULOSUS）Extract, lichee（LITCHI CHINENSIS）Pericarp extract, rice（ORYZA SATIVA）Germ extracts, Mi Luomu（MYROTHAMNUS FLABELLIFOLIA）Leaf/stem extraction, hydrolysis monkey-bread tree（ADANSONIA DIGITATA）Extract, Wild soybean （GLYCINE SOJA）Seed extract, Tokyo oriental cherry（PRUNUS YEDOENSIS）Leaf extract, purple perilla（PERILLA OCYMOIDES）Leaf extract, grape（VITIS VINIFERA）Seed extract, edelweiss（LEONTOPODIUM ALPINUM）Extract, wing seed Moringa（MORINGA PTERYGOSPERMA）Seed extract, sweet almond（PRUNUS AMYGDALUS DULCIS）One or more of seed extract.

7. a kind of preparation method of makeup remover as claimed in any one of claims 1 to 6, which is characterized in that include the following steps：

（1）Grease, nonionic surfactant are weighed according to proportioning, mixing is heated to 70-75 DEG C, and first is added at a slow speed in stirring Silylation silica, low speed homogeneous 3-5 minutes is to being completely dispersed uniformly；

（2）Stirring is cooled to 45-40 DEG C, and water, antioxidant, skin conditioning agent, the plant extraction liquid weighed according to proportioning is added, To homogeneous transparent, discharging is filling to get makeup remover within 5-10 minutes for stirring.