CN108315755A - A kind of hydrogen-rich cup - Google Patents

A kind of hydrogen-rich cup Download PDF

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Publication number
CN108315755A
CN108315755A CN201810159115.3A CN201810159115A CN108315755A CN 108315755 A CN108315755 A CN 108315755A CN 201810159115 A CN201810159115 A CN 201810159115A CN 108315755 A CN108315755 A CN 108315755A
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CN
China
Prior art keywords
hydrogen
oxygen
cup
electrolysis unit
voltage
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Pending
Application number
CN201810159115.3A
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Chinese (zh)
Inventor
王泽智
关鸿杰
张根荣
陈致东
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Shenzhen City Quantum Hydrogen Biotechnology Co Ltd
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Shenzhen City Quantum Hydrogen Biotechnology Co Ltd
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Priority to CN201810159115.3A priority Critical patent/CN108315755A/en
Publication of CN108315755A publication Critical patent/CN108315755A/en
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70Assemblies comprising two or more cells
    • C25B9/73Assemblies comprising two or more cells of the filter-press type
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00Operating or servicing cells
    • C25B15/02Process control or regulation
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Automation & Control Theory (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The invention discloses hydrogen-rich cups, including pressure control solubilising cup lid, cup body and hydrogen-oxygen detach electrolysis system, cup lid interface is arranged in cup body rim of a cup, pressure control solubilising cup lid is detachably connected with cup body by cup lid interface, pressure control solubilising cup lid is equipped with air hole, and water proof ventilated membrane is provided in air hole, and hydrogen-oxygen detaches electrolysis system and is arranged in bottom of cup.The hydrogen-rich cup of the present invention may be implemented cup body and keep under pressure, increasing hydrogen and being dissolved into the concentration in water by pressure control solubilising cup lid, while the pressure for controlling cup body is not too large causes danger.

Description

A kind of hydrogen-rich cup
Technical field
The present invention relates to electrolysis tech fields, more particularly to can make the hydrogen-rich cup of hydrogen-rich water.
Background technology
Scientific research proves that the nearly all chronic disease of human body has substantial connection with Free radicals injury.From 2007 Year, Japanese Ohta Shigeo professor delivered authoritative paper, it was demonstrated that there is hydrogen selectivity to neutralize hydroxy radical and nitrous acid anion Etc. poisonous and harmful free radical, to which since playing selective antioxidation, hydrogen medicine rapidly develops in health industry.With The offer of quality of life, people focus more on the health of itself.
The major way of human intake's hydrogen drinks hydrogen-rich water, injection hydrogen physiological saline, is directly sucked in hydrogen etc., wherein Hydrogen applies earliest hydrogen-rich water field.The product of market is mainly hydrogen-rich cup at present, it is stored in water by the way that hydrogen is molten, is led to It crosses and directly drinks acquisition hydrogen.Which is more convenient, but molten degree of depositing is very low in water for hydrogen under normal temperature and pressure, generally 0.5-0.8ppm (mass concentration is 8/1/1000000ths five to million), will play its therapeutic effect, need to drink With a large amount of hydrogen water.
The hydrogen-rich cup or do not provide to the water supercharging in cup that the prior art provides so that hydrogen soluble in water It is limited, while causing the hydrogen largely generated and being dispersed into air, it causes to waste.Although providing supercharging equipment, But without suitable release of pressure mechanism so that the pressure of cup body is increasing, easy tos produce danger.
Invention content
The problem of for existing hydrogen-rich cup, the embodiment of the present invention provide hydrogen-rich cup, can increase the certain pressure of water, The concentration of hydrogen in water is set to be greatly improved.Simultaneously when pressure is more than certain value, hydrogen can be discharged from cup, avoid Pressure causes greatly very much danger in cup.
A kind of hydrogen-rich cup provided in an embodiment of the present invention, including pressure control solubilising cup lid, cup body and hydrogen-oxygen separation electrolysis system Cup lid interface is arranged in system, cup body rim of a cup, and pressure control solubilising cup lid is detachably connected with cup body by cup lid interface, pressure control solubilising cup lid It is equipped with air hole, water proof ventilated membrane is provided in air hole, hydrogen-oxygen detaches electrolysis system and is arranged in bottom of cup.
Hydrogen-rich cup provided in an embodiment of the present invention is arranged logical by providing pressure control solubilising cup lid in pressure control solubilising cup lid Stomata, while water proof ventilated membrane is set in air hole.The characteristics of water proof ventilated membrane is the gas only when pressure is more than 0.1MPa Body can just be discharged from water proof ventilated membrane, and will not leak.In insufficient pressure 0.1MPa, gas cannot be discharged, to protect The operating pressure demonstrate,proved in cup body is maintained close to 0.1MPa always.This both can fully increase hydrogen in water by pressure Solubility improves hydrogen-rich water concentration in the working unit time, and can stablize the pressure maintained in cup body, it is ensured that cup makes With safety.So as to avoid explosion may occur for hydrogen-oxygen mixing, pressure crosses danger and the pressure mistake of bulk container leak or explosion The too low deficiency of hydrogen-rich water concentration in the low unit interval.Hydrogen-rich cup provided by the invention, not complicated electronics or control Structure, equipment is simple, and assembling realization is simple for process, stable and reliable in work.
Preferably, pressure control solubilising cup lid includes upper cover and lower cover, and upper cover and lower cover opposite position are both provided with air hole, The setting of water proof ventilated membrane is correspondingly arranged between the upper cover, lower cover, and with air hole, and lower cover is fixed on upper cover bottom surface.
Preferably, upper cover includes air hole column jacket, and lower cover includes air hole inner prop, and water proof ventilated membrane is fitted tightly over ventilative On the stomata of hole inner prop, air hole inner prop is inserted into air hole column jacket.
Preferably, pressure control solubilising cup lid further includes the 4th sealed silicon cushion rubber, and through-hole is provided among the 4th sealed silicon cushion rubber, 4th sealed silicon cushion rubber is nested in by through-hole on lower lid.
Preferably, hydrogen-oxygen separation electrolysis system includes hydrogen-oxygen separation electrolysis unit and hydrogen-oxygen separation electrolysis unit control system System;Hydrogen-oxygen, which detaches electrolysis unit set-up of control system and detaches the bottom of electrolysis unit in the hydrogen-oxygen and sealed with bottom plate, to be connected It connects.
Hydrogen-oxygen detaches electrolysis unit, including electrolysis generator, upper mounted plate and bottom plate, electrolysis generator include cathode Piece, anode strip, selective proton penetrate film, and cathode connection end, cathode connection end external power supply cathode, anode strip is arranged in cathode sheets Anode connection end is set, and anode connection end external power supply is positive, electrode hole is arranged on bottom plate, anode connection end and cathode connect Line end passes through electrode hole, top surface setting and cathode sheets, the selective proton of the bottom surface of upper mounted plate and the bottom plate to penetrate The matched accommodating cavity of film, anode plate shape, bottom plate are detachably connected with upper mounted plate, and cathode sheets, selective proton are saturating Cross film, anode strip is fixed in the accommodating cavity between upper mounted plate and bottom plate, cathode sheets penetrate film with selective proton Between form hydrogen generation area, anode strip and selective proton through forming oxygen generation area, the setting of hydrogen generation area between film Hydrogen generation area is discharged in hydrogen discharge confession hydrogen and water enters hydrogen generation area, and oxygen generation area is arranged oxygen floss hole and supplies oxygen Oxygen generation area is discharged in gas.
Preferably, hydrogen-oxygen separation electrolysis unit further includes battery plate spiral cover, and bottom plate corresponds to the setting of electrolysis generator region Through-hole, battery plate spiral cover are arranged in through-hole, and battery plate spiral cover can be moved up and down along the through-hole.
Preferably, multiple air holes are set on cathode sheets and anode strip.
Preferably, cathode sheets, anode strip, selective proton are disposed as size through film, upper mounted plate and bottom plate Matched circle, cathode sheets, selective proton are fixed on upper mounted plate and lower solid through film, anode strip by sequence from top to bottom Between fixed board, oxygen floss hole is arranged on bottom plate, and anode strip, selective proton are penetrated and sealed between film and bottom plate Connection.
Preferably, selective proton is to penetrate film from humidification type proton through film.
Preferably, further include moisturizing silicagel pad, the moisturizing silicagel pad is removably disposed in hydrogen-oxygen separation electrolysis unit On.
Preferably, hydrogen-oxygen detaches electrolysis unit control system, including microprocessor, memory, automatic Regulation module and opens Powered-down road, microprocessor are separately connected memory, automatic Regulation module and switching circuit, outside automatic Regulation modular power source input terminal Connect power supply, the anode of the external hydrogen-oxygen separation electrolysis unit of automatic Regulation modular power source output head anode, automatic Regulation modular power source The cathode of the external hydrogen-oxygen separation electrolysis unit of negative pole of output end;
Memory is stored with detaches the preset booting voltage detecting value of electrolysis unit operating voltage according to hydrogen-oxygen, controls voltage Step value and computer executable program, computer executable program in microcomputer reads memory simultaneously realize following control Method:
Be switched on voltage detecting step:The supply voltage of external power supply is detected, if the supply voltage is less than booting voltage inspection Measured value is stopped and prompts undertension, otherwise, executes next step;
Automatic boosting step:Control automatic Regulation module is stepped up with preset control voltage steps value is input to hydrogen-oxygen The voltage for detaching electrolysis unit cathode and anode, until the real work voltage that hydrogen-oxygen detaches electrolysis unit cathode and anode reaches Be switched on voltage detecting value.
Preferably, hydrogen-oxygen detaches electrolysis unit control system, further includes sampling comparison circuit, and circuit input end is compared in sampling It is separately connected automatic Regulation modular power source output head anode and cathode, circuit output end connection microprocessor, sampling are compared in sampling Comparison circuit obtains the real work voltage of hydrogen-oxygen separation electrolysis unit, and is input to microprocessor, and microprocessor executes calculating Machine executable program realizes following control method:
Automatic Regulation step:The size for comparing the real work voltage and the booting voltage detecting value, if practical Operating voltage is more than the booting voltage detecting value, and control automatic Regulation module reduces the electricity that output detaches electrolysis unit to hydrogen-oxygen Pressure, until the real work voltage is equal to booting voltage detecting value, if real work voltage is less than booting voltage detecting value, It controls automatic Regulation module and increases the voltage that output detaches electrolysis unit to hydrogen-oxygen, until real work voltage is equal to booting voltage Detected value.
Preferably, hydrogen-oxygen separation electrolysis unit control system further includes management of charging and discharging module and accumulator, automatic Regulation For module by management of charging and discharging module external power supply, accumulator is separately connected external power supply and automatic by management of charging and discharging module Voltage regulating module, management of charging and discharging module is in external power supply, for the capacitance adjustment charging voltage and charging electricity according to accumulator Stream;Management of charging and discharging module is in storage battery power supply, for carrying out overcurrent or overload protection to accumulator.
Preferably, hydrogen-oxygen separation electrolysis unit control system further includes light display apparatus, light display apparatus and Wei Chu Device connection is managed, light display apparatus is used to receive the signal of microprocessor, and display working condition, and working condition includes that booting is examined Survey, automatic boosting, automatic Regulation or power voltage insufficient.
Hydrogen-rich cup provided in an embodiment of the present invention may be implemented cup body and be maintained at certain by pressure control solubilising cup lid Under pressure, increases hydrogen and be dissolved into the concentration in water, while the pressure for controlling cup body is not too large causes danger.
Description of the drawings
Fig. 1 is a kind of hydrogen-rich water cup structure schematic diagram in the embodiment of the present invention;
Fig. 2 is pressure control solubilising cup lid structure schematic diagram in the embodiment of the present invention;
Fig. 3 is that hydrogen-oxygen detaches electrolysis unit control system architecture schematic diagram in the embodiment of the present invention;
Fig. 4 is that hydrogen-oxygen detaches electrolysis unit control system preferred embodiment structural schematic diagram in the embodiment of the present invention;
Fig. 5 is that hydrogen-oxygen detaches electrolysis unit decomposition figure structure schematic representation in the embodiment of the present invention;
Fig. 6 is that hydrogen-oxygen detaches electrolysis unit assembly structure diagram in the embodiment of the present invention.
In attached drawing:100, hydrogen-oxygen detaches electrolysis unit;111, cathode sheets;1112, cathode connection end;1113, cathode sheets are convex Platform;112, anode strip;1122, anode connection end;1123, anode strip boss;113, selective proton penetrates film;121, lower fixation Plate;122, electrode hole;131, upper mounted plate;132, fixed spiral cover;133, electrode card slot;134, cavity is housed;135, bayonet lock; 141, battery plate spiral cover;142, oxygen floss hole;151, the first sealed silicon cushion rubber;152, the second sealed silicon cushion rubber;153, third is close Seal silica gel ring;154, the 4th sealed silicon cushion rubber;161, hydrogen generation area;162, oxygen generation area;170, moisturizing silicagel pad; 200, hydrogen-oxygen detaches electrolysis unit control system;210, microprocessor;220, automatic Regulation module;230, memory;240, it opens Powered-down road;250, comparison circuit is sampled;260, management of charging and discharging module;270, accumulator;280, light display apparatus;290、 Inclination inducing system;300, cup body;310, pedestal is controlled;400, external power supply;500, pressure control solubilising cup lid;510, upper cover; 511, air hole column jacket;520, lower cover;521, air hole inner prop;530, water proof ventilated membrane.
Specific implementation mode
In the following, in conjunction with attached drawing and specific implementation mode, the present invention is described further, it should be noted that not Under the premise of conflicting, new implementation can be formed between various embodiments described below or between each technical characteristic in any combination Example.
A kind of hydrogen-rich cup provided in an embodiment of the present invention.Hydrogen-oxygen separation electrolysis system includes hydrogen-oxygen separation electrolysis unit, For producing hydrogen-rich water in daily life, disease prevention and conditioning body are carried out using hydrogen-rich water to meet people, is avoided in vivo Free radicals injury the problem of.
Embodiment 1:
As shown in Figure 1 and Figure 2, hydrogen-rich cup provided in an embodiment of the present invention, including pressure control solubilising cup lid 500, cup body 300 Electrolysis system is detached with hydrogen-oxygen, cup lid interface is arranged in 300 rim of a cup of cup body, and pressure control solubilising cup lid 500 passes through cup lid with cup body 300 Interface is detachably connected, and pressure control solubilising cup lid 500 is equipped with air hole, and water proof ventilated membrane 530, hydrogen-oxygen point are provided in air hole It is arranged in 300 bottom of cup body from electrolysis system.Pressure control solubilising cup lid 500 includes spiral shell by the connection of cup lid interface with cup body 300 Line connection snaps connection or using other common cooperation mounting means connections, such as being press-connected using elastomeric element. Preferably using threaded connection in technical scheme of the present invention.External screw thread is set in the rim of a cup of cup body 300, in pressure control solubilising cup lid Internal thread is arranged in 500 insides, and cup body 300 and pressure control solubilising cup lid 500 are linked together by the matching of screw thread.Cup body 300 is adopted With dedicated hydrogen-rich cup cup body, i.e., installing mechanism is set in the bottom of cup body 300, to install hydrogen-oxygen separation electrolysis system In 300 bottom of cup body.The control interface for providing waterproof simultaneously is connected to 300 outer wall of cup body, such as control switch, power interface etc..
Hydrogen-rich cup provided in an embodiment of the present invention, by providing pressure control solubilising cup lid 500, in pressure control solubilising cup lid 500 Venthole is set, while water proof ventilated membrane 530 is set in air hole.The characteristics of water proof ventilated membrane 530 is only super in pressure When crossing 0.1MPa, gas can just be discharged from water proof ventilated membrane 530, and will not leak.In insufficient pressure 0.1MPa, gas It cannot be discharged, to ensure that the operating pressure in cup body 300 is maintained close to 0.1MPa always.This can both be filled by pressure Divide and increase the solubility of hydrogen in water, improve hydrogen-rich water concentration in the working unit time, and can stablize and maintain in cup body 300 Pressure, it is ensured that cup it is safe to use.So as to avoid explosion may occur for hydrogen-oxygen mixing, pressure crosses bulk container leak or quick-fried Fried danger and the too low deficiency of hydrogen-rich water concentration in the hypotony unit interval.Hydrogen-rich cup provided by the invention, does not have Complicated electronics or control structure, equipment is simple, and assembling realization is simple for process, stable and reliable in work.
Wherein, pressure control solubilising cup lid 500 includes upper cover 510 and lower cover 520, and upper cover 510 and 520 opposite position of lower cover are equal It is provided with air hole, the setting of water proof ventilated membrane 530 is correspondingly arranged between the upper cover 510, lower cover 520, and with air hole, under Lid 520 is fixed on 510 bottom surface of upper cover.Upper cover 510 includes air hole column jacket 511, and lower cover 520 includes air hole inner prop 521, water proof Ventilated membrane 530 is fitted tightly on the stomata of air hole inner prop 521, and air hole inner prop 521 is inserted into air hole column jacket 511.
Pressure control solubilising cup lid 500 further includes the 4th sealed silicon cushion rubber 154, is provided among the 4th sealed silicon cushion rubber 154 logical Hole, the 4th sealed silicon cushion rubber 154 are nested in by through-hole on lower cover 520.By the way that the 4th sealed silicon cushion rubber 154, Ke Yizeng is arranged Add the water resistance and heat-insulating property of pressure control solubilising cup lid 500.
Hydrogen-oxygen separation electrolysis system includes hydrogen-oxygen separation electrolysis unit 100 and hydrogen-oxygen separation electrolysis unit control system 200; Hydrogen-oxygen separation electrolysis unit control system 200 by fixing piece be fixed on hydrogen-oxygen detach electrolysis unit 100 bottom and with it is lower solid Fixed board 121 is tightly connected.Hydrogen-oxygen detaches electrolysis system setting on control pedestal 310.In 300 bottom of cup body, installation knot is set Hydrogen-oxygen is detached the bottom of a cup that electrolysis system is fixed on cup body 300 by structure by the fixed pedestal 310 that controls.Hydrogen-oxygen detaches electrolysis system Hydrogen-oxygen separation electrolysis unit control system 200 and the concrete structure of hydrogen-oxygen separation electrolysis unit 100 refer to 2 He of embodiment Embodiment 3.
Embodiment 2:
As shown in Figure 3, Figure 4, a kind of hydrogen-oxygen separation electrolysis unit control system 200 provided in an embodiment of the present invention, including Microprocessor 210, memory 230, automatic Regulation module 220 and switching circuit 240, microprocessor 210 are separately connected memory 230, automatic Regulation module 220 and switching circuit 240,220 power input external power supply 400 of automatic Regulation module are automatic to adjust The anode of the external hydrogen-oxygen separation electrolysis unit 100 of die block 220 power output end anode, the output of 220 power supply of automatic Regulation module Hold the cathode of the external hydrogen-oxygen separation electrolysis unit 100 of cathode;
Memory 230 is stored with detaches the preset booting voltage detecting value of 100 operating voltage of electrolysis unit, control according to hydrogen-oxygen Voltage steps value processed and computer executable program, microprocessor 210 read the computer executable program in memory 230 simultaneously Realize following control method:
Be switched on voltage detecting step:The supply voltage of external power supply 400 is detected, if supply voltage is less than booting voltage detecting Value, is stopped and prompts undertension, otherwise, executes next step;
Automatic boosting step:Control automatic Regulation module 220 is stepped up with preset control voltage steps value to be input to Hydrogen-oxygen detaches the voltage of electrolysis unit 100 cathode and anode, until hydrogen-oxygen detaches the reality of electrolysis unit 100 cathode and anode Operating voltage reaches booting voltage detecting value.
In one of which preferred embodiment, preset booting voltage detecting value is set as hydrogen-oxygen separation electricity in memory 230 Solve the rated operational voltage of device.Automatic Regulation module 220 is input to hydrogen being stepped up with preset control voltage steps value The voltage of oxygen separating electrolysis unit 100 cathode and anode, it is increase 0.5V per second, output that control voltage steps value, which can such as be arranged, Reasonable voltage electric current detaches electrolysis unit 100 to hydrogen-oxygen.Reasonable voltage refers to electrode on-load voltage requirement and slowly boosts.
Switching circuit 240 control hydrogen-oxygen separation electrolysis system on/off, during shutdown, switching circuit 240 simultaneously with Unlike signal handles unlike signal operation timing, at the end of timing, microprocessor to microprocessor 210, microprocessor 210 210 by off signal to automatic Regulation module 220, complete to shut down.
A kind of hydrogen-oxygen separation electrolysis unit control system 200 provided in an embodiment of the present invention, passes through the detection electricity in booting Voltage increase to operating voltage is gradually avoided hydrogen-oxygen separation electrolysis by source voltage when starting hydrogen-oxygen and detaching electrolysis unit 100 Device 100 inputs the High variation voltage of moment being electrolysed the when of starting, to avoid generating ozone.
Hydrogen-oxygen separation electrolysis unit control system 200 provided in this embodiment can be directly connected to household by adapter and match Electricity.But which limit the uses of equipment.Since hydrogen-oxygen detaches the voltage and electricity that electrolysis unit 100 at work need not be very high Stream, in a kind of preferred embodiment, hydrogen-oxygen separation electrolysis unit control system 200 provided in an embodiment of the present invention further includes filling Management module 260 of discharging and accumulator 270, automatic Regulation module 220 pass through management of charging and discharging module 260 while external power supply 400 and accumulator 270.When powering using external power supply 400, the 5V voltage outputs of voltage stabilizing, charge and discharge are provided by charger Management module 260 can be according to the capacitance adjustment charging voltage and charging current of accumulator 270;External power supply 400 is not being accessed, And when being powered by accumulator 270, management of charging and discharging module 260 is provided carries out overcurrent or overload protection to accumulator 270.Charge and discharge Electric management module 260 can not damage battery simultaneously with quick charge, prolong by being protected to the charging and discharging of accumulator 270 The service life of slow battery.
Further include sampling comparison circuit 250 in a kind of preferred embodiment of the present embodiment, sampling comparison circuit 250 is defeated Enter end and be separately connected 220 power output end of automatic Regulation module anode and cathode, sampling 250 output end of comparison circuit connection is micro- Processor 210, sampling comparison circuit 250 obtain the real work voltage of hydrogen-oxygen separation electrolysis unit 100, and are input to microprocessor Device 210, microprocessor 210 execute computer executable program and realize following control method:
Automatic Regulation step:The size for comparing real work power supply and the voltage detecting value that is switched on, if real work voltage More than booting voltage detecting value, control automatic Regulation module 220 reduces the voltage that output detaches electrolysis unit 100 to hydrogen-oxygen, directly It is equal to booting voltage detecting value to real work voltage, if real work voltage is less than booting voltage detecting value, control is automatic Voltage regulating module 220 increases the voltage that output detaches electrolysis unit 100 to hydrogen-oxygen, until real work voltage is equal to booting voltage Detected value.
Comparison circuit 250 is sampled by setting, detects the operating voltage of hydrogen-oxygen separation electrolysis unit in real time, and in time by it Operating voltage adjusts the operating voltage and work electricity that hydrogen-oxygen separation electrolysis unit can be kept to keep stable to rated operational voltage Stream.Especially when being powered using accumulator 270, due to the electric quantity change with battery, it is easy to cause and is output to hydrogen-oxygen The operating voltage of separation electrolysis unit converts.It can ensure to generate hydrogen by providing stable operating voltage and operating current The stability of gas, while ensureing the meltage of hydrogen in water, ensure hydrogen water concentration.The operating voltage and operating current of Simultaneous Stabilization It is also beneficial to extend the service life of equipment.
Computer program realization can be executed by microprocessor 210 by sampling comparison circuit 250, can also pass through circuit reality It is existing.Hydrogen-oxygen is preset in sampling comparison circuit 250 detaches 100 rated operational voltage of electrolysis unit.Comparison circuit 250 is sampled to be arranged Sample circuit and comparison circuit, sample circuit obtain the real work voltage of hydrogen-oxygen separation electrolysis unit 100, and input and compare Circuit, the real work voltage of acquisition and rated operational voltage value relatively and are judged size by comparison circuit, and are exported and compared knot Fruit is to microprocessor 210.
Further include light display apparatus 280 in a kind of preferred embodiment of the present embodiment, light display apparatus 280 with Microprocessor 210 connects.For switching circuit 240 with unlike signal to microprocessor 210, microprocessor 210 handles unlike signal, Light signal is exported to light display apparatus 280, light display apparatus 280 is used to receive the signal of microprocessor 210, according to Unlike signal lights different light.Such as be switched on detection, automatic boosting, automatic Regulation or power voltage insufficient, different timing system The hydrogen time can also be shown by light display apparatus 280.Light display apparatus 280 can be shown by different light Different working condition, to remind operating personnel to take adequate measures.
Embodiment 3:
The embodiment of the present invention 2 provides a kind of hydrogen-oxygen separation electrolysis system.Including hydrogen-oxygen separation electrolysis unit 100 and strictly according to the facts The hydrogen-oxygen separation electrolysis unit control system 200 of example 1 is applied, hydrogen-oxygen detaches electrolysis unit control system 200 and is arranged in the hydrogen-oxygen Detach the lower end of electrolysis unit 100 and sealed connection.
As shown in Figure 5, Figure 6, hydrogen-oxygen separation electrolysis unit 100 includes electrolysis generator, upper mounted plate 131 and lower fixation Plate 121, electrolysis generator include cathode sheets 111, anode strip 112, selective proton through 113 films, upper mounted plate 131 and under Cathode connection end 1112 is arranged in fixed plate 121, cathode sheets 111, and 1112 external power supply of cathode connection end, 400 cathode is specifically, cloudy Pole terminals 1112 connect 220 power output end cathode of automatic Regulation module;Anode connection end 1122, sun is arranged in anode strip 112 1122 external power supply of pole terminals, 400 anode, specifically, anode connection end 1122 connect the 220 power supply output of automatic Regulation module Rectify pole pole;Electrode hole 122 is set on bottom plate 121, and anode connection end 1122 and cathode connection end 1112 pass through electrode hole 122, it can be saturating in the bottom surface of upper mounted plate 131 or the setting of the top surface of bottom plate 121 and cathode sheets 111, selective proton The matched accommodating cavity 134 of film 113,112 shape of anode strip is crossed, it can also be simultaneously in the bottom surface of upper mounted plate 131 and lower fixation The top surface setting of plate 121 is with cathode sheets 111, selective proton through film 113, the matched accommodating cavity of 112 shape of anode strip 134, bottom plate 121 is detachably connected with upper mounted plate 131, and cathode sheets 111, selective proton are through film 113, anode strip 112 are fixed in the accommodating cavity 134 between upper mounted plate 131 and bottom plate 121, and cathode sheets 111 and selective proton are saturating Formation hydrogen generation area 161, anode strip 112 and selective proton are generated through formation oxygen between film 113 between crossing film 113 Area 162, hydrogen discharge confession hydrogen discharge hydrogen generation area 161 is arranged in hydrogen generation area 161 and water enters hydrogen generation area 161,142 oxygen discharge oxygen generation area 162 of oxygen floss hole is arranged in oxygen generation area 162.
It is equipped with through-hole at the middle part of upper mounted plate 131, through-hole extends to cathode sheets 111 and cathode sheets and selectivity Proton penetrates the hydrogen generation area 161 between film 113.The through-hole at 131 middle part of upper mounted plate forms hydrogen discharge mouth.Electrolysis needs The water wanted directly enters cathode sheets 111 from through-hole and selective proton penetrates film 113, and is penetrated full of entire selective proton Accommodating chamber portion more than film.Hydrogen can be dissolved directly into after the generation of hydrogen generation area 161 positioned at hydrogen generation area In 161 water, it can also be discharged in cup body, be dissolved into other water by the way that the through-hole in the middle part of upper mounted plate 131 is arranged. Cup body will be discharged by rim of a cup from water in extra hydrogen.
The bottom edge of upper mounted plate 131 is equipped with the electrode card slot that connection houses cavity 134 and upper mounted plate side outer wall 133, cathode sheets boss 1113 and anode strip boss 1123, cathode sheets are respectively set at the edge of cathode sheets 111 and anode strip 112 Boss 1113 and anode strip boss 1123 are fastened in electrode card slot 133, to consolidate to cathode sheets 111 and anode strip 112 It is fixed.
Wherein, selective proton is to penetrate film from humidification type proton through film 113.Specifically, it is penetrated from humidification type proton Film is perfluorosulfonic acid ion film.Film is penetrated using from humidification type proton, oxygen generation area 162 need not inject water, hydrogen in advance Water in generation area 161, which can be penetrated, penetrates into a small amount of water from humidification type proton membrane to oxygen generation area 162 to meet electrolysis needs, Then a small amount of water of oxygen generation area 162 is transmitted to hydrogen generation area 161 by the form of proton hydrate (H3O+), to prevent The water of oxygen generation area 162 is flowed out with the oxygen of generation, avoids generating waste liquid.
Wherein, multiple air holes are set on cathode sheets 111 and anode strip 112.By the way that multiple air holes are arranged, make generation The form that hydrogen forms minute bubbles enters in water, and the diameter of hydrogen can be made small, large specific surface area, and gas rises escape slowly, Dissolution rate higher.
Cathode sheets 111 and anode strip 112 are all made of Ti electrode, pass through transfer printing, mould by the titanium particle of three kinds of different-grain diameters Platen press, electrochemical deposition method, immersion reduction method or vacuum sputtering are prepared, and are in honeycomb arrangement.
Wherein, the connection between upper mounted plate 131 and bottom plate 121 may be used snap connection, screw connection or The achievable connection type of others.The present embodiment uses screw to connect as described in Figure 1, is threaded on upper mounted plate 131 blind Hole, 121 corresponding position of bottom plate are threaded through-hole, are closely connected upper mounted plate 131 and bottom plate 121 by screw Together.Bayonet lock 135 can be set on 131 bottom surface of upper mounted plate, and 121 corresponding position of bottom plate is arranged card hole, passes through card Pin 135 and card hole position upper mounted plate 131 and bottom plate 121.
Hydrogen-oxygen provided by the invention detaches electrolysis unit 100, and film 113 is penetrated by 111 He of cathode sheets by selective proton Anode strip 112 separates, and forms hydrogen generation area 161 and oxygen generation area 162.Selective proton is to allow to be hydrated through film 113 Proton (H3O+) by film, proton hydrate is combined with selective proton through the group in film 113, then from a group It is transmitted to another group, eventually arrives at another side.It is first powered on rear water and just loses electronics e- generation hydrogen in anode strip 112 at once Ion and oxygen (2H2O-4e-=4H++O2 ↑), oxygen are discharged from oxygen floss hole 142.Hydrogen ion is with proton hydrate (H3O+) Form cathode sheets 111 are transmitted to through film 113 by selective proton, acquisition is electronically generated hydrogen (4H3O++4e-=4H2O + H2 ↑), hydrogen is dissolved into hydrogen generation area 161 in water, some hydrogen is discharged to from hydrogen discharge mouth in cup body, Stablize separation to reach oxyhydrogen safe, while oxygen or ozone being avoided to be dissolved into water.
In a kind of a kind of preferred embodiment of hydrogen-oxygen separation electrolysis unit 100 provided by the invention, cathode sheets 111, sun Pole piece 112, selective proton are disposed as the matched circle of size through film 113, upper mounted plate 131 and bottom plate 121, with Just preferably for making hydrogen-rich cup or hydrogen-rich water dispenser.Cathode sheets 111, selective proton are through film 113, anode strip 112 can be from top to bottom be ranked sequentially, can also be from top to bottom be ranked sequentially.The preferred cathode sheets 111 of the embodiment of the present invention, Selective proton is fixed on upper mounted plate 131 and bottom plate 121 through film 113, anode strip 112 by sequence from top to bottom Between accommodating cavity 134 in, anode strip 112, selective proton between film 113 and bottom plate 121 through being tightly connected.This Kind setting can facilitate oxygen floss hole 142 to be arranged on bottom plate 121, be conducive to oxygen passing through bottom remover Outside, to which when making hydrogen-rich cup, directly oxygen is discharged outside cup body by bottom of a cup.Meanwhile sealed set can prevent water not It is directly entered oxygen generation area 162 through film 113 by selective proton, forms waste water.Wherein, cathode sheets 111 and upper fixation It is arranged between plate 131 between first sealed silicon cushion rubber 151, anode strip 112 and bottom plate 121 and second sealed silicon cushion rubber is set 152.By the way that sealed silicon cushion rubber is arranged, increase the air-tightness and water proofing property connected between all parts.
The embodiment of the present invention provides a kind of further improved hydrogen-oxygen separation electrolysis unit 100, further includes battery plate spiral cover 141, the top of battery plate spiral cover 141 is set as flat surface, and bottom plate 121 corresponds to electrolysis generator region and through-hole, electricity is arranged Plate spiral cover 141 is arranged in through-hole, and battery plate spiral cover 141 can be moved up and down along through-hole.In a kind of embodiment, in battery plate spiral cover External screw thread is set on 141, on the side wall in through-hole setting with the matched internal thread of 141 screw thread of battery plate spiral cover, battery plate spiral cover 141 with It is connected through a screw thread between bottom plate 121.In electrolytically generated device, cathode sheets 111, selective proton penetrate film 113 and sun Pole piece 112 is fixed on from top to bottom between upper mounted plate 131 and bottom plate 121, passes through the smooth flat of 141 top of battery plate spiral cover Face can adjust the distance between anode strip 112 and cathode sheets 111, make the distance between anode strip 112 and cathode sheets 111 more Equilibrium, it is also more balanced by the electric current between anode strip 112 and cathode sheets 111, to make cell reaction in entire anode strip 112 and cathode sheets 111 on it is all balanced occur, improve the efficiency that hydrogen generates.Meanwhile compressing sun by adjusting battery plate spiral cover 141 The distance of pole piece 112 and cathode sheets 111 makes anode strip 112 and cathode sheets 111 are bonded more through film across selective proton Closely, to make the resistance smaller between them, electric current higher, the power and speed of decomposition are all faster.
Hydrogen-oxygen separation electrolysis unit control provided in an embodiment of the present invention is in 2100 further preferred embodiment, also Including inclination inducing system 290, inclination inducing system 290 and microprocessor 210 connect, and are used for the angle of inclination of detection device, And alarm is sent out when inclination angle is more than preset value or cuts off the voltage for being input to the cathode sheets 111 and anode strip 112.It is logical Setting inclination inducing system 290 is crossed to detect the inclined degree that hydrogen-oxygen detaches electrolysis unit, is tilted in hydrogen-oxygen separation electrolysis unit, When anode strip 112 and cathode sheets 111 are not in contact with to water, by closing circuit, the electrolysis system of anti-locking apparatus is impaired.
Further include electricity in the further preferred embodiment of hydrogen-oxygen separation electrolysis unit 100 provided in an embodiment of the present invention Solution system card slot and fixed spiral cover 132, fixed the upper surface of spiral cover 132 and upper mounted plate 131 are detachably connected, provided by the invention In technical solution, external screw thread is set in 131 top surface of upper mounted plate, fixed 132 bottom surface of spiral cover is arranged endoporus, on the side wall of endoporus Setting and the matched internal thread of 131 screw thread of upper mounted plate are connected through a screw thread between fixed spiral cover 132 and upper mounted plate 131.Electricity Solution system card slot is equipped with bayonet, and bayonet is connected between upper mounted plate 131 and fixed spiral cover 132, will be electric by fixed spiral cover 132 Solution generator is fixed in electrolysis system card slot, and third sealed silicon cushion rubber is arranged between fixed spiral cover 132 and upper mounted plate 131 153, to increase water proofing property.Through-hole is arranged simultaneously in the through hole at intermediate 131 middle part of corresponding upper mounted plate of fixed spiral cover 132, with It is connected to form hydrogen discharge mouth with fixed spiral cover 132 for upper mounted plate 131.In wherein a kind of preferred embodiment, solid Determine that moisturizing silicagel pad 170 can also be arranged on spiral cover 132, moisturizing silicagel pad 170 can be by absorption, buckle or others even Mode is connect to connect with fixed spiral cover 132.When the hydrogen-oxygen separation needs of electrolysis unit 100 compare and do not work for a long time, can select Property at the hydrogen generation area 161 between film 113 and cathode sheets 111 through certain water is poured into, then by moisturizing silicagel pad It is fixed on fixed spiral cover 132.Moisturizing silicagel pad can keep the moisture in hydrogen generation area 161 not evaporate easily, protect The wettability that selective proton penetrates film 113 is held, to ensure the good function of hydrogen-oxygen separation electrolysis unit 100 and use the longevity Life.
The above embodiment is only the preferred embodiment of the present invention, and the scope of protection of the present invention is not limited thereto, The variation and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention Claimed range.

Claims (14)

1. a kind of hydrogen-rich cup, which is characterized in that including pressure control solubilising cup lid, cup body and hydrogen-oxygen detach electrolysis system, the cup Cup lid interface is arranged in body rim of a cup, and the pressure control solubilising cup lid is detachably connected with cup body by the cup lid interface, the pressure control Solubilized cup lid is equipped with air hole, and water proof ventilated membrane is provided in the air hole, and the hydrogen-oxygen separation electrolysis system setting exists The bottom of cup.
2. hydrogen-rich cup as described in claim 1, which is characterized in that the pressure control solubilising cup lid includes upper cover and lower cover, institute It states upper cover and lower cover opposite position is both provided with air hole, the water proof ventilated membrane is arranged between the upper cover, lower cover, and It is correspondingly arranged with the air hole, the lower cover is fixed on the upper cover bottom surface.
3. hydrogen-rich cup as claimed in claim 2, which is characterized in that the upper cover includes air hole column jacket, the lower cover packet Air hole inner prop is included, the water proof ventilated membrane is fitted tightly on the stomata of the air hole inner prop, and the air hole inner prop is inserted Enter the air hole column jacket.
4. hydrogen-rich cup as claimed in claim 3, which is characterized in that the pressure control solubilising cup lid further includes the 4th sealed silicone It encloses, is provided with through-hole among the 4th sealed silicon cushion rubber, the 4th sealed silicon cushion rubber is nested in lower cover by the through-hole On.
5. the hydrogen-rich cup as described in Claims 1-4 is any, which is characterized in that the hydrogen-oxygen separation electrolysis system includes hydrogen Oxygen separating electrolysis unit and hydrogen-oxygen detach electrolysis unit control system;
The hydrogen-oxygen detaches electrolysis unit, including electrolysis generator, upper mounted plate and bottom plate, the electrolysis generator include Cathode sheets, anode strip, selective proton penetrate film, cathode sheets setting cathode connection end, the external electricity in cathode connection end Source cathode, anode strip setting anode connection end, anode connection end external power supply is positive, is arranged on the bottom plate Electrode hole, the anode connection end and cathode connection end pass through the electrode hole, the bottom surface of fixed plate and/or it is described under The top surface setting of fixed plate is with cathode sheets, selective proton through film, the matched accommodating cavity of anode plate shape, the lower fixation Plate is detachably connected with upper mounted plate, and the cathode sheets, selective proton penetrates film, anode strip is fixed on upper mounted plate and lower solid In accommodating cavity between fixed board, the cathode sheets and selective proton are through formation hydrogen generation area, the anode between film Piece and selective proton are discharged through oxygen generation area, the hydrogen generation area setting hydrogen discharge confession hydrogen is formed between film Hydrogen generation area and water enter hydrogen generation area, and the oxygen generation area setting oxygen floss hole oxygen is discharged oxygen and generates Area;
The hydrogen-oxygen separation electrolysis unit set-up of control system detaches the bottom of electrolysis unit and and bottom plate in the hydrogen-oxygen It is tightly connected.
6. the hydrogen-rich cup as described in claim 5 is any, which is characterized in that the hydrogen-oxygen separation electrolysis unit further includes battery plate Spiral cover, the bottom plate correspond to electrolysis generator region setting through-hole, and the battery plate spiral cover is arranged in through-hole, the battery plate Spiral cover can be moved up and down along the through-hole.
7. the hydrogen-rich cup as described in claim 5 is any, which is characterized in that be arranged in the cathode sheets and anode strip multiple Stomata.
8. hydrogen-rich cup as claimed in claim 5, which is characterized in that the cathode sheets, anode strip, selective proton penetrate Film, upper mounted plate and bottom plate are disposed as the matched circle of size, and the cathode sheets, selective proton are through film, anode Piece is fixed on by sequence from top to bottom between upper mounted plate and bottom plate, and the oxygen floss hole is arranged in bottom plate On, the anode strip, selective proton are penetrated and are tightly connected between film and bottom plate.
9. hydrogen-rich cup as claimed in claim 8, which is characterized in that the selectivity proton is from humidification type proton through film Through film.
10. hydrogen-rich cup as claimed in claim 8, which is characterized in that further include moisturizing silicagel pad, the moisturizing silicagel pad can Releasably it is arranged on hydrogen-oxygen separation electrolysis unit.
11. the hydrogen-rich cup as described in Claims 1-4 is any, which is characterized in that the hydrogen-oxygen separation electrolysis system includes hydrogen Oxygen separating electrolysis unit and hydrogen-oxygen detach electrolysis unit control system;The hydrogen-oxygen detaches electrolysis unit control system sealed set In hydrogen-oxygen separation electrolysis unit bottom;
The hydrogen-oxygen detaches electrolysis unit control system, including microprocessor, memory, automatic Regulation module and switching circuit, The microprocessor is separately connected memory, automatic Regulation module and switching circuit, the automatic Regulation modular power source input terminal External power supply, the anode of the external hydrogen-oxygen separation electrolysis unit of automatic Regulation modular power source output head anode, the automatic tune The cathode of the external hydrogen-oxygen separation electrolysis unit of die block power output end cathode;
The memory is stored with detaches the preset booting voltage detecting value of electrolysis unit operating voltage according to hydrogen-oxygen, controls voltage Step value and computer executable program, computer executable program in the microcomputer reads memory are simultaneously realized following Control method:
Be switched on voltage detecting step:The supply voltage of external power supply is detected, if the supply voltage is less than booting voltage detecting value, It is stopped and prompts undertension, otherwise, execute next step;
Automatic boosting step:Control automatic Regulation module is stepped up with preset control voltage steps value is input to hydrogen-oxygen separation The voltage of electrolysis unit cathode and anode, until the real work voltage that hydrogen-oxygen detaches electrolysis unit cathode and anode reaches booting Voltage detecting value.
12. hydrogen-rich cup as claimed in claim 11, which is characterized in that the hydrogen-oxygen detaches electrolysis unit control system, also Including sampling comparison circuit, the sampling compares circuit input end and is separately connected automatic Regulation modular power source output head anode and bears Circuit output end connection microprocessor is compared in pole, the sampling, and the sampling comparison circuit obtains hydrogen-oxygen separation electrolysis unit Real work voltage, and it is input to microprocessor, the microprocessor executes computer executable program and realizes following controlling party Method:
Automatic Regulation step:The size for comparing the real work voltage and the booting voltage detecting value, if real work Voltage is more than the booting voltage detecting value, and controlling the automatic Regulation module reduces the electricity that output detaches electrolysis unit to hydrogen-oxygen Pressure, until the real work voltage is equal to the booting voltage detecting value, if real work voltage is less than booting electricity Detected value is pressed, the automatic Regulation module is controlled and increases the voltage that output detaches electrolysis unit to hydrogen-oxygen, until the practical work Make voltage and is equal to the booting voltage detecting value.
13. hydrogen-rich cup as claimed in claim 12, which is characterized in that the hydrogen-oxygen separation electrolysis unit control system is also wrapped Management of charging and discharging module and accumulator are included, the automatic Regulation module is described by the management of charging and discharging module external power supply Accumulator is separately connected external power supply and automatic Regulation module, the management of charging and discharging module by the management of charging and discharging module In external power supply, for the capacitance adjustment charging voltage and charging current according to accumulator;The management of charging and discharging module exists When storage battery power supply, for carrying out overcurrent or overload protection to accumulator.
14. hydrogen-rich cup as claimed in claim 13, which is characterized in that the hydrogen-oxygen separation electrolysis unit control system is also wrapped Light display apparatus is included, the light display apparatus is connect with microprocessor, and the light display apparatus is for receiving microprocessor The signal of device, and display working condition, the working condition include booting detection, automatic boosting, automatic Regulation or power supply electricity Pressure is insufficient.
CN201810159115.3A 2018-02-26 2018-02-26 A kind of hydrogen-rich cup Pending CN108315755A (en)

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CN109160579A (en) * 2018-09-27 2019-01-08 广州赛爱环境保护技术开发有限公司 It is electrolysed mould group and electrolysis cup
CN109354274A (en) * 2018-09-04 2019-02-19 中国辐射防护研究院 A kind of hydrogen-rich water preparation method and device based on computer control
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CN113186550A (en) * 2021-05-12 2021-07-30 氢星(上海)生物科技有限公司 Water electrolysis device and hydrogen-rich water cup
CN114016056A (en) * 2021-11-25 2022-02-08 珠海格力电器股份有限公司 Ozone water disinfectant manufacturing machine and high-pressure prevention control method thereof
CN114436388A (en) * 2022-01-28 2022-05-06 长三角健康农业研究院(浙江)有限公司 Hydrogen-rich water cup capable of displaying hydrogen concentration in real time

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Publication number Priority date Publication date Assignee Title
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CN114016056A (en) * 2021-11-25 2022-02-08 珠海格力电器股份有限公司 Ozone water disinfectant manufacturing machine and high-pressure prevention control method thereof
CN114436388A (en) * 2022-01-28 2022-05-06 长三角健康农业研究院(浙江)有限公司 Hydrogen-rich water cup capable of displaying hydrogen concentration in real time

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