CN108315103A - A kind of jewellery cleaner and preparation method thereof - Google Patents
A kind of jewellery cleaner and preparation method thereof Download PDFInfo
- Publication number
- CN108315103A CN108315103A CN201810083069.3A CN201810083069A CN108315103A CN 108315103 A CN108315103 A CN 108315103A CN 201810083069 A CN201810083069 A CN 201810083069A CN 108315103 A CN108315103 A CN 108315103A
- Authority
- CN
- China
- Prior art keywords
- jewellery
- cleaner
- enzyme preparation
- organic solvent
- nonionic surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
- C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38636—Preparations containing enzymes, e.g. protease or amylase containing enzymes other than protease, amylase, lipase, cellulase, oxidase or reductase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
Abstract
The present invention is suitable for detergent technical field, provides a kind of jewellery cleaner and preparation method thereof, jewellery cleaner, by weight, including following component：Nonionic surfactant：8%~10%；Enzyme preparation：0.5%~1.5%；Organic solvent：24.5%~32.5%；Surplus is deionized water.The jewellery cleaner of the present invention, the synergistic effect having using enzyme preparation and surfactant can be effectively removed the various spots on bullion surface, and the performances such as color and luster for not damaging bullion, while be formulated mildly, non-stimulated to skin, safe.
Description
Technical field
The invention belongs to detergent technical fields more particularly to a kind of jewellery cleaner and preparation method thereof.
Background technology
As the improvement of people's living standards, various bullions have become the adornment of the daily wearing of people, and pearl
The precious wearing ornaments time is grown, and dirt is often infected on surface, such as cleans not in time, it is possible to can damage jewelry itself
Color and luster, or even chemically react, to influence the cosmetic look of jewelry；In addition, the oily matter of human secretory also adheres to
On jewellery, bacterium is easily grown, it is very unfavorable to health.The bullion of the daily wearing of people should be carried out often thus
Cleaning, fully to keep their cleaning beautiful.
Such as bullion is sent in the shop of special cleaning jewellery and is cleaned, money has not only been spent but also has expended the time；Make simultaneously
For customer, precious bullion is delivered other people and is cleaned, inevitably there is a kind of worried feeling, so, people are more inclined to
In self-cleaning of being in.
However, people be in most of the traditional cleaning formulations of jewelry be with cleanings such as water or liquid detergents, it is clean
Ineffective, particularly with the more complicated jewelry of moulding, cleaning performance is worse.
Invention content
The embodiment of the present invention provides a kind of jewellery cleaner, it is intended to solve to carry out jewelry using water or liquid detergent etc. clear
It washes, the bad problem of cleaning effect.
The embodiment of the present invention is achieved in that a kind of jewellery cleaner, by weight, including following component：Nonionic
Surfactant：8%~10%；Enzyme preparation：0.5%~1.5%；Organic solvent：24.5%~32.5%；Surplus is deionization
Water.
Preferably, jewellery cleaner, by weight, including following component：Nonionic surfactant：10%；Enzyme preparation：
1.5%；Organic solvent：26.5%；Surplus is deionized water.
Preferably, jewellery cleaner, by weight, including following component：Nonionic surfactant：8%~10%；Enzyme
Preparation：0.5%~1.5%；Organic solvent：24.5%~32.5%；Essence：0.2%~0.3%；Surplus is deionized water.
Preferably, jewellery cleaner, by weight, including following component：Nonionic surfactant：10%；Enzyme preparation：
1.5%；Organic solvent：26.5%；Essence：0.2%；Surplus is deionized water.
Preferably, the enzyme preparation is at least three in protease, lipase, amylase, cellulase or lysozyme
The mixture of kind.
It is furthermore preferred that the enzyme preparation is the mixture of protease, lipase and lysozyme.
Preferably, the nonionic surfactant is nonylphenol polyoxyethylene ether, octyl phenol polyoxyethylene ether, fatty alcohol
At least two mixing in polyoxyethylene ether, alkyl glycosides, cocoanut fatty acid diethanolamide or sucrose fatty ester
Object.
Preferably, the organic solvent be ethyl alcohol, isopropanol, ethylene glycol, cellosolvo, dipropylene or
In ethylene glycol monobutyl ether any one or at least two mixture.
More preferably, organic solvent is the mixture of ethyl alcohol and dipropylene, and the two is applied in combination can not only
Solubilizing surfactant improves the stability of formula, reduces the cloud point of formula, additionally aids dissolving grease, promotes going for dirt
It removes, while not interfering with the activity of enzyme preparation.
Preferably, the nonionic surfactant includes the substance of following weight ratio：Fatty alcohol polyoxyethylene ether
7%, alkyl glycosides 3%；
The enzyme preparation includes the substance of following weight ratio：Proteinase-10 .5%, lipase 0.6%, lysozyme 0.4%；
The organic solvent includes the substance of following weight ratio：Dipropylene 4.5%, ethyl alcohol 22%.
The embodiment of the present invention additionally provides a kind of preparation method of jewellery cleaner, includes the following steps：
Step 1：Each component is weighed according to the formula of above-mentioned jewellery cleaner, it is spare.
Step 2：Portions of de-ionized water is added into ingredients pot；Preferably, going for 50%~60% (weight ratio) is added
Ionized water.
Step 3：Nonionic surfactant and organic solvent are put into ingredients pot, and are stirred to being completely dissolved.
Step 4：Remaining deionized water is added.
Step 5：Enzyme preparation is added into ingredients pot, and stirs to being completely dissolved, obtains jewellery cleaner.
Below to each raw material in above-mentioned jewellery cleaner the effect of and ingredient do specific description：
Protease：Protein can be hydrolyzed into soluble amino acid by protease, to be easy to be washed away, such as blood, sweat
The albumen dirt such as stain, coffee.
Lipase：It is capable of the oily matter of effective human secretory.
Amylase：Starch dirt such as chocolate, mashed potatoes, noodles, congee etc. can be resolved into dextrin or maltose.
Lysozyme：It is a kind of to hydrolyze the alkaline enzyme that polysaccharide is sticked in pathogenic bacteria.Mainly by destroying the N- acetyl in cell wall
β-Isosorbide-5-Nitrae glycosidic bond between muramic acid and n-acetylglucosamine makes the insoluble glutinous polysaccharide of cell wall resolve into soluble glycopeptide,
Cell wall rupture content is caused to escape and make bacterolysis.Lysozyme can also be bound directly with negatively charged virus protein,
Double salt is formed with DNA, RNA, apoprotein, is made virally inactivated.Therefore, which has the effects that antibacterial, anti-inflammatory, antiviral,
And it is safe.
Cellulase:Cellulase can remove the microtriche and bobbles remained in jewelry gap.
Nonylphenol polyoxyethylene ether：It is nonionic surfactant of good performance for light yellow soft paste, it is main to use
In various cleaning agents, textile industry auxiliary agent, lubricating oil, resin emulsifier etc..
Octyl phenol polyoxyethylene ether：It is a kind of multi-functional nonionic surface active agent, there is outstanding wetability, decontamination
Power, hard surface and metal cleaning performance, and remarkable emulsifiability.
Fatty alcohol polyoxyethylene ether：From sustainable energy, extremely mildly, nonirritant and sensitization is healthy and safe,
Foam especially enriches stabilization and cleaning capacity is considerable, and biological degradability is good.
Alkyl glycosides：Synergistic effect can be generated with various ionics, nonionic surface active agent compounding, foaming characteristic is good,
Foaming abundancy is fine and smooth, and dissolubility is good, and resistance to highly basic and electrolyte have good thickening capabilities, good with skin intermiscibility, significantly improve
The mildness of formula, nontoxic, non-stimulated, easily biological-degradable.
Cocoanut fatty acid diethanolamide：Belong to nonionic surfactant, without cloud point.Character is faint yellow to amber
Amber color thick liquid, it is soluble easily in water, have the function of good foaming, is foam stabilizing, infiltration decontamination, hard water resistance etc..Belong to non-ionic surface
Activating agent, when anion surfactant is in acidity, compatibility thickening effect is particularly evident therewith, can be with a variety of surfactants
Compatibility.
Sucrose fatty ester：A kind of nonionic surfactant, the simple substance generated through esterification by sucrose and aliphatic acid
Or mixture.Its, easily biological-degradable nontoxic with its and good surface property are widely used in food, medicine, daily use chemicals, biological work
The industries such as enzyme preparation, oil exploitation, weaving and the farming and animal husbandry of journey.
Cellosolvo：It is readily biodegradable, it is environmental-friendly.Dipropylene performance is high, can significant increase cleaning
Effect, low smell, impurity is few, has excellent infiltration, solubility property.
Ethyl alcohol：The components of cosmetics of global general-use, it is multi-purpose to make solvent, astringent, viscosity reductant etc., when mass fraction in formula
More than 15%, it is converted into from protective system；It is acted on as sterilization and anticorrosion, mass fraction was more than in 60% 1 minute to be acted as completely
With.
Isopropanol, ethylene glycol：Dissolution is played in cosmetics, can be used for dissolving other compositions, product is made to have
Certain performance and dosage form.
Dipropylene, ethylene glycol monobutyl ether：The two is commonly used for aqueous woodware paint, water-based ink, household cleaners, wet
In paper handkerchief.
Essence：The selection of essence can select to meet as needed《GB/T22731-2008》Daily essence standard, international perfume
Smart fragrance association (IFRA), European Union's cosmetics instruction (26 essence anaphylactogens of European directive avoid) requirement, suitable essence can
The bullion after cleaning is set to carry pleasant pure and fresh taste.
Jewellery cleaner provided in an embodiment of the present invention, the synergistic effect having using enzyme preparation and surfactant, can
The various spots on bullion surface, and the performances such as color and luster for not damaging bullion are effectively removed, while being formulated mildly, it is right
Skin is non-stimulated, safe.
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, below in conjunction with specific embodiment, to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.
Jewellery cleaner provided in an embodiment of the present invention, the synergistic effect having using enzyme preparation and surfactant, can
The various spots on bullion surface, and the performances such as color and luster for not damaging bullion are effectively removed, while being formulated mildly, it is right
Skin is non-stimulated, safe.
Technical scheme of the present invention and technique effect are described further below by way of specific embodiment.
Embodiment 1：
A kind of jewellery cleaner, by weight, including following component：Nonionic surfactant (aliphatic alcohol polyethenoxy
Ether 6.4%, alkyl glycosides 4.2%), totally 10.6%；Enzyme preparation (proteinase-10 .2%, lipase 0.2%, lysozyme 0.1%),
Totally 0.5%；Organic solvent (ethyl alcohol 25%, dipropylene 7.5%), totally 32.5%；Essence 0.2%；Surplus is deionization
Water.
In an embodiment of the present invention, the preparation method of above-mentioned jewellery cleaner, includes the following steps：
Step 1：Each component is weighed according to the formula of above-mentioned jewellery cleaner, it is spare.
Step 2：Portions of de-ionized water is added into ingredients pot；Preferably, going for 50%~60% (weight ratio) is added
Ionized water.
Step 3：Nonionic surfactant and organic solvent are put into ingredients pot, and are stirred to being completely dissolved.
Step 4：Remaining deionized water is added.
Step 5：It is added enzyme preparation into ingredients pot, and stirs to being completely dissolved, then put into essence, stir evenly, obtain
Jewellery cleaner.
Embodiment 2：
A kind of jewellery cleaner, by weight, including following component：Nonionic surfactant (aliphatic alcohol polyethenoxy
Ether 6%, alkyl glycosides 4.2%), totally 10.2%；Enzyme preparation (proteinase-10 .3%, lipase 0.4%, lysozyme 0.3%), altogether
1%；Organic solvent (ethyl alcohol 20%, dipropylene 5.5%), totally 25.5%；Essence 0.3%；Surplus is deionized water.
In embodiments of the present invention, the preparation method of jewellery cleaner is same as Example 1.
Embodiment 3：
A kind of jewellery cleaner, by weight, including following component：Nonionic surfactant (aliphatic alcohol polyethenoxy
Ether 6.8%, alkyl glycosides 2.5%), totally 9.3%；Enzyme preparation (proteinase-10 .5%, lipase 0.5%, lysozyme 0.5%), altogether
1.5%；Organic solvent (ethyl alcohol 20%, dipropylene 4.5%), totally 24.5%；Essence 0.2%；Surplus is deionized water.
In embodiments of the present invention, the preparation method of jewellery cleaner is same as Example 1.
Embodiment 4：
A kind of jewellery cleaner, by weight, including following component：Nonionic surfactant (aliphatic alcohol polyethenoxy
Ether 7%, alkyl glycosides 3%), totally 10%；Enzyme preparation (proteinase-10 .5%, lipase 0.6%, lysozyme 0.4%), altogether
1.5%；Organic solvent (ethyl alcohol 22%, dipropylene 4.5%), totally 26.5%；Essence 0.2%；Surplus is deionized water.
In embodiments of the present invention, the preparation method of jewellery cleaner is same as Example 1.
Embodiment 5：
A kind of jewellery cleaner, by weight, including following component：Nonionic surfactant (aliphatic alcohol polyethenoxy
Ether 7.2%, alkyl glycosides 2.5%), totally 9.7%；Enzyme preparation (proteinase-10 .3%, lipase 0.3%, lysozyme 0.4%), altogether
1%；Organic solvent (ethyl alcohol 22%, dipropylene 5.5%), totally 27.5%；Essence 0.3%；Surplus is deionized water.
In embodiments of the present invention, the preparation method of jewellery cleaner is same as Example 1.
Embodiment 6：
A kind of jewellery cleaner, by weight, including following component：Nonionic surfactant (Nonyl pheno
Ether 1%, fatty alcohol polyoxyethylene ether 6%, alkyl glycosides 3%), totally 10%；Enzyme preparation (proteinase-10 .3%, lipase 0.3%,
Amylase 0.3%, lysozyme 0.3%), totally 1.2%；Organic solvent (ethyl alcohol 25%)；Essence 0.25%；Surplus is deionization
Water.
In embodiments of the present invention, the preparation method of jewellery cleaner is same as Example 1.
Embodiment 7：
A kind of jewellery cleaner, by weight, including following component：Nonionic surfactant (octylphenol polyethylene ethylene oxide
Ether 1%, fatty alcohol polyoxyethylene ether 4%, alkyl glycosides 4%, cocoanut fatty acid diethanolamide 1%), totally 10%；Enzyme system
Agent (proteinase-10 .2%, cellulase 0.2%, lysozyme 0.1%), totally 0.5%；Organic solvent (ethyl alcohol 24%, isopropanol
8%), totally 32%；Surplus is deionized water.
In an embodiment of the present invention, the preparation method of jewellery cleaner is substantially the same manner as Example 1, and difference exists
In：Step 5：Enzyme preparation is added into ingredients pot, and stirs to being completely dissolved, obtains jewellery cleaner.
Embodiment 8：
A kind of jewellery cleaner, by weight, including following component：Nonionic surfactant (aliphatic alcohol polyethenoxy
Ether 2.5%, alkyl glycosides 4.5%, cocoanut fatty acid diethanolamide 1%, sucrose fatty ester 1%), totally 9%；Enzyme preparation
(proteinase-10 .3%, lipase 0.3%, amylase 0.3%, cellulase 0.3%, lysozyme 0.3%), totally 1.5%；It is organic
Solvent (ethyl alcohol 20%, ethylene glycol 2%, dipropylene 2.5%), totally 24.5%；Surplus is deionized water.
In embodiments of the present invention, the preparation method of jewellery cleaner is same as Example 7.
Embodiment 9：
A kind of jewellery cleaner, by weight, including following component：Nonionic surfactant (aliphatic alcohol polyethenoxy
Ether 3.5%, alkyl glycosides 4.5%), totally 8%；Enzyme preparation is (proteinase-10 .2%, lipase 0.2%, cellulase 0.4%, molten
Bacterium enzyme 0.3%), totally 1.1%；Organic solvent (ethyl alcohol 23%, cellosolvo 3%, dipropylene 4.5%, ethylene glycol
Monobutyl ether 2%), totally 32.5%；Surplus is deionized water.
In embodiments of the present invention, the preparation method of jewellery cleaner is same as Example 7.
Embodiment 10：
A kind of jewellery cleaner, by weight, including following component：Nonionic surfactant (octylphenol polyethylene ethylene oxide
Ether 1%, fatty alcohol polyoxyethylene ether 4%, alkyl glycosides 2.5%, cocoanut fatty acid diethanolamide 1%, sucrose-fatty
Ester 1.5%), totally 10%；Enzyme preparation (proteinase-10 .3%, lipase 0.2%, cellulase 0.5%, lysozyme 0.5%), altogether
1.5%；Organic solvent (ethyl alcohol 21%, isopropanol 2%, dipropylene 3.5%), totally 26.5%；Surplus is deionized water.
In embodiments of the present invention, the preparation method of jewellery cleaner is same as Example 7.
It should be noted that in embodiments of the present invention, enzyme preparation be protease, lipase, amylase, cellulase or
At least three kinds of mixture in person's lysozyme.For convenience of description, above embodiments only show several preferred groups therein
Conjunction mode can arbitrarily choose three kinds, four kinds or five kinds enzymes therein and be compounded in practical applications, it is only necessary to which keeping should
Shared weight ratio is 0.5%~1.5% to compound in formula, and one of the various combinations are just not listed one by one herein
Mode.
Based on above-mentioned identical reason, the nonionic surfactant involved in the embodiment of the present invention is polyoxyethylene nonyl phenyl second
Alkene ether, octyl phenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, alkyl glycosides, cocoanut fatty acid diethanolamide or sugarcane
At least two mixture in sugar fatty acid ester；Organic solvent is ethyl alcohol, isopropanol, ethylene glycol, cellosolvo, dipropyl
Glycol butyl ether either any one in ethylene glycol monobutyl ether or at least two mixture.Various groups of these above-mentioned components
Conjunction mode does not also enumerate herein.
The advantageous effect for the jewellery cleaner that embodiment provides in order to further illustrate the present invention, below in conjunction with specific experiment
Example further elaborates：
Experiment one：Acute oral toxicity test
1, test specimen：The jewellery cleaner that the embodiment of the present invention 1~10 provides.
2, the preparation of experimental liquid：25 grams of jewellery cleaner to the number for weighing Examples 1 to 10 offer respectively is 1~10
In volumetric flask, ultra-pure water is added and is settled to 100mL, mixing is as experimental liquid.
Trial test：Oral gavage experiment is carried out to experimental animal using the experimental liquid of 5000mg/kg body weight doses, is not found
There is death in experimental animal, therefore formal test design dosage is 5000mg/kg weight.
Formal test：110 healthy, 18~20 grams of weight SPF grade kunming mices are chosen, stochastic averagina is divided into 11
Group, every group each 10, half male and half female, and it is 1~11 to number, wherein group 1 is blank control group, by the amount of 0.2mL/10g weight
Ultra-pure water is given with oral 1 gavage of gastric perfusion needle；Oral 1 time of the amount gastric perfusion needle of 0.2mL/10g weight is pressed respectively in group 2~groups 11
Gavage gives 1~No. 10 experimental liquid, that is, organizes 2 and give No. 1 experimental liquid, group 3 gives No. 2 experimental liquids, and group 4 gives No. 3 experimental liquids, group
5 give No. 4 experimental liquids ..., and group 11 gives No. 10 experimental liquids.Each group animal fasting 16 hours, freely drink before gavage
Water gives normal diet after gavage, the Routine Management under conditions of 22 ± 1 DEG C of room temperature, humidity 60 ± 5%；Raise identical day
Number observes the poisoning symptom and death condition of mouse daily, and after the completion of experiment in 14 days, data statistics is carried out to test result.
Wherein, it during this experiment, is poisoned during finger to finger test, mouse occurs trembling, twitch, salivate, diarrhea, drowsiness
With stupor etc. symptoms.Oral toxicity classification is as shown in table 1 below：
Table 1
| LD50(mg/Kg) | ≤50 | 51~500 | 501~5000 | ＞ 5000 |
| Toxicity grading | High poison | Medium poison | Low toxicity | It is practical nontoxic |
During entire experiment, the diet activity of each group animal subject normally has no apparent poisoning symptom and death.By
This as it can be seen that jewellery cleaner provided in an embodiment of the present invention mouse oral toxicity LD50>5000mg/kg weight, safety are good.
Experiment two：Skin irritation test
(1) skin closure type patch test
1, test specimen：Jewellery cleaner sample provided in an embodiment of the present invention.
2, test method：From 55 volunteers of a certain regional choice, the age of volunteer, body was strong between 20~45 years old
Health, in the recent period non-drug administration, nonbreast-fed women or gravid woman, non-constitution sensitive subjects.Volunteer is divided into 11 groups at random,
Every group of five people.Wherein, group 1 is blank control group, and the small interior of spot examination device does not place any substance, spot is tried the low sensitization glue of device
Band is pasted on the back of volunteer or forearm bends side, is gently pressed with palm and is allowed to equably stick on the skin；Group 2~groups 11 with
The processing method of group 1 is identical, unlike：The jewellery cleaner that will be provided respectively added with the 0.025mL embodiment of the present invention 1~10
It is put into the small interior of spot examination device；I.e. group 2 it is corresponding be the embodiment of the present invention 1 provide jewellery cleaner, group 3 it is corresponding be the present invention
The jewellery cleaner that embodiment 2 provides, it is jewellery cleaner ... that the embodiment of the present invention 3 provides that group 4 is corresponding,
Group 11 it is corresponding be the embodiment of the present invention 10 provide jewellery cleaner.After each group test duration 24 hours, 48 hours, spot is removed
30min observes the response situation and record for sticking place's skin after impression disappearance after trying device.
Wherein, skin closure type patch test dermoreaction grade scale see the table below 2.
Table 2
During entire experiment, the dermoreaction of the recipient site of the subject of group 1- groups 11 is negative.By
This, which can be seen that jewellery cleaner provided in an embodiment of the present invention, will not cause the allergy and stimulate the reaction of skin, safety good.
(2) repeatability is opening smears experiment
1, test specimen:Jewellery cleaner sample provided in an embodiment of the present invention.
2, test method：From a certain region select 55 volunteers, the age of volunteer between 20-45 Sui, body
Health, in the recent period non-drug administration, nonbreast-fed women or gravid woman, non-constitution sensitive subjects.Volunteer is divided into 11 at random
Group, every group of five people.Wherein, group 1 is blank control group, is bent using forearm as recipient site, 3 × 3cm of area2, recipient site
Drying is kept, avoids contact with before tested and during by gesture other external preparations, with ultra-pure water 0.05 ± 0.005g/ times, equably
Smear recipient site；Group 2~groups 11 are respectively test group, unlike group 1：It is provided using the embodiment of the present invention 1~10
Jewellery cleaner sample 0.05 equably smears recipient site ± 0.005g/ times；Wherein, group 2 corresponds to the embodiment of the present invention 1 and provides
Jewellery cleaner sample, group 3 correspond to the embodiment of the present invention 2 provide jewellery cleaner samples, group 4 correspond to the embodiment of the present invention
The 3 jewellery cleaner samples ... provided and so on, group 11 corresponds to the jewellery cleaner sample that the embodiment of the present invention 10 provides.
Each group carries out 2 times and equably smears recipient site daily, and long run test completes experiment, observes the tested of subject daily after 7 days
The dermoreaction situation at position simultaneously records.During experiment, if there is 3 points or more of dermoreaction in such as the following table 3
When situation, it can stop continuing to test and record result.
Wherein, table 3 is that opening smear of skin repeatability tests dermoreaction judgment criteria table.
Table 3
During entire experiment, the tested partial skin reaction of the subject of group 1~11 is negative, so this
The jewellery cleaner that inventive embodiments provide will not cause the allergy and irritative response of skin, very mild to skin, safety
Property is good.
Experiment three：Dirt-removing power is tested
1, test specimen：Jewellery cleaner provided in an embodiment of the present invention and contrast product (founding white liquid detergent).
2, test method：
The preparation of artificial dirt：50g yellow soils, 30g urea are weighed in 500mL beakers, and 20mL clear water, side stirring is added
1g peanut oil, 10g white sugar, 5g egg clear liquids is added in side, is uniformly mixed.
Test the preparation of solution：The embodiment of the present invention 1~10 is provided with 250mg/kg hard water jewellery cleaner and
Contrast product-founds the test solution that white liquid detergent is configured to a concentration of 1%.And respectively by the test solution of each embodiment point
It is spare (for example, the test solution of embodiment 1 is contained in respectively in 1~No. 4 beaker loaded in 4 beakers；The test of embodiment 2
Solution is contained in respectively in 5~No. 8 beakers ...).
It is 24 each to choose clean jewel bracelet (ruby bangle, crystal bangle, Diamond Bracelet, agate bangle), and point
The quality for also known as measuring each bangle, is denoted as m0(being accurate to 1mg).Then, it is equably smeared on every bangle a certain amount of artificial
Dirt (dirt amount on every bangle is 0.5g~1g), and the quality of every bangle is weighed after placement 4h at ambient temperature,
It is denoted as m1(being accurate to 1mg).
It is elaborated below with the decontamination cleaning step of ruby bangle:24 ruby bangles are divided into 12 groups, often
Then each group ruby bangle is respectively placed in clear water (tap water), vertical white liquid detergent test solution and embodiment 1 by group two
The taking-up of each group bangle is placed in room temperature after 10min and dried by soaking and washing in~10 test solution, and extension dries in the air and weighs each hand after 3h
The quality of chain, is denoted as m2(being accurate to 1mg) calculates decontamination force value, and under equal conditions, the gap for the bangle that detects by an unaided eye
Whether the dirt residual condition at place simultaneously has greasy feeling with hand touch perception bangle and records.
Wherein, crystal bangle, Diamond Bracelet, agate bangle decontamination cleaning step with reference to ruby bangle test side
Method, the difference is that the object of cleaning is different between them, other all sames.
3, test result：Refer to the following table 4, wherein decontamination force value=100% × (m1-m2)/(m1-m0)。
Table 4
Bangle is compared to other jewellery, it is easier to be infected with sweat stain and other complicated spots, therefore the pollution condition of dirt
Generally can be more serious than other jewellery, and as can be seen that jewelry provided in an embodiment of the present invention is clear from the test result of upper table 4
Lotion to ruby bangle, crystal bangle, Diamond Bracelet, agate bangle decontamination force value up to 99% or more, hence it is evident that be higher than water
The decontamination force value for washing or standing white liquid detergent cleaning, so product of the present invention is good to the clean effect of bangle.
In addition, under comparable conditions, the result for visually observing and touching each group bangle after cleaning is as follows：Use this hair
Bangle clean surface after the jewellery cleaner cleaning of bright Examples 1 to 10 is for example new, does not have remaining dirt at bangle gap, touches
Feel non-greasy；Bangle after being cleaned using clear water, surface smut are still had, and sense of touch is greasy；It is clear using vertical white liquid detergent
The spot of bangle after washing, surface largely removes, sense of touch non-greasy, but still remains part dirt at the gap of bangle
Dirt.It follows that in this experiment, jewellery cleaner provided in an embodiment of the present invention can be effectively removed various bangle surfaces
On dirt, and do not damage the color and luster etc. of bangle, cleaning effect is best.
Jewellery cleaner provided in an embodiment of the present invention, the synergistic effect having using enzyme preparation and surfactant, can
The various spots on bullion surface, and the performances such as color and luster for not damaging bullion are effectively removed, while being formulated mildly, it is right
Skin is non-stimulated, safe.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
All any modification, equivalent and improvement etc., should all be included in the protection scope of the present invention made by within refreshing and principle.
Claims (10)
1. a kind of jewellery cleaner, which is characterized in that by weight, including following component：
Nonionic surfactant：8%~10%；
Enzyme preparation：0.5%~1.5%；
Organic solvent：24.5%~32.5%；
Surplus is deionized water.
2. jewellery cleaner as described in claim 1, which is characterized in that by weight, including following component：
Nonionic surfactant：10%；
Enzyme preparation：1.5%；
Organic solvent：26.5%；
Surplus is deionized water.
3. jewellery cleaner as described in claim 1, which is characterized in that by weight, including following component：
Nonionic surfactant：8%~10%；
Enzyme preparation：0.5%~1.5%；
Organic solvent：24.5%~32.5%；
Essence：0.2%~0.3%；
Surplus is deionized water.
4. jewellery cleaner as claimed in claim 3, which is characterized in that by weight, including following component：
Nonionic surfactant：10%；
Enzyme preparation：1.5%；
Organic solvent：26.5%；
Essence：0.2%；
Surplus is deionized water.
5. jewellery cleaner as described in claim 1, which is characterized in that the enzyme preparation is protease, lipase, starch
At least three kinds of mixture in enzyme, cellulase or lysozyme.
6. jewellery cleaner as claimed in claim 5, which is characterized in that the enzyme preparation is protease, lipase and bacteriolyze
The mixture of enzyme.
7. jewellery cleaner as described in claim 1, which is characterized in that the nonionic surfactant is polyoxyethylene nonyl phenyl
Vinethene, octyl phenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, alkyl glycosides, cocoanut fatty acid diethanolamide or
At least two mixture in sucrose fatty ester.
8. jewellery cleaner as claimed in claim 3, which is characterized in that the organic solvent is ethyl alcohol, isopropanol, second two
Alcohol, cellosolvo, dipropylene either any one in ethylene glycol monobutyl ether or at least two mixture.
9. jewellery cleaner as described in claim 3 or 4, which is characterized in that the nonionic surfactant includes as follows
The substance of weight ratio：Fatty alcohol polyoxyethylene ether 7%, alkyl glycosides 3%；
The enzyme preparation includes the substance of following weight ratio：Proteinase-10 .5%, lipase 0.6%, lysozyme 0.4%；
The organic solvent includes the substance of following weight ratio：Dipropylene 4.5%, ethyl alcohol 22%.
10. the preparation method of jewellery cleaner as described in claim 1~9 any one, which is characterized in that including walking as follows
Suddenly：
Each component is weighed according to the formula of the jewellery cleaner as described in claim 1~9 any one, it is spare；
The part deionized water is added into ingredients pot；
It puts into the nonionic surfactant and organic solvent into the ingredients pot, and stirs to being completely dissolved；
The remaining deionized water is added；
The enzyme preparation is added into the ingredients pot, and stirs to being completely dissolved, obtains the jewellery cleaner.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810083069.3A CN108315103A (en) | 2018-01-29 | 2018-01-29 | A kind of jewellery cleaner and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810083069.3A CN108315103A (en) | 2018-01-29 | 2018-01-29 | A kind of jewellery cleaner and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108315103A true CN108315103A (en) | 2018-07-24 |
Family
ID=62887983
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810083069.3A Pending CN108315103A (en) | 2018-01-29 | 2018-01-29 | A kind of jewellery cleaner and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108315103A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110396325A (en) * | 2019-07-09 | 2019-11-01 | 江西瑞思博新材料有限公司 | A kind of screen printing ink cleaning agent and preparation method thereof |
| CN113430056A (en) * | 2021-08-04 | 2021-09-24 | 上海淑苑科技有限公司 | Jewelry and precious metal cleaning agent and preparation method thereof |
| CN113563989A (en) * | 2021-08-04 | 2021-10-29 | 上海淑苑科技有限公司 | Jewelry cleaning agent and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101831362A (en) * | 2010-06-10 | 2010-09-15 | 中国皮革和制鞋工业研究院 | High efficiency low-foaming blue leather degreaser |
| CN103642601A (en) * | 2013-12-04 | 2014-03-19 | 青岛安信医疗器械有限公司 | Bio-enzyme cleaner for medical devices |
| CN103865663A (en) * | 2012-12-12 | 2014-06-18 | 深圳市绿微康生物工程有限公司 | Medical multi-enzyme cleaning agent and preparation method thereof |
| CN105838508A (en) * | 2016-05-11 | 2016-08-10 | 于文 | Concentrated efficient enzyme-added type machine dishwashing detergent and preparation method thereof |
| CN105907484A (en) * | 2016-05-25 | 2016-08-31 | 深圳市洁王精细化工科技有限公司 | Detergent as stain removal pen and preparation method of detergent |
| CN106906059A (en) * | 2017-02-20 | 2017-06-30 | 广州市南大实业有限公司 | A kind of solidifying pearl of Low-foam and easily rinsing laundry and preparation method and application |
-
2018
- 2018-01-29 CN CN201810083069.3A patent/CN108315103A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101831362A (en) * | 2010-06-10 | 2010-09-15 | 中国皮革和制鞋工业研究院 | High efficiency low-foaming blue leather degreaser |
| CN103865663A (en) * | 2012-12-12 | 2014-06-18 | 深圳市绿微康生物工程有限公司 | Medical multi-enzyme cleaning agent and preparation method thereof |
| CN103642601A (en) * | 2013-12-04 | 2014-03-19 | 青岛安信医疗器械有限公司 | Bio-enzyme cleaner for medical devices |
| CN105838508A (en) * | 2016-05-11 | 2016-08-10 | 于文 | Concentrated efficient enzyme-added type machine dishwashing detergent and preparation method thereof |
| CN105907484A (en) * | 2016-05-25 | 2016-08-31 | 深圳市洁王精细化工科技有限公司 | Detergent as stain removal pen and preparation method of detergent |
| CN106906059A (en) * | 2017-02-20 | 2017-06-30 | 广州市南大实业有限公司 | A kind of solidifying pearl of Low-foam and easily rinsing laundry and preparation method and application |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110396325A (en) * | 2019-07-09 | 2019-11-01 | 江西瑞思博新材料有限公司 | A kind of screen printing ink cleaning agent and preparation method thereof |
| CN113430056A (en) * | 2021-08-04 | 2021-09-24 | 上海淑苑科技有限公司 | Jewelry and precious metal cleaning agent and preparation method thereof |
| CN113563989A (en) * | 2021-08-04 | 2021-10-29 | 上海淑苑科技有限公司 | Jewelry cleaning agent and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6881710B1 (en) | Personal care products based upon surfactants based upon alkyl polyglucoside quaternary compounds | |
| CN108315103A (en) | A kind of jewellery cleaner and preparation method thereof | |
| CN108893212A (en) | A kind of solidifying pearl and preparation method thereof of doing washing | |
| CN102395269B (en) | Antiviral agent and cleanser | |
| CN106590984B (en) | A kind of concentrated tableware detergent | |
| CN108096055A (en) | A kind of face cleaning cream and preparation method thereof | |
| CN107982135A (en) | A kind of shampoo and preparation method thereof | |
| CN107998028A (en) | A kind of shower cream and preparation method thereof | |
| CN110184135A (en) | A kind of antibacterial dish washing liquid of propolis and preparation method thereof | |
| CN108300606A (en) | Liquid detergent | |
| CN107929104A (en) | A kind of three-in-one wash and maintenance liquid of biology enzyme and preparation method thereof | |
| CN108192760A (en) | A kind of anhydrous liquid detergent and preparation method thereof | |
| CN106727151A (en) | A kind of mildy wash and preparation method thereof | |
| CN107400570A (en) | Novel low-foaming Multi-enzyme detergent and preparation method thereof | |
| CN106726869A (en) | A kind of shampoo of natural no stimulation and preparation method thereof | |
| Mawani et al. | Formulation and evaluation of antidandruff shampoo using mannosylerythritol lipid (MEL) as a bio-surfactant | |
| CN110974722A (en) | Application of biological polysaccharide in washing and protecting products | |
| JPH05112795A (en) | Detergent composition | |
| CN108300603A (en) | A kind of toy cleaning solution and preparation method thereof | |
| CN108130222A (en) | A kind of glasses cleaning agent and preparation method thereof | |
| CN113278472B (en) | Composition for enhancing mildness of hand dishwashing detergent and hand dishwashing detergent containing same | |
| CN107287059A (en) | Baby's children's clothes thing bio-enzyme cleaning agent | |
| EP1222242B1 (en) | Cleaning agents which contain surfactants and enzyme inhibitors | |
| CN113599322A (en) | A shampoo formula containing Gleditsia sinensis saponin and its preparation method | |
| CN112915054A (en) | Wet tissue solution, preparation method thereof and wet tissue |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180724 |