CN108314929A - A kind of preparation method of colour transfer pattern cement products - Google Patents
A kind of preparation method of colour transfer pattern cement products Download PDFInfo
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- CN108314929A CN108314929A CN201810435303.4A CN201810435303A CN108314929A CN 108314929 A CN108314929 A CN 108314929A CN 201810435303 A CN201810435303 A CN 201810435303A CN 108314929 A CN108314929 A CN 108314929A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/14—Printing inks based on carbohydrates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/53—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone involving the removal of at least part of the materials of the treated article, e.g. etching, drying of hardened concrete
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/72—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone involving the removal of part of the materials of the treated articles, e.g. etching
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/82—Coloured materials
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Decoration By Transfer Pictures (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a kind of preparation methods of colour transfer pattern cement products, and steps are as follows:1)The retarder of retarder not of the same race or various concentration is mixed with different colours ink, stabilizer, water respectively, obtains the transfer ink of different deferred actions;2)It is plotted on transfer carrier by required pattern flip horizontal 180 degree, and using transfer ink;3)It by the cement admixture placement layer by layer of different colours to transfer carrier, is demoulded after maintenance, then the transfer ink of different deferred actions is attached to cement products surface, and cement products surface forms transfer pattern and cement products surface slow setting degree is different;4)Above-mentioned cement products surface is washed away with water, the cement products surface of different slow setting degree shows different colors, forms colored complex pattern to get to colour transfer pattern cement products.The present invention is a kind of method for the colour transfer pattern cement products being simple and efficient, and is convenient for heavy industrialization application, promotes the apparent effect of various cement products, beautifying constructure facade.
Description
Fields
The invention belongs to building material technical fields, and in particular to a kind of preparation method of colour transfer pattern cement products.
Background technology
With the progress of modern society and the raising of living standards of the people, people require physical environment not being singly to meet
The practicality, but will have artistry, show in building trade field, exactly to elevation of building and decoration and environment
More stringent requirements are proposed for beautification.
Current all types of elevations of building, metope picture category decoration technique are mostly based on printing, picture mosaic or art sculpture.These
Technology and product be inadequate including:It is long-term to be used in outdoor, by factors such as ultraviolet light irradiation and environmental pollutions, can cause
It is pattern or image fade, thin out;Limited by printing equipment, it is impossible to print larger specification pattern or image on decorative panel;
It is high to the flatness of base material plate face, smoothness requirements.Art sculpture is to pass through general intaglio gimmick formation figure in decorative board
Case or image.Long in time limit, of high cost, same pattern or image can not ensure completely the same, and nothing in different plate face engravings
Method realizes industrialized mass production, and puzzle pattern or image unobvious.
Chinese patent 201510354203.5 and 201611182624.5 discloses a kind of transfer finished concrete technology,
So that imaging picture is applied to pre-cast concrete products surface becomes economical, can be produced in batches with heavy industrialization.But these
It is the color contrast using aggregate and surface in patent, formation is surface black and white and monochromatic simple pattern, can not be formed
Complicated multicolour pattern.
Invention content
The technical problem to be solved by the present invention is to provide one kind simply just in view of the deficiency of the prior art
Pattern, is drawn on by the preparation method of prompt colour transfer pattern cement products using the transfer ink containing different slow setting concentration
Multi layer colour cement products surface, after shaping and demoulding, the slow setting amount on cement products surface is different, and not solidified cement depth is not yet
Together, after water washes away, different colors is shown on the cement products surface of different depth, forms colored complex pattern.
The present invention be solve the problems, such as it is set forth above used by technical solution be:
A kind of preparation method of colour transfer pattern cement products, steps are as follows:
1) retarder of retarder not of the same race or various concentration is mixed to molten respectively with ink, stabilizer, water
Solution, obtains the transfer ink of different deferred actions;Wherein, the color of ink is also different in the transfer ink of different deferred actions;
2) by required multicolour pattern flip horizontal 180 degree, and transfer is plotted to using the transfer ink of different deferred actions
On carrier;
3) by the cement admixture of different colours on certain thickness placement layer by layer to transfer carrier, 5-100 DEG C conserves
It demoulds after a certain period of time, then the transfer ink of different deferred actions is attached to cement products surface, and cement products surface, which is formed, to be turned
It is patterned and cement products surface slow setting degree is different;
4) above-mentioned cement products surface is washed away with water, until the pattern needed for the exposing and color, different slow setting degree
Cement products surface shows different colors, forms colored complex pattern to get to colour transfer pattern cement products.
By said program, the retarder is one or more of white sugar, sodium gluconate, sodium citrate etc. by arbitrary
The mixture of ratio;Ink is the different printings colors such as yellow, cyan, magenta, black;Stabilizer is cellulose ether, xanthan
The mixture of one or more of glue, polyvinyl alcohol, polyamide etc. in any proportion.
By said program, when retarder is identical, the content of retarder is different in the transfer ink of different deferred actions.Example
Such as, the ink colors in the transfer ink of four kinds of different deferred actions are respectively yellow, cyan, magenta, black, then this four kinds
The transfer ink of different deferred actions is respectively yellow transfer ink, cyan transfer ink, magenta transfer ink, black transfer
Ink.Wherein, the content of retarder can be 1-15% in yellow transfer ink;The content of retarder can in cyan transfer ink
Think 15-30%;The content of retarder can be 30-45% in magenta transfer ink;Retarder in black transfer ink
Content can be 45-60%.
By said program, in the transfer ink, the mass fraction of ink is 5-35%;The mass fraction of retarder is 1-
60%;The mass fraction of stabilizer is 0.5-1%;Remaining group is divided into deionized water.
By said program, the pattern flip horizontal 180 degree, and method for drafting is one in Freehandhand-drawing, spraying, printing etc.
Kind or several be used in mixed way.
By said program, the transfer carrier is paper, plastic plate, glass mold, wood mold coupled, steel mould, aluminium
One or more of matter mold etc..
By said program, the sequence of the cement admixture placement layer by layer of the different colours is every layer from light color to dark color
The thickness poured is 0.5-10mm.
By said program, the demoulding time of the cement products is the 6-24 hours after the completion of pouring.
By said program, the cement admixture is that one or more of cement paste, mortar, concrete etc. are made.
Compared with prior art, the beneficial effects of the invention are as follows:
The present invention utilizes the transfer ink containing different deferred actions that pattern is needed on multi layer colour cement products surface,
After shaping and demoulding, the slow setting degree on cement products surface is different, and not solidified cement depth is also different, after water washes away, in difference
The cement products surface of depth shows different colors, forms colored complex pattern, and product meets concrete strength
It is required that being a kind of method of the complicated colour transfer pattern cement products of the preparation being simple and efficient, answered convenient for large-scale industrialization
With promoting the apparent effect of various cement products, beautifying constructure facade.
Description of the drawings
Fig. 1 is the multicolour pattern of required design in embodiment 1.
Fig. 2 is the pattern after the multicolour pattern flip horizontal 180 degree of required design in embodiment 1.
Fig. 3 is the colour transfer pattern cement products prepared by embodiment 1.
Specific implementation mode
For a better understanding of the present invention, with reference to the embodiment content that the present invention is furture elucidated, but the present invention is not
It is limited only to the following examples.
Each cement paste, cement mortar, concrete are the general proportioning in market in the present invention, and basic composition has silicate cement
Mud, flyash, miberal powder, sandstone aggregate, the compositions such as water-reducing agent, water, can be achieved with the present invention.It is with cement paste in embodiment 1
Example matches as follows substantially:230 kilograms of portland cement, 70 kilograms of miberal powder, 86 kilograms of water, 1.2 kilograms of water-reducing agent and difference
10 kilograms of the pigment of type.
Embodiment 1
A kind of preparation method of colour transfer pattern cement products, steps are as follows:
1) it by the Portugals 5g sodium, 5g white sugar, 5g sodium citrates, 10g Yellow inks, 1g polyvinyl alcohol and 74g water, stirs to molten
Solution, obtains yellow transfer ink;By the Portugals 10g sodium, 10g white sugar, 10g sodium citrates, 10g cyan inks, 1g polyvinyl alcohol and 59g
Water, stirring obtain cyan transfer ink to dissolving;By the Portugals 15g sodium, 15g white sugar, 15g sodium citrates, 10g magenta inks, 1g
Polyvinyl alcohol and 44g water, stirring obtain magenta transfer ink to dissolving;By the Portugals 20g sodium, 20g white sugar, 20g sodium citrates,
10g black inks, 1g polyvinyl alcohol and 29g water, stirring obtain black transfer ink to dissolving.
2) by multicolour pattern (as shown in Figure 1) the flip horizontal 180 degree (as shown in Figure 2) of required design, and step is used
1) transfer ink of gained different colours prints on paper.
3) paper is tiled to pouring in mold, the one side of print pattern upward, according to the color of printing pattern, is poured successively
It is net to build the white cement net slurry of 0.5mm, the yellow cement paste of 0.5mm, the blue cement net slurry of 0.5mm, the grey cement of 1mm
The black cement paste of slurry, 10mm, after the completion of pouring, 50 DEG C of maintenances.
4) form removal after 10 hours is conserved, washes away cement mortar product surface with water, pattern and color needed for the exposing
Until to get to colour transfer pattern cement products (as shown in Figure 3), the compression strength of cement products is 36.2Mpa after tested.
As shown in figure 3, the strong word of the required different colours being related in Fig. 1 is presented on cement products surface.
Embodiment 2
A kind of preparation method of colour transfer pattern cement products, steps are as follows:
1) by the Portugals 5g sodium, 10g white sugar, 15g Yellow inks, 0.5g xanthans and 69.5g water, stirring obtains Huang to dissolving
Color transfer ink;By the Portugals 10g sodium, 20g white sugar, 15g cyan inks, 0.5g xanthans and 54.5g water, stirring is obtained to dissolving
Cyan transfer ink;By the Portugals 15g sodium, 30g white sugar, 15g magenta inks, 0.5g xanthans and 39.5g water, stirring is extremely dissolved,
Obtain magenta transfer ink;The Portugals 20g sodium, 40g white sugar, 15g black inks, 0.5g xanthans and 24.5g water are stirred to molten
Solution, obtains black transfer ink.
2) by the multicolour pattern flip horizontal 180 degree of design, and steel mould is printed to using the transfer ink of different colours
On plate.
3) in steel mould, the one side of printing pattern upward, according to the color of printing pattern, pours the Huang of 1mm successively
Color cement mortar, the cyan cement mortar of 1mm, the magenta cement mortar of 1mm, the black cement mortar of 10mm, pour completion
Afterwards, 30 DEG C of maintenances.
4) form removal after 16 hours is conserved, washes away cement mortar product surface with water, pattern and color needed for the exposing
Until to get to colour transfer pattern cement products, the compression strength of cement products is 40.5Mpa after tested.
Embodiment 3
A kind of preparation method of colour transfer pattern cement products, steps are as follows:
1) by the Portugals 10g sodium, 10g Yellow inks, 1g cellulose ethers and 79g water, stirring obtains yellow transfer oil to dissolving
Ink;By the Portugals 20g sodium, 10g cyan inks, 1g cellulose ethers and 69g water, stirring obtains cyan transfer ink to dissolving;By 40g
Portugal's sodium, 10g magenta inks, 1g cellulose ethers and 49g water, stirring obtain magenta transfer ink to dissolving;By the Portugals 50g sodium,
10g black inks, 1g cellulose ethers and 39g water, stirring obtain black transfer ink to dissolving;
2) by the multicolour pattern flip horizontal 180 degree of design, and the transfer ink Freehandhand-drawing of above-mentioned four kinds of different colours is used
Onto wooden template;
3) in wood mold coupled, the one side of hand drawing pattern upward, according to the color of hand drawing pattern, pours 0.5mm's successively
The black cement paste of yellow cement paste, the cyan cement paste of 0.5mm, the magenta cement paste of 1mm, 2mm, has poured
Cheng Hou, 40 DEG C of maintenances;
4) form removal after 12 hours is conserved, washes away cement paste product surface with water, pattern and color needed for the exposing
Until to get to colour transfer pattern cement products, the compression strength of cement products is 45.8Mpa after tested.
Embodiment 4
A kind of preparation method of colour transfer pattern cement products, steps are as follows:
1) by 5g white sugar, 10g sodium citrates, 30g Yellow inks, 0.5g polyamide and 54.5g water, stirring is obtained to dissolving
To yellow transfer ink;10g white sugar, 20g sodium citrates, 30g cyan inks, 0.5g polyamide and 39.5g water are stirred to molten
Solution, obtains cyan transfer ink;By 15g white sugar, 30g sodium citrates, 30g magenta inks, 0.5g polyamide and 24.5g water,
Stirring obtains magenta transfer ink to dissolving;By 20g white sugar, 40g sodium citrates, 30g black inks, 0.5g polyamide and
9.5g water, stirring obtain black transfer ink to dissolving.
2) it by the multicolour pattern flip horizontal 180 degree of design, and is printed on paper using the transfer ink of different colours.
3) paper is tiled to pouring in mold, the one side of print pattern upward, according to the color of printing pattern, is poured successively
Build the yellow cement paste of 0.5mm, the cyan cement mortar of 1mm, the magenta cement mortar of 2mm, 5mm black concrete,
After the completion of pouring, 100 DEG C of maintenances.
4) form removal after 6 hours is conserved, washes away cement mortar product surface with water, pattern and color are needed for the exposing
Only to get to colour transfer pattern cement products, the compression strength of cement products is 35.8Mpa after tested.
The above is only a preferred embodiment of the present invention, it is noted that come for those of ordinary skill in the art
It says, without departing from the concept of the premise of the invention, several modifications and variations can also be made, these belong to the present invention's
Protection domain.
Claims (10)
1. a kind of preparation method of colour transfer pattern cement products, it is characterised in that its steps is as follows:
1)By the retarder of retarder not of the same race or different amounts respectively with ink, stabilizer, water, dissolving is mixed to,
Obtain the transfer ink of different deferred actions;
2)According to the pattern formed after required multicolour pattern flip horizontal 180 degree, different deferred actions obtained by step 1) are reused
Transfer ink be plotted to transfer carrier on;
3)It by the cement admixture placement layer by layer of different colours to transfer carrier, is demoulded after maintenance, then different deferred actions
Transfer ink is attached to cement products surface, cement products surface form transfer pattern and cement products surface slow setting degree not
Together;
4)Above-mentioned cement products surface is washed away with water, until the multicolour pattern needed for the exposing and its color, different slow setting degree
Cement products surface show different colors, form multicolour pattern to get to the colour transfer pattern of required multicolour pattern
Cement products.
2. a kind of preparation method of colour transfer pattern cement products according to claim 1, it is characterised in that described slow
Solidifying agent is the mixture of one or more of white sugar, Portugal's sodium, sodium citrate in any proportion.
3. a kind of preparation method of colour transfer pattern cement products according to claim 1, it is characterised in that described steady
It is the mixture of one or more of cellulose ether, xanthans, polyvinyl alcohol, polyamide in any proportion to determine agent.
4. a kind of preparation method of colour transfer pattern cement products according to claim 1, it is characterised in that described turn
In printing ink, the mass fraction of ink is 5-35%;The mass fraction of retarder is 1-60%;The mass fraction of stabilizer is 0.5-
1%;Remaining group is divided into deionized water.
5. a kind of preparation method of colour transfer pattern cement products according to claim 1, it is characterised in that step 2)
The pattern formed after multicolour pattern flip horizontal 180 degree needed for middle basis reuses turning for different deferred actions obtained by step 1)
Printing ink is plotted on transfer carrier, step 4)Middle gained multicolour pattern is identical as required multicolour pattern.
6. a kind of preparation method of colour transfer pattern cement products according to claim 1, it is characterised in that it is described not
Sequence with the cement admixture placement layer by layer of color is from light color to dark color, and every layer of thickness poured is 0.5-10mm.
7. a kind of preparation method of colour transfer pattern cement products according to claim 1, it is characterised in that step 3)
It is demoulded after middle 5-100 DEG C of maintenance.
8. a kind of preparation method of colour transfer pattern cement products according to claim 1, it is characterised in that the water
The demoulding time of mud product is the 6-24 hours after the completion of pouring.
9. a kind of preparation method of colour transfer pattern cement products according to claim 1, it is characterised in that described turn
Print carrier is one or more of paper, plastic plate, glass mold, wood mold coupled, steel mould, aluminum mold.
10. a kind of preparation method of colour transfer pattern cement products according to claim 1, it is characterised in that the water
Mud mixture is one or more of cement paste, mortar, concrete.
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Cited By (8)
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CN109591178A (en) * | 2018-12-24 | 2019-04-09 | 湖北工业大学 | The preparation method of masstone pattern transfer concrete |
CN109773956A (en) * | 2018-12-24 | 2019-05-21 | 湖北工业大学 | Without mold architectural concrete production method and transfer base film |
CN110143804A (en) * | 2019-06-14 | 2019-08-20 | 广州市建筑科学研究院有限公司 | Transfer pattern inorganic artificial stone slab and preparation method thereof |
CN111848217A (en) * | 2020-07-28 | 2020-10-30 | 中建商品混凝土有限公司 | Preparation method of image cement product |
CN112679171A (en) * | 2021-03-12 | 2021-04-20 | 广东博智林机器人有限公司 | Self-leveling mortar and preparation method and application thereof |
CN113787597A (en) * | 2021-09-08 | 2021-12-14 | 中建商品混凝土有限公司 | Preparation method of image cement product without film uncovering |
CN115464748A (en) * | 2022-08-18 | 2022-12-13 | 华润水泥技术研发有限公司 | UHPC formula image concrete and preparation method thereof |
CN116102303A (en) * | 2022-08-18 | 2023-05-12 | 华润水泥技术研发有限公司 | Self-leveling image concrete and manufacturing method thereof |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109591178A (en) * | 2018-12-24 | 2019-04-09 | 湖北工业大学 | The preparation method of masstone pattern transfer concrete |
CN109773956A (en) * | 2018-12-24 | 2019-05-21 | 湖北工业大学 | Without mold architectural concrete production method and transfer base film |
CN109591178B (en) * | 2018-12-24 | 2020-06-02 | 湖北工业大学 | Preparation method of multi-tone pattern transfer printing concrete |
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