CN108318428A - A kind of photoelectric sensing measuring device - Google Patents
A kind of photoelectric sensing measuring device Download PDFInfo
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- CN108318428A CN108318428A CN201810465363.0A CN201810465363A CN108318428A CN 108318428 A CN108318428 A CN 108318428A CN 201810465363 A CN201810465363 A CN 201810465363A CN 108318428 A CN108318428 A CN 108318428A
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- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
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- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
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- CIWXFRVOSDNDJZ-UHFFFAOYSA-L ferroin Chemical compound [Fe+2].[O-]S([O-])(=O)=O.C1=CN=C2C3=NC=CC=C3C=CC2=C1.C1=CN=C2C3=NC=CC=C3C=CC2=C1.C1=CN=C2C3=NC=CC=C3C=CC2=C1 CIWXFRVOSDNDJZ-UHFFFAOYSA-L 0.000 description 1
- IMBKASBLAKCLEM-UHFFFAOYSA-L ferrous ammonium sulfate (anhydrous) Chemical compound [NH4+].[NH4+].[Fe+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O IMBKASBLAKCLEM-UHFFFAOYSA-L 0.000 description 1
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- 229910052753 mercury Inorganic materials 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/27—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands using photo-electric detection ; circuits for computing concentration
Abstract
The invention belongs to photoelectric sensing technical field of measuring equipment,It is related to a kind of photoelectric sensing measuring device,Transparent window is devised on the circumference of filter wheel,Testing light source and photodetector are installed in the coaxial optical path for correspond to transparent window,For wavelength to be accurately positioned,Filter wheel and light source,The polarizer,Lens combination,Sample bin,Detector and Simple mechanical holder combination are fabricated to the photoelectric sensing measuring device based on Wavelength tunable light source,Filter wheel rotation is driven by motor,Change the optical filter to work in light path lens combination sample bin,Different wavelength is accurately positioned,The polarised light that polarizer obtains in the natural light that light source is sent out forms directional light after lens combination,The optical signal of directional light is converted to current signal after being detected by detector,Current signal obtains analog voltage by amplifying circuit,It is the digital voltage value that can be read by microcontroller analog-to-digital conversion,On-line checking value is obtained using the quantitative model of voltage value and location parameter.
Description
Technical field:
The invention belongs to photoelectric sensing technical field of measuring equipment, are related to a kind of photoelectric sensing measuring device, using optical filtering
The bandpass filter of different wave length, is placed in the different transparent windows of optical filtering rim of wheel circumference by the structure of wheel and Wavelength tunable light source
In, the function of selection wavelength is realized using the rotation of filter wheel.
Background technology:
With the propulsion of global industry process, the living standard of the mankind is higher and higher, but the environmental problem occurred is further
Seriously, environmental pollution is just drastically influencing the living environment of the mankind and animals and plants.Water quality monitoring is monitoring and measures dirty in water body
Type, the concentration and variation tendency of each pollutant of object are contaminated, the range of the process of evaluating water quality situation, water quality monitoring is very wide
It is general, including be not contaminated and contaminated natural water (river, river, lake, sea and underground water) and various industrial water drainages etc..
The main monitoring project of water quality can be divided into two major classes:One kind be reflect water quality condition overall target, as temperature, coloration, turbidity,
PH value, conductivity, suspended matter, dissolved oxygen, COD and biochemical oxygen demand (BOD) etc.;Another kind of is some noxious materials, as phenol,
Cyanogen, arsenic, lead, chromium, cadmium, mercury and organic agricultural chemicals etc..For the situation of objective appraisal rivers and ocean water quality, above-mentioned monitoring project is removed
Outside, the measurement of progress flow velocity and flow is needed sometimes.Currently, China's water environment water quality monitoring technology achieves the hair of fast speed
Exhibition, water quality monitoring technology mainly based on physics and chemistry monitoring technology, including chemical method, electrochemical process, atomic absorption spectrophotometry,
Ion selective electrode method, the chromatography of ions, gas chromatography, plasma emission spectroscopy (ICP-AES) method etc..Wherein, ion
Selecting electrode method (qualitative, quantitative), chemical method (gravimetric method, volumetric precipitation method and spectrophotometry), at home and abroad water quality routine is supervised
It is generally used in survey.Biological monitoring in recent years, remote sensing monitoring technology have been also applied in water quality monitoring.
Traditional physics and chemistry monitoring:In surface water quality monitoring, since monitoring instrument is fairly simple, physical monitoring achievement data
It is often easier to obtain, common physical index monitoring instrument has the transmissometer for measuring water turbidity, measures the filter used in coloration
Light photometer measures conductivity conductivity meter etc., and also multi-functional water quality monitor realizes while measuring multinomial physics
The effect of index.The monitoring of chemical index is the emphasis of earth's surface water monitoring, as country is to the weight of toxic organic compound pollution monitoring
Depending on, instrument cause and research and development in terms of achieve certain progress, some monitoring stations have had been introduced by large and medium-sized laboratory prison
Instrument is surveyed, it can heavy metals and halogen, ammonium nitrogen, nitrite nitrogen, cyanide, the phenol such as field monitoring Zn, Fe, Pb, Cd, Hg, Mn
The substances such as class, anionic detergent and Se.
Biological monitoring:Biological monitoring is one of water environment pollution monitoring method, it is to utilize bion, population or group
Reaction caused by environmental pollution variation illustrates the pollution situation of environment, has sensibility, enriching, chronicity and comprehensive
The features such as.The Bio-monitoring method applied in actual monitoring at present mainly refers to including biotic index method, specific diversity
Number method, microbial community monitoring method, biological toxicity test, biological residual hazard measure, ecology manages malicious method etc., the water being related to
Raw biology covers unicellular alga, protist, benthon, fish and amphibian animal.
Remote sensing monitoring technology:Inland Water Remote Sensing Techniques in Determining Water Quality is the spectrum based on experience, statistical analysis or water quality parameter
Characteristic, selection remote sensing wave band data and ground actual measurement water quality parameter data carry out mathematical analysis, establish water quality parameter inversion algorithm
It realizes.Remote Sensing Techniques in Determining Water Quality method can reflect distribution situation and variation of the water quality on room and time, find some often
The pollution sources and pollutant that rule method is difficult to disclose migrate feature, and with monitoring range is wide, speed is fast, at low cost and be convenient for
The advantage of long-term dynamics monitoring.
Permanganimetric method (potassium permanganate titration) is the oxygen using potassium permanganate as titrant
Change reductometry, in strongly acidic solution, potassium permanganate is strong oxidizer, and solution acidity should be controlled is in 1-2mol/L
Preferably, acidity is too high, and potassium permanganate is easy to decompose;Acidity is too low, and reaction speed is slow, and will produce manganese dioxide precipitate.It adjusts molten
Liquid acidity often uses sulfuric acid.Because nitric acid has oxidisability, should not use.And hydrochloric acid has reproducibility, understands by potassium permanganate oxidation,
It is also not suitable for using.
The principle of potassium dichromate method is the reproducibility object in a certain amount of potassium dichromate oxidation water sample in strongly acidic solution
Matter, excessive potassium bichromate make indicator, with l ferrous ammonium sulfate solution residual titration with ferroin.It is calculated in water sample also according to dosage
The oxygen of immunogenic substance consumption.Acid potassium dichromate oxidation is very strong, and oxidable major part organic matter is added silver sulfate and makees catalyst
When, linear aliphatic compound can be aoxidized completely, and aromatic series organic matter is not easy to be aoxidized, and pyridine is not oxidized, volatilization
Property the organic matters such as linear aliphatic compound, benzene be present in vapor phase, cannot be contacted with oxidant liquid, aoxidize unobvious.Chlorine
Ion can be aoxidized by bichromate, and can be acted on silver sulfate and be generated precipitation.
In the above detection method, permanganimetric method and potassium dichromate method are common water quality detection means, permanganimetric method
Lighter water sample is polluted suitable for measuring, but is easy to be interfered by chlorion;Potassium dichromate method is suitable for measuring seriously polluted
Water sample, but be affected by external environment;That there is minutes is long, complicated for operation for both of which, real-time is poor
The shortcomings that.In recent years, since near-infrared and ultraviolet spectroscopy can analyze detection material composition in real time, (absorption of ultraviolet spectra is brighter
It is aobvious), the detecting system based on spectroscopic methodology, which is just increasingly being, to be widely applied.201610872807.3 disclosure of Chinese patent
The online full spectral water quality analyzer of one kind include light path module and TT&C system, the light path module communicates to connect the survey
Control system, the light path module include light source driving units, light source unit, focussed collimated spectrophotometric unit, Measurement channel unit, ginseng
Than channel unit, the first one-to-two optical fiber, collimation unit, focusing unit, the second one-to-two optical fiber and spectrometer, the light source drives
The output end of moving cell connects the driving end of the light source unit, and the light beam that the light source unit is sent out is divided by focussed collimated
Unit, which focuses, enters the single-ended of the first one-to-two optical fiber, and light beam is entered standard by the both-end of the first one-to-two optical fiber respectively
Straight unit, light beam enter beam selector by collimation unit, and light beam respectively enters Measurement channel unit by beam selector
And reference channel unit, the light beam of the Measurement channel unit and the output of reference channel unit pass through focusing unit and enter the respectively
The both-end of two one-to-two optical fiber, the input terminal of the single-ended connection spectrometer of the second one-to-two optical fiber;Chinese patent
A kind of multi-parameter water quality real time on-line monitoring device based on spectroscopic methodology disclosed in 201611258828.2 includes hernia lamp source, preceding
Set light path, spectrum acquiring unit, quick processing platform and output unit;Hernia lamp source emergent light is divided into after preposition light path
Correct reference path and optical path;Correction reference path is incident to spectrum acquiring unit by water sample to be measured;Optical path
It is incident to spectrum acquiring unit by standard water sample;Correction reference path and optical path are synchronized by spectrum acquiring unit and are obtained
It is sent to fast processing unit after being converted to two groups of curve of spectrum digital signals after taking;Fast processing unit is respectively to two groups of spectrum
Curve digital signal passes through output after obtaining the concentration of test substance present in water sample to be measured and test substance after being handled
Unit is output to Local or Remote to realize monitoring;Fast processing unit is flat for the multi-parameter water-quality Intelligent treatment based on ARM
Platform;Disclosed in Chinese patent 201611217385.2 it is a kind of based on uv-vis spectra detection water quality detection system include light
Test cell one, spectrum test unit two and power supply are composed, the spectrum test unit one and spectrum test unit two are equal
Include light source, detection probe and spectrometer, spectrum test unit one and spectrum test unit two respectively with industrial computer one
It is connected with industrial computer two, industrial computer one and industrial computer two are connect with master control computer, the master control meter
Calculation machine is connected separately with warning device, memory module, display module and instrument control module, and instrument control module is connected separately with cleaning system
And flow path system, cleaning system connect flow path system, are connected with sample pretreatment apparatus on flow path system, flow path system is given respectively
Spectrum test unit one and spectrum test unit two provide test sample, and the power supply is to system power supply, specimen preprocessing
It manages device to remove the impurity in sample, then by flow path system by sample collection to spectrum test unit one and spectrum test list
Member two, ultraviolet-visible light is transmitted to detection probe by light source by input path, after light is absorbed by sample, passes through emergent light
Photoelectric signal transformation at digital spectrum data and is transferred to industrial computer one and industrial computer by road to spectrometer, spectrometer
Two, industrial computer one and industrial computer two respectively obtain the uv-visible absorption spectroscopy of water quality, and calculate water quality ginseng
Calculated water quality parameter is transmitted to master control computer by number, industrial computer one and industrial computer two respectively, and master control calculates
The corresponding parameter of each two is compared by machine, when gap exceeds preset range, starts warning device, if gap does not have
Beyond preset range, master control computer takes data of the average value of two data as last test, sends respectively
It is stored and is shown to memory module and display module, cleaning system is controlled by instrument control module, and flow path system carries out
Cleaning;It includes detection that Chinese patent 201720003938.8, which discloses a kind of multi-parameter water quality detector based on spectrum analysis,
Case, collimated light source, embedded system, single-chip computer control system, the detection case is interior to be equipped with detection cell and ultrasonic tank, detection cell
It is separated by partition board with ultrasonic tank, electric heater is installed in detection case middle part of sliding channel, detect the side installation of lower box part
There is collimated light source, the other side for detecting lower box part is equipped with focalizer, and the side of focalizer is equipped with spectroanalysis instrument, spectrum point
The signal output end of analyzer is connected with embedded system, and embedded system is connected with single-chip computer control system by serial communication
It connects, the bottom of detection case is equipped with supersonic generator, and supersonic generator is connected with ultrasonic transducer;Chinese patent
A kind of multi-parameter water quality real time on-line monitoring device based on spectroscopic methodology disclosed in 201621477557.5 includes hernia lamp source, preceding
Set light path, spectrum acquiring unit, quick processing platform and output unit;Hernia lamp source emergent light is divided into after preposition light path
Correct reference path and optical path;Correction reference path is incident to spectrum acquiring unit by water sample to be measured;Optical path
It is incident to spectrum acquiring unit by standard water sample;Correction reference path and optical path are synchronized by spectrum acquiring unit and are obtained
It is sent to fast processing unit after being converted to two groups of curve of spectrum digital signals after taking;Fast processing unit is respectively to two groups of spectrum
Curve digital signal passes through output after obtaining the concentration of test substance present in water sample to be measured and test substance after being handled
Unit is output to Local or Remote to realize monitoring;Fast processing unit is flat for the multi-parameter water-quality Intelligent treatment based on ARM
Platform;A kind of rotation adjustable type spectroanalysis instrument disclosed in Chinese patent 201710909925.1 includes fixed bottom plate and weldment,
Support plate is installed on the fixed bottom plate, stud is provided in the threaded block, one end of the stud is equipped with sleeve, institute
The one end for stating sleeve is equipped with fixed link, and one end of the fixed link is equipped with fastening seat, and the surface of the fastening seat is provided with
One end of clamping screw, the shaft is equipped with U-shaped fixed frame, and one end of the U-shaped fixed frame is equipped with powerful electromagnetic chuck, described
There are four powerful electromagnetic chuck is arranged altogether, two powerful electromagnetic chucks are one group, and spectroanalysis instrument is provided between two groups of powerful electromagnetic chucks, described
The top of support plate is equipped with pedestal, and dustproof cover is equipped on the pedestal;Spectral analysis technique can not only analyze substance
Constituent also carries out quantitative analysis, easy to operate, analysis using the relationship of the absorbance of spectrum and material concentration to substance
Speed is fast, secondary pollution is not present, and spectroscopy measurements water quality more meets the idea of development of modern measuring instrument;But the above patent
Product and spectral analysis apparatus in the prior art are expensive, and volume is larger, are unfavorable for real-time on-site detection.Therefore, it researches and develops
Design a kind of small volume and less weight, photoelectric sensing measuring device of low cost, easy to use and highly practical, have good society and
Economic value has a extensive future.
Invention content:
It is an object of the invention to overcome disadvantage of the existing technology, a kind of small volume and less weight of R & D design, it is of low cost,
Photoelectric sensing measuring device easy to use and highly practical, using the structure of filter wheel and Wavelength tunable light source, by different waves
Long bandpass filter is placed in the different transparent windows of optical filtering rim of wheel circumference, and selection wavelength is realized using the rotation of filter wheel
Function, carry out quickly analysis and non-secondary pollution water quality monitoring.
To achieve the goals above, the agent structure of photoelectric sensing measuring device of the present invention includes pedestal, No.1
Holder, No. two holders, No. three holders, No. four holders, No. five holders, No. six holders, light source, the polarizer, lens combination, motor,
Filter wheel, through-hole, optical filter, transparent window, sample bin, dummy pipe, rear tube and detector;The pedestal of rectangular plate-like structure
Upper surface is disposed with No.1 holder, No. two holders, No. three holders, No. four holders, No. five holders and No. six branch from left to right
Frame, pedestal connect with No.1 holder, No. two holders, No. three holders, No. four holders, No. five holders and No. six support bracket bolt formulas respectively
It connects, the top of No.1 holder is equipped with light source, and the top of No. two holders is equipped with the polarizer, and the top of No. three holders is equipped with
Microscope group is closed, and the agent structure of lens combination includes heavy caliber collimating lens, focusing lens and small-bore collimation lens, and heavy caliber is accurate
Straight lens, condenser lens and small-bore collimation lens array from left to right, heavy caliber collimating lens, focusing lens and osculum
The center of diameter collimation lens is located on the same line, and the top of No. four holders is equipped with motor, the filter of motor and circular configuration
Halo connects, and the through-hole of n-2 circular configuration is equidistantly offered on the circumference of filter wheel, is equipped in wherein n-1 through-hole
The different optical filter of the wavelength of circular sheet-like structures is equipped with the transparent window of circular configuration, No. five holders in remaining 1 through-hole
Top the sample bin of hollow type rectangular parallelepiped structure is installed, be provided with the leading of circular configuration on the front side of sample bin
It manages, the rear tube of circular configuration is provided in the rear side of sample bin, the top of No. six holders is provided with detector;Lens group
The center of conjunction, one of optical filter, sample bin and detector is in same horizontal optical path.
Pedestal, No.1 holder, No. two holders, No. three holders, No. four holders, No. five holders and No. six branch of the present invention
The material of frame is stainless steel;Light source be include deuterium lamp, halogen tungsten lamp, xenon lamp, light emitting diode, super-radiation light source, semiconductor
The wide spectrum light source of image intensifer, fiber amplifier, non-single-mode optics and composite light source from space;The polarizer can be from natural light
Middle acquisition polarised light;Heavy caliber collimation lens in lens combination is the collimation lens that clear aperture is 1 millimeter to 7 centimetres, is gathered
Focus lens are transmission-type lens, and small-bore collimation lens is the collimation lens that clear aperture is 0.01 millimeter to 1 centimetre;Motor is
Decelerating motor, servo motor or DC stepping motor drive filter wheel rotation to select light path lens combination-sample when motor rotates
The optical filter of different wave length in product storehouse;The quantity of through-hole on filter wheel is selected according to the quantity of the optical filter of required different wave length
Take, the quantity of through-hole than optical filter quantity more than 1;Optical filter is bandpass-type optical filter;Transparent window is used as and sends out other waves
The testing light source of Duan Bochang passes through window;Sample bin is for storing testing liquid;Dummy pipe flows into sample as testing liquid
The channel in storehouse;Rear tube flows out the channel of sample bin as testing liquid;Detector is photon detector.
Photoelectric sensing measuring device of the present invention in use, by the through-hole number consecutively on filter wheel be 0,1,2,
3 ... N, and it is placed in the through-hole that number is 1,2,3 ... N the optical filter of different wave length, the corresponding wavelength of optical filter successively
Respectively λ1, λ2……λN, the through-hole without being placed in optical filter that number is 0 is transparent window, is installed in the left side of transparent window
Testing light source installs photodetector on the right side of transparent window, and the wavelength of testing light source is λ0, testing light source and photodetection
The light path of device is located on same axis, and testing light source includes laser, light emitting diode, lamp and natural light, wavelength X0It is packet
A wavelength in testing light source spectral band is included, photodetector being capable of a length of λ of probing wave0Light;Opening motor makes it
Filter wheel rotation is driven, waits for the center of lens combination, the optical filter in No. 1 through-hole, sample bin and detector in same level
When in light path, light source is opened, light source sends out natural light, and the polarizer obtains the polarised light in natural light, and polarised light passes through heavy caliber
Directional light is coupled as by heavy caliber collimation lens when collimation lens, directional light is focused lens focus when passing through condenser lens be small
The light of light field range is coupled as small light field model when the light of small light field range passes through small-bore collimation lens by small-bore collimation lens
The directional light of the directional light enclosed, small light field range becomes monochromatic light after the optical filter in No. 1 through-hole, and monochromatic light passes through sample
The optical signal for carrying sample message is formed behind product storehouse, the optical signal detected is converted to current signal, current signal by detector
Analog voltage is obtained by amplifying circuit, analog voltage is the digital voltage value that can be read by microcontroller analog-to-digital conversion, is utilized
The quantitative model of digital voltage value and location parameter can obtain on-line checking value;Period, when photodetector detects test
When the optical signal that light source is sent out, illustrate the optical filter in No. 1 through-hole on the optical axis of light path lens combination-sample bin, detector
Detect be wavelength be λ1Optical signal, the time that filter wheel uniform rotation one is enclosed is T, and filter wheel has N number of through-hole, detector
It is the corresponding optical signal of wavelength X, the optical signal that photodetector detects to detect optical signal a P, P every the time of T/N
For P0, P0For wavelength X0Corresponding optical signal, then wavelength X, optical signal P and P0Shown in correspondence following table with time T:
, it can be seen that wavelength X can be accurately positioned in testing light source and photodetector from upper table, moreover it is possible to it
He is accurately positioned wavelength, to accurately obtain response of the detector to different wave length.
Compared with prior art, the present invention a transparent window is devised on the circumference of filter wheel, it is transparent corresponding to
A testing light source and photodetector are installed in the coaxial optical path of window, for wavelength to be accurately positioned, filter wheel and light source rise
Inclined device, lens combination, sample bin, detector and Simple mechanical holder combination are fabricated to the photoelectric sensing based on Wavelength tunable light source
Measuring device drives filter wheel rotation, to change the optical filter to work in light path lens combination-sample bin, come accurate by motor
Determine that the different wavelength in position, the polarised light in the natural light that polarizer acquisition light source is sent out form parallel after lens combination
Light, the optical signal of directional light are converted to current signal after being detected by detector, and current signal is simulated by amplifying circuit
Voltage is the digital voltage value that can be read using microcontroller analog-to-digital conversion, utilizes the quantitative model of voltage value and location parameter
It can obtain on-line checking value;Its is simple in structure, small volume and less weight, at low cost, is easy to make, convenient to use, real-time,
There is no secondary pollutions, are particularly suitable for deep ultraviolet light wave band.
Description of the drawings:
Fig. 1 is the agent structure principle schematic of the present invention.
Fig. 2 is the agent structure principle schematic of lens combination of the present invention.
Fig. 3 is the agent structure principle schematic of filter wheel of the present invention.
Fig. 4 is the agent structure principle schematic of sample bin of the present invention.
Fig. 5 is the principle schematic that photoelectric sensing measuring device of the present invention carries out wavelength positioning.
Specific implementation mode:
The present invention is described further by way of example and in conjunction with the accompanying drawings.
Embodiment 1:
The agent structure for the photoelectric sensing measuring device that the present embodiment is related to includes 2, No. two pedestal 1, No.1 holder holders
3,6, No. six holders 7 of No. three holders of holder 5, five of holder 4, four, light source 8, the polarizer 9, lens combination 10, motor 11, filter
Halo 12, through-hole 13, optical filter 14, transparent window 15, sample bin 16, dummy pipe 17, rear tube 18 and detector 19;Rectangular slab
The upper surface of the pedestal 1 of shape structure is disposed with 4, No. four holders of holder of holder 3, three of No.1 holder 2, two from left to right
5, No. five holders 6 and No. six holders 7, pedestal 1 respectively with 4, No. four holders 5, five of holder of holder 3, three of No.1 holder 2, two
Number holder 6 is connected with No. six 7 bolt types of holder, and the top of No.1 holder 2 is equipped with light source 8, and the top of No. two holders 3 is equipped with
The top of the polarizer 9, No. three holders 4 is equipped with lens combination 10, and the agent structure of lens combination 10 includes that heavy caliber collimation is saturating
Mirror 101, condenser lens 102 and small-bore collimation lens 103, heavy caliber collimation lens 101, condenser lens 102 and small-bore standard
Straight lens 103 array from left to right, heavy caliber collimation lens 101, condenser lens 102 and small-bore collimation lens 103
Center is located on the same line, and the top of No. four holders 5 is equipped with motor 11, and motor 11 and the filter wheel 12 of circular configuration connect
It connects, the through-hole 13 of n-2 (n is more than 2 integer) a circular configuration, wherein n-1 is equidistantly offered on the circumference of filter wheel 12
The different optical filter 14 of the wavelength of circular sheet-like structures is installed in a through-hole 13, round knot is installed in remaining 1 through-hole 13
The top of the transparent window 15 of structure, No. five holders 6 is equipped with the sample bin 16 of hollow type rectangular parallelepiped structure, the front of sample bin 16
It is provided with the dummy pipe 17 of circular configuration on side, the rear tube 18 of circular configuration is provided in the rear side of sample bin 16,
The top of No. six holders 7 is provided with detector 19;Lens combination 10, one of optical filter 14, sample bin 16 and detector 19
Center in same horizontal optical path.
Pedestal 1 that the present embodiment is related to, the holder 6 of holder 5, five of holder 4, four of holder 3, three of No.1 holder 2, two
Material with No. six holders 7 is stainless steel;Light source 8 be include deuterium lamp, it is halogen tungsten lamp, xenon lamp, light emitting diode (LED), super
Radiating light source, semiconductor optical amplifier, fiber amplifier, the non-single-mode optics (sunlight) from space and composite light source (shine
Wavelength is from ultraviolet, visible to infrared) wide spectrum light source;The polarizer 9 can obtain polarised light from natural light;In lens combination 10
Heavy caliber collimation lens 101 be collimation lens that clear aperture is 1 millimeter to 7 centimetres, condenser lens 102 is that transmission-type is saturating
Mirror, small-bore collimation lens 103 are the collimation lens that clear aperture is 0.01 millimeter to 1 centimetre;Motor 11 is decelerating motor, watches
Motor or DC stepping motor are taken, drives the rotation of filter wheel 12 to select light path lens combination 10- sample bins when motor 11 rotates
The optical filter 14 of different wave length in 16;The quantity of through-hole 13 on filter wheel 12 is according to the optical filter 14 of required different wave length
Quantity is chosen, the quantity of through-hole 13 than optical filter 14 quantity more than 1;Optical filter 14 is bandpass-type optical filter;Transparent window 15
Pass through window as the testing light source 200 for sending out other band wavelengths;Sample bin 16 is for storing testing liquid;Dummy pipe 17
The channel of sample bin 16 is flowed into as testing liquid;Rear tube 18 flows out the channel of sample bin 16 as testing liquid;Detector
19 be photon detector.
Photoelectric sensing measuring device that the present embodiment is related in use, be 0 by 13 number consecutively of through-hole on filter wheel 12,
1,2,3 ... N, and it is placed in the through-hole 13 that number is 1,2,3 ... N the optical filter 14 of different wave length, optical filter 14 successively
Corresponding wavelength is respectively λ1, λ2……λN, the through-hole 13 without being placed in optical filter 14 that number is 0 is transparent window 15, saturating
Testing light source 200 is installed in the left side of bright window 15, and photodetector 300, testing light source 200 are installed on the right side of transparent window 15
Wavelength be λ0, the light path of testing light source 200 and photodetector 300 is located on same axis, and testing light source 200 includes swashing
Light device, light emitting diode, lamp and natural light, wavelength X0A wavelength being included in 200 spectral band of testing light source, photoelectricity
Detector 300 being capable of a length of λ of probing wave0Light;Opening motor 11 makes it that filter wheel 12 be driven to rotate, and waits for lens combination 10,1
Light source 8, light are opened when in same horizontal optical path in the center of optical filter 14, sample bin 16 and detector 19 in through-hole 13
Source 8 sends out natural light, and the polarizer 9 obtains the polarised light in natural light, by big mouth when polarised light passes through heavy caliber collimation lens 101
Diameter collimation lens 101 is coupled as directional light, and directional light is focused lens 102 when passing through condenser lens 102 and is focused to small light field model
The light enclosed is coupled as small light field model when the light of small light field range passes through small-bore collimation lens 103 by small-bore collimation lens 103
The directional light of the directional light enclosed, small light field range becomes monochromatic light, monochromatic light warp after the optical filter 14 in No. 1 through-hole 13
The optical signal for carrying sample message is formed after crossing sample bin 16, the optical signal detected is converted to current signal by detector 19,
Current signal obtains analog voltage by amplifying circuit, and analog voltage is the digital voltage that can be read by microcontroller analog-to-digital conversion
Value, on-line checking value can be obtained using the quantitative model of digital voltage value and location parameter;Period, when photodetector 300
When detecting the optical signal that testing light source 200 is sent out, illustrate the optical filter 14 in No. 1 through-hole 13 in light path lens combination 10- samples
On the optical axis in product storehouse 16, what detector 19 detected is that wavelength is λ1Optical signal, 12 uniform rotation one of filter wheel circle time
For T, filter wheel 12 has N number of through-hole 13, and it is that wavelength X is corresponding that detector 19 detects optical signal a P, P every the time of T/N
Optical signal, the optical signal that photodetector 300 detects are P0, P0For wavelength X0Corresponding optical signal, then wavelength X, optical signal P
And P0Shown in correspondence following table with time T:
T | 0 | T/N | 2T/N | …… | (N-1)T/N | T | T+T/N | T+2T/N | …… |
λ | λ1 | λ2 | λ3 | …… | λN | λ1 | λ2 | λ3 | …… |
P0 | 1 | 0 | 0 | …… | 0 | 1 | 0 | 0 | …… |
P | P1 | P2 | P3 | …… | Pn | P1 | P2 | P3 | …… |
, it can be seen that wavelength X can be accurately positioned in testing light source 200 and photodetector 300 from upper table, also
Other wavelength can be accurately positioned, to accurately obtain response of the detector 19 to different wave length.
Claims (3)
1. a kind of photoelectric sensing measuring device, it is characterised in that agent structure include pedestal, No.1 holder, No. two holders, No. three
Holder, No. four holders, No. five holders, No. six holders, light source, the polarizer, lens combination, motor, filter wheel, through-hole, optical filter,
Transparent window, sample bin, dummy pipe, rear tube and detector;The upper surface of the pedestal of rectangular plate-like structure is from left to right successively
Be provided with No.1 holder, No. two holders, No. three holders, No. four holders, No. five holders and No. six holders, pedestal respectively with No.1 branch
Frame, No. two holders, No. three holders, No. four holders, No. five holders and No. six support bracket bolt formula connections, the top installation of No.1 holder
There are light source, the top of No. two holders that the polarizer is installed, the top of No. three holders is equipped with lens combination, the main body of lens combination
Structure includes heavy caliber collimating lens, focusing lens and small-bore collimation lens, heavy caliber collimating lens, focusing lens and osculum
Diameter collimation lens arrays from left to right, and the center of heavy caliber collimating lens, focusing lens and small-bore collimation lens is located at
On same straight line, the top of No. four holders is equipped with motor, the filter wheel connection of motor and circular configuration, the circumference of filter wheel
On equidistantly offer the through-hole of n-2 circular configuration, the wavelength that circular sheet-like structures are equipped in wherein n-1 through-hole is different
Optical filter, the transparent window of circular configuration is installed, it is rectangular that the tops of No. five holders is equipped with hollow type in remaining 1 through-hole
The sample bin of body structure is provided with the dummy pipe of circular configuration on the front side of sample bin, is set in the rear side of sample bin
It is equipped with the rear tube of circular configuration, the top of No. six holders is provided with detector;Lens combination, one of optical filter, sample
Storehouse and the center of detector are in same horizontal optical path.
2. a kind of photoelectric sensing measuring device according to claim 1, it is characterised in that the pedestal, No.1 holder, two
Number holder, No. three holders, No. four holders, No. five holders and No. six holders material be stainless steel;Light source be include deuterium lamp, halogen
Tungsten lamp, xenon lamp, light emitting diode, super-radiation light source, semiconductor optical amplifier, fiber amplifier, the non-single mode from space
The wide spectrum light source of light and composite light source;The polarizer can obtain polarised light from natural light;Heavy caliber collimation in lens combination
Lens are the collimation lens that clear aperture is 1 millimeter to 7 centimetres, and condenser lens is transmission-type lens, and small-bore collimation lens is
The collimation lens that clear aperture is 0.01 millimeter to 1 centimetre;Motor is decelerating motor, servo motor or DC stepping motor, electricity
Drive filter wheel rotation to select the optical filter of the different wave length in light path lens combination-sample bin when machine rotates;On filter wheel
The quantity of through-hole chosen according to the quantity of the optical filter of required different wave length, the quantity of through-hole than optical filter quantity more than 1;
Optical filter is bandpass-type optical filter;Transparent window passes through window as the testing light source for sending out other band wavelengths;Sample bin
For storing testing liquid;Dummy pipe flows into the channel of sample bin as testing liquid;Rear tube flows out sample as testing liquid
The channel in product storehouse;Detector is photon detector.
3. photoelectric sensing measuring device according to claim 1, it is characterised in that in use, by the through-hole on filter wheel according to
Secondary number is 0,1,2,3 ... N, and is placed in the optical filter of different wave length successively in the through-hole that number is 1,2,3 ... N, filter
The corresponding wavelength of mating plate is respectively λ1, λ2……λN, the through-hole without being placed in optical filter that number is 0 is transparent window, transparent
Testing light source is installed in the left side of window, installs photodetector on the right side of transparent window, the wavelength of testing light source is λ0, test
The light path of light source and photodetector is located on same axis, and testing light source includes laser, light emitting diode, lamp and nature
Light, wavelength X0A wavelength being included in testing light source spectral band, photodetector being capable of a length of λ of probing wave0Light;
Opening motor makes it drive filter wheel rotation, waits for the center of lens combination, the optical filter in No. 1 through-hole, sample bin and detector
When in same horizontal optical path, light source is opened, light source sends out natural light, and the polarizer obtains the polarised light in natural light, polarization
Directional light is coupled as by heavy caliber collimation lens when light passes through heavy caliber collimation lens, directional light is focused when passing through condenser lens
Lens focus is the light of small light field range, by small-bore collimation lens coupling when the light of small light field range passes through small-bore collimation lens
It is combined into the directional light of small light field range, the directional light of small light field range becomes monochromatic light after the optical filter in No. 1 through-hole,
Monochromatic light forms the optical signal for carrying sample message after sample bin, and the optical signal detected is converted to electric current by detector to be believed
Number, current signal obtains analog voltage by amplifying circuit, and analog voltage is the number that can be read by microcontroller analog-to-digital conversion
Voltage value can obtain on-line checking value using the quantitative model of digital voltage value and location parameter;Period works as photodetector
When detecting the optical signal that testing light source is sent out, illustrate the optical filter in No. 1 through-hole light path lens combination-sample bin optical axis
On, what detector detected is that wavelength is λ1Optical signal, the time that filter wheel uniform rotation one is enclosed is T, and filter wheel has N number of logical
Hole, it is the corresponding optical signal of wavelength X that detector detects optical signal a P, P every the time of T/N, and photodetector detects
Optical signal be P0, P0For wavelength X0Corresponding optical signal, then wavelength X, optical signal P and P0With the correspondence following table institute of time T
Show:
, it can be seen that wavelength X can be accurately positioned in testing light source and photodetector from upper table, moreover it is possible to other waves
Length is accurately positioned, to accurately obtain response of the detector to different wave length.
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