CN108328563B - MEMS chip for measuring viscosity of liquid and measuring method thereof - Google Patents

MEMS chip for measuring viscosity of liquid and measuring method thereof Download PDF

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Publication number
CN108328563B
CN108328563B CN201810256851.0A CN201810256851A CN108328563B CN 108328563 B CN108328563 B CN 108328563B CN 201810256851 A CN201810256851 A CN 201810256851A CN 108328563 B CN108328563 B CN 108328563B
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liquid
cantilever beam
viscosity
driving electrode
measuring
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CN108328563A (en
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王新亮
马硕
温赛赛
胡慧珊
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Suzhou In Situ Chip Technology Co ltd
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Suzhou In Situ Chip Technology Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B7/00Microstructural systems; Auxiliary parts of microstructural devices or systems
    • B81B7/02Microstructural systems; Auxiliary parts of microstructural devices or systems containing distinct electrical or optical devices of particular relevance for their function, e.g. microelectro-mechanical systems [MEMS]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B3/00Devices comprising flexible or deformable elements, e.g. comprising elastic tongues or membranes
    • B81B3/0018Structures acting upon the moving or flexible element for transforming energy into mechanical movement or vice versa, i.e. actuators, sensors, generators
    • B81B3/0021Transducers for transforming electrical into mechanical energy or vice versa
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N11/00Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N11/00Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties
    • G01N2011/006Determining flow properties indirectly by measuring other parameters of the system

Abstract

The invention provides a MEMS chip for measuring liquid viscosity, which comprises a substrate, wherein a liquid storage tank, a cantilever beam positioned above the liquid storage tank, a liquid flow channel arranged on one side of the liquid storage tank and a liquid dropping port communicated with the liquid flow channel are arranged on the substrate; the substrate is also provided with a second driving electrode corresponding to the first driving electrode; the liquid storage tank is used for accommodating liquid to be measured; the cantilever beam is used to measure the viscosity change of the liquid. The MEMS chip has simpler structure, lower production cost and higher production efficiency, and can be widely applied to the technical fields of medical treatment and sanitation, petroleum, chemical industry, metallurgy, national defense and the like. In addition, the measuring method for measuring the viscosity of the liquid by adopting the MEMS chip has higher detection precision and higher compatibility with an IC, and is more suitable for personalized and household use.

Description

MEMS chip for measuring viscosity of liquid and measuring method thereof
Technical Field
The invention relates to the field of liquid viscosity measurement, in particular to a chip for measuring liquid viscosity and a measuring method thereof.
Background
Viscosity measurement is a necessary technology in a plurality of fields such as petroleum, chemical industry, metallurgy, national defense, medical treatment and health, and has a dense and indispensible relationship with the acquisition of accurate detection data, the control of production flow, the improvement of product quality, the development and the energy conservation. In particular, when the liquid is flowing steadily, it is generally the case that the laminar flow is stabilized, i.e. the liquid flow conditions on the same level are exactly the same. If the flow rates between the layers within the liquid are different, then relative motion will occur between adjacent layers within the liquid, and an interaction force, referred to as a viscous force, will occur between the two layers within the liquid, and a physical quantity that measures the magnitude of this viscous force is referred to as viscosity.
In recent years, health care has been a field of interest, and in order to solve the health monitoring of numerous people, it is necessary to make the device more portable, easy to operate, economical and accurate. However, the viscosity of the liquid is currently monitored mainly by stirring the magnetic beads, and the viscosity of the liquid is evaluated by the rotation speed of the stirring of the magnetic beads. In the related art, the measured liquid is placed in a smooth glass vessel, a certain mass of magnetic beads are added, the magnetic beads rotate around the bottom of the vessel after being subjected to an external force, and the rotating speed of the magnetic beads is calculated through a counter, so that the liquid viscosity information is obtained. However, the existing viscosity measurement method has the following problems: the operation steps are complicated; the degree of wetting of the glass ware with liquid affects the accuracy of the test; special instruments and equipment are needed for detection, and the detection is complicated; the liquid with larger viscosity can not be detected, and the selectivity is poor; the instrument and equipment are more expensive and the detection cost is higher.
Therefore, it is necessary to provide a new chip for measuring the viscosity of a liquid and a measuring method thereof.
Disclosure of Invention
In order to solve the problems, the invention provides a MEMS chip for measuring the viscosity of liquid, which comprises a substrate, wherein a liquid storage tank, a cantilever beam positioned above the liquid storage tank, a liquid flow channel arranged at one side of the liquid storage tank and a liquid dropping port communicated with the liquid flow channel are arranged on the substrate, and a first driving electrode for electrostatic driving is arranged on the cantilever beam; the substrate is also provided with a second driving electrode corresponding to the first driving electrode; the liquid storage tank is used for accommodating liquid to be measured; the cantilever beam is used to measure the viscosity change of the liquid.
Preferably, an electrostatic force is applied to the cantilever beam by the first and second driving electrodes to drive the cantilever beam to vibrate and bring it into contact with the liquid to be measured.
Preferably, the material of the first driving electrode and the second driving electrode is one of gold, chromium, nickel, tungsten, iron, copper, aluminum, platinum, and titanium, or an alloy thereof.
Preferably, the first and second driving electrodes have a width of 50nm to 1cm and a length of 200 μm to 10cm.
Preferably, the MEMS chip further comprises a heating electrode for maintaining the temperature of the liquid to be measured in a constant temperature state, and/or the heating electrode has a width of 50nm to 1cm and a length of 200 μm to 10cm.
Preferably, the liquid flow channel is arranged on one side of the substrate away from the cantilever beam; and/or the liquid flow channel has a depth of 10 μm to 1cm and a width of 2 μm to 1cm.
The invention also provides a measuring method for measuring the viscosity of the liquid by adopting the MEMS chip, which comprises the following steps:
electrostatically driving the cantilever beam to vibrate;
measuring the vibration frequency of the cantilever after the cantilever contacts the liquid in the liquid storage tank;
comparing the vibration frequency before and after the cantilever beam contacts the liquid to obtain the viscosity of the liquid;
obtaining the viscosity change of the liquid according to the vibration frequency change of the cantilever beam after contacting the liquid;
the MEMS chip comprises a substrate, wherein a liquid storage tank, a cantilever beam positioned above the liquid storage tank, a liquid flow channel arranged at one side of the liquid storage tank and a liquid dropping port communicated with the liquid flow channel are arranged on the substrate, and a first driving electrode for electrostatic driving is arranged on the cantilever beam; and a second driving electrode corresponding to the first driving electrode is also arranged on the substrate.
Preferably, the liquid storage tank is used for containing liquid to be measured; and/or the cantilever beam is used to measure a change in viscosity of the liquid.
Preferably, an electrostatic force is applied to the cantilever beam by the first and second driving electrodes to drive the cantilever beam to vibrate and bring it into contact with the liquid to be measured.
Preferably, the MEMS chip further comprises a heating electrode for maintaining the temperature of the liquid to be measured in a constant temperature state.
The invention has the beneficial effects that:
compared with the prior art, the MEMS chip has simpler structure, simplified process flow, lower production cost and higher production efficiency, and can be widely applied to the technical fields of medical treatment and sanitation, petroleum, chemical industry, metallurgy, national defense and the like. In addition, the measuring method for measuring the viscosity of the liquid by adopting the MEMS chip has higher detection precision and higher compatibility with an IC, and is more suitable for personalized and household use.
Drawings
Fig. 1 is a schematic perspective view of a MEMS chip of the present invention.
Fig. 2 is a schematic plan view of a MEMS chip of the present invention.
Fig. 3 is a schematic side view of a MEMS chip of the present invention.
FIG. 4 is a flow chart of the MEMS chip of the present invention for detecting the viscosity of a liquid.
Detailed Description
The following detailed description of specific embodiments of the invention is provided in connection with the accompanying drawings and examples in order to provide a better understanding of the aspects of the invention and advantages thereof. However, the following description of specific embodiments and examples is for illustrative purposes only and is not intended to be limiting of the invention.
Example 1
As shown in fig. 1 and 2, the present invention provides a MEMS chip for measuring the viscosity of a liquid, the MEMS chip comprising a substrate 10, a liquid storage tank 11 provided on the substrate 10, a cantilever 12 provided above the liquid storage tank 11, a first driving electrode 13 provided on the cantilever 12, and a second driving electrode provided on the substrate, wherein electrostatic force is applied to the cantilever by the first driving electrode 13 and the second driving electrode. In addition, a heating electrode 14 is disposed on the MEMS chip, and the heating electrode 14 is, for example, a loop disposed on the cantilever 12. A liquid flow channel 15 arranged at one side of the liquid storage tank 11 and a liquid drop port 16 communicated with the liquid flow channel 15, wherein the first driving electrode 13 is used for driving the cantilever beam 12 to vibrate and contact with liquid; the pair of heating electrodes 14 and the cantilever beam 12 form a loop to ensure that the liquid to be measured is in a constant temperature state, but the method is not limited to this, and the liquid to be measured is in a constant temperature state in many ways, as long as the liquid to be measured is in a constant temperature state. For example, heating or insulating means are provided below the reservoir 11.
In this embodiment, the cantilever structure may be a single cantilever or two independent and identical cantilevers, and the liquid storage tank 11 is symmetrically provided with a liquid drop port communicated with the liquid storage tank on a side far away from the cantilever, so that a half structure of the MEMS chip is taken as an example for illustration. As shown in fig. 1 and 2, the thickness of the cantilever 12 is 200nm-10 μm, and the material of the cantilever 12 may be silicon, silicon oxide, quartz, silicon nitride, polyimide, polyethylene, etc., see fig. 3; the liquid reservoir 11 has a square cross-sectional shape, and further has a width of 2 μm to 1cm and a height of 10 μm to 1mm, but is not limited thereto, and may have other shapes such as a rectangle, a pentagon, and the like; the drip opening 16 is circular, and the diameter of the drip opening is 2 μm-1cm; the depth of the liquid flow channel 15 is 10 mu m-1cm, and the width is 2 mu m-1cm; the heating electrode 14 is made of one or alloy of gold, chromium, nickel, tungsten, iron, copper, aluminum, platinum and titanium, and the width of the heating electrode 14 is 50nm-1cm, and the length is 200 μm-10cm; the first driving electrode 13 and the second driving electrode are made of one or alloy of gold, chromium, nickel, tungsten, iron, copper, aluminum, platinum and titanium, and the width of the driving electrode is 50nm-1cm, and the length is 200 μm-10cm. The above is merely illustrative, and the MEMS chip is not limited thereto, and the number of the cantilever beams may be two in the present embodiment, but may be one or more.
The liquid may be a body fluid such as blood, sweat, urine, or the like.
Example 2
As shown in fig. 4, the present invention also provides a method for measuring the viscosity of a liquid, which uses the MEMS chip of the present invention to evaluate the frequency change of the nano-cantilever after the introduction of the liquid by comparing the vibration frequencies of the cantilever before and after the contact with the liquid. Specifically, the measurement method includes the steps of:
electrostatically driving the cantilever beam to vibrate;
measuring the vibration frequency of the cantilever after the cantilever contacts the liquid in the liquid storage tank;
comparing the vibration frequency before and after the cantilever beam contacts the liquid to obtain the viscosity of the liquid;
and obtaining the viscosity change of the liquid according to the vibration frequency change of the cantilever beam after contacting the liquid.
Working principle of MEMS chip for measuring viscosity of liquid
When a driving current is applied to the first driving electrode 13, the cantilever beam 12 is subjected to electrostatic force, electrostatic vibration is generated along with the driving current, when liquid drops into the liquid drop port, the liquid flows into the liquid storage tank along with the liquid flow channel, the cantilever beam 12 is contacted with the liquid in the liquid storage tank in the vibration process, the vibration frequency of the cantilever beam is compared with the vibration frequency of the cantilever beam after the liquid is introduced, the vibration frequency variation of the cantilever beam is obtained, and then the viscosity variation of the liquid is obtained according to the vibration frequency before and after the cantilever beam contacts the liquid and the variation of the driving electrostatic force. In addition, in the detection process, it is preferable to use a pair of heating electrodes in this embodiment in order to keep the liquid such as blood, sweat, etc. consistent with the body temperature. See fig. 1 and 2.
The electrostatic drive and the resonant frequency of the micromechanical structure under the electrostatic drive are described below. Electrostatic actuation mainly uses electrostatic forces between different objects to move the objects. The electrostatic force is analyzed mainly according to the theory of the physical electromagnetic field and is deduced and calculated through the electric potential energy stored by the electrostatic field of the structural device. The electrostatic force is formulated as follows:
the potential stored by the capacitance between the upper and lower platesC represents the capacitance between the upper and lower electrode plates, and V represents the voltage applied across the upper and lower electrode plates. When a voltage source is applied to the upper polar plate and the lower polar plate with a constant voltage, a charge and discharge process is carried out on a capacitor formed by the upper polar plate and the lower polar plate, and the potential energy of the cantilever beam can be expressed as:
wherein q=c·v.
Wherein V is a constant voltage, i.e. a constant, so
From the above, it can be seen that the electrostatic force between the upper and lower plates is related to the structural capacitance only, so that the electrostatic force between the upper and lower plates can be obtained by only requiring the change in the structural capacitance.
In addition, the resonant frequency of the micromechanical structure becomes:
f in 0 For the inherent resonance frequency of the cantilever beam, M is the mass of the cantilever beam, k' is the effective elastic coefficient of the capacitance structure system, A is the capacitance area of the upper and lower polar plates, d is the distance between the upper and lower polar plates, epsilon 0 (=8.854×10 -12 F/m) is the vacuum dielectric constant, ε is the relative dielectric constant of the medium between the polar plates, and V is a constant voltage. Thus, the resonant frequency of the cantilever beam in motion is also a nonlinear function of the drive voltage, and will decrease as the drive voltage amplitude increases.
Compared with the prior art, the MEMS chip has simpler structure, simplified process flow, lower production cost and higher production efficiency, and can be widely applied to the technical fields of medical treatment and sanitation, petroleum, chemical industry, metallurgy, national defense and the like. In addition, the MEMS chip is adopted to measure the viscosity of the liquid, the vibration frequency of the nano cantilever beam before and after the nano cantilever beam contacts the liquid is compared to evaluate the frequency change of the nano cantilever beam after the liquid is introduced so as to measure the viscosity change of the liquid.
The foregoing is only a preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any changes or substitutions easily contemplated by those skilled in the art within the technical scope of the present invention should be covered by the scope of the present invention.

Claims (6)

1. The MEMS chip is characterized by comprising a substrate, wherein a liquid storage tank, a cantilever beam positioned above the liquid storage tank, a liquid runner arranged on one side of the liquid storage tank and a liquid drop port communicated with the liquid runner are arranged on the substrate, one end of the cantilever beam is connected to the substrate, the other end of the cantilever beam is suspended above the liquid storage tank, and a first driving electrode for electrostatic driving is arranged on the cantilever beam; the substrate is also provided with a second driving electrode corresponding to the first driving electrode; the liquid storage tank is used for accommodating liquid to be measured; the cantilever beam is used for measuring the viscosity change of the liquid according to the change of the vibration frequency of the cantilever beam; the width of the first driving electrode and the second driving electrode is 50nm-1cm, and the length is 200 mu m-10cm; the MEMS chip further comprises a heating electrode, wherein the heating electrode is used for keeping the temperature of the liquid to be measured in a constant temperature state, the width of the heating electrode is 50nm-1cm, and the length of the heating electrode is 200 mu m-10cm; the liquid flow channel is arranged on one side of the substrate far away from the cantilever beam; the depth of the liquid flow channel is 10 mu m-1cm, and the width is 2 mu m-1cm.
2. The MEMS chip for measuring the viscosity of a liquid according to claim 1, wherein an electrostatic force is applied to the cantilever beam by the first driving electrode and the second driving electrode to drive the cantilever beam to vibrate and bring it into contact with the liquid to be measured.
3. The MEMS chip for measuring viscosity of liquid according to claim 2, wherein the material of the first driving electrode and the second driving electrode is one of gold, chromium, nickel, tungsten, iron, copper, aluminum, platinum, titanium, or an alloy.
4. A method for measuring the viscosity of a liquid using the MEMS chip for measuring the viscosity of a liquid according to claim 1, comprising the steps of:
electrostatically driving the cantilever beam to vibrate;
measuring the vibration frequency of the cantilever after the cantilever contacts the liquid in the liquid storage tank;
comparing the vibration frequency before and after the cantilever beam contacts the liquid to obtain the viscosity of the liquid;
and obtaining the viscosity change of the liquid according to the vibration frequency change of the cantilever beam after contacting the liquid.
5. The method of measuring the viscosity of a liquid according to claim 4, wherein an electrostatic force is applied to the cantilever beam by the first driving electrode and the second driving electrode to drive the cantilever beam to vibrate and bring it into contact with the liquid to be measured.
6. The method of measuring the viscosity of a liquid according to claim 4, wherein the material of the first driving electrode and the second driving electrode is one of gold, chromium, nickel, tungsten, iron, copper, aluminum, platinum, titanium, or an alloy.
CN201810256851.0A 2018-03-27 2018-03-27 MEMS chip for measuring viscosity of liquid and measuring method thereof Active CN108328563B (en)

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Publication number Priority date Publication date Assignee Title
US4938053A (en) * 1987-08-28 1990-07-03 Thorm EMI Flow Measurement Limited Fluid metering system
US5872309A (en) * 1996-12-11 1999-02-16 Robert Bosch Gmbh Method for checking the sealing of a package and apparatus for measuring viscosity
JP2003139675A (en) * 1994-11-25 2003-05-14 Ngk Insulators Ltd Equipment for measuring viscosity and equipment for measuring characteristics of fluid
US7148611B1 (en) * 2005-10-11 2006-12-12 Honeywell International Inc. Multiple function bulk acoustic wave liquid property sensor
JP2010203992A (en) * 2009-03-05 2010-09-16 Epson Toyocom Corp Viscosity sensor and method of measuring viscosity
JP2018028451A (en) * 2016-08-16 2018-02-22 国立大学法人九州工業大学 Biological fluid viscosity measurement device
CN208150962U (en) * 2018-03-27 2018-11-27 苏州原位芯片科技有限责任公司 It is a kind of for measuring the MEMS chip of liquid viscosity

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4938053A (en) * 1987-08-28 1990-07-03 Thorm EMI Flow Measurement Limited Fluid metering system
JP2003139675A (en) * 1994-11-25 2003-05-14 Ngk Insulators Ltd Equipment for measuring viscosity and equipment for measuring characteristics of fluid
US5872309A (en) * 1996-12-11 1999-02-16 Robert Bosch Gmbh Method for checking the sealing of a package and apparatus for measuring viscosity
US7148611B1 (en) * 2005-10-11 2006-12-12 Honeywell International Inc. Multiple function bulk acoustic wave liquid property sensor
JP2010203992A (en) * 2009-03-05 2010-09-16 Epson Toyocom Corp Viscosity sensor and method of measuring viscosity
JP2018028451A (en) * 2016-08-16 2018-02-22 国立大学法人九州工業大学 Biological fluid viscosity measurement device
CN208150962U (en) * 2018-03-27 2018-11-27 苏州原位芯片科技有限责任公司 It is a kind of for measuring the MEMS chip of liquid viscosity

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