CN108336178A - A kind of silicon/crystalline silicon heterojunction double-side solar cell structure - Google Patents

A kind of silicon/crystalline silicon heterojunction double-side solar cell structure Download PDF

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Publication number
CN108336178A
CN108336178A CN201810198908.6A CN201810198908A CN108336178A CN 108336178 A CN108336178 A CN 108336178A CN 201810198908 A CN201810198908 A CN 201810198908A CN 108336178 A CN108336178 A CN 108336178A
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silicon
layer
solar cell
passivation
crystalline silicon
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袁吉仁
周浪
黄海宾
高超
岳之浩
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Nanchang University
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Nanchang University
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/06Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers
    • H01L31/072Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers the potential barriers being only of the PN heterojunction type
    • H01L31/0745Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers the potential barriers being only of the PN heterojunction type comprising a AIVBIV heterojunction, e.g. Si/Ge, SiGe/Si or Si/SiC solar cells
    • H01L31/0747Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers the potential barriers being only of the PN heterojunction type comprising a AIVBIV heterojunction, e.g. Si/Ge, SiGe/Si or Si/SiC solar cells comprising a heterojunction of crystalline and amorphous materials, e.g. heterojunction with intrinsic thin layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Energy (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Photovoltaic Devices (AREA)

Abstract

A kind of silicon/crystalline silicon heterojunction double-side solar cell structure, using N-shaped crystal silicon chip as substrate, transmitting pole-face is divided into emitter conductive region and passivation entering light region:The former is made of intrinsic amorphous silicon passivation layer, heavily-doped p-type amorphous silicon layer, metal grid lines I, and the latter is penetrated a layer I and constituted by heavily-doped p-type crystalline silicon field passivation layer I, passivated reflection reducing;Back of the body electric field surface is divided into passivation entering light region and back of the body electric field conductive region:The former is penetrated a layer II and is constituted by highly doped n-type crystal silicon layer II, passivated reflection reducing;The latter is made of highly doped n-type crystal silicon layer II, metal grid lines II.The present invention maintains characteristic that is two-sided into light characteristic, while obtaining high open circuit voltage and high short circuit current, improves the generating capacity of crystal-silicon solar cell.The use of valuable transparent conductive oxide is avoided completely compared to HIT and HAC D structures, while being reduced carrier and being transmitted caused series resistance losses on TCO.

Description

A kind of silicon/crystalline silicon heterojunction double-side solar cell structure
Technical field
The invention belongs to solar cells and field of semiconductor devices.It is related to the technology of preparing of solar cell.
Background technology
For ground solar cell, the structure actual power generation of two-sided entering light is higher than the single side entering light of same nominal power The understanding of solar cell is generally received by industry.The two-sided entering light solar cell of mainstream is with N-shaped crystal silicon chip at present For substrate.One is the n-PERT structures based on pn homogeneity junction structures, feature is that short circuit current is big, and open-circuit voltage is low;It is another Class is so that based on pn heterojunction structures, using HIT structures as representative, feature is that short circuit current is small, and open-circuit voltage is high.How to improve The former open-circuit voltage and the short circuit current for improving the latter are always difficult point in the industry, and the direction made great efforts.As can in conjunction with two The characteristics of person, invents a kind of new structure, while the advantages of obtain high short circuit current, high open circuit voltage, is expected to further increase The performance of two-sided crystal-silicon solar cell.The pervious invention of University Of Nanchang is in the progress that this side up(Middle promulgated by the State Council Bright patent, No. 201510776929.8), structure is known as HAC-D structures, means that the structure combines HAC (heterojunction of amorphous silicon and crystalline silicon)Hetero-junctions and diffusion are standby Homojunction (Diffused homojunction of crystalline silicon)).It can get compared to HIT structures Higher short circuit current, and the characteristics of certifiable HIT structure high open circuit voltages.But the structure still makes progress space, and the present invention is just It is to be further improved to HAC-D structures.Compared to the electric current and open circuit electricity that HAC-D structures can further improve solar cell Pressure reduces series resistance, and reduces valuable transparent conductive oxide(TCO)Dosage.
Invention content
The main object of the present invention is to propose a kind of silicon/crystalline silicon heterojunction double-side solar cell structure, short in conjunction with pn homojunction height The advantages of road electric current and pn hetero-junctions high open circuit voltages, reasonable disposition device is constituted, to further increase the two-sided sun of crystalline silicon The generating efficiency of battery reduces the consumption of valuable raw material.
The present invention is achieved by the following technical solutions.
A kind of silicon/crystalline silicon heterojunction double-side solar cell structure of the present invention, with N-shaped crystal silicon chip(6)As substrate, It emits pole-face and is divided into emitter-conductive region and passivation-entering light region:Emitter-conductive region by substrate outward successively by Intrinsic amorphous silicon passivation layer(3), heavily-doped p-type amorphous silicon layer(2), metal grid lines I(1)It constitutes, passivation-entering light region is by substrate Outward successively by heavily-doped p-type crystalline silicon field passivation layer I(5), passivated reflection reducing penetrate a layer I(4)It constitutes.The two region cross-distributions And it is not overlapped.
To improve metal grid lines I(1)With heavily-doped p-type amorphous silicon layer(2)Between contact electric conductivity, preferably the two it Between be inserted into a transition tco layer.
Passivated reflection reducing of the present invention penetrates a layer I(4)It is preferred that silicon nitride.
Emitter of the present invention and heavily-doped p-type crystalline silicon field passivation layer I(5)Between preferably carry out insulation processing.
Further, it is the performance of raising device, the heavily-doped p-type crystalline silicon field passivation layer I(5)Thickness it is preferred 1-300nm。
A kind of back of the body electric field surface structure of silicon/crystalline silicon heterojunction double-side solar cell structure of the present invention:Be divided into passivation-into Light region and back of the body electric field-conductive region:Passivation-entering light region is followed successively by highly doped n-type crystal silicon layer II by substrate outward(7)、 Passivated reflection reducing penetrates a layer II(8);Back of the body electric field-conductive region is followed successively by highly doped n-type crystal silicon layer II by substrate outward(7), metal Grid line II(9).It the two region cross-distributions and is not overlapped.
Wherein, passivated reflection reducing penetrates a layer II(8)It is preferred that silicon nitride.
Further, it is the performance of raising device, N-shaped crystal silicon chip of the present invention(6)Can with two-sided making herbs into wool, with into One step improves solar cell short circuit current.
Further, N-shaped crystal silicon chip(6)Two-sided making herbs into wool situation can be different, use reduced size gold word on one side The matte of tower structure, in addition one side is using the pyramid matte of large-size or without pyramidal polishing structure.
Further, there are metal grid lines(Metal grid lines I, metal grid lines II)Region can polish or do larger size gold word The matte of tower improves the open-circuit voltage of solar cell to reduce recombination loss.
Further, device surface metal grid lines(Metal grid lines I, metal grid lines II)Total area coverage ratio is preferably 1 ~ 3%, to improve the short circuit current of solar cell and ensure electric conductivity good enough.
Invention has the technical effect that:Under the premise of keeping the characteristic of the two-sided entering light of crystal-silicon solar cell, while obtaining height The characteristic of open-circuit voltage and high short circuit current improves the generating capacity of crystal-silicon solar cell to the greatest extent.Its mechanism is logical The amorphous silicon emitter and supporting structure crossed under metal grid lines area coverage obtain high open-circuit voltage, in not metal grid lines Place is using the structure of heavily-doped p-type crystalline silicon mating surface antireflective passivation layer compared to conventional non-crystalline silicon/silicon/crystalline silicon heterogenous Connection solar cell can reduce shading loss, the sunlight of more incidences is efficiently translated into photo-generated carrier, and can reduce photoproduction Lateral transport recombination loss of the carrier in silicon chip surface region.In transmitting pole-face, the photohole of generation is in highly doped n-type layer Enter inside body silicon under the promotion of the built in field of formation, then concentrate and flow to emitter region, forms the similar optically focused sun The high current effect of battery, can further improve the Built-in potential of solar cell, to further increase the voltage of solar cell; And the electronics generated can only flow to the metal electricity of the other one side of silicon chip because the highly doped n-type region of transmitting pole-face does not have electrode Pole is collected.In addition, the present invention can completely avoid valuable electrically conducting transparent oxygen compared to HIT structures and HAC-D structures The use of compound, while carrier can be decreased and transmit caused series resistance losses on TCO.
Description of the drawings
Attached Fig. 1 the structural representation of present invention.Wherein:1 is metal grid lines I;2 be heavily-doped p-type amorphous silicon layer;3 be this Levy amorphous silicon passivation layer;4 penetrate a layer I for passivated reflection reducing;5 attach most importance to doped p-type crystalline silicon field passivation layer I;6 be N-shaped crystal silicon chip;7 For highly doped n-type crystal silicon layer II;8 penetrate a layer II for passivated reflection reducing;9 be metal grid lines II.
Specific implementation mode
The present invention will be described further by following embodiment.
Embodiment 1.
A kind of silicon/crystalline silicon heterojunction double-side solar cell structure as shown in Fig. 1.The two-sided of N-shaped crystal silicon chip 6 is all made of The thickness of average ~ 2 microns of pyramid structure matte, heavily-doped p-type crystalline silicon field passivation layer I 5 is 10nm, and highly doped n-type is brilliant 7 thickness of body silicon layer II is 200nm, and passivated reflection reducing penetrates layer I 4 and passivated reflection reducing penetrates layer II 8 and is all made of silicon nitride film, metal Grid line I 1 and metal grid lines II 9 is all made of the Ag grid line structures of primary and secondary gratings cooperation, and masked area is the 3% of silicon chip surface product.It should Structure is two-sided very excellent into light characteristic, i.e., any one side can be used as main into smooth surface.Such as it is used as single side entering light solar cell It uses, then can plate one layer of metal as reflective layer in shady face, increase the short circuit current as single side entering light solar cell.
Two surfaces of the structure it is very excellent into light characteristic, can be used as main into smooth surface.Such as it is used as single side entering light Solar cell uses, then can plate one layer of metal as reflective layer in shady face, increase the short circuit as single side entering light solar cell Electric current.
Embodiment 2.
A kind of crystal-silicon solar cell of two-sided HAC-D structures as shown in Fig. 1.The two-sided of N-shaped crystal silicon chip 6 is adopted Thickness with average ~ 1 micron of pyramid structure matte, heavily-doped p-type crystalline silicon field passivation layer I 5 is 100nm, heavy doping n 7 thickness of type crystal silicon layer II is 300nm, and passivated reflection reducing penetrates layer I 4 and passivated reflection reducing penetrates layer II 8 and is all made of silica (10nm)/ silicon nitride(80nm)Laminated film, metal grid lines I 1 and metal grid lines II 9 are all made of the Ag grid lines of primary and secondary gratings cooperation Structure, masked area are the 3% of silicon chip surface product.The structure is two-sided very excellent into light characteristic, i.e., any one side can be used as It leads into smooth surface.It is such as used as single side entering light solar cell, then can plate one layer of metal as reflective layer in shady face, increase conduct The short circuit current of single side entering light sun solar cell.
Two surfaces of the structure it is very excellent into light characteristic, can be used as main into smooth surface.Such as it is used as single side entering light Solar cell uses, then can plate one layer of metal as reflective layer in shady face, increase as single side entering light sun solar cell Short circuit current.
Embodiment 3.
A kind of crystal-silicon solar cell of two-sided HAC-D structures as shown in Fig. 1.The two-sided of N-shaped crystal silicon chip 6 is adopted With average ~ 1 micron of pyramid structure matte, but chemical polishing structure is used in the region that metal grid lines cover.Heavily-doped p-type The thickness of crystalline silicon field passivation layer I 5 is 50nm, and 7 thickness of highly doped n-type crystal silicon layer II is 150nm, and passivated reflection reducing penetrates a layer I 4 and passivated reflection reducing penetrate layer II 8 and be all made of aluminium oxide(20nm)/ silicon nitride(80nm)Laminated film, metal grid lines I 1 and metal Grid line II 9 is all made of the Ag grid line structures of primary and secondary gratings cooperation, and masked area is the 1.5% of silicon chip surface product.The structure it is two-sided into Light characteristic is very excellent, i.e., any one side can be used as main into smooth surface.Such as used as single side entering light solar cell, then it can be Shady face plates one layer of metal as reflective layer, increases the short circuit current as single side entering light sun solar cell.
Two surfaces of the structure it is very excellent into light characteristic, can be used as main into smooth surface.Such as it is used as single side entering light Solar cell uses, then can plate one layer of metal as reflective layer in shady face, increase as single side entering light sun solar cell Short circuit current.
Embodiment 4.
A kind of crystal-silicon solar cell of two-sided HAC-D structures as shown in Fig. 1.The two-sided of N-shaped crystal silicon chip 6 is adopted Thickness with average ~ 2 microns of pyramid structure matte, heavily-doped p-type crystalline silicon field passivation layer I 5 is 10nm, highly doped n-type 7 thickness of crystal silicon layer II is 200nm, and passivated reflection reducing penetrates layer I 4 and passivated reflection reducing penetrates layer II 8 and is all made of silicon nitride film, gold Belong to the Ag grid line structures that grid line I 1 and metal grid lines II 9 is all made of primary and secondary gratings cooperation, masked area is the 3% of silicon chip surface product. There is the ITO of one layer of 10nm between metal grid lines I1 and heavily-doped p-type amorphous silicon layer 2.The structure it is two-sided into light characteristic very Excellent, i.e., any one side can be used as main into smooth surface.It is such as used as single side entering light solar cell, then can plate one layer in shady face Metal increases the short circuit current as single side entering light sun solar cell as reflective layer.
Two surfaces of the structure it is very excellent into light characteristic, can be used as main into smooth surface.Such as it is used as single side entering light Solar cell uses, then can plate one layer of metal as reflective layer in shady face, increase as single side entering light sun solar cell Short circuit current.

Claims (10)

1. a kind of silicon/crystalline silicon heterojunction double-side solar cell structure, it is characterized in that with N-shaped crystal silicon chip(6)As substrate, transmitting Pole-face is divided into emitter-conductive region and passivation-entering light region:Emitter-conductive region is by substrate outward successively by intrinsic non- Crystal silicon passivation layer(3), heavily-doped p-type amorphous silicon layer(2), metal grid lines I(1)Constitute, passivation-entering light region by substrate outward according to It is secondary by heavily-doped p-type crystalline silicon field passivation layer I(5), passivated reflection reducing penetrate a layer I(4)It constitutes, the two region cross-distributions and does not weigh It is folded;
It carries on the back electric field surface structure:It is divided into passivation-entering light region and back of the body electric field-conductive region:Passivation-entering light region is outside by substrate It is followed successively by highly doped n-type crystal silicon layer II(7), passivated reflection reducing penetrate a layer II(8);Electric field-conductive region is carried on the back by substrate outward successively For highly doped n-type crystal silicon layer II(7), metal grid lines II(9), the two region cross-distributions and it is not overlapped.
2. a kind of silicon/crystalline silicon heterojunction double-side solar cell structure according to claim 1, it is characterized in that metal grid lines I(1) With heavily-doped p-type amorphous silicon layer(2)Between be inserted into a transition tco layer.
3. a kind of silicon/crystalline silicon heterojunction double-side solar cell structure according to claim 1, it is characterized in that the passivation subtracts Reflecting layer I(4)For silicon nitride.
4. a kind of silicon/crystalline silicon heterojunction double-side solar cell structure according to claim 1, it is characterized in that the emitter With heavily-doped p-type crystalline silicon field passivation layer I(5)Between carry out insulation processing.
5. a kind of silicon/crystalline silicon heterojunction double-side solar cell structure according to claim 1, it is characterized in that the heavy doping p Type crystalline silicon field passivation layer I(5)Thickness be 1-300nm.
6. a kind of silicon/crystalline silicon heterojunction double-side solar cell structure according to claim 1, it is characterized in that the passivation subtracts Reflecting layer II(8)For silicon nitride.
7. a kind of silicon/crystalline silicon heterojunction double-side solar cell structure according to claim 1, it is characterized in that the N-shaped crystal Silicon chip(6)For two-sided making herbs into wool.
8. a kind of silicon/crystalline silicon heterojunction double-side solar cell structure according to claim 1, it is characterized in that N-shaped crystal silicon chip (6)Two-sided making herbs into wool situation:The matte of small size pyramid structure is used on one side, and in addition one side uses large-sized pyramid Matte or without pyramidal polishing structure.
9. a kind of silicon/crystalline silicon heterojunction double-side solar cell structure according to claim 1, it is characterized in that there is metal grid lines area Domain polishes or does the pyramidal matte of large scale.
10. a kind of silicon/crystalline silicon heterojunction double-side solar cell structure according to claim 1, it is characterized in that device surface metal The total area coverage ratio of grid line is preferably 1 ~ 3%.
CN201810198908.6A 2018-03-12 2018-03-12 A kind of silicon/crystalline silicon heterojunction double-side solar cell structure Pending CN108336178A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111326606A (en) * 2020-03-11 2020-06-23 苏州光汇新能源科技有限公司 N-type slicing solar cell structure and manufacturing method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101562207A (en) * 2008-04-14 2009-10-21 黄麟 Crystalline silicon solar battery
CN102169923A (en) * 2011-03-05 2011-08-31 常州天合光能有限公司 Method for passivating P-type doping layer of N-type silicon solar cell and cell structure
CN102437243A (en) * 2011-12-08 2012-05-02 常州天合光能有限公司 Heterojunction with intrinsic thin layer (HIT) solar cell structure with heterogeneous floating junction back passivation, and preparation process thereof
CN104412394A (en) * 2012-06-29 2015-03-11 洛桑联邦理工学院 Solar cell
CN105322043A (en) * 2015-11-16 2016-02-10 南昌大学 Crystalline silicon solar cell capable of realizing double-side light entrance and preparation method therefor
CN105810771A (en) * 2016-05-12 2016-07-27 南昌大学 Back crystal silicon heterojunction two-sided solar cell and preparation method therefor

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101562207A (en) * 2008-04-14 2009-10-21 黄麟 Crystalline silicon solar battery
CN102169923A (en) * 2011-03-05 2011-08-31 常州天合光能有限公司 Method for passivating P-type doping layer of N-type silicon solar cell and cell structure
CN102437243A (en) * 2011-12-08 2012-05-02 常州天合光能有限公司 Heterojunction with intrinsic thin layer (HIT) solar cell structure with heterogeneous floating junction back passivation, and preparation process thereof
CN104412394A (en) * 2012-06-29 2015-03-11 洛桑联邦理工学院 Solar cell
CN105322043A (en) * 2015-11-16 2016-02-10 南昌大学 Crystalline silicon solar cell capable of realizing double-side light entrance and preparation method therefor
CN105810771A (en) * 2016-05-12 2016-07-27 南昌大学 Back crystal silicon heterojunction two-sided solar cell and preparation method therefor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111326606A (en) * 2020-03-11 2020-06-23 苏州光汇新能源科技有限公司 N-type slicing solar cell structure and manufacturing method thereof

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