CN108323517A - Bactericidal composition containing benzo alkene fluorine bacterium azoles and its application - Google Patents
Bactericidal composition containing benzo alkene fluorine bacterium azoles and its application Download PDFInfo
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- CN108323517A CN108323517A CN201810147845.1A CN201810147845A CN108323517A CN 108323517 A CN108323517 A CN 108323517A CN 201810147845 A CN201810147845 A CN 201810147845A CN 108323517 A CN108323517 A CN 108323517A
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- CN
- China
- Prior art keywords
- bactericidal composition
- terpenol
- bacterium azoles
- benzo alkene
- alkene fluorine
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/06—Oxygen or sulfur directly attached to a cycloaliphatic ring system
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Composition pesticide containing terpenol and benzo alkene fluorine bacterium azoles the present invention relates in and its application for preventing corps diseases, the weight ratio of terpenol and benzo alkene fluorine bacterium azoles is 30 in the composition pesticide:1‑1:20, preferably 10:1‑1:1.Further, the weight percentage of composition shared by benzo alkene fluorine bacterium azoles and terpenol is 1 90%, preferably 20 50% in the bactericidal composition, remaining is the conventional auxiliary element in Pesticide formulation.The composition of the present invention can be processed into the arbitrary dosage form for agriculturally allowing to use by the customary preparation methods in Pesticide formulation, including but not limited to wettable powder, water dispersible granules, aqueous emulsion, microemulsion, dispersible oil-suspending agent, the composition pesticide control effect is good, at low cost.
Description
Technical field
The invention belongs to biological bactericide fields, and in particular to be a kind of bactericidal composition containing benzo alkene fluorine bacterium azoles
And its application for preventing corps diseases.
Background technology
Powdery mildew is a kind of worldwide disease occurred extensively, and chemical pesticide control powdery mildew, mesh are mainly used in production
Before rely primarily on benzimidazole, triazole type, methoxy acrylic bactericide.However, killing for single kind is used for a long time
Microbial inoculum can make disease generate different degrees of resistance, and control effect reduces.
Benzo alkene fluorine bacterium azoles are a kind of pyrazole amide series bactericidal agents, by inhibiting on mitochondrial inner membrane in electron transport chain
Succinate dehydrogenase so that disease fungus can not generate energy via breathing, and then disintegrate the growth of germ, and the compound is independent
Higher operating costs and the generation for being easy hair resistance again, to reduce the service life of pesticide species.
Terpenol is the biological bactericide of biological pesticide company of Israel exploitation, currently, having 40.2% terpenol mother
Medicine and 9% terpenol missible oil success industrialization, for preventing the diseases such as powdery mildew of strawberry and early blight of tomato.
Rational pesticide activity component compounding is to solve the common measures such as pesticide residue, resistance development, some pesticides are lived
Property ingredient compounding after, also have the function of in a certain range expand fungicidal spectrum, improve control effect, synergy, therefore,
How a hot spot obtaining the agriculture chemical compounding with above-mentioned effect as research is screened.Present inventor is by a large amount of
It tests, on the basis of the field control effectiveness test of determination of activity combination indoors, screening obtains benzo alkene fluorine bacterium azoles and terpenol compounding
Apparent synergistic function is shown to the prevention of multiple kinds of crops disease afterwards, after further research, completes the present invention,
Currently, it is not yet found that the relevant report compounded about terpenol and benzo alkene fluorine bacterium azoles.
Invention content
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to provide, a kind of control effect is good, environment amenable association
Same Synergistic bactericidal composition.
It is described to kill another object of the present invention is to provide the application that the bactericidal composition is used to prevent corps diseases
Bacteria composition is particularly suitable for preventing a variety of oomycetes diseases, such as downy mildew, powdery mildew, phytophthora root rot etc., meanwhile, it is of the invention
The prevention spectrum of agricultural chemical compound conjugate also necessarily covers the prevention spectrum of single active constituent.
In order to achieve the above object, the present invention adopts the following technical scheme that:
A kind of bactericidal composition, which is characterized in that active constituent includes at least benzo alkene fluorine bacterium azoles and terpenol, wherein
Benzo alkene fluorine bacterium azoles and the weight ratio of terpenol are preferably 30:1-1:20, further, the weight ratio is preferably 10:1-1:
1。
Further, in the bactericidal composition composition shared by benzo alkene fluorine bacterium azoles and terpenol weight percentage
For 1-90%, preferably 20-50%, remaining is the conventional auxiliary element in Pesticide formulation.
Further, the bactericidal composition can be processed into agricultural by the customary preparation methods in Pesticide formulation
On allow the arbitrary dosage form used, including but not limited to wettable powder, water dispersible granules, aqueous emulsion, microemulsion, dispersible oil
Suspending agent.
Further, bactericidal composition of the invention can provide i.e. in composition each substance in the form of finished product preparation
Mixing, can also be provided with unit dose form, directly be mixed, be then diluted to required dense in proportion in bucket or tank using preceding
Degree.
Further, other agricultural active ingredients, such as fungicide, desinsection can also be added in bactericidal composition of the invention
The agricultural actives ingredient such as agent, herbicide, fertilizer.
Further, bactericidal composition of the invention can also occur just in application before disease generation in disease
Phase or disease occur the later stage and use, and also it can be made to use respectively in difference, and can be caused harm according to disease degree, prevention of dosage is made
The difference of object, application method, use environment etc. changes within the scope of wider.
Compared with prior art, bactericidal composition of the invention has the beneficial effect that:
1, in certain range after active constituent terpenol and benzo alkene fluorine bacterium azoles compound in bactericidal composition of the invention
It is interior to reach apparent synergistic function, it is possible to reduce pesticide activity component usage amount improves control effect;
2, the active constituent mechanism of action is different in bactericidal composition of the invention, and the two combined use can be reduced
And/or delay the generation of pathogen drug resistance;
3, bactericidal composition control effect of the invention is good, and dosage is low, is particularly suitable for prevention oomycetes diseases.
Specific implementation mode
In order to make the purpose of the present invention, technical solution be more clearly understood, the mode of present invention embodiment is to the present invention
It is illustrated, but present invention feel is not limited to these examples.It is as described below to be only the preferred embodiment of the present invention, it is used only for describing
The present invention is not considered as limiting the invention, it is noted that all timess done in the spirit and principles in the present invention
What modifications, equivalent substitutions and improvements etc., should all be included in the protection scope of the present invention, therefore, the protection of patent of the present invention
Range should be determined by the appended claims.
Specific implementation mode
In order to make the purpose of the present invention, technical solution be more clearly understood, the mode of present invention embodiment is to the present invention
It is illustrated, but present invention feel is not limited to these examples.It is as described below to be only the preferred embodiment of the present invention, it is used only for describing
The present invention is not considered as limiting the invention, it is noted that all timess done in the spirit and principles in the present invention
What modifications, equivalent substitutions and improvements etc., should all be included in the protection scope of the present invention, therefore, the protection of patent of the present invention
Range should be determined by the appended claims.
One, indoor bioassay
1, for trying pathogen:Cucumber downy mildew germ;
2, reagent agent:After terpenol and benzo alkene fluorine bacterium azoles are dissolved with solvent, it is configured to the mother liquor of 10000ug/mL,
It is preserved in 4 DEG C of refrigerators, for use.
3, test method:After the effective inhibition concentration for determining terpenol and benzo alkene fluorine bacterium azoles is tested in prerun, setting two
The various concentration of kind medicament, reference《Farm-chemical indoor determination test rule fungicide》It carries out, using mycelial growth rate method
Medicament is measured to the virulence of crop germ, colony diameter is measured with crossing method after 72h, calculates each processing net growth, bacterium
Silk growth inhibition ratio.Control effect is converted into probit value (y), and liquor strength (ug/mL) is converted into logarithm (x), with minimum
Concentration EC during multiplication calculates virulence equation and inhibits50, the toxicity index and co-toxicity coefficient (CTC) of medicament are calculated according to Sun Yunpei's Method.
Test result is shown in Table 1.
The indoor virulence of 1 terpenol of table and benzo alkene fluorine bacterium azoles different ratio to cucumber downy mildew
As can be seen from Table 1, terpenol and benzo alkene fluorine bacterium azoles are 30:1-1:It is compounded in the range of 20, to cucumber downy mildew
The prevention of disease shows synergistic function.Wherein, when the two compound proportion is 10:1-1:10, co-toxicity coefficient close to 160 or
160 or more, synergistic function is opposite to be become apparent from.
Two, example of formulations
1, embodiment 1:30% terpenol benzo alkene triflumizole wettable powder (1:1)
The preparation method of the wettable powder:By above-mentioned formula by pesticide original medicine and dispersant, wetting agent and filler
Mixing, stirs evenly in a stirring kettle, is remixed after air-flow crushing uniformly, you can wettable powder of the present invention is made
Agent.
2, embodiment 2:29% terpenol benzo alkene fluorine bacterium azoles missible oil (9:20)
The preparation method of the missible oil is:By above-mentioned formula by active constituent, solvent, cosolvent and emulsifier according to certain
Sequence be added configuration kettle in, stir evenly and can be prepared by missible oil of the present invention.
3, embodiment 3:24% terpenol benzo alkene fluorine bacterium azoles suspending agent (1:3)
The preparation method of the suspending agent is:First each auxiliary agent of pesticide is uniformly mixed, is uniformly mixed through high speed shear, so
Terpenol and benzo alkene fluorine bacterium azoles are added afterwards, abrading-ball 2-3 hours in ball crusher so that preparation grain size is at 5 microns hereinafter, i.e.
Suspending agent of the present invention can be made.
4, embodiment 4:33% terpenol benzo alkene triflumizole water dispersant (1:10)
The preparation method of the water dispersible granules:By above-mentioned formula by active ingredient terpenol and benzo alkene fluorine bacterium azoles, point
Powder, wetting agent, disintegrant and filler are uniformly mixed, and are crushed with micro jet, and through mediating, fluid bed is then added
Be granulated in granulating and drying machine, dry, sieve after through sampling analysis, you can obtained water-dispersible grain of the present invention
Agent.
Three, field control effectiveness test
1, subjects:Cucumber downy mildew
2, test medicine:With the pesticidal preparations of embodiment 1-4 to test medicine, with 9% terpenol missible oil and 10% benzo
Alkene triflumizole wettable powder is comparison medicament;
3, test method:Experimental field it is arranged in city of the Qingzhou in Shandong province towns Dong Xia green cucumber, each plot area is
50m2, it is repeated 4 times, carries out foliar spray processing in cucumber early stage, twice, spraying equipment is WS-16 type backpacks for dispenser
Hand sprayer carries out cucumber downy mildew disease index investigation before chemicals treatment, 7,14 days investigation cucumber after second of dispenser
Downy mildew incidence.Investigation method, classification, drug effect calculate according to《Farmland test of pesticide effectiveness criterion (one)》It carries out.Test result
As shown in table 2:
Field control effectiveness test of 2 different agents of table to cucumber downy mildew
Field control effectiveness test result show terpenol and benzo alkene fluorine bacterium azoles compounding after composition pesticide to cucumber downy mildew
The control effect of disease is better than control 9% terpenol missible oil of single dose and 10% benzo alkene triflumizole wettable powder, shows terpenol
Certain synergistic function is shown to the prevention of cucumber downy mildew after being compounded with benzo alkene fluorine bacterium azoles.Especially embodiment 2
Composition pesticide, to the control effect of cucumber downy mildew 90% or more, hence it is evident that be better than other embodiments.In addition, with
It within the scope of medicine, does not find that the pesticidal preparations of the present invention have poisoning generation to cucumber crop, shows the composition pesticide peace of the present invention
Full property is also preferable.
Claims (7)
1. a kind of bactericidal composition, which is characterized in that active constituent includes terpenol and benzo alkene fluorine bacterium azoles.
2. bactericidal composition according to claim 1, which is characterized in that the active constituent kind terpenol and benzo alkene fluorine
The weight ratio of bacterium azoles is 30:1-1:20.
3. bactericidal composition according to claim 2, which is characterized in that the weight ratio is preferably 10:1-1:1.
4. bactericidal composition according to claim 2, which is characterized in that in the bactericidal composition benzo alkene fluorine bacterium azoles and
The weight percentage of composition shared by terpenol is 1-90%.
5. bactericidal composition according to claim 2, which is characterized in that the bactericidal composition can be prepared into suitable agriculture
Any one preparation in industry production.
6. bactericidal composition according to claim 5, which is characterized in that the type of preparation is wettable powder, moisture
It is any in shot agent, aqueous emulsion, microemulsion, dispersible oil-suspending agent.
7. the bactericidal composition according to any one of claim 1-6 claims is for preventing answering for corps diseases
With.
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CN201810147845.1A CN108323517A (en) | 2018-02-12 | 2018-02-12 | Bactericidal composition containing benzo alkene fluorine bacterium azoles and its application |
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CN201810147845.1A CN108323517A (en) | 2018-02-12 | 2018-02-12 | Bactericidal composition containing benzo alkene fluorine bacterium azoles and its application |
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CN201810147845.1A Withdrawn CN108323517A (en) | 2018-02-12 | 2018-02-12 | Bactericidal composition containing benzo alkene fluorine bacterium azoles and its application |
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Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104066335A (en) * | 2011-11-09 | 2014-09-24 | 斯托克顿(以色列)有限公司 | Combinations of antifungal compounds and tea tree oil |
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2018
- 2018-02-12 CN CN201810147845.1A patent/CN108323517A/en not_active Withdrawn
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104066335A (en) * | 2011-11-09 | 2014-09-24 | 斯托克顿(以色列)有限公司 | Combinations of antifungal compounds and tea tree oil |
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