CN108342901A - A kind of Antistatic Fabric - Google Patents
A kind of Antistatic Fabric Download PDFInfo
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- CN108342901A CN108342901A CN201710048717.7A CN201710048717A CN108342901A CN 108342901 A CN108342901 A CN 108342901A CN 201710048717 A CN201710048717 A CN 201710048717A CN 108342901 A CN108342901 A CN 108342901A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
- D06M2101/28—Acrylonitrile; Methacrylonitrile
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/38—Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of Antistatic Fabrics.The fiber surface of the fabric is covered with epithelium resin layer, and at least contains alkyl quaternaries compound in epithelium resin layer.Production method of the present invention is simple, of low cost, on the basis of ensuring antistatic property, while imparting the excellent water imbibition of fabric, soft, can be used for making underwear etc..
Description
Technical field
The invention belongs to textile fields, are related to a kind of Antistatic Fabric, and in particular to one kind can be used for underwear and simultaneously
Fabric with antistatic, water suction and soft feel.
Background technology
Continuous improvement with the change and people of people life style to health status attention rate, underwear fabric is in addition to flower
Color and style will meet outside customer demand, and snugness of fit and functional requirement are also being continuously improved.Currently, in the market
Simultaneously have it is antistatic, water suction and soft feel chemical fiber plus material substantially without.
In daily life, electrostatic hazard is very important, is not only brought a lot of discomfort to people's life, but also to work
Industry produces very harmful, it is therefore necessary to which attention overcomes.Anti-static precautions, from principle for, generally comprise minimizing electrostatic amount
With the mode for leading electrostatic.It is specific as follows, when to fabric carry out antistatic finish, including wash most method, one-bath dyeing method and after
Arrange padding method；Second is that by the high fiber of conductive fiber or hydroscopicity, the fabric that use is blended, intertexture or other methods mix, again
Or antistatic agent is added in spinning solution when spinning, to reach antistatic property.
For example, disclosing a kind of antistatic textile and its manufacturing method in patent document CN101492885A.The weaving
The quality of polyamide component is 20% or more of gross mass in product fiber, and epithelium resin composition of layer is polyether polyurethane, acrylic acid
One or more of Arrcostab, alkyl alkylacrylate, siloxanes quaternary amine, obtain preferable antistatic property.Its
Middle polyether polyurethane, alkyl acrylate, alkyl alkylacrylate are polymer electrolyte, of high cost, dosage is big, and are needed
Coordinate compatilizer and processing conditions appropriate that can reach ideal effect, especially with the compatibility of other resins also compared with
Difference；And siloxanes quaternary amine, although feel can be improved to a certain extent, since silicon atom in siloxanes and oxygen atom are handed over
For composition, the methyl on silicon atom can be rotated around silica chain, be vibrated, and three hydrogen atoms on each methyl are just as distracted
Gamp causes oxygen atom and is covered by methyl, cannot be close with the hydrogen atom of hydrone, hydrophobicity is brought, for polyamide
For hydrophobic synthetic fibre in addition, the effect that antistatic property improves and water imbibition improves is very little.
For another example, a kind of durable antistatic textile is disclosed in patent document CN104514153A, by by synthesizing fibre
The textile that peacekeeping cellulose fibre is formed reacts the nano involucra to form specific thicknesses using azo-initiator, anti-improving
While electrostatic washing resistance, the problems such as finished color caused by conventional peroxide initiator changes is solved, but due to skin
The main component of film layer be polyurethanes, aziridines, isocyanates or melamine class compound in it is one or more,
The problem of high cost and with other resin compatibles difference that front is said is equally existed, and azo-initiator easy tos produce
A large amount of bubble can leave medicament spot in textile surface, influence the quality of finished product；In addition, control leather film thickness can only be kept
The original feel of fabric can not improve the flexibility of textile, and the water suction sex chromosome mosaicism of textile is not also resolved.
Invention content
The purpose of the present invention is to provide a kind of of low cost, best in quality, and have simultaneously water imbibition, flexibility it is anti-
Electrostatic fabric.
To achieve the goals above, technical solution of the invention is as follows：
The Antistatic Fabric of the present invention, including synthetic fibers, the single fiber surface of wherein at least synthetic fibers is covered with epithelium tree
Lipid layer, and at least contain alkyl quaternaries compound in epithelium resin layer, structural formula is as follows：
,
Wherein, R, R1、R2、R3In at least one be with-OH ,-NH2, in-COOH one or several kinds of groups alkyl.
The Antistatic Fabric of the present invention has superior washing resistance, while having good water imbibition, soft
Etc. characteristics, can be used for underwear etc..The present invention is suitable for the antistatic processing of a variety of synthetic fibers class fabrics, and processing method is simply easy
Row.
Specific implementation mode
It is well known that the type of antistatic agent is divided into cationic, anionic, nonionic, amphoteric and macromolecule
Five major class of type.（1）Cationic antistatic agent：Antistatic property is excellent, while having prodigious suction to negatively charged fiber
Attached power can assign fabric good washing resistance.Even if concentration is very dilute, its good antistatic effect also can be fully played
Fruit.（2）Anionic antistatic agent：It is mainly used for the static elimination of synthetic fiber oiling agent, it is poor with the compatibility of resin, and
It is very poor to the adsorptivity of negatively charged fiber, influence whether washing resistance.（3）Non-ionic antistatic agent：Due to cannot picture
Ionic anti-static agent can carry out conductive leak charge using the ion of itself like that, in order to obtain same antistatic effect
Fruit, dosage are big, of high cost.（4）Amphoteric antistatic agent：It is mainly used for plastics and fibrous inside antistatic agent, and on the high side.
（5）Polymer Antistatic Agent：Although having good washing resistance, in contrast dosage is big, of high cost, needs to coordinate
Compatilizer and processing conditions appropriate can be only achieved ideal effect；And it is poor with the compatibility of other resins, it is difficult to and other
Functional medicine be used together.
Contain synthetic fibers in the fabric of the present invention, and in the epithelium resin layer of the single fiber surface covering of synthetic fibers,
At least contain alkyl quaternaries compound, structural formula is as follows：
,
Wherein, R, R1、R2、R3In at least one be with-OH ,-NH2, in-COOH one or several kinds of groups alkyl.
The alkyl quaternary ammonium salt compound of the present invention not but not hinders fabric due to carrying hydrophilic radical in alkyl
Water imbibition, and with the increase of hydrophilic radical, the water imbibition of fabric can also become better and better.
In the present invention, synthetic fibers are preferably conventional polyester fiber（Common PET）, cationic dyeable polyester fiber（CDP）、
Polyacrylonitrile fibre（Acrylic fibers, Ac）One or more of, content is preferably 60 weight % or more；It is fine relative to other synthesis
Dimension, such as Fypro, common PET, CDP and acrylic fibers are in heat insulating ability, light weight, in price slightly advantage, therefore conduct
It is preferred that.Taking cost into account, synthetic fibers content is higher, relative to other as the content of cellulose fibre is lower, cost
Lower, the content of above-mentioned fiber is preferably 60 weight % or more in the present invention.
In the present invention, the filament denier of common PET and CDP are preferably 0.5~3.0dtex.Filament denier is more than
When 3.0dtex, feel have the tendency that it is partially hard, it is difficult to be improved to super softness；When filament denier is less than 0.5dtex, spinning can
It can be relatively difficult.
In the present invention, the preferred CDP of preceding note synthetic fibers and acrylic fibers, this is mainly in view of they have good dyeability
Can, but also can with the natural fibers co-bathing dyeing such as wool, convenient for simplifying the dyeing of blended fabric.
In the present invention, when using above-mentioned synthetic fibers and other fiber blends or interweaving, other fibers can be cotton,
One or more of natural fibers such as fiber crops, wool；Viscose rayon（R）, one or more of regenerated fibers such as acetate fiber；
Spandex（PU）Deng.
In the present invention, the film thickness of epithelium resin layer is preferably 5~600nm.It is washable when epithelium resin layer thickness is less than 5nm
Washing frictional property has the tendency that variation, i.e. anti-static properties durability are poor；And thickness is when being more than 600nm, cost have it is increased become
Gesture, and feel is possible to be deteriorated.
After the fabric of the present invention washs 5 times, it is measured according to 1094 B methods of JIS L it is charged by friction and be pressed in 2500V or less.
Washing standard is according to 0217 No. 103 methods of home washings JIS L, it is contemplated that the flower Wang Jie used in the standard seizes by force beautiful white washing powder
Test to being charged by friction pressure has an impact, and the present invention is washed using lion king and uses synthetic detergent powder.
The fabric of the present invention is surveyed after being washed 10 times according to 0217 No. 103 methods of JIS L further according to 1097 dropping methods of JIS L
Its absorbent time is obtained at 1 second or less.After perspiring, fabric of the invention can promptly absorb sweat, and it is glutinous to reduce skin
Feeling, improve comfort；Quaternary ammonium salts antistatic agent belongs to surfactant-based antistatic agent again simultaneously, can reduce face
The friction coefficient of material can make web surface have smooth and soft feeling, further improve snugness of fit and feel, special
It Shi Heyongyu not the purposes such as underwear.
In the present invention, to fabric or knitted fabric, using the working fluid containing alkyl quaternary ammonium salts antistatic agent into
Antistatic Fabric is obtained after row processing, drying.In order to assign fabric more superior functionality, its added value is improved, rear
In the working fluid for arranging processing, other functional auxiliary agents, including the water suction of inorganic antiseptic, polyester polyethers can also be contained
One or more of agent, modified organic silicon softening agent, cationic fixing agent.The dosage of alkyl quaternary ammonium salts antistatic agent 3~
Between 6%owf.Using hot water treatment, temperature is 60~80 DEG C, and processing time is 15~30min.
In alkyl quaternary ammonium salts antistatic agent used in the present invention, the molecular weight of alkyl is relatively large, preferably 280 or more.This
Mainly in view of low molecular weight antistatic agent is easy to migrate to fibrous inside, and surface concentration is made to decline, destroys surface
It is continuously distributed, after processed goods is long placed in, trend that antistatic effect is decreased significantly.
In alkyl quaternary ammonium salts antistatic agent used in the present invention, contain hydrophilic radical on alkyl, hydrophilic radical and water can be with
Hydrogenbond is formed, and in this, as polar centers, is further combined with water, continuous water phase is formed, further improves anti-
Static behaviour.
The measuring and calculation method of each parameter according to the present invention is as follows.
（1）It is charged by friction pressure
With reference to JIS L 1094-1997 standards.
（2）It is charged by friction pressure washing method
With reference to 0217 103-2010 standards of JIS L, lion king washs with synthetic detergent powder, washing 5 times.
（3）Water imbibition
With reference to JIS L 1097-2010 dropping method standards.
（4）Water imbibition washing method
With reference to 0217 103-2010 standards of JIS L, flower Wang Jie seizes by force beautiful white washing powder, washs 10 times.
（5）Feel
It is evaluated by 4 grades about feels such as fabric soft feelings.◎：It is very soft, zero：Softness, △：It is not soft, ×：A little
It is coarse（10 people evaluate, with the most grade of number for final grade）.
Medicament used is as follows in following embodiment and comparative example：
Antistatic agent A：Alkyl quaternaries（Nantong Dong Rou Trade Co., Ltd.s, DR-SN4；Molecular weight 438, have amide groups and
Hydroxyl）
Antistatic agent B：Alkyl quaternaries（Guangzhou Zhuan Jie Chemical Co., Ltd.s, GK-23；Molecular weight 292.5 has hydroxyl）
Antistatic agent C：Esters of acrylic acid（Japanese Song Ben Pharmaceutical Co., Ltd, AS-10）
Antistatic agent D:Siloxanes quaternary ammonium salts（Chang Lai Ou Ji coloured chemicals Co., Ltd, AEM5700）
Polyester polyethers water absorbing agent：（Nantong Dong Rou Trade Co., Ltd.s, DR-405）
Inorganic antiseptic：（Japanese chemistry research and development Co., Ltd, ZP-700）
Modified organic silicon softening agent：（Japanese chemistry research and development Co., Ltd, AQ-1538）
Cationic fixing agent：（Japanese chemistry research and development Co., Ltd, RX-202）.
Embodiment 1
Circle volume machine on, using 84dtex-72f-CDP DTY, 40 viscose glue/Nitrilon cospinning yarns and 22dtex naked spandex yarns with
45：50：5 ratio latitude plain stitch carries out weaving obtained fabric, then by fabric processing before 90 DEG C of * 10min are carried out, then
Using the dye of positive ion to CDP and acrylic fibres dyeing under the conditions of 115 DEG C of * 30min, then work is used under the conditions of 60 DEG C of * 60min
Property dyestuff viscose rayon is dyed, obtain grammes per square metre be 150g/ ㎡ knitted fabric.
By the knitted fabric after above-mentioned dyeing in 70 DEG C of * 20min, bath raio 1：Antistatic treatment is carried out under conditions of 20, it is dry
After obtain Antistatic Fabric.
Antistatic agent A 4%.owf
Then the fabric after antistatic processing is put into the working fluid formed as follows and uses an immersing and rolling, pick-up rate 70%-80%
The mode of padding handled, and it is dry under the conditions of 130 DEG C of * 2min after obtain the fabric of the present invention, design parameter is shown in Table 1.
Polyester polyethers water absorbing agent 10g/L
Inorganic antiseptic 1.25g/L
Retrofit silicone softening agent 10g/L
Cationic fixing agent 20g/L
Remaining is soft water.
Embodiment 2
The usage amount of antistatic agent A is adjusted to 6%.owf, remaining obtains the fabric of the present invention with embodiment 1, and design parameter is shown in
Table 1.
Embodiment 3
Without padding processing, remaining obtains the fabric of the present invention with embodiment 1, and design parameter is shown in Table 1.
Embodiment 4
The usage amount of antistatic agent A is adjusted to 3%.owf, remaining obtains the fabric of the present invention with embodiment 3, and design parameter is shown in
Table 1.
Embodiment 5
On circle volume machine, using 84dtex-72f-CDP DTY, 40 cotton yarns and 22dtex naked spandex yarns with 30：65：5 ratio
Example latitude plain stitch carries out weaving obtained fabric, then by fabric processing before 100 DEG C of * 40min are carried out, then in 115 DEG C of *
Under the conditions of 30min using the dye of positive ion to CDP dye, then under the conditions of 70 DEG C of * 60min using reactive dye to cotton fiber into
Row dyeing obtains the knitted fabric that grammes per square metre is 170g/ ㎡, remaining obtains the fabric of the present invention with embodiment 3, and design parameter is shown in Table
1。
Embodiment 6
On circle volume machine, using 84dtex-96f-PET DTY, 40 viscose glues/PET mixed yarns and 22dtex spandexs with 40：
53：7 ratio latitude plain stitch carries out weaving obtained fabric, then by fabric processing before 100 DEG C of * 40min are carried out, then exists
PET fiber is dyed using disperse dyes under the conditions of 130 DEG C of * 30min, then uses reactive dye pair under the conditions of 70 DEG C of * 60min
Cotton fiber is dyed, and the knitted fabric that grammes per square metre is 160g/ ㎡ is obtained, remaining obtains the fabric of the present invention, specifically with embodiment 3
Parameter is shown in Table 1.
Embodiment 7
Antistatic agent A is replaced with into antistatic agent B, remaining obtains the fabric of the present invention with embodiment 3, and design parameter is shown in Table 1.
Embodiment 8
The usage amount of antistatic agent B is adjusted to 2%.owf, remaining obtains the fabric of the present invention with embodiment 7, and design parameter is shown in
Table 1.
Comparative example 1
Antistatic agent A is replaced with into antistatic agent C, with embodiment 3, obtained fabric, design parameter is shown in Table 1 for remaining.
Comparative example 2
Antistatic agent A is replaced with into antistatic agent D, with embodiment 3, obtained fabric, design parameter is shown in Table 1 for remaining.
Comparative example 3
Without antistatic processing, with embodiment 1, obtained fabric, design parameter is shown in Table 1 for remaining.
Table 1
According to upper table,
(1) it is found that under equal conditions, antistatic agent dosage is fabric and antistatic agent obtained by 4%.owf for embodiment 1 and embodiment 2
Dosage is that fabric obtained by 6%.owf is compared, and the water imbibition of the two, soft feeling are suitable, but the antistatic property of the latter（It is charged by friction pressure
It is low）Than the former slightly advantage.
(2) by embodiment 1 and embodiment 3 it is found that being carried out at the same time antistatic processing and flexible absorbent pads processing gained face
Material compared with only carrying out fabric obtained by antistatic processing, the two be charged by friction pressure and water imbibition is suitable, but the former soft feeling
Better than the latter.
(3) by embodiment 3 and embodiment 5 it is found that under equal conditions, fabric and conjunction that synthetic fibers content is 80 weight %
It is compared at the fabric that fiber content is 35 weight %, the former is charged by friction pressure, water imbibition, soft feeling not as good as the latter.
(4) by embodiment 3 and embodiment 7 it is found that under equal conditions, antistatic agent A (there are two hydrophilic radicals for tool) is processed
Gained fabric is compared with antistatic agent B (there are one hydrophilic radicals for tool) processing gained fabric, the water imbibition and soft feeling phase of the two
When, but the former antistatic property（It is charged by friction and forces down）Better than the latter.
(5) by embodiment 7 and embodiment 8 it is found that under equal conditions, antistatic agent B dosage be fabric obtained by 4%.owf with
Antistatic agent B dosage is that fabric obtained by 2%.owf is compared, and the soft feeling of the two is suitable, but the former antistatic property（It is charged by friction
It forces down）It is better than the latter with water imbibition.
(6) by comparative example 1 and embodiment 3 it is found that under equal conditions, antistatic agent C（Esters of acrylic acid）Processing gained face
Material and antistatic agent A（Alkyl quaternaries）Processing gained fabric is compared, the former antistatic property（It is high to be charged by friction pressure）, water suction
Property, soft feeling are far away from the latter.
(7) by comparative example 2 and embodiment 3 it is found that under equal conditions, antistatic agent D（Siloxanes quaternary ammonium salts）Processing institute
Obtain fabric and antistatic agent A（Alkyl quaternaries）Processing gained fabric is compared, and the soft feeling of the two is suitable, but the former is anti-quiet
Electrically（It is high to be charged by friction pressure）, water imbibition is far away from the latter.
(8) by comparative example 3 and embodiment 1 it is found that under equal conditions, without using antistatic agent process gained fabric with resist it is quiet
Electric agent A（Alkyl quaternaries）Processing gained fabric is compared, and the water imbibition and soft feeling of the two are suitable, but the former antistatic property
（It is high to be charged by friction pressure）Much not as good as the latter.
Claims (4)
1. a kind of Antistatic Fabric, including synthetic fibers, it is characterized in that：The single fiber surface of the synthetic fibers is covered with epithelium
Resin layer, alkyl quaternaries compound is at least contained in the epithelium resin layer, and structural formula is as follows：
,
Wherein, R, R1、R2、R3In at least one be with-OH ,-NH2, in-COOH one or several kinds of groups alkyl.
2. Antistatic Fabric according to claim 1, it is characterized in that：The synthetic fibers be conventional polyester fiber, sun from
One or more of sub- dyeable dacron, polyacrylonitrile fibre, and its content is 60 weight % or more.
3. Antistatic Fabric according to claim 1 or 2, it is characterized in that：The fabric wash 5 times after according to JIS L
1094 B methods, which measure it and are charged by friction, is pressed in 2500V or less.
4. Antistatic Fabric according to claim 1 or 2, it is characterized in that：The fabric is according to JIS L 0,217 103
Method further according to 1097 dropping methods of JIS L measures its absorbent time at 1 second or less after washing 10 times.
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| CN201710048717.7A CN108342901A (en) | 2017-01-23 | 2017-01-23 | A kind of Antistatic Fabric |
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| CN201710048717.7A CN108342901A (en) | 2017-01-23 | 2017-01-23 | A kind of Antistatic Fabric |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109645584A (en) * | 2019-01-31 | 2019-04-19 | 宁波市海曙华比欧服饰有限公司 | A kind of the princess's skirt and its processing technology of environmentally-friefabric fabric |
| CN116217879A (en) * | 2023-05-06 | 2023-06-06 | 江苏富淼科技股份有限公司 | Cationic antistatic agent, preparation method and application |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06316869A (en) * | 1993-05-07 | 1994-11-15 | Kanebo Ltd | Antistatic and water-repelling treatment of syntetic fiber-structural article |
| CN1143988A (en) * | 1994-01-14 | 1997-02-26 | 丹拿克朗有限公司 | Cardable hydrophobic polyolefin fibres comprising cationic spin finishes |
| CN101565896A (en) * | 2008-12-22 | 2009-10-28 | 上海氟聚化学产品有限公司 | Quaternary amino cation modified polysiloxane softening agent and preparation method thereof |
| CN102720057A (en) * | 2012-07-03 | 2012-10-10 | 河南省科学院化学研究所有限公司 | Fibre material containing quaternary ammonium groups and synthetic method thereof |
| CN103422352A (en) * | 2013-07-31 | 2013-12-04 | 天津新纶科技有限公司 | Polyhydroxyl polyether chain segment quaternary ammonium salt antistatic agent and preparation method thereof, and antistatic finishing agent prepared by same |
| CN104120603A (en) * | 2014-07-16 | 2014-10-29 | 广州大学 | Fabric antistatic agent and fabric antistatic finishing technology |
-
2017
- 2017-01-23 CN CN201710048717.7A patent/CN108342901A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06316869A (en) * | 1993-05-07 | 1994-11-15 | Kanebo Ltd | Antistatic and water-repelling treatment of syntetic fiber-structural article |
| CN1143988A (en) * | 1994-01-14 | 1997-02-26 | 丹拿克朗有限公司 | Cardable hydrophobic polyolefin fibres comprising cationic spin finishes |
| CN101565896A (en) * | 2008-12-22 | 2009-10-28 | 上海氟聚化学产品有限公司 | Quaternary amino cation modified polysiloxane softening agent and preparation method thereof |
| CN102720057A (en) * | 2012-07-03 | 2012-10-10 | 河南省科学院化学研究所有限公司 | Fibre material containing quaternary ammonium groups and synthetic method thereof |
| CN103422352A (en) * | 2013-07-31 | 2013-12-04 | 天津新纶科技有限公司 | Polyhydroxyl polyether chain segment quaternary ammonium salt antistatic agent and preparation method thereof, and antistatic finishing agent prepared by same |
| CN104120603A (en) * | 2014-07-16 | 2014-10-29 | 广州大学 | Fabric antistatic agent and fabric antistatic finishing technology |
Non-Patent Citations (1)
| Title |
|---|
| 胡学贵: "《高分子化学及工艺学》", 31 May 1991 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109645584A (en) * | 2019-01-31 | 2019-04-19 | 宁波市海曙华比欧服饰有限公司 | A kind of the princess's skirt and its processing technology of environmentally-friefabric fabric |
| CN116217879A (en) * | 2023-05-06 | 2023-06-06 | 江苏富淼科技股份有限公司 | Cationic antistatic agent, preparation method and application |
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