CN108329801A - A kind of environment protection integrated waterproof coating and preparation method thereof - Google Patents

A kind of environment protection integrated waterproof coating and preparation method thereof Download PDF

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Publication number
CN108329801A
CN108329801A CN201810169431.9A CN201810169431A CN108329801A CN 108329801 A CN108329801 A CN 108329801A CN 201810169431 A CN201810169431 A CN 201810169431A CN 108329801 A CN108329801 A CN 108329801A
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Prior art keywords
parts
environment protection
waterproof coating
protection integrated
integrated waterproof
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CN201810169431.9A
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CN108329801B (en
Inventor
马增利
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Guangzhou Jannock Shi Decoration Engineering Co Ltd
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Guangzhou Jannock Shi Decoration Engineering Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a kind of environment protection integrated waterproof coatings and preparation method thereof, are composed of the following parts by weight parts:60 70 parts of modified epoxies, 13 parts of wetting agents, 12 parts of dispersants, 36 parts of lubricants, 8 10 parts of cross-linked modifiers, 13 parts of fillers, 24 parts of fire retardants, 15 parts of inorganic nano materials, 29 parts of nano silicon dioxides, 0.5 3.5 parts of mica powders, 16 parts of hydroxyethyl celluloses, 12 parts of ultra-violet absorbers, 0.1 0.2 parts of antiseptics.Service life of the present invention is long, and the raw materials for production selected are environment-friendly type, produce and work progress in, it is pollution-free finally so that product is more environmentally-friendly, while there is good physics, chemical property, good water-proof effect, it is ageing-resistant, there is strength antibacterial effect.

Description

A kind of environment protection integrated waterproof coating and preparation method thereof
Technical field
The present invention relates to a kind of technical field of coating, especially a kind of environment protection integrated waterproof coating and its preparation side Method.
Background technology
Coating (coating) is that coating once applies obtained solid-state continuous film, is the insulation in order to protect, decoration etc. Purpose, is coated on metal, fabric, the plastic sheet on the matrixes such as plastics.Coating can be gaseous state, liquid, solid-state, generally according to The matrix sprayed is needed to determine the type and state of coating.Higher and higher with national requirements for environmental protection simultaneously, environmental protection equipment exists Compare in adverse circumstances and use, can be entered by water in usual shell and finally be corroded, therefore in order to solve this problem, existing skill In art housing outer surface one layer of protective coating would generally be smeared to protect shell, this coating often to cannot be satisfied environmentally friendly and comprehensive again The requirement of performance is closed, the antiseptic property of equipment is poor, and the wear-resisting property of coating and water resistance etc. are not good enough, and equipment is caused to use Short life, of high cost etc., thus need to improve.
Invention content
The purpose of the present invention is to provide a kind of environment protection integrated waterproof coatings and preparation method thereof, it can effectively be solved Certainly the problem of background technology.
To achieve the above object, the present invention provides the following technical solutions:A kind of environment protection integrated waterproof coating, by following The composition of parts by weight forms:60-70 parts of modified epoxies, 1-3 parts of wetting agents, 1-2 parts of dispersants, 3-6 parts of lubricants, 8- 10 parts of cross-linked modifiers, 1-3 parts of fillers, 2-4 parts of fire retardants, 1-5 parts of inorganic nano materials, 2-9 parts of nano silicon dioxides, 0.5-3.5 parts of mica powders, 1-6 parts of hydroxyethyl celluloses, 1-2 parts of ultra-violet absorbers, 0.1-0.2 parts of antiseptics.
Further, it is composed of the following parts by weight parts:65-70 parts of modified epoxies, 2-3 parts of wetting agents, 1-2 parts Dispersant, 3-6 parts of lubricants, 9-10 parts of cross-linked modifiers, 2-3 parts of fillers, 3-4 parts of fire retardants, 1-5 parts of nanometer titanium dioxides Titanium, 3-9 parts of nano silicon dioxides, 2-3.5 parts of mica powders, 3-6 parts of hydroxyethyl celluloses, 1-2 parts of ultra-violet absorbers, 0.1- 0.2 part of antiseptic.
Further, further include being composed of the following parts by weight parts:3-5 parts of glass powders.
Further, the modified epoxy is the content by following components and mass fraction:90-100 parts of modified bisphenol As Type epoxy resin, 0-10 parts of quartz sands.
Further, the inorganic nano material is nano-titanium dioxide, nano silicon-based oxide, graphene, nanometer aluminium base One or more compoundings in oxide, simple particle size range 20-60nm.
The invention also discloses a kind of preparation methods of environment protection integrated waterproof coating, specifically include following steps:
(1) raw material is weighed according to formula, by inorganic nano material grinding distribution;
(2) step 1 is obtained product and modified epoxy mixing, be added wetting agent, dispersant, cross-linked modifier, Filler, fire retardant, nano silicon dioxide, mica powder, hydroxyethyl cellulose, ultra-violet absorber are uniformly mixed;
(3) antiseptic, lubricant are added in step 2, is uniformly mixed and obtains product.
Compared with prior art, the beneficial effects of the invention are as follows:Long product lifecycle, and the raw materials for production selected are Environment-friendly type, it is pollution-free finally to make product more environmentally-friendly in production and work progress, while there is good physics, chemistry Performance, good water-proof effect, it is ageing-resistant, have strength antibacterial effect.
Specific implementation mode
With reference to the present embodiment, the invention will be further described.
Embodiment one:
A kind of environment protection integrated waterproof coating provided in this embodiment, is composed of the following parts by weight parts:60-70 Part modified epoxy, 1-3 parts of wetting agents, 1-2 parts of dispersants, 3-6 parts of lubricants, 8-10 parts of cross-linked modifiers, 1-3 parts of fillings Agent, 2-4 parts of fire retardants, 1-5 parts of inorganic nano materials, 2-9 parts of nano silicon dioxides, 0.5-3.5 parts of mica powders, 1-6 parts of hydroxyl second Base cellulose, 1-2 parts of ultra-violet absorbers, 0.1-0.2 parts of antiseptics.
Further, which is composed of the following parts by weight parts:60 parts of modified epoxies, 3 parts of wetting agents, 1 part Dispersant, 6 parts of lubricants, 8 parts of cross-linked modifiers, 2 parts of fillers, 2 parts of fire retardants, 5 parts of nano-titanium dioxides, 9 parts of nanometers two Silica, 0.8 part of mica powder, 1 part of hydroxyethyl cellulose, 2 parts of ultra-violet absorbers, 0.2 part of antiseptic.
Further, the modified epoxy is the content by following components and mass fraction:90-100 parts of modified bisphenol As Type epoxy resin, 0-10 parts of quartz sands.The modified epoxy is by following components and mass fraction in the present embodiment Content:90 parts of modified bisphenol A type epoxy resin, 10 parts of quartz sands.
Further, the inorganic nano material is nano-titanium dioxide, nano silicon-based oxide, graphene, nanometer aluminium base One or more compoundings in oxide, simple particle size range 20-60nm.It is to receive to state inorganic nano material in the present embodiment The compounding of rice titanium dioxide, nano silicon-based oxide, graphene, simple particle size range 20nm.
The present embodiment also discloses a kind of preparation method of environment protection integrated waterproof coating, specifically includes following step Suddenly:
(1) raw material is weighed according to formula, by inorganic nano material grinding distribution;
(2) step 1 is obtained product and modified epoxy mixing, be added wetting agent, dispersant, cross-linked modifier, Filler, fire retardant, nano silicon dioxide, mica powder, hydroxyethyl cellulose, ultra-violet absorber are uniformly mixed;
(3) antiseptic, lubricant are added in step 2, is uniformly mixed and obtains product.
The beneficial effects of the invention are as follows:Long product lifecycle, and select raw materials for production be environment-friendly type, production and It is pollution-free finally to make product more environmentally-friendly in work progress, while there is good physics, chemical property, good water-proof effect, It is ageing-resistant, have strength antibacterial effect.
Embodiment two:
A kind of environment protection integrated waterproof coating provided in this embodiment, the coating by following parts by weight composition group At:61 parts of modified epoxies, 3 parts of wetting agents, 1 part of dispersant, 5 parts of lubricants, 8 parts of cross-linked modifiers, 2 parts of fillers, 2 parts Fire retardant, 4 parts of nano-titanium dioxides, 8 parts of nano silicon dioxides, 1.8 parts of mica powders, 2 parts of hydroxyethyl celluloses, 2 parts of ultraviolet lights Absorbent, 0.2 part of antiseptic.
Further, the modified epoxy is the content by following components and mass fraction:91 parts of modified bisphenol A type rings Oxygen resin, 9 parts of quartz sands.
Further, the inorganic nano material is nano silicon-based oxide, simple particle size range 50nm.
The invention also discloses a kind of preparation methods of environment protection integrated waterproof coating, specifically include following steps:
(4) raw material is weighed according to formula, by inorganic nano material grinding distribution;
(5) step 1 is obtained product and modified epoxy mixing, be added wetting agent, dispersant, cross-linked modifier, Filler, fire retardant, nano silicon dioxide, mica powder, hydroxyethyl cellulose, ultra-violet absorber are uniformly mixed;
(6) antiseptic, lubricant are added in step 2, is uniformly mixed and obtains product.
Embodiment three:
A kind of environment protection integrated waterproof coating provided in this embodiment, is composed of the following parts by weight parts:62 parts Modified epoxy, 2 parts of wetting agents, 2 parts of dispersants, 4 parts of lubricants, 9 parts of cross-linked modifiers, 1 part of filler, 3 parts of fire retardants, 2 parts of nano-titanium dioxides, 7 parts of nano silicon dioxides, 2.8 parts of mica powders, 2.9 parts of hydroxyethyl celluloses, 1 part of ultraviolet radiation absorption Agent, 0.1 part of antiseptic.
Further, the modified epoxy is the content by following components and mass fraction:100 parts of modified bisphenol A types Epoxy resin, 0 part of quartz sand.
Further, the inorganic nano material is the compounding of graphene, nano aluminum base oxide, simple particle size range 60nm。
The invention also discloses a kind of preparation methods of environment protection integrated waterproof coating, specifically include following steps:
(1) raw material is weighed according to formula, by inorganic nano material grinding distribution;
(2) step 1 is obtained product and modified epoxy mixing, be added wetting agent, dispersant, cross-linked modifier, Filler, fire retardant, nano silicon dioxide, mica powder, hydroxyethyl cellulose, ultra-violet absorber are uniformly mixed;
(3) antiseptic, lubricant are added in step 2, is uniformly mixed and obtains product.
The beneficial effects of the invention are as follows:Long product lifecycle, and select raw materials for production be environment-friendly type, production and It is pollution-free finally to make product more environmentally-friendly in work progress, while there is good physics, chemical property, good water-proof effect, It is ageing-resistant, have strength antibacterial effect.
Example IV:
A kind of environment protection integrated waterproof coating provided in this embodiment, is composed of the following parts by weight parts:65-70 Part modified epoxy, 2-3 parts of wetting agents, 1-2 parts of dispersants, 3-6 parts of lubricants, 9-10 parts of cross-linked modifiers, 2-3 parts of fillings Agent, 3-4 parts of fire retardants, 1-5 parts of nano-titanium dioxides, 3-9 parts of nano silicon dioxides, 2-3.5 parts of mica powders, 3-6 parts of ethoxys Cellulose, 1-2 parts of ultra-violet absorbers, 0.1-0.2 parts of antiseptics;3-5 parts of glass powders.
The coating includes in the present embodiment:It is composed of the following parts by weight parts:65 parts of modified epoxies, 2 parts Wetting agent, 2 parts of dispersants, 4 parts of lubricants, 9 parts of cross-linked modifiers, 2 parts of fillers, 3 parts of fire retardants, 1 part of nano-titanium dioxide, 4 parts of nano silicon dioxides, 3.5 parts of mica powders, 3 parts of hydroxyethyl celluloses, 1 part of ultra-violet absorber, 0.1 part of antiseptic;3 parts of glass Glass powder.
Further, the modified epoxy is the content by following components and mass fraction:96 parts of modified bisphenol A type rings Oxygen resin, 4 parts of quartz sands.
Further, the inorganic nano material is nano silicon-based oxide, simple particle size range 40nm.
The invention also discloses a kind of preparation methods of environment protection integrated waterproof coating, specifically include following steps:
(1) raw material is weighed according to formula, by inorganic nano material and glass powder grinding distribution;
(2) step 1 is obtained product and modified epoxy mixing, be added wetting agent, dispersant, cross-linked modifier, Filler, fire retardant, nano silicon dioxide, mica powder, hydroxyethyl cellulose, ultra-violet absorber are uniformly mixed;
(3) antiseptic, lubricant are added in step 2, is uniformly mixed and obtains product.
The beneficial effects of the invention are as follows:Long product lifecycle, and select raw materials for production be environment-friendly type, production and It is pollution-free finally to make product more environmentally-friendly in work progress, while there is good physics, chemical property, good water-proof effect, It is ageing-resistant, have strength antibacterial effect.
Embodiment five:
A kind of environment protection integrated waterproof coating provided in this embodiment, is composed of the following parts by weight parts:70 parts Modified epoxy, 1 part of wetting agent, 1 part of dispersant, 3 parts of lubricants, 8 parts of cross-linked modifiers, 1 part of filler, 2 parts of fire retardants, 1 part of inorganic nano material, 2 parts of nano silicon dioxides, 3.5 parts of mica powders, 1 part of hydroxyethyl cellulose, 1 part of ultra-violet absorber, 0.1 part of antiseptic;5 parts of glass powders.
Further, the modified epoxy is the content by following components and mass fraction:93 parts of modified bisphenol A type rings Oxygen resin, 7 parts of quartz sands.
Further, the inorganic nano material is nano aluminum base oxide, simple particle size range 50nm.
The invention also discloses a kind of preparation methods of environment protection integrated waterproof coating, specifically include following steps:
(1) raw material is weighed according to formula, by inorganic nano material grinding distribution;
(2) step 1 is obtained product and modified epoxy mixing, be added wetting agent, dispersant, cross-linked modifier, Filler, fire retardant, nano silicon dioxide, mica powder, hydroxyethyl cellulose, ultra-violet absorber are uniformly mixed;
(3) antiseptic, lubricant are added in step 2, is uniformly mixed and obtains product.

Claims (8)

1. a kind of environment protection integrated waterproof coating, which is characterized in that be composed of the following parts by weight parts:60-70 parts change Property epoxy resin, 1-3 parts of wetting agents, 1-2 parts of dispersants, 3-6 parts of lubricants, 8-10 parts of cross-linked modifiers, 1-3 parts of fillers, 2-4 parts of fire retardants, 1-5 parts of inorganic nano materials, 2-9 parts of nano silicon dioxides, 0.5-3.5 parts of mica powders, 1-6 parts of ethoxys are fine Dimension element, 1-2 parts of ultra-violet absorbers, 0.1-0.2 parts of antiseptics.
2. a kind of environment protection integrated waterproof coating according to claim 1, which is characterized in that by following parts by weight Composition forms:65-70 parts of modified epoxies, 2-3 parts of wetting agents, 1-2 parts of dispersants, 3-6 parts of lubricants, 9-10 parts of crosslinkings change Property agent, 2-3 parts of fillers, 3-4 parts of fire retardants, 1-5 parts of nano-titanium dioxides, 3-9 parts of nano silicon dioxides, 2-3.5 parts of micas Powder, 3-6 parts of hydroxyethyl celluloses, 1-2 parts of ultra-violet absorbers, 0.1-0.2 parts of antiseptics.
3. a kind of environment protection integrated waterproof coating according to claim 1 or 2, which is characterized in that further include by following The composition of parts by weight forms:3-5 parts of glass powders.
4. a kind of environment protection integrated waterproof coating according to claim 1 or 2, which is characterized in that the modified epoxy Resin is the content by following components and mass fraction:Modified bisphenol A type epoxy resin:90-100 parts, quartz sand:0-10 parts.
5. a kind of environment protection integrated waterproof coating according to claim 3, which is characterized in that the modified epoxy It is the content by following components and mass fraction:90-100 parts of modified bisphenol A type epoxy resin, 0-10 parts of quartz sands.
6. a kind of environment protection integrated waterproof coating according to claim 1 or 2, it is characterised in that:The inorganic nano Material is one or more compoundings in nano-titanium dioxide, nano silicon-based oxide, graphene, nano aluminum base oxide, Simple particle size range 20-60nm.
7. a kind of preparation method of environment protection integrated waterproof coating, which is characterized in that specifically include following steps:
(1) raw material is weighed according to formula, by inorganic nano material grinding distribution;
(2) product and the modified epoxy mixing obtained step 1, is added wetting agent, dispersant, cross-linked modifier, filling Agent, fire retardant, nano silicon dioxide, mica powder, hydroxyethyl cellulose, ultra-violet absorber are uniformly mixed;
(3) antiseptic, lubricant are added in step 2, is uniformly mixed and obtains product.
8. a kind of preparation method of environment protection integrated waterproof coating according to claim 7, it is characterised in that:Further include Glass powder is added in step 1.
CN201810169431.9A 2018-02-28 2018-02-28 Environment-friendly integrated waterproof coating and preparation method thereof Active CN108329801B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111362639A (en) * 2020-03-19 2020-07-03 北京慕洋新材料技术研究有限公司 Cement matrix waterproof coating
CN112876992A (en) * 2021-01-22 2021-06-01 涂晶 Anti-aging coating for building exterior wall and preparation method thereof
CN115322682A (en) * 2022-09-06 2022-11-11 东莞大宝化工制品有限公司 Waterproof antibacterial paint and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007084751A (en) * 2005-09-26 2007-04-05 Dainippon Ink & Chem Inc Reactive hot-melt coating composition and coated woody base material
CN101328389A (en) * 2008-07-25 2008-12-24 魏大勇 Nanometer grade environment-friendly type color aqueous waterproof coating material
CN106085118A (en) * 2016-06-30 2016-11-09 太仓市金新涂料有限公司 A kind of environment-friendly waterproof antibiotic paint and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007084751A (en) * 2005-09-26 2007-04-05 Dainippon Ink & Chem Inc Reactive hot-melt coating composition and coated woody base material
CN101328389A (en) * 2008-07-25 2008-12-24 魏大勇 Nanometer grade environment-friendly type color aqueous waterproof coating material
CN106085118A (en) * 2016-06-30 2016-11-09 太仓市金新涂料有限公司 A kind of environment-friendly waterproof antibiotic paint and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111362639A (en) * 2020-03-19 2020-07-03 北京慕洋新材料技术研究有限公司 Cement matrix waterproof coating
CN112876992A (en) * 2021-01-22 2021-06-01 涂晶 Anti-aging coating for building exterior wall and preparation method thereof
CN115322682A (en) * 2022-09-06 2022-11-11 东莞大宝化工制品有限公司 Waterproof antibacterial paint and preparation method thereof

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Denomination of invention: A kind of environment-friendly integrated waterproof coating and preparation method thereof

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Pledgee: Bank of China Limited Guangzhou Pearl River Branch

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