CN108342257A

CN108342257A - Liquid cleanser composition

Info

Publication number: CN108342257A
Application number: CN201810007376.3A
Authority: CN
Inventors: 矢野诚二; 季侃; 朱叶; 王强绪; 杨天运; 窪田裕; 窪田裕一
Original assignee: Kao Corp
Current assignee: Kao Corp
Priority date: 2017-01-25
Filing date: 2018-01-04
Publication date: 2018-07-31
Also published as: WO2018139388A1

Abstract

The present invention provides a kind of liquid cleanser composition, contains following (a)~(c) ingredients：(a) sulfuric ester salt form anion surfactant and/or sulfonate type anion surfactant；(b) amine oxide type surfactant；And (c) water Combination organic solvent, wherein, content and (a) ingredient and (b) mass ratio of total content of ingredient as (c) ingredient, (c)/((a)+(b)) is 0.5 hereinafter, and total content of surfactant other than aliphatic acid is 2~40 mass %.Liquid cleanser composition according to the present invention, for the smearing strong cleaning force of cooking oil waste, in hand washing and washing of drum type washing machine, blistering is rapid, and can simply be rinsed in rinsing.

Description

Liquid cleanser composition

Technical field

The present invention relates to the liquid cleanser compositions of the fibres such as liquid cleanser composition, especially clothing.

Background technology

As the washing methods of clothing, it is roughly divided into 2 kinds of hand washing washing and washing of drum type washing machine.

In Asia, it is very high to wash by hand the case where washing clothing, even if using washing of drum type washing machine, is doing washing Before machine washing is washed, pre-washing with hand can be carried out mostly.

This is because in Asia, people often eat the food of a large amount of oil-containings, the such cooking oil adhered on clothing Dirt, it is difficult to be effectively removed to rely solely on washing machine, only by by hand wash by rubbing with the hands, or in advance at greasy dirt smear clothing it is clear Washing machine cleaning is put into after clean dose of pretreatment again, can just effectively remove such cooking oil waste.

In detergent field, for dirt cleaning capacity, cleaning when blister rich and rinse after cleaning Easiness is important project.This shows particularly evident in being washed for the hand washing of cooking oil waste.

It is in the suds, since cooking oil waste is plain stubborn, seek the excellent cleaning capacity for it, in turn, When hand washing washing, due to sufficiently acting the satisfaction for steeping oneself-meeting and making one to expect high cleaning, and influencing detergent user in washing by rubbing with the hands Degree, thus, seek sufficient foaming characteristic.In addition, from the viewpoint of water-saving and is laborsaving, being strongly desired foam in rinsing can be fast Speed disappears, and just completes to rinse with a small amount of water.Common detergent can not all be taken into account to spot, especially simultaneously in washing process It is easy rinsability this 3 points after the rich and cleaning blistered when cleaning capacity, the cleaning to cooking oil waste, therefore, seeks This 3 points of new technology can be taken into account.

In patent document 1, it is 0.5 to disclose using containing alkyl (C10~18) amine oxide and average addition molal quantity The liquid cleanser composition for kitchen use of~5 polyxyethylated (C10~20) ether sulfate, can obtain excellent cleaning Power, the effect of storage stability under rinsability and low temperature, but for use sulfovinate or hydrocarbyl sulfonate and Surfactant total amount does not provide any technical inspiration.

In patent document 2, it discloses using containing alkyl or hydroxyalkyl (C10~18) amine oxide and specific polyoxygenated The liquid cleanser composition of allylic alkylation ether sulfate, can obtain high cleaning capacity and the preservation beneficial in a low temperature of is stablized The effect of property, but for using sulfovinate or hydrocarbyl sulfonate and water Combination organic solvent and surfactant Ratio does not provide any technical inspiration.

Existing technical literature

Patent document

Patent document 1：JP 2012-12436A

Patent document 2：US 8071521B1

Invention content

Present inventor is specialized in, as a result, it has been found that：It lives according to containing following sulfuric ester salt form anionic surfaces Property agent and/or sulfonate type anion surfactant [(a) ingredient] and amine oxide type surfactant [(b) ingredient] as must Must ingredient, and then selectively contain water Combination organic solvent [(c) ingredient], and (c) ingredient/((a) ingredient+(b) at Point) mass ratio be 0.5 hereinafter, and surfactant other than aliphatic acid total content be 2~40 mass % liquid it is clear Clean dose of composition, it is cleaning capacity and foaming characteristic to greasy dirt, rinsability excellent, especially cooking oil waste is played excellent Cleaning capacity, so as to complete the present invention.

The present invention provides a kind of liquid cleanser composition, contains following (a)~(c) ingredients：

(a) it is indicated with the sulfuric ester salt form anion surfactant of the following general formula (1) expression and/or with general formula (2) Sulfonate type anion surfactant,

R^a-O-SO₃M (1)

R^b-SO₃M (2)

R^a、R^bSeparately indicate that carbon atom number is the saturated or unsaturated alkyl of 12~18 linear chain or branched chain, M Indicate the counter ion of forming salt and in alkali metal ion, alkaline-earth metal ions, ammonium ion and the alkanol ammonium ion from Son；

(b) the amine oxide type surfactant represented by the following general formula (3) is used,

R¹Indicate the saturated or unsaturated alkyl for the straight chain or branch that carbon atom number is 6~10, R²Indicate carbon atom number For 1~3 alkylidene, R³、R⁴Independently of each other and indicate that carbon atom number is 1~3 alkyl or hydroxyalkyl；Or R³、R⁴It is logical Hetero atom is crossed to be combined with each other and separately indicate that alkylidene or hydroxyl alkylidene that carbon atom number is 1~3, X indicate choosing From the group in-COO- ,-CONH- and-O-, the number that m is 0 or 1；And

(c) water Combination organic solvent,

Wherein, the mass ratio of total content of ingredient as the content of (c) ingredient and (a) ingredient and (b), (c)/((a)+ (b)) it is 0.5 hereinafter, also, total content of surfactant other than aliphatic acid is 2~40 mass %.

According to the present invention it is possible to provide not only to greasy dirt, particularly cooking oil waste with high smearing cleaning force, and It blisters when cleaning abundant, and the foam quick disappearance in rinsing, can quickly and easily complete the liquid cleaner group of rinsing Close object.Also, the effect of the present invention obtains in the case where being cleaned, being rinsed with the washings of high rigidity.

Specific implementation mode

Each ingredient contained by the liquid cleanser composition to the present invention is described in detail below.

<(a) ingredient>

(a) ingredient be have carbon atom number be 12~18 alkyl sulfuric ester salt form anion surfactant and/or Sulfonate type anion surfactant, wherein sulfuric ester salt form anion surfactant indicates with the following general formula (1), Sulfonate type anion surfactant is indicated with the following general formula (2).

R^a-O-SO₃M (1)

R^b-SO₃M (2)

R^a、R^bIndicate that carbon atom number is the saturated or unsaturated alkyl of 12~18 linear chain or branched chain respectively, M indicates shape At salt counter ion and be ion in alkali metal ion, alkaline-earth metal ions, ammonium ion and alkanol ammonium ion.

In above-mentioned general formula (1), from the viewpoint of keeping foaming characteristic and smearing cleaning force better, R^aPreferably straight chain or The alkyl of the alkyl of person's branch either alkenyl more preferably straight chain or branch, the further preferably alkyl of straight chain.

Also, from the viewpoint of keeping foaming characteristic and smearing cleaning force better, R^aCarbon atom number be 12 or more, separately Outside, from the same viewpoint, for 18 hereinafter, preferably 16 hereinafter, be 12~18, preferably from the same viewpoint in turn It is 12~16.

In above-mentioned general formula (2), from the viewpoint of keeping foaming characteristic and smearing cleaning force better, R^bPreferably straight chain or The alkyl or alkenyl of person's branch.

Also, from the viewpoint of keeping foaming characteristic and smearing cleaning force better, R^bCarbon atom number be 12 or more, preferably It is 13 or more, more preferably 14 or more, in addition, being 18 hereinafter, preferably 17 or less from the same viewpoint.

In above-mentioned general formula (1), (2), from the viewpoint of keeping foaming characteristic and smearing cleaning force better, M is selected from alkali Ion in metal ion, alkaline-earth metal ions, ammonium ion and alkanol ammonium ion, more preferably in alkali metal ion from Son.

As alkali metal ion, from the viewpoint of make foaming characteristic and smear cleaning force it is better, be preferably selected from sodium from Ion in son and potassium ion, more preferably sodium ion.

In conclusion as with the specific example of the sulfuric ester salt form anion surfactant represented by general formula (1), it can To enumerate R^aFor dodecyl, myristyl or cetyl, and the alkyl sulfate that M is sodium ion is (that is, dodecyl sulphur Sour sodium, sodium tetradecyl sulfate or sodium hexadecyl sulfate).

As with the specific example of the sulfonate type anion surfactant represented by general formula (2), R can be enumerated^bFor The secondary alkyl of carbon atom number 13~17, and the secondary alkyl sulfonate that M is sodium ion；Or R^bFor the alkene of carbon atom number 14~16 Base, and the alpha-olefin sodium sulfonate that M is sodium ion.

(a) ingredient can be used alone, can also be by two or more appropriately combined use.Make by two or more combination , can be by two or more appropriately combined use of the sulfate represented by general formula (1) in the case of, it can also be by general formula (1) institute 1 kind or more the appropriately combined use of a kind or more of the sulfate of expression and the sulfonate represented by general formula (2), can also will lead to Two or more appropriately combined use of sulfonate represented by formula (2).It rapidly disappears from foam when taking into account foaming characteristic, rinsing easy From the perspective of rinsability and smearing cleaning force, two or more particularly preferably by the sulfate represented by general formula (1) is appropriate It is applied in combination.

It is fast from foam when taking into account foaming characteristic, rinsing as the content of (a) ingredient in the liquid cleanser composition of the present invention Disappear easy to be rinsability of speed and from the perspective of smearing cleaning force, preferably 0.75 mass % or more, more preferably 1 matter % or more, further preferably 2 mass % or more are measured, is still more preferably 3 mass % or more, is still more preferably 5 matter Measure % or more, additionally, it is preferred that for 25 mass % hereinafter, more preferably 20 mass % or less.These comprehensive viewpoints, the present invention's The content of (a) ingredient is preferably 0.75~25 mass % in liquid cleanser composition, more preferably 1~20 mass %, into one Step is preferably 2~20 mass %, is still more preferably 5~20 mass %.

In turn, in (a) ingredient comprising sodium hexadecyl sulfate (that is, in formula (1), R^aFor cetyl, and M is sodium Ion) in the case of, the viewpoint of easy rinsability, to greasy dirt the smearing cleaning force to rapidly disappear from foam when taking into account rinsing goes out Hair, the mass ratio of the content of sodium hexadecyl sulfate of the invention relative to the content of (a) ingredient, preferably 0.03 or more, more Preferably 0.07 or more, further preferably 0.13 or more are still more preferably 0.2 or more, and excellent from foaming characteristic Viewpoint is set out, and preferably 1 hereinafter, more preferably 0.43 hereinafter, further preferably 0.3 or less.In conclusion from being steeped when rinsing Easy rinsability excellent viewpoint, the smearing cleaning force to greasy dirt that foam rapidly disappears excellent viewpoint and foaming characteristic are excellent Viewpoint is set out, and the content of sodium hexadecyl sulfate is preferably 0.03~1 relative to the mass ratio of the content of (a) ingredient, more preferably It is 0.07~1, further preferably 0.13~0.43, is still more preferably 0.2~0.3.

In the liquid cleanser composition of the present invention, the anion surfactant other than (a) ingredient can be contained.From drift When washing foam rapidly disappear it is easy it is rinsability from the perspective of, other than the content of (a) ingredient is relative to (a) ingredient and (a) ingredient The mass ratio ((a)/anion surfactant) of total content of anion surfactant be preferably 0.2 or more, it is more excellent It is selected as 0.35 or more, further preferably 0.45 or more, is still more preferably 0.55 or more.

<(b) ingredient>

(b) ingredient be have carbon atom number be 6~10 alkyl amine oxide type surfactant.It is as carbon atom number 6~10 alkyl can enumerate alkyl or alkenyl that carbon atom number is 6~10, they can be straight chains, can also be branch Chain.Rapidly disappear from the viewpoint of foam when making rinsing easy to be rinsability and to the smearing cleaning force of greasy dirt it is better, (b) ingredient is preferably the amine oxide type surfactant for the alkyl for being 6~8 with carbon atom number, further preferably has carbon The amine oxide type surfactant for the alkyl that atomicity is 8.

As the amine oxide type surfactant of the present invention, the compound represented by the following general formula (3) can be enumerated.

R¹Indicate the saturated or unsaturated alkyl for the straight chain or branch that carbon atom number is 6~10, R²Indicate carbon atom number For 1~3 alkylidene, R³、R⁴Independently of each other and indicate that carbon atom number is 1~3 alkyl or hydroxyalkyl；Or R³、R⁴It is logical Hetero atom is crossed to be combined with each other and separately indicate that alkylidene or hydroxyl alkylidene that carbon atom number is 1~3, X indicate choosing From the group in-COO- ,-CONH- and-O-, the number that m is 0 or 1.

In above-mentioned general formula (3), easy to be rinsability and for greasy dirt the smearing to rapidly disappear from foam when making rinsing is clear From the perspective of clean power is better, R¹The preferably alkyl or alkenyl of straight chain either branch, more preferably the alkyl of straight chain or Person's alkenyl, the further preferably alkyl of straight chain are still more preferably primary alkyl.

In addition, easy the to be rinsability and smearing cleaning force for greasy dirt to rapidly disappear from foam when making rinsing is better From the perspective of, R¹Carbon atom number be 6 or more, preferably 8 or more, be 10 hereinafter, more in addition, from the same viewpoint Preferably 8 hereinafter, in turn, is 6~10 from the same viewpoint, preferably 8~10, more preferably 8.

The example of compound as preferred (b) ingredient, can enumerate R in general formula (3)¹It is 6~10 for carbon atom number Straight chained alkyl, R³、R⁴All it is methyl or R³、R⁴It is be combined with each other by oxygen atom and is all ethylidene, and m is 0 change Close object, wherein easy to be rinsability and to greasy dirt the superior viewpoint of smearing cleaning force to rapidly disappear from foam when making rinsing It sets out, is preferably selected from hexyl dimethyl amine, octyldimethyl amine oxide, decyl dimethyl amine oxide and N- decyls 1 kind in methylmorpholine-N-oxide or two or more, be more preferably selected from octyldimethyl amine oxide, decyl dimethyl aoxidizes 1 kind in amine and N- decyl methylmorpholine-N-oxides or two or more, further preferably octyldimethyl amine oxide.

(b) ingredient can be used alone, can also be by two or more appropriately combined use.It is fast from foam when taking into account rinsing From the perspective of easy rinsability, the smearing cleaning force that speed disappears, it is 6~10 that being further preferably used alone, which has carbon atom number, The amine oxide type surfactant of alkyl, alternatively, by the amine oxide type of the alkyl of more than two kinds for being 6~10 with carbon atom number Surfactant package uses.

As the content of (b) ingredient in the liquid cleanser composition of the present invention, rapidly disappear from foam when making rinsing From the perspective of easily rinsability and smearing cleaning force is better, preferably 0.3 mass % or more, more preferably 0.5 mass % More than, further preferably 1 mass % or more is still more preferably 1.5 mass % or more, is still more preferably 2 matter Measure % or more, and preferably 6 mass % hereinafter, more preferably 5 mass % hereinafter, further preferably 3 mass % or less.It is comprehensive These viewpoints are closed, the content of (b) ingredient is preferably 0.3~6 mass % in the liquid cleanser composition of the present invention, more preferably It is still more preferably 0.5~3 mass %, still more preferably for 0.3~5 mass, further preferably 0.5~5 mass % It is still more preferably 1.5~3 mass % for 1~3 mass %, is still more preferably 2~3 mass %.

In addition, total content as (a) ingredient and (b) ingredient, from smearing cleaning force, the foaming characteristic to cooking oil waste Viewpoint is set out, and (a)+(b) is preferably 2 mass % or more, further preferably 3 mass % or more, more preferably 5 mass % with On, be still more preferably 7 mass % or more, and preferably 30 mass % hereinafter, further preferably 25 mass % hereinafter, More preferably 20 mass % or less.These comprehensive viewpoints, in the liquid cleanser composition of the present invention, (a)+(b) is preferred It is still more preferably 5~20 for 2~30 mass %, more preferably 2~25 mass %, further preferably 3~25 mass % Quality % is still more preferably 7~20 mass %.

<(c) ingredient>

The liquid cleanser composition of the present invention can also contain suitable (c) water Combination organic solvent.As (c) at Point, can be common water Combination organic solvent in arbitrary liquid cleanser composition, it is however preferred to have be selected from hydroxyl and ether The water Combination organic solvent of a kind or 2 kinds of group in base.Water Combination organic solvent described in the present invention refers in 1L 25 DEG C of deionized waters in dissolve 50g or more organic solvent, that is, the organic solvent relative to water dissolution 50g/L or more.

As water Combination organic solvent, (1) alkane alcohols can be enumerated；(2) ethylene glycol, propylene glycol, butanediol or The aklylene glycol class or glycerine (hereinafter, can sometimes be known as glycols) that the carbon atom numbers such as hexylene glycol are 2~6；(3) by carbon The polyalkylene glycols that the aklylene glycol unit that atomicity is 2~4 is constituted；(4) diethylene glycol monomethyl ether, diethylene glycol two Methyl ether, triethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol diethyl ether, dipropylene glycol monomethyl ether, dipropylene glycol list second Ether, Tripropylene glycol monomethyl Ether, diethylene glycol monobutyl ether, 1- methoxy-2-propanols or 1- ethyoxyl -2- propyl alcohol etc. by carbon What the alkanol that (poly-) aklylene glycol and carbon atom number for the aklylene glycol unit that atomicity is 2~4 are 1~5 was constituted (poly-) aklylene glycol (list or two) alkyl ether (hereinafter, otherwise referred to as alkyl ether)；(5) it is 1~8 with carbon atom number The alkyl glycerol ethers of alkyl；(6) virtue of (poly-) aklylene glycol for the aklylene glycol unit for being 2~3 with carbon atom number Fragrant race's ethers.

As (c) ingredient, it is preferable to use from above-mentioned from the viewpoint of the dissolubility and product stability for reaching excellent (1) a kind or more of the substance selected in the classification of~(6), more preferable use is from above-mentioned (1) alkane alcohols, (2) glycols, (4) The solvent selected in alkyl ether and (6) aromatic series ethers.In the present invention, as preference, specifically, can lift Go out a kind in propylene glycol and diethylene glycol monobutyl ether or 2 kinds.

From the viewpoint of the smearing cleaning force to cooking oil waste, preferably in the liquid cleanser composition of the present invention, (c) the fewer the content of water Combination organic solvent the better, specifically, the present invention liquid cleanser composition in, (c) at Point content be preferably 10 mass % hereinafter, % below more preferably 9 mass, % below further preferably 7 mass, more into one Step is preferably 5 mass % hereinafter, being still more preferably 1 mass % hereinafter, being still more preferably 0.1 mass % hereinafter, more Further preferably 0.01 mass % is hereinafter, be still more preferably 0 mass %, that is, does not contain still more preferably.

As (c) ingredient and (a) ingredient and (b) ratio of total content of ingredient, from the smearing cleaning force to cooking oil waste From the perspective of, (c)/((a)+(b)) be 0.5 hereinafter, preferably 0.4 hereinafter, more preferably 0.3 hereinafter, further it is excellent 0.1 is selected as hereinafter, still more preferably for 0.01 hereinafter, being still more preferably 0.

<(d) ingredient>

The present invention liquid cleanser composition in, other than mentioned component, can also contain (d) ingredient it is non-from Sub- surfactant.

As the nonionic surfactant of (d) ingredient, it can be cited for example that：Selected from polyoxyalkylene alkyl, polyoxygenated Alkene alkene ether, alkyl polyglucoside, alkyl glucoside, fatty acid cane sugar ester, polyglyceryl fatty acid ester, aliphatic acid monoethanol acyl Amine, fatty diglycollic amide, Crodaret, polyoxyethylene sorbitan aliphatic ester, polyoxyethylene 1 kind in sorbitan fatty acid ester and alkyl sugar surfactants or two or more.Wherein, to dirts such as cooking oil wastes From the perspective of the cleaning force and product stability of stain, be preferably selected from polyoxyalkylene alkyl, fatty monoethanol amide and 1 kind in fatty diglycollic amide or two or more, be more preferably selected from polyoxyalkylene alkyl and aliphatic acid monoethanol 1 kind in amide or two or more.From the viewpoint of easily it is rinsability it is excellent, further preferably polyoxyalkylene alkyl.

From the viewpoint of to the cleaning force of the spots such as cooking oil waste and product stability, the polyoxyalkylene alkyl Alkyl is preferably straight chain.

From the viewpoint of to the cleaning force of the spots such as cooking oil waste and product stability, the polyoxyalkylene alkyl Alkylidene is preferably selected from a kind or 2 kinds in ethylidene and propylidene, more preferably ethylidene.

From the viewpoint of to the cleaning force of the spots such as cooking oil waste and product stability, the polyoxyalkylene alkyl The carbon atom number of alkyl is preferably 8 or more, more preferably 10 or more, further preferably 12 or more, in addition, from same viewpoint It sets out, preferably 18 hereinafter, more preferably 16 hereinafter, further preferably 14 or less.

From the viewpoint of to the cleaning force of the spots such as cooking oil waste and product stability, the polyoxyalkylene alkyl The addition molal quantity of oxyalkylene group is preferably 1 or more, more preferably 5 or more, further preferably 10 or more, in addition, from same From the perspective of, preferably 30 hereinafter, more preferably 25 hereinafter, further preferably 21 or less.

From the viewpoint of to the cleaning force of the spots such as cooking oil waste and product stability, the fatty monoethanol amide The carbon atom number for being preferably selected from alkyl be a kind or 2 kinds in 7 or more and 21 aliphatic acid below and monoethanol amide with On, a kind more preferably in fatty monoethanol amide and palm kernel fatty acid single ethanol amide or 2 kinds, More preferably fatty monoethanol amide.

Easy to be rinsability and to cooking oil waste the superior sight of smearing cleaning force to rapidly disappear from foam when making rinsing Point sets out, and the content of the nonionic surfactant as (d) ingredient of the invention is preferably 16 mass % hereinafter, more preferably 10 mass % hereinafter, further preferably 6 mass % hereinafter, still more preferably be 1 mass % or less.

On the other hand, foaming characteristic when washing of drum type washing machine, the nonionic as (d) ingredient of the invention The content of surfactant is preferably 0.3 mass % or more, more preferably 0.6 mass % or more.

Rapidly disappear from the viewpoint of foam when taking into account rinsing it is easy it is rinsability, to the smearing cleaning force of cooking oil waste, The content of the nonionic surfactant of (d) ingredient as the present invention and mass ratio (d)/(a) of the content of (a) ingredient are preferred For 7 hereinafter, more preferably 4.4 hereinafter, further preferably 2.3 or less.

On the other hand, foaming characteristic when washing of drum type washing machine, the nonionic of (d) ingredient as the present invention Mass ratio (d)/(a) of the content of surfactant and the content of (a) ingredient is preferably 0.02 or more, more preferably 0.04 with On.

Easy to be rinsability and to cooking oil waste the superior viewpoint of smearing cleaning force to rapidly disappear from foam when rinsing It sets out, the mass ratio (d) of the content of content and (b) ingredient of the nonionic surfactant of (d) ingredient as the present invention/ (b) it is preferably 10 hereinafter, more preferably 6 hereinafter, further preferably 2.7 or less.

On the other hand, foaming characteristic when washing of drum type washing machine, the nonionic of (d) ingredient as the present invention The content of surfactant and mass ratio (d)/(b) of the content of (b) ingredient are preferably 0.1 or more, and more preferably 0.2 or more.

In the liquid cleanser composition of the present invention, other than mentioned component, it can also not damage the present invention's Coordinate other ingredients in the range of purpose or effect.As other ingredients, can enumerate for example：The present invention (a) ingredient with Amphoteric surfactant other than (b) ingredient of outer anion surfactant, the present invention；And it is commonly used in cleaning liquid Chelating agent, foam improver in agent composition, builder, antirust agent, viscosity modifier, pH adjusting agent, antioxidant, antibacterial Any ingredient of mould resistant, preservative, colouring matter, fragrance etc..

As the anion surfactant other than (a) ingredient of the present invention, it can be cited for example that：Dodecyl benzene sulfonic acid The alkylbenzene sulfonates such as sodium, sodium 2-ethylhexyl sulfate, sodium decyl sulfate, sodium laureth sulfate, alkylsurfuric acid Salt, polyoxyalkylene alkyl sulfate etc..

As the amphoteric surfactant other than (b) ingredient of the present invention, it can be cited for example that：Dodecyl dimethyl oxygen Change the alkyl amine oxides such as amine, tetradecyldimethylamine oxide, cetyl dimethyl amine oxide；And lauryl imidazoline sweet tea The alkyl imidazolines type glycine betaine such as dish alkali, coco imidoazolinium betaine；Lauroylamidopropyl betaine, palm kernel fatty acid The amido propyl betaines such as amido propyl betaine, fatty acid distribution of coconut oil amido propyl betaine；Bay base oxethyl sulfobetaines The alkyl sulfo betaines such as alkali, stearyl ethoxy sulfobetaines；Fatty acid distribution of coconut oil hydroxyl sulfo betaine, lauryl hydroxyl The hydroxyl sulfo betaines such as sulfobetaines, myristyl hydroxyl sulfo betaine；It is bis-lauryl dimethyl carboxybetaine, hard The alkyl carboxyls glycine betaines such as aliphatic radical hexyl methyl carboxybetaine.

As chelating agent, it can be cited for example that：Ethylenediamine tetra-acetic acid, phosphonates etc..

As builder, it can be cited for example that：Sodium tripolyphosphate, sodium metasilicate, sodium carbonate, sodium sulphate, sodium citrate, poly- third Olefin(e) acid sodium etc..

As antirust agent, it can be cited for example that：Pentaerythritol ester, inositol hexaphosphate etc..

As viscosity modifier, it can be cited for example that：Hydroxyethyl cellulose, methylcellulose, carboxyl vinyl polymer Deng.

As pH adjusting agent, it can be cited for example that：Sodium hydroxide, potassium hydroxide, alkanolamine, sulfuric acid, hydrochloric acid, lemon Acid, lactic acid, tartaric acid, oxalic acid, malic acid etc..

As antioxidant, it can be cited for example that：Butylated hydroxytoluene, distyrenated cresol, sodium sulfite and Asia Niter cake etc..

As antibacterial mould resistant, it can be cited for example that：Silver ion class antiseptic, zinc oxide, copper oxide, biphosphate Ammonium, lithium carbonate, vanillic aldehyde or ethylene vanilla aldehyde compound etc..

As preservative, it can be cited for example that：Methyl p-hydroxybenzoate, butyl p-hydroxybenzoate, 1,2- benzo thiophenes Oxazoline -3- ketone etc..

In turn, in the liquid cleanser composition of the present invention, as above-mentioned (a) ingredient~(d) ingredients and arbitrarily at Surplus other than point, can be water.As water, preferably deionized water etc. does not have influential water to composition.

Also, from the viewpoint of to the smearing cleaning force of cooking oil waste, rinsing when foam rapidly disappear it is easy it is rinsability, PH value of the liquid cleanser composition of the present invention at 25 DEG C is preferably 7 or less, more preferably 6 or less, further preferably 5 Below.

In addition, from the viewpoint of use in rinsing, the pH value of liquid cleanser composition of the invention at 25 DEG C is excellent It is selected as 1 or more, more preferably 3 or more, further preferably 3.5 or more.PH value can be adjusted using above-mentioned pH adjusting agent Section.

Also selectively contain the amphoteric surfactant other than (b) ingredient in the liquid cleanser composition of the present invention In the case of, content and (b) ingredient of (b) ingredient contained in the liquid cleanser composition as the present invention and (b) ingredient with The mass ratio of total content of outer amphoteric surfactant, when rinsing it is rinsability it is good, preferably 0.2 with It is upper and 1 hereinafter, more preferably 0.4 or more and 1 hereinafter, further preferably 0.6 or more and 1 hereinafter, be still more preferably 0.8 Above and 1 hereinafter, be still more preferably 1.

In the present invention, total content of the surfactant other than aliphatic acid be 2~40 mass %, preferably 5~ 32.5 mass %, more preferably 7~25 mass %.Here, " surfactant other than aliphatic acid " refers to the liquid of the present invention The all surfaces activating agent other than aliphatic acid contained by cleanser compositions.

The liquid cleanser composition of the present invention can be manufactured by properly mixing each ingredient.

It is exemplified below embodiments of the present invention.

[1] a kind of liquid cleanser composition, wherein

Contain following (a)~(c) ingredients：

R^a-O-SO₃M (1)

R^b-SO₃M (2)

(c) water Combination organic solvent,

Wherein, the mass ratio of total content of ingredient as the content of (c) ingredient and (a) ingredient and (b), (c)/((a)+ (b)) be 0.5 hereinafter, also, in the liquid cleanser composition of the present invention, surfactant other than aliphatic acid it is total Content is 2~40 mass %.

[2] liquid cleanser composition described in above-mentioned [1], wherein (a) ingredient includes sodium hexadecyl sulfate.

[3] liquid cleanser composition described in above-mentioned [1] or [2], wherein the content phase of the sodium hexadecyl sulfate Mass ratio for the content of (a) ingredient is preferably 0.03 or more, more preferably 0.07 or more, further preferably 0.13 with On, be still more preferably 0.2 or more, and preferably 1 hereinafter, more preferably 0.43 hereinafter, further preferably 0.3 with Under, also, preferably 0.03~1, more preferably 0.07~1, further preferably 0.13~0.43, still more preferably for 0.2~0.30.

[4] liquid cleanser composition described in any one of above-mentioned [1]~[3], wherein the R in general formula (1)^aIt is preferred that For the alkyl of straight chain either alkyl either the alkenyl more preferably straight chain or branch of branch, the further preferably alkane of straight chain Base.

[5] liquid cleanser composition described in any one of above-mentioned [1]~[4], wherein the R in general formula (1)^aCarbon Atomicity is preferably 16 hereinafter, in turn, and preferably 12~16.

[6] liquid cleanser composition described in any one of above-mentioned [1]~[5], wherein the R in general formula (2)^bIt is preferred that For the alkyl or alkenyl of straight chain either branch.

[7] liquid cleanser composition described in any one of above-mentioned [1]~[6], wherein the R in general formula (2)^bCarbon Atomicity is preferably 13 or more, and more preferably 14 or more, additionally, it is preferred that being 17 or less.

[8] liquid cleanser composition described in any one of above-mentioned [1]~[7], wherein in general formula (3), R¹Preferably The alkyl or alkenyl of the straight chain either alkyl either alkenyl more preferably straight chain of branch, the further preferably alkyl of straight chain, Still more preferably it is primary alkyl.

[9] liquid cleanser composition described in any one of above-mentioned [1]~[7], wherein in general formula (3), R¹Carbon it is former Subnumber is preferably 8~10, and more preferably 8.

[10] liquid cleanser composition described in above-mentioned [1], wherein further contain the anion other than (a) ingredient The content of surfactant, (a) ingredient contains relative to the total of anion surfactant other than (a) ingredient and (a) ingredient The mass ratio of amount is 0.2 or more, preferably 0.35 or more, more preferably 0.45 or more, further preferably 0.55 or more.

[11] liquid cleanser composition described in any one of above-mentioned [1]~[10], wherein (b) ingredient preferably selects From hexyl dimethyl amine, octyldimethyl amine oxide, decyl dimethyl amine oxide and N- decyl methylmorpholine-N-oxides In a kind or two or more, more preferably be selected from octyldimethyl amine oxide, decyl dimethyl amine oxide and N- decyls 1 kind in quinoline-N- oxides or two or more, further preferably octyldimethyl amine oxide.

[12] liquid cleanser composition described in any one of above-mentioned [1]~[11], wherein as (a) ingredient and (b) Total content of ingredient, (a)+(b) are preferably 2 mass % or more, further preferably 3 mass % or more, more preferably 5 matter % or more is measured, is still more preferably 7 mass % or more, and preferably 30 mass % are hereinafter, further preferably 25 matter Measure % hereinafter, more preferably 20 mass % hereinafter, also, preferably 2~30 mass %, more preferably 2~25 mass %, into One step is preferably 3~25 mass %, is still more preferably 5~20 mass %, is still more preferably 7~20 mass %.

[13] liquid cleanser composition described in any one of above-mentioned [1]~[12], wherein as containing for (c) ingredient Amount and (a) ingredient and (b) mass ratio of total content of ingredient, (c)/((a)+(b)) are preferably 0.4 hereinafter, more preferably 0.3 Hereinafter, further preferably 0.1 hereinafter, be still more preferably 0.01 hereinafter, being still more preferably 0.

[14] liquid cleanser composition described in any one of above-mentioned [1]~[13], wherein it is non-further to contain (d) Ionic surface active agent.

[15] liquid cleanser composition described in any one of above-mentioned [1]~[14], wherein the non-ionic surface is lived Property agent is preferably selected from polyoxyalkylene alkyl, polyoxyalkylene alkenyl ether, alkyl polyglucoside, alkyl glucoside, aliphatic acid sugarcane Sugar ester, polyglyceryl fatty acid ester, fatty monoethanol amide, fatty diglycollic amide, Crodaret, polyoxy 1 in ethylene sorbitan fatty ester, polyoxyethylene sorbitol aliphatic ester and alkyl sugar surfactants Kind or two or more, more preferably be selected from polyoxyalkylene alkyl, fatty monoethanol amide and fatty diglycollic amide In a kind or two or more, a kind further preferably in polyoxyalkylene alkyl and fatty monoethanol amide or Person two or more.

[16] liquid cleanser composition described in any one of above-mentioned [1]~[15], wherein as containing for (d) ingredient The mass ratio of amount and the content of (a) ingredient, (d)/(a) are preferably 7 hereinafter, more preferably 4.4 hereinafter, further preferably 2.3 Hereinafter, and preferably 0.02 or more, more preferably 0.04 or more.

[17] liquid cleanser composition described in any one of above-mentioned [1]~[16], wherein as containing for (d) ingredient The mass ratio of amount and the content of (b) ingredient, (d)/(b) be preferably 10 hereinafter, more preferably 6 hereinafter, further preferably 2.7 with Under, and preferably 0.1 or more, more preferably 0.2 or more.

[18] liquid cleanser composition described in any one of above-mentioned [1]~[17], wherein further contain (b) at Amphoteric surfactant other than point.

[19] liquid cleanser composition described in above-mentioned [18], wherein the content of (b) ingredient relative to (b) ingredient and (b) mass ratio of total content of the amphoteric surfactant other than ingredient is preferably 0.2 or more and 1 hereinafter, more preferably 0.4 Above and 1 hereinafter, further preferably 0.6 or more and 1 hereinafter, still more preferably be 0.8 or more and 1 hereinafter, further Preferably 1.

[20] liquid cleanser composition described in any one of above-mentioned [1]~[19], wherein the content of (a) ingredient is excellent Be selected as 0.75 mass % or more, more preferably 1 mass % or more, further preferably 2 mass % or more, still more preferably for 3 mass % or more are still more preferably 5 mass % or more, additionally, it is preferred that for 25 mass % hereinafter, more preferably 20 matter % is measured hereinafter, also, preferably 0.75~25 mass %, more preferably 1~20 mass %, further preferably 2~20 matter % is measured, is still more preferably 5~20 mass %.

[21] liquid cleanser composition described in any one of above-mentioned [1]~[20], wherein the content of (b) ingredient is excellent It is selected as 0.3 mass % or more, more preferably 0.5 mass % or more, further preferably 1 mass % or more, still more preferably It is still more preferably 2 mass % or more for 1.5 mass % or more, and preferably 6 mass % are hereinafter, more preferably 5 matter Measure % hereinafter, further preferably 3 mass % hereinafter, and preferably 0.3~6 mass %, more preferably 0.3~5 mass, into One step is preferably 0.5~5 mass %, is still more preferably 0.5~3 mass %, is still more preferably 1~3 mass %, more Further preferably 1.5~3 mass % are still more preferably 2~3 mass %.

[22] liquid cleanser composition described in any one of above-mentioned [1]~[21], wherein the content of (c) ingredient is excellent 10 mass % are selected as hereinafter, % below more preferably 9 mass, % below further preferably 7 mass, is still more preferably 5 Quality % is hereinafter, be still more preferably 1 mass % hereinafter, being still more preferably 0.1 mass % hereinafter, still more preferably For 0.01 mass % hereinafter, being still more preferably 0 mass %.

[23] liquid cleanser composition described in any one of above-mentioned [1]~[22], wherein the content of (d) ingredient is excellent Be selected as 16 mass % hereinafter, more preferably 10 mass % hereinafter, further preferably 6 mass % hereinafter, still more preferably be 1 Quality % is hereinafter, also, preferably 0.3 mass % or more, more preferably 0.6 mass % or more.

[24] use of the liquid cleanser composition described in any one of above-mentioned [1]~[23].

[25] a kind of washing methods of clothing, wherein use the liquid cleaner described in any one of above-mentioned [1]~[23] Composition.

The liquid cleanser composition of the present invention can be adapted for the fibres such as dress material, bedding, cloth and silk, preferably as clothing Object is used with detergent.

Embodiment

Hereinafter, being further stated that by embodiment and disclosing embodiments of the present invention.The embodiment is only this hair Bright illustration, without any restriction the intent of the present invention.Using each ingredient shown in following tables, embodiment, comparative example are obtained Each liquid cleanser composition.The numerical value of the amount of each ingredient in table indicates that surplus is as active ingredient with quality % Ionized water.The value of the mass ratio of ingredient in table omits denominator (/ 1) to record.

Each ingredient shown in mixture table 1~9, obtains the composition of embodiment and comparative example.Use obtained each group It closes object and carries out following each evaluations.As a result as shown in table 1~9.

Modulate " evaluation half sleeve shirt of cotton " by the following method.Specifically, by commercially available half bushings of cotton of 2.5kg (Shanghai Three Gun (group) Co., Ltd. manufactures shirt, crew neck, size：L, cotton content：100%) it is placed in washing machine (Qingdao Haier Washing MachineCo., Ltd., specification：XQS60-ZY1128 in), detergent is added, in temperature 20 DEG C, the hard water of 89.5mg/L is scaled (by CaCl with calcium carbonate₂With MgCl₂·6H₂O is with 6:4 molar ratio mixing) under, if It fixs condition of stating and repeats rinsing 5 times.The condition rinsed every time is：Water 54L, dosage of scour 27g are (that is, the dosage of detergent 2 times, dehydration 5 minutes are rinsed relative to water (detergent (g)/water (L) be 0.5g/L), wash time 12 minutes, water storage.It is above-mentioned Detergent is that (average addition has 6 moles of oxygen to nonionic surfactant on the primary alconol for the alkyl for being 12 with carbon atom number Polyoxyethylene alkyl ether made of vinyl, trade name：EMULGEN 108) with noncrystalline sodium metasilicate and sodium carbonate with 1:1:3 The mixture that mass ratio mixes.

It will be placed in two-tub washing machine (Panasonic manufactures, XPB52-500S) after half sleeve shirt of cotton being finally dehydrated, made It is scaled the hard water of 89.5mg/L with 20 DEG C of temperature, with calcium carbonate, is rinsed to completely without foam, then 5 points of dehydration with flowing water Clock is then spontaneously dried, is made " half sleeve shirt of evaluation cotton ".

It is shown in the assay method of the basicity of the water used in the modulation of the water dilution below (as long as hereinafter, not special It does not record, basicity of the invention refers to the value measured using this method).

100ml test waters are taken with 200ml beakers, and 0.15ml bromocresol greens-methyl red ethanol solution is added, and (and light is pure Medicine Industrial Co., Ltd manufactures) it is used as indicator.When having residual chlorine in test water, in advance to 100ml test waters Middle addition hypo solution (0.3w/v%) removes residual chlorine.It is slowly stirred the solution and is titrated to 10mmol/l sulfuric acid The color of solution becomes aubergine from indigo plant.Basicity is calculated by following formula.

Basicity (CaCO₃Mg/l)=a × 10

In formula, a：Titrate required 10mmol/l sulfuric acid (ml)

The addition indicator discoloration such as sample after coloring is unconspicuous, substitutes indicator and uses pH meter, by pH The amount (ml) that value reaches 4.8 required 10mmol/l sulfuric acid is used as a.

Three above-mentioned evaluations are placed in vertical washing machine (Qingdao HaierWashing with half sleeve shirt of cotton Machine Co., Ltd.s, specification：XQS60-ZY1128), by the washing pattern that mode tuning is 22L, the application is added and implements Each 22g of composition manufactured by example and comparative example, being scaled 179mg/L using 20 DEG C of water temperature, with calcium carbonate, (this hard water is equivalent to 10 ° of DH in terms of Deutschland hardness), basicity 65CaCO₃The hard water of mg/L, pH7.1 are [to calcium chloride (CaCl₂·2H₂O)1.57g With magnesium sulfate (MgSO₄·6H₂O) 1.45g and sodium bicarbonate (NaHCO₃) hydrochloric acid tune is used in combination to 10L in addition deionized water in 1.6g Save, Ca/Mg=6/4 (molar ratio)], wash that (wash time 10 minutes, water storage rinse 2 times, dehydration automatically by washing machine 2 minutes).It begins to pass through after five minutes from washing, once stopping, is inserted to ruler is slightly horizontal to strike off foam surface in foam, Then it measures since the water surface to the height of foam upper end, is marked with centimetre (cm).Assuming that foam is very few, foam is not covered with water The case where face, as 0cm.

Into round washbowl (bottom surface internal diameter 28cm, surface internal diameter 35cm, height 13.5cm), injection 20 DEG C of water temperature, with Calcium carbonate is scaled 179mg/L (this hard water is equivalent to 10 ° of DH in terms of Deutschland hardness), basicity 65CaCO₃Mg/L, pH7.1's is hard Water is [to calcium chloride (CaCl₂·2H₂O) 1.57g and magnesium sulfate (MgSO₄·6H₂O) 1.45g and sodium bicarbonate (NaHCO₃) in 1.6g Addition deionized water is to 10L, hard water made of being used in combination hydrochloric acid to adjust, Ca/Mg=6/4 (molar ratio)] 3L.Wherein, this Shen is added Please embodiment and comparative example manufacture each 15g of composition, be allowed to uniform dissolution while being stirred with hand.Then, it throws thereto Enter 3 evaluation half sleeve shirts of cotton modulated by the above method, 1 point is placed in the state of cleaning solution with thorough impregnation Clock.After placing 1 minute, each evaluation washes 50 times by rubbing with the hands with half sleeve shirt of cotton and (rubs cloth and cloth with the hands 1 to convert within (about 1 second) back and forth It it is 1 time).Then, take out evaluation half sleeve shirt of cotton, from apart from the top of washbowl 30cm by evaluation half sleeve shirt of cotton Squeeze out to water content becomes 100~140 mass % relative to half sleeve shirt of evaluation cotton, confirms 3 cleaning solutions just squeezed out The state in face.It is inserted to ruler is slightly horizontal to strike off surfactant foam in foam, then measures since the water surface to foam upper end Height, marked with centimetre (cm).

In this evaluation, the situation of 2cm or more is qualification, and the numerical value the big the more preferred.

Into round washbowl (bottom surface internal diameter 28cm, surface internal diameter 35cm, height 13.5cm), injection 20 DEG C of water temperature, with Calcium carbonate is scaled 179mg/L (this hard water is equivalent to 10 ° of DH in terms of Deutschland hardness), basicity 65CaCO₃Mg/L, pH7.1's is hard Water is [to calcium chloride (CaCl₂·2H₂O) 1.57g and magnesium sulfate (MgSO₄·6H₂O) 1.45g and sodium bicarbonate (NaHCO₃) in 1.6g Addition deionized water is to 10L, hard water made of being used in combination hydrochloric acid to adjust, Ca/Mg=6/4 (molar ratio)] 5L, put into 3 above-mentioned Evaluation half sleeve shirt of cotton squeezed out in the evaluation of bubble property.After evaluation is unclamped with half sleeve shirt of cotton in rinse water, from Evaluation after unclamping every 1 in water catches collar part to carry upwards and (carries and integrally leave washing to clothing with half sleeve shirt of cotton The height of the liquid water surface about 5cm), then put back in rinse water again.For every 1 evaluation, half sleeve shirt of cotton, 10 are repeated Secondary such rinsing to move up and down, then from apart from the top of washbowl 30cm by evaluation with half sleeve shirt of cotton squeeze out to containing Water relative to evaluation with half sleeve shirt of cotton become 100~140 mass %, confirm 3 just squeeze out after washing liquid level shape State.It is inserted to ruler is slightly horizontal to strike off the foam on surface in foam, then measures since the water surface to the height of foam upper end Degree is marked with centimetre (cm).This is 1 evaluation.In turn, it for the evaluation squeezed out half sleeve shirt of cotton, is repeated 1 times same The evaluation of sample (is evaluated, used evaluation cotton about from a kind of contained liquid detergent composition of above-mentioned foaming characteristic evaluation Half sleeve shirt is 3).

In this evaluation, the situation that the 2nd value is 1cm or more is qualified, and numerical value is smaller the more preferred.In addition, at the 2nd time In the case of numerical value is identical, the 1st numerical value is smaller more more preferable.

Assuming that foam is very few, it, will be opposite " by the area of the water surface of foam coverage " in the case that foam is not covered with the water surface It is marked with " % " in the ratio of " area of water surface entirety ".

The case where foam can not confirm is marked with "None".Numerical value is smaller the more preferred in this case.

Used artificial contamination's cloth be will cut out for 6cm × 6cm cottons (cotton 100%, cotton 40S, from Shanghai Le Yibu Industry Co., Ltd buys), every 1 is smeared the chili oil that 0.01ml is modulated by the following method, and the dark place 2 for being statically placed in not illumination is small When.

* chili oil

Friend plus paprika (Sichuan You Jia Food Co., Ltd) 50g are added into soybean oil (refining level-one, golden dragonfish) 200g In, after being stirred 2 hours at 80 DEG C, with Whatman filter paper, (1 grade, particle keeps energy：11 μm) it filters and uses.

As the evaluation of each liquid cleanser composition, above-mentioned artificial contamination's cloth is set as 41 group.By each artificial contamination After cloth smears the liquid cleanser composition of each 0.5g and stands 15 minutes respectively, the artificial dirt of cleanser compositions will be coated with It dyes cloth 4 to put into and is scaled 179mg/L (this hard water is equivalent to 10 ° of DH in terms of Deutschland hardness), alkali to 20 DEG C of water temperature, by calcium carbonate Spend 65CaCO₃The hard water of mg/L, pH7.1 are [to calcium chloride (CaCl₂·2H₂O) 1.57g and magnesium sulfate (MgSO₄·6H₂O)1.45g With sodium bicarbonate (NaHCO₃) addition deionized water is to 10L in 1.6g, hard water made of being used in combination hydrochloric acid to adjust, Ca/Mg=6/4 (molar ratio)] in 1L (cleanser compositions contained by each artificial contamination's cloth add up to 2.0g), use Terg-O-Tometer (Tergotometer) (the vertical decontamination measuring machine of RIDCi RHLQIII types, Chinese detergents and cosmetic industrial research institute system) is with rotating speed 200rpm, wash time 10 minutes, the condition of 20 DEG C of temperature are washed.By washed artificial contamination's cloth (hereinafter, being recorded as Treatment cloth) with after two-tub washing machine (Panasonic manufacture, XPB52-500S) dehydration 1 minute, after 1 hour dry at 40 DEG C, with survey Color colour difference meter (Nippon Denshoku Industries Co., Ltd., Color meter ZE 6000) measures reflectivity (2 degree of visuals field of illuminant-C), note Record Z values.

In this evaluation, 76 or more situation is qualification, and the numerical value the big the more preferred.

It is the pH meter (D-52) and pH electrodes (6367-10D) for using Horiba Ltd that pH, which is measured, according to following Sequence carries out.Titer is the pH4 titer (product identifications for manufacturing Yokogawa Electric Corporation：K9084KF), pH7 standards Liquid (product identification：K9084KG), pH9 titers (product identification：K9084KH it) is transferred in 50ml beakers and uses.

PH electrodes are thoroughly cleaned with ion exchange water, tissue paper (tissue paper) is used in combination to wipe.Open pH electrodes Internal liquid supply port, by pH electrodes immerse equipped with pH7 titers beaker in.In the shape that pH electrodes are immersed to sample 3cm Under state, " CAL " key is pressed after 1 minute.After " HOLD " instruction stops flicker, pH electrodes are thoroughly cleaned with ion exchange water, and It is wiped with tissue paper.Then, using pH4 titers, pH9 titers, repetition similarly operates and implements three point calibrations.It has corrected Cheng Hou immerses electrode in 7 titers of pH under correction mode, presses " ENTER " key, carries out pH reproducibility inspections, if Within 0.05pH, then complete to correct.

Then, pH electrodes are thoroughly cleaned with ion exchange water, tissue paper is used in combination to wipe.In the inside liquid for confirming pH electrodes After body supply port is opened, in the state that pH electrodes are immersed sample 3cm, " MEAS " key is pressed after 2 minutes and is measured.

Note：Each gradation composition used in embodiment and comparative example is as shown below together.

<(a) ingredient>

(a-1)：Lauryl sodium sulfate (manufacturer：Tokyo Chemical Industry Co., Ltd)

The numerical value of (a-1) of the embodiment 7 and embodiment 8 in ※ tables 1 and the embodiment 44 in table 7 and embodiment 48 It further includes the dodecyl sulphate from polyoxyethylene joined together (EO be averaged addition molal quantity=3) sodium laureth sulfate to be The concentration of sodium.

(a-2)：Sodium tetradecyl sulfate (manufacturer：Wako Chemical,Ltd.)

(a-3)：Sodium hexadecyl sulfate (manufacturer：Wako Chemical,Ltd.)

(a-4)：C14/C16 alpha-olefin sodium sulfonate (trade names：Hostapur OS Liquid, active constituent content：42 matter Measure %, manufacturer：Clariant Produkte(Deutschland)GmbH)

(a-5)：Sodium secondary alkyl sulfonate (trade name：Hostapur SAS 60, active constituent content：60 mass %, manufacture Quotient：Clariant Produkte(Deutschland)GmbH)

<(a ') ingredient>[anion surfactant other than (a) ingredient]

(a’-1)：Sodium 2-ethylhexyl sulfate (trade name：Disponil EHS 47, active constituent content：47 mass %, Manufacturing company：BASF SE)

(a’-2)：Sodium decyl sulfate (trade name：EMAL 3F, active constituent content：33 mass %, manufacturing company：Flower king Co., Ltd.)

(a’-3)：Polyoxyethylene (EO be averaged addition molal quantity=3) sodium laureth sulfate (trade name：EMAL 20C, have Effective component content：25 mass %, the content of lauryl sodium sulfate：5.5 mass %, manufacturer：Kao Corp)

Numerical value in ※ tables 1 and table 7 is polyoxyethylene joined together (EO be averaged addition molal quantity=3) laureth sulfate The concentration of the active ingredient other than lauryl sodium sulfate in sodium.

(a’-4)：Neopelex (trade name：NEOPELEX G-25, active constituent content：25 mass %, system Make quotient：Kao Corp)

<(b) ingredient>

(b-1)：Octyldimethyl amine oxide (trade name：AMPHITOL 08N, active constituent content：50 mass %, manufacture Quotient：Kao Corp)

(b-2)：Decyl dimethyl amine oxide (manufacturer：Kao Corp)

(b-3)：N- decyl morpholine N-Oxides (manufacturer：Kao Corp)

<(b ') ingredient>[amphoteric surfactant other than (b) ingredient]

(b’-1)：Lauryl dimethyl amine oxide (trade name：AMPHITOL 20N, active constituent content：35 mass %, Manufacturer：Kao Corp)

(b’-2)：Lauryl hydroxyl sulfo betaine (trade name：AMPHITOL 20HD, active constituent content：30 matter Measure %, manufacturer：Kao Corp)

<(c) ingredient>

(c-1)：Propylene glycol (trade name：PROPYLENE GLYCOL USP/EP (US) (BR) (TH), manufacturer：Dow Chemical Company)

(c-2)：Diethylene glycol monobutyl ether (trade name：SINOPOL BDG-LS, manufacturer：SINO-JAPAN CHEMICAL CO.,LTD.)

<(d) ingredient>

(d-1)：Polyoxyethylene addition (the average addition molal quantity 10 of EO) polyoxyethylene lauryl ether is poly- with myristyl Mixture (the trade name of ethylene oxide ether：KAO EMULGEN 110L, manufacturer：Flower king (Shanghai) Chemical Co., Ltd.)

(d-2)：Polyoxyethylene addition (the average addition molal quantity 21 of EO) polyoxyethylene lauryl ether (trade name： EMULGEN 121, manufacturer：Kao Corp)

(d-3)：Fatty monoethanol amide (coconut oleoyl amine MEA) (trade name：AMINON C-01S, manufacturer：On Seaflower king Chemical Co., Ltd.)

Table 1

Table 2

Table 3

Table 4

Table 5

Table 6

Table 7

Table 8

Table 9

From 1~table of table 9 it is found that containing (a) ingredient and (b) ingredient as essential component, and then selectively contain (c) Ingredient, and (c) ratio ((c)/((a)+(b))) and fat of the ingredient relative to (a) ingredient and total content of (b) ingredient In embodiment of the total content of surfactant other than acid in prescribed limit, liquid cleanser composition can be taken into account Foaming characteristic (foaming characteristic when hand washing washing and foaming characteristic when washing of drum type washing machine), the smearing cleaning force to cooking oil waste, drift What foam rapidly disappeared when washing is easy to be rinsability.

In turn, contain other than (d) ingredient, (a) ingredient to being also an option that property of liquid cleanser composition of the invention Thus anion surfactant, and/or (b) amphoteric surfactant other than ingredient can also realize the effect of the present invention. Containing these ingredients, preferred total content ((a)+(b)), and/or (a-3) ingredient of (a) ingredient and (b) ingredient (sodium hexadecyl sulfate) ratio ((a-3)/(a)) shared in (a) ingredient, and/or the content of (a) ingredient are relative to (a) The mass ratio ((a)/anion surfactant) of total content of anion surfactant other than ingredient and (a) ingredient, And/or (b) ingredient relative to amphoteric surfactant mass ratio ((b)/amphoteric surfactant), and/or (d) ingredient contains Measure the mass ratio ((d)/(a)), and/or (d) content of the content of ingredient relative to (b) ingredient of the content relative to (a) ingredient Mass ratio ((d)/(b)) meet particular range, thus, it is possible to obtain superior effect.

In conclusion the liquid cleanser composition of the present invention washes the smearing strong cleaning force of cooking oil waste in hand washing It washs and blisters rapidly with when washing of drum type washing machine, and can simply be rinsed in rinsing, particularly suitable as clothing with clearly Clean dose of use.

Claims

1. a kind of liquid cleanser composition, wherein

Contain following (a)~(c) ingredients：

(a) the sulfuric ester salt form anion surfactant that the following general formula (1) indicates and/or the sulfonic acid indicated with general formula (2) are used Salt form anion surfactant,

R^a-O-SO₃M (1)

R^b-SO₃M (2)

R^a、R^bSeparately indicate that carbon atom number is the saturated or unsaturated alkyl of 12~18 linear chain or branched chain, M is indicated The counter ion of forming salt and be ion in alkali metal ion, alkaline-earth metal ions, ammonium ion and alkanol ammonium ion；

R¹Indicate the saturated or unsaturated alkyl for the straight chain or branch that carbon atom number is 6~10, R²Indicate that carbon atom number is 1 ~3 alkylidene, R³、R⁴Independently of each other and indicate that carbon atom number is 1~3 alkyl or hydroxyalkyl；Or R³、R⁴Pass through Hetero atom be combined with each other and separately indicate carbon atom number be 1~3 alkylidene or hydroxyl alkylidene, X indicate selected from- Group in COO- ,-CONH- and-O-, the number that m is 0 or 1；And

(c) water Combination organic solvent,

Wherein, the mass ratio of total content of ingredient, (c)/((a)+(b)) as the content of (c) ingredient and (a) ingredient and (b) For 0.5 hereinafter, and total content of surfactant other than aliphatic acid is 2~40 mass %.

2. liquid cleanser composition according to claim 1, wherein

(a) ingredient includes sodium hexadecyl sulfate.

3. liquid cleanser composition according to claim 2, wherein

The content of sodium hexadecyl sulfate is 0.03 or more and 1 or less relative to the mass ratio of the content of (a) ingredient.

4. liquid cleanser composition according to claim 1, wherein

Further contain the anion surfactant other than (a) ingredient, also, the content of (a) ingredient relative to (a) ingredient and (a) mass ratio of total content of the anion surfactant other than ingredient is 0.2 or more.

5. liquid cleanser composition according to claim 1, wherein

Further contain the amphoteric surfactant other than (b) ingredient.

6. liquid cleanser composition according to claim 5, wherein

(b) mass ratio of the content of ingredient relative to total content of the amphoteric surfactant other than (b) ingredient and (b) ingredient It is 0.2 or more and 1 or less.

7. liquid cleanser composition according to claim 1, wherein

Further contain (d) nonionic surfactant.

8. liquid cleanser composition according to claim 7, wherein

(d) nonionic surfactant is selected from polyoxyalkylene alkyl, polyoxyalkylene alkenyl ether, alkyl polyglucoside, alkyl Glucoside, fatty acid cane sugar ester, polyglyceryl fatty acid ester, fatty monoethanol amide, fatty diglycollic amide, polyoxyethylene Rilanit special, polyoxyethylene sorbitan aliphatic ester, polyoxyethylene sorbitol aliphatic ester and alkyl carbohydrate 1 kind in surfactant or two or more.

9. liquid cleanser composition according to claim 1, wherein

R in general formula (3)¹It is the alkyl or alkenyl of the straight chain that carbon atom number is 8~10.

10. according to liquid cleanser composition according to any one of claims 1 to 9, wherein

As total content of (a) ingredient and (b) ingredient, (a)+(b) is 2~30 mass %.

11. according to liquid cleanser composition according to any one of claims 1 to 9, wherein

As total content of (a) ingredient and (b) ingredient, (a)+(b) is 2~25 mass %.