CN108341596A - A kind of high temperature resistant New Glasses Materials and preparation method thereof - Google Patents
A kind of high temperature resistant New Glasses Materials and preparation method thereof Download PDFInfo
- Publication number
- CN108341596A CN108341596A CN201810169048.3A CN201810169048A CN108341596A CN 108341596 A CN108341596 A CN 108341596A CN 201810169048 A CN201810169048 A CN 201810169048A CN 108341596 A CN108341596 A CN 108341596A
- Authority
- CN
- China
- Prior art keywords
- parts
- high temperature
- temperature resistant
- kaolinite
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/06—Other methods of shaping glass by sintering, e.g. by cold isostatic pressing of powders and subsequent sintering, by hot pressing of powders, by sintering slurries or dispersions not undergoing a liquid phase reaction
Abstract
The invention belongs to technical field of glass materials, a kind of high temperature resistant New Glasses Materials and preparation method thereof are provided, include SiO in the high temperature resistant New Glasses Materials formula that the present invention researches and develops2、V2O5、TeO2、La2O3、BaO、Er2O3、Sb2O3, sillimanite powder, mullite synthesizing powder, Kaolinite/Formamide compound, heat stabilizer ingredient, there is more excellent high temperature resistance by latter made glass material of the above-mentioned each ingredient Jing Guo certain proportioning, the crack resistance for improving glass has prevented the phenomenon that being easy to melt under hot conditions.
Description
Technical field
The invention belongs to technical field of glass materials, and in particular, to a kind of high temperature resistant New Glasses Materials and its preparation
Method.
Background technology
Glass is unformed, noncrystal homogeneous colleague material, and the primary raw material for forming glass is quartz sand, carbonic acid
Salt etc..Glass can be divided into the kinds such as simple glass, polished glass, ground glass, figured glass by surface state.Glass can be with
The product with different color and various properties is made by the techniques such as coloring, surface treatment, compound, such as heat reflection glass
Glass, vacuum glass, radium irradiation glass, hollow glass, tempered glass, wired reticulated glass, laminated glass, coloured glass, Low emissivity plating
Film glass etc..The transparency of glass is big, and translucency is strong, and with good waterproof, the performance of acid-proof and alkali prevention, and appropriateness
The property of scratch resistance.Also, the plasticity of glass is strong, and fusibleness is high, malleability is big, suitable for moulding for various moulding and skin texture, can also mix
Necessary substance makes it generate various colors.
However, the high temperature resistance of glass is not ideal enough, cracking or broken is all easy in the case of temperature jump.Cause
This, needs to research and develop a kind of high temperature resistant New Glasses Materials and preparation method thereof.
Invention content
For the defects in the prior art, the object of the present invention is to provide a kind of high temperature resistant New Glasses Materials and preparation sides
Method.
A kind of high temperature resistant New Glasses Materials provided according to an aspect of the present invention, the high temperature resistant New Glasses Materials
Include the raw material of following parts by weight：SiO222-39 parts, V2O510-20 parts, TeO2 11-12 parts, La2O3 11-13 parts, BaO
1-7 parts, Er2O33-11 parts, Sb2O35-12 parts, 3-11 parts of sillimanite powder, 11-15 parts of mullite synthesizing powder, kaolinite/
2-7 parts of formyl amine compound, 5-12 parts of heat stabilizer；
Wherein, the mass ratio of the kaolinite and formyl amine compound is 10-20:1.
Preferably, the high temperature resistant New Glasses Materials include the raw material of following parts by weight：SiO222-31 parts,
V2O512-20 parts, TeO2 11-12 parts, La2O3 11-12 parts, 1-5 parts of BaO, Er2O34-11 parts, Sb2O36-12 parts, silicon line
5-11 parts of stone powder, 11-14 parts of mullite synthesizing powder, 2-5 parts of Kaolinite/Formamide compound, 6-12 parts of heat stabilizer；
Wherein, the mass ratio of the kaolinite and formyl amine compound is 13-20:1.
Preferably, the high temperature resistant New Glasses Materials include the raw material of following parts by weight：SiO225 parts, V2O5
16 parts, TeO2 11 parts, La2O3 11 parts, 3 parts of BaO, Er2O37 parts, Sb2O38 parts, 7 parts of sillimanite powder, mullite synthesizing powder
13 parts of end, 3 parts of Kaolinite/Formamide compound, 7 parts of heat stabilizer；
Wherein, the mass ratio of the kaolinite and formyl amine compound is 17:1.
Preferably, the heat stabilizer is rare earth oxide.
Preferably, the mullite synthesizing powder is preprocessed, and preprocess method is to be heated to 1500 DEG C under normal pressure, is protected
Warm 1-2h.
Preferably, the Kaolinite/Formamide compound is that it is swollen to carry out intercalation to kaolinite using formamide as intercalator
It is swollen, it obtains.
A kind of preparation method of high temperature resistant New Glasses Materials, includes the following steps：
Step 1: weighing SiO according to parts by weight2、V2O5、TeO2 、La2O3 、BaO 、Er2O3、Sb2O3, sillimanite powder, synthesis
Mullite Powder, Kaolinite/Formamide compound, heat stabilizer；
Ball milling is carried out Step 2: each component prepared in step 1 is put into ball mill, so that dispensing is uniformly mixed, grinding rate
For 360-440r/min, milling time 35-50min；
It is put into sintering furnace Step 3: the good material of ball milling in step 2 is placed in crucible, with 4 ± 3 DEG C/min heating rates
850 ± 10 DEG C are risen to, is pre-sintered, the pre-sintering time is 35 ± 10min；
Step 4: after being pre-sintered, it is stirred in 1360 ± 20 DEG C of 40 ± 5min of heat preservation sintering, sintering process, keeps melt equal
It is even；
Water Quenching is carried out Step 5: the melt melted in step 4 is quickly poured into cold water, obtains high temperature resistant novel glass
Glass material.
Preferably, the mullite synthesizing powder grain passes through below 200 mesh.
Compared with prior art, the present invention has following advantageous effect：
1, the present invention provides a kind of high temperature resistant New Glasses Materials, is wrapped in the high temperature resistant New Glasses Materials formula that the present invention researches and develops
Containing SiO2、V2O5、TeO2 、La2O3 、BaO 、Er2O3、Sb2O3, sillimanite powder, mullite synthesizing powder, Kaolinite/Formamide
Compound, heat stabilizer ingredient are had more excellent by latter made glass material of the above-mentioned each ingredient Jing Guo certain proportioning
High temperature resistance improves the crack resistance of glass, has prevented the phenomenon that being easy to melt under hot conditions.
2, the present invention provides a kind of high temperature resistant New Glasses Materials, in glass material base in the high temperature resistant New Glasses Materials
Mullite synthesizing powder is compounded on the basis of this ingredient, mullite has the characteristics that high temperature resistant, intensity high thermal conductivity coefficient are small, will
It is used in glass material act synergistically with other compositions, greatly enhances the high temperature resistance of glass material.
3, the present invention provides a kind of high temperature resistant New Glasses Materials, be added in the high temperature resistant New Glasses Materials kaolinite/
Formyl amine compound, during preparing glass material, Kaolinite/Formamide compound is using glass melting object as basis material
It is wrapped up, and is formed on its surface one layer of fine and close protective layer, the glass material after cladding is made to keep product in the high temperature environment
Matter.
Specific implementation mode
Present invention will be further explained below with reference to specific examples.It should be understood that these embodiments are merely to illustrate the present invention
Rather than it limits the scope of the invention.
Embodiment 1
A kind of high temperature resistant New Glasses Materials provided in this embodiment, the high temperature resistant New Glasses Materials include following weight
The raw material of number：SiO239 parts, V2O510 parts, TeO2 12 parts, La2O3 11 parts, 7 parts of BaO, Er2O33 parts, Sb2O312 parts,
3 parts of sillimanite powder, 15 parts of mullite synthesizing powder, 2 parts of Kaolinite/Formamide compound, 12 parts of heat stabilizer；
Wherein, the mass ratio of the kaolinite and formyl amine compound is 20:1.
Preferably, the heat stabilizer is rare earth oxide.
Preferably, the mullite synthesizing powder is preprocessed, and preprocess method is to be heated under normal pressure
1500 DEG C, keep the temperature 2h.
Preferably, the Kaolinite/Formamide compound is inserted to kaolinite using formamide as intercalator
Layer expansion, obtains.
A kind of preparation method of high temperature resistant New Glasses Materials, includes the following steps：
Step 1: weighing SiO according to parts by weight2、V2O5、TeO2 、La2O3 、BaO 、Er2O3、Sb2O3, sillimanite powder, synthesis
Mullite Powder, Kaolinite/Formamide compound, heat stabilizer；
Ball milling is carried out Step 2: each component prepared in step 1 is put into ball mill, so that dispensing is uniformly mixed, grinding rate
For 440r/min, milling time 50min；
It is put into sintering furnace Step 3: the good material of ball milling in step 2 is placed in crucible, is risen to 7 DEG C/min heating rates
It 855 DEG C, is pre-sintered, the pre-sintering time is 37min；
Step 4: after being pre-sintered, it is stirred in 1370 DEG C of heat preservation sintering 43min, sintering process, keeps melt uniform；
Water Quenching is carried out Step 5: the melt melted in step 4 is quickly poured into cold water, obtains high temperature resistant novel glass
Glass material.
Preferably, the mullite synthesizing powder grain passes through below 200 mesh.
Embodiment 2
A kind of high temperature resistant New Glasses Materials provided in this embodiment, the high temperature resistant New Glasses Materials include following weight
The raw material of number：SiO222 parts, V2O520 parts, TeO2 11 parts, La2O3 13 parts, 1 part of BaO, Er2O311 parts, Sb2O35 parts,
11 parts of sillimanite powder, 11 parts of mullite synthesizing powder, 7 parts of Kaolinite/Formamide compound, 5 parts of heat stabilizer；
Wherein, the mass ratio of the kaolinite and formyl amine compound is 10:1.
Preferably, the heat stabilizer is rare earth oxide.
Preferably, the mullite synthesizing powder is preprocessed, and preprocess method is to be heated under normal pressure
1500 DEG C, keep the temperature 1h.
Preferably, the Kaolinite/Formamide compound is inserted to kaolinite using formamide as intercalator
Layer expansion, obtains.
A kind of preparation method of high temperature resistant New Glasses Materials, includes the following steps：
Step 1: weighing SiO according to parts by weight2、V2O5、TeO2 、La2O3 、BaO 、Er2O3、Sb2O3, sillimanite powder, synthesis
Mullite Powder, Kaolinite/Formamide compound, heat stabilizer；
Ball milling is carried out Step 2: each component prepared in step 1 is put into ball mill, so that dispensing is uniformly mixed, grinding rate
For 370r/min, milling time 39min；
It is put into sintering furnace Step 3: the good material of ball milling in step 2 is placed in crucible, is risen to 6 DEG C/min heating rates
It 860 DEG C, is pre-sintered, the pre-sintering time is 25min；
Step 4: after being pre-sintered, it is stirred in 1365 DEG C of heat preservation sintering 47min, sintering process, keeps melt uniform；
Water Quenching is carried out Step 5: the melt melted in step 4 is quickly poured into cold water, obtains high temperature resistant novel glass
Glass material.
Preferably, the mullite synthesizing powder grain passes through below 200 mesh.
Embodiment 3
A kind of high temperature resistant New Glasses Materials provided in this embodiment, the high temperature resistant New Glasses Materials include following weight
The raw material of number：SiO231 parts, V2O512 parts, TeO2 12 parts, La2O3 11 parts, 5 parts of BaO, Er2O34 parts, Sb2O312 parts,
5 parts of sillimanite powder, 14 parts of mullite synthesizing powder, 2 parts of Kaolinite/Formamide compound, 12 parts of heat stabilizer；
Wherein, the mass ratio of the kaolinite and formyl amine compound is 13:1.
Preferably, the heat stabilizer is rare earth oxide.
Preferably, the mullite synthesizing powder is preprocessed, and preprocess method is to be heated under normal pressure
1500 DEG C, keep the temperature 1h.
Preferably, the Kaolinite/Formamide compound is inserted to kaolinite using formamide as intercalator
Layer expansion, obtains.
A kind of preparation method of high temperature resistant New Glasses Materials, includes the following steps：
Step 1: weighing SiO according to parts by weight2、V2O5、TeO2 、La2O3 、BaO 、Er2O3、Sb2O3, sillimanite powder, synthesis
Mullite Powder, Kaolinite/Formamide compound, heat stabilizer；
Ball milling is carried out Step 2: each component prepared in step 1 is put into ball mill, so that dispensing is uniformly mixed, grinding rate
For 360r/min, milling time 35min；
It is put into sintering furnace Step 3: the good material of ball milling in step 2 is placed in crucible, is risen to 2 DEG C/min heating rates
It 870 DEG C, is pre-sintered, the pre-sintering time is 27min；
Step 4: after being pre-sintered, it is stirred in 1360 ± 20 DEG C of 40 ± 5min of heat preservation sintering, sintering process, keeps melt equal
It is even；
Water Quenching is carried out Step 5: the melt melted in step 4 is quickly poured into cold water, obtains high temperature resistant novel glass
Glass material.
Preferably, the mullite synthesizing powder grain passes through below 200 mesh.
Embodiment 4
A kind of high temperature resistant New Glasses Materials provided in this embodiment, the high temperature resistant New Glasses Materials include following weight
The raw material of number：SiO222 parts, V2O520 parts, TeO2 11 parts, La2O3 12 parts, 1 part of BaO, Er2O311 parts, Sb2O36 parts,
11 parts of sillimanite powder, 11 parts of mullite synthesizing powder, 5 parts of Kaolinite/Formamide compound, 6 parts of heat stabilizer；
Wherein, the mass ratio of the kaolinite and formyl amine compound is 17:1.
Preferably, the heat stabilizer is rare earth oxide.
Preferably, the mullite synthesizing powder is preprocessed, and preprocess method is to be heated under normal pressure
1500 DEG C, keep the temperature 2h.
Preferably, the Kaolinite/Formamide compound is inserted to kaolinite using formamide as intercalator
Layer expansion, obtains.
A kind of preparation method of high temperature resistant New Glasses Materials, includes the following steps：
Step 1: weighing SiO according to parts by weight2、V2O5、TeO2 、La2O3 、BaO 、Er2O3、Sb2O3, sillimanite powder, synthesis
Mullite Powder, Kaolinite/Formamide compound, heat stabilizer；
Ball milling is carried out Step 2: each component prepared in step 1 is put into ball mill, so that dispensing is uniformly mixed, grinding rate
For 390r/min, milling time 38min；
It is put into sintering furnace Step 3: the good material of ball milling in step 2 is placed in crucible, is risen to 2 DEG C/min heating rates
It 853 DEG C, is pre-sintered, the pre-sintering time is 28min；
Step 4: after being pre-sintered, it is stirred in 1363 DEG C of heat preservation sintering 42min, sintering process, keeps melt uniform；
Water Quenching is carried out Step 5: the melt melted in step 4 is quickly poured into cold water, obtains high temperature resistant novel glass
Glass material.
Preferably, the mullite synthesizing powder grain passes through below 200 mesh.
Embodiment 5
A kind of high temperature resistant New Glasses Materials provided in this embodiment, the high temperature resistant New Glasses Materials include following weight
The raw material of number：SiO225 parts, V2O516 parts, TeO2 11 parts, La2O3 11 parts, 3 parts of BaO, Er2O37 parts, Sb2O38 parts,
7 parts of sillimanite powder, 13 parts of mullite synthesizing powder, 3 parts of Kaolinite/Formamide compound, 7 parts of heat stabilizer；
Wherein, the mass ratio of the kaolinite and formyl amine compound is 17:1.
Preferably, the heat stabilizer is rare earth oxide.
Preferably, the mullite synthesizing powder is preprocessed, and preprocess method is to be heated under normal pressure
1500 DEG C, keep the temperature 2h.
Preferably, the Kaolinite/Formamide compound is inserted to kaolinite using formamide as intercalator
Layer expansion, obtains.
A kind of preparation method of high temperature resistant New Glasses Materials, includes the following steps：
Step 1: weighing SiO according to parts by weight2、V2O5、TeO2 、La2O3 、BaO 、Er2O3、Sb2O3, sillimanite powder, synthesis
Mullite Powder, Kaolinite/Formamide compound, heat stabilizer；
Ball milling is carried out Step 2: each component prepared in step 1 is put into ball mill, so that dispensing is uniformly mixed, grinding rate
For 440r/min, milling time 50min；
It is put into sintering furnace Step 3: the good material of ball milling in step 2 is placed in crucible, is risen to 4 DEG C/min heating rates
It 850 DEG C, is pre-sintered, the pre-sintering time is 35min；
Step 4: after being pre-sintered, it is stirred in 1360 DEG C of heat preservation sintering 40min, sintering process, keeps melt uniform；
Water Quenching is carried out Step 5: the melt melted in step 4 is quickly poured into cold water, obtains high temperature resistant novel glass
Glass material.
Preferably, the mullite synthesizing powder grain passes through below 200 mesh.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of high temperature resistant New Glasses Materials, it is characterised in that：The high temperature resistant New Glasses Materials include following weight
The raw material of number：SiO222-39 parts, V2O510-20 parts, TeO2 11-12 parts, La2O3 11-13 parts, 1-7 parts of BaO, Er2O3
3-11 parts, Sb2O35-12 parts, 3-11 parts of sillimanite powder, 11-15 parts of mullite synthesizing powder, Kaolinite/Formamide compound
2-7 parts, 5-12 parts of heat stabilizer；
Wherein, the mass ratio of the kaolinite and formyl amine compound is 10-20:1.
2. a kind of high temperature resistant New Glasses Materials according to claim 1, it is characterised in that：The high temperature resistant novel glass
Glass material includes the raw material of following parts by weight：SiO222-31 parts, V2O512-20 parts, TeO2 11-12 parts, La2O3 11-12
Part, 1-5 parts of BaO, Er2O34-11 parts, Sb2O36-12 parts, 5-11 parts of sillimanite powder, 11-14 parts of mullite synthesizing powder,
2-5 parts of Kaolinite/Formamide compound, 6-12 parts of heat stabilizer；
Wherein, the mass ratio of the kaolinite and formyl amine compound is 13-20:1.
3. a kind of high temperature resistant New Glasses Materials according to claim 1, it is characterised in that：The high temperature resistant novel glass
Glass material includes the raw material of following parts by weight：SiO225 parts, V2O516 parts, TeO2 11 parts, La2O3 11 parts, 3 parts of BaO,
Er2O37 parts, Sb2O38 parts, 7 parts of sillimanite powder, 13 parts of mullite synthesizing powder, 3 parts of Kaolinite/Formamide compound, heat
7 parts of stabilizer；
Wherein, the mass ratio of the kaolinite and formyl amine compound is 17:1.
4. a kind of high temperature resistant New Glasses Materials according to claim 1, it is characterised in that：The heat stabilizer is rare earth
Oxide.
5. a kind of high temperature resistant New Glasses Materials according to claim 1, it is characterised in that：The mullite synthesizing powder
Preprocessed, preprocess method is to be heated to 1500 DEG C under normal pressure, keeps the temperature 1-2h.
6. a kind of high temperature resistant New Glasses Materials according to claim 1, it is characterised in that：The Kaolinite/Formamide
Compound is to carry out intercalation expansion using formamide as intercalator to kaolinite, obtain.
7. a kind of preparation method of high temperature resistant New Glasses Materials as claimed in any one of claims 1 to 6, it is characterised in that：Packet
Include following steps：
Step 1: weighing SiO according to parts by weight2 、V2O5 、TeO2 、La2O3 、BaO 、Er2O3 、Sb2O3, sillimanite powder,
Mullite synthesizing powder, Kaolinite/Formamide compound, heat stabilizer；
Ball milling is carried out Step 2: each component prepared in step 1 is put into ball mill, so that dispensing is uniformly mixed, grinding rate
For 360-440r/min, milling time 35-50min；
It is put into sintering furnace Step 3: the good material of ball milling in step 2 is placed in crucible, with 4 ± 3 DEG C/min heating rates
850 ± 10 DEG C are risen to, is pre-sintered, the pre-sintering time is 35 ± 10min；
Step 4: after being pre-sintered, it is stirred in 1360 ± 20 DEG C of 40 ± 5min of heat preservation sintering, sintering process, keeps melt equal
It is even；
Water Quenching is carried out Step 5: the melt melted in step 4 is quickly poured into cold water, obtains high temperature resistant novel glass
Glass material.
8. a kind of preparation method of high temperature resistant New Glasses Materials according to claim 7, it is characterised in that：The synthesis
Mullite Powder grain passes through below 200 mesh.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810169048.3A CN108341596A (en) | 2018-03-01 | 2018-03-01 | A kind of high temperature resistant New Glasses Materials and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810169048.3A CN108341596A (en) | 2018-03-01 | 2018-03-01 | A kind of high temperature resistant New Glasses Materials and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108341596A true CN108341596A (en) | 2018-07-31 |
Family
ID=62959539
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810169048.3A Withdrawn CN108341596A (en) | 2018-03-01 | 2018-03-01 | A kind of high temperature resistant New Glasses Materials and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108341596A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113233760A (en) * | 2021-06-21 | 2021-08-10 | 新华农大(武汉)科技有限公司 | Glass net for making tea and preparation method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102276150A (en) * | 2011-06-02 | 2011-12-14 | 重庆仪表材料研究所 | High-temperature and high-pressure resistant glass material for sealing and preparation method thereof |
| CN103482639A (en) * | 2013-09-27 | 2014-01-01 | 中国矿业大学(北京) | Preparation method of kaolinite/quaternary ammonium salt intercalation compound |
| CN104743875A (en) * | 2015-03-05 | 2015-07-01 | 苏州经贸职业技术学院 | Impact-resistant glass material and preparation method thereof |
| CN104876604A (en) * | 2015-05-29 | 2015-09-02 | 柳州普亚贸易有限公司 | Brick resistant to abrasion and corrosion |
-
2018
- 2018-03-01 CN CN201810169048.3A patent/CN108341596A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102276150A (en) * | 2011-06-02 | 2011-12-14 | 重庆仪表材料研究所 | High-temperature and high-pressure resistant glass material for sealing and preparation method thereof |
| CN103482639A (en) * | 2013-09-27 | 2014-01-01 | 中国矿业大学(北京) | Preparation method of kaolinite/quaternary ammonium salt intercalation compound |
| CN104743875A (en) * | 2015-03-05 | 2015-07-01 | 苏州经贸职业技术学院 | Impact-resistant glass material and preparation method thereof |
| CN104876604A (en) * | 2015-05-29 | 2015-09-02 | 柳州普亚贸易有限公司 | Brick resistant to abrasion and corrosion |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113233760A (en) * | 2021-06-21 | 2021-08-10 | 新华农大(武汉)科技有限公司 | Glass net for making tea and preparation method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2707527B2 (en) | Lead-free glass frit composition and method for preparing the same | |
| CN106336116B (en) | A kind of ceramic glaze and preparation method thereof, the method for utilizing its production ceramics | |
| JPH05208846A (en) | Colored glass-ceramic article with surface pattern and its production | |
| CN104529548A (en) | Red-spot crystalline glaze and preparation method of ceramic adopting same | |
| CN106977098B (en) | A kind of low-temperature lead-free colored glaze | |
| CN105347685A (en) | Glass ceramic and preparation method thereof | |
| CN106542737B (en) | A kind of glaze compositions and its method for cooking | |
| CN108793747A (en) | The preparation method of bluish yellow cladding furnace transmutation glaze product on a kind of pottery tire | |
| CN108341596A (en) | A kind of high temperature resistant New Glasses Materials and preparation method thereof | |
| CN104973782A (en) | Frosted glass production process | |
| CN108863304B (en) | Ceramic blank, ceramic vessel and preparation method thereof | |
| CN104591793B (en) | A kind of colored Pengyang china stone and preparation method thereof | |
| KR101911408B1 (en) | Manufacturing method of enamel product | |
| CN107043214A (en) | Brownish black floor iron red colored crystalline point ceramic glaze and the method using its preparation ceramics | |
| CN107382281A (en) | A kind of burning process of emerald green stove an ancient unit of weight | |
| CN110713345B (en) | Enamel color material, preparation method and application in repairing enamel cultural relics painted on porcelain body | |
| JP3088074B2 (en) | Manufacturing method of paint for ceramics | |
| US2063252A (en) | Vitreous enamel and method of making same | |
| CN107673609A (en) | A kind of mint flavored fluorescence coloured glaze | |
| JPS6224365B2 (en) | ||
| CN107285607B (en) | Preparation process of crackle colored glaze product | |
| US3859102A (en) | Frit compositions and glaze and flux compositions obtained therefrom | |
| CN107673599A (en) | It is a kind of lead-free gluzed | |
| JPH03215328A (en) | Enamel color for pottery and its production | |
| CN111470754B (en) | Method for calendering and coloring microcrystalline glass and product processing technology thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180731 |
|
| WW01 | Invention patent application withdrawn after publication |