CN108314814A - 一种环保阻燃贝壳粉橡胶复合材料 - Google Patents

一种环保阻燃贝壳粉橡胶复合材料 Download PDF

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CN108314814A
CN108314814A CN201810135707.1A CN201810135707A CN108314814A CN 108314814 A CN108314814 A CN 108314814A CN 201810135707 A CN201810135707 A CN 201810135707A CN 108314814 A CN108314814 A CN 108314814A
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张瑜
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Chengdu Warp And Weft Technology Co Ltd
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Abstract

本发明提供一种环保阻燃贝壳粉橡胶复合材料，其原料按重量份计为：三元乙丙橡胶30~50份、氯丁橡胶30~50份、贝壳粉15~50份、稀土磷酸盐12~18份、三聚磷酸铝10~15份、四氧化三铁6~9份、氧化锆5~7份、阻燃剂60~90份、阻燃协效剂10~15份、促进剂3~6份、硫化剂3~6份、抗氧剂1~4份。本发明的复合材料具有良好的抗张强度，防静电、耐磨损、阻燃等性能较好，生产成本低，使用寿命长，能够满足包括通讯、机柜、耐火设备等多种使用领域的需求。

Description

一种环保阻燃贝壳粉橡胶复合材料
技术领域
本发明涉及材料技术领域，具体涉及一种环保阻燃贝壳粉橡胶复合材料。
技术背景
贝壳粉作为一种新型环保材料，具有生产成本低，防静电性能佳，抗菌、抗氧化等优点；它与橡胶结合能够生产出性能较好的产品，是工业的发展方向，具有极好的市场前景。
目前市场上的橡胶制产品性能不能满足要求，在长期的热和辐射作用下，材料劣化明显，需要进一步提高耐磨性、耐热性、阻燃性。
发明内容为解决上述技术问题，本发明提供了以下技术方案：
一种环保阻燃贝壳粉橡胶复合材料，其原料按重量份计为：三元乙丙橡胶30~50份、氯丁橡胶30~50份、贝壳粉15~50份、稀土磷酸盐12~18份、三聚磷酸铝10~15份、四氧化三铁6~9份、氧化锆5~7份、阻燃剂60~90份、阻燃协效剂10~15份、促进剂3~6份、硫化剂3~6份、抗氧剂1~4份。
作为优选，其原料按重量份计为：三元乙丙橡胶38份、氯丁橡胶35份、贝壳粉40份、稀土磷酸盐15份、三聚磷酸铝12份、四氧化三铁7份、氧化锆6份、阻燃剂75份、阻燃协效剂12份、促进剂4份、硫化剂4份、抗氧剂2份。
作为优选，所述贝壳粉为贻贝、扇贝、牡蛎壳、河蚬壳、花甲壳中一种或多种磨制而成的贝壳粉。
作为优选，所述阻燃剂为氢氧化铝与氢氧化镁复配的阻燃体系，其重量配比为30~50：15~25。
作为优选，所述阻燃协效剂为六苯氧基环三磷腈与三聚氰胺聚磷酸盐的一种或组合。
作为优选，所述促进剂为促进剂TMTM。
与现有技术相比，本发明方案具有有益效果：本发明方案采用特种橡胶、贝壳粉和阻燃剂复配，能有效提高抗张强度，具有良好的防静电性、耐磨损性、抗氧化性等，并通过氢氧化铝与氢氧化镁复配的阻燃体系，加强了阻燃性，生产成本低，使用寿命长，能够满足包括通讯、机柜、耐火设备等多种使用领域的需求。
具体实施方式
下面通过具体实施例子对本发明做进一步的详细描述。
实施例1：
一种环保阻燃贝壳粉橡胶复合材料，其原料按重量份计为：三元乙丙橡胶30份、氯丁橡胶50份、贝壳粉50份、稀土磷酸盐12份、三聚磷酸铝15份、四氧化三铁6份、氧化锆5份、阻燃剂60份、阻燃协效剂10份、促进剂TMTM 6份、硫化剂6份、抗氧剂4份。
所述贝壳粉为贻贝、扇贝磨制而成的贝壳粉。
所述阻燃剂为氢氧化铝与氢氧化镁复配的阻燃体系，其重量配比为30：25。
所述阻燃协效剂为六苯氧基环三磷腈。
实施例2：
一种环保阻燃贝壳粉橡胶复合材料，其原料按重量份计为：三元乙丙橡胶50份、氯丁橡胶30份、贝壳粉15份、稀土磷酸盐18份、三聚磷酸铝10份、四氧化三铁9份、氧化锆7份、阻燃剂90份、阻燃协效剂15份、促进剂3份、硫化剂3份、抗氧剂1份。
所述贝壳粉为扇贝、牡蛎壳、河蚬壳、花甲壳磨制而成的贝壳粉。
所述阻燃剂为氢氧化铝与氢氧化镁复配的阻燃体系，其重量配比为50：15。
所述阻燃协效剂为三聚氰胺聚磷酸盐。
实施例3：
一种环保阻燃贝壳粉橡胶复合材料，其原料按重量份计为：三元乙丙橡胶38份、氯丁橡胶35份、贝壳粉40份、稀土磷酸盐15份、三聚磷酸铝12份、四氧化三铁7份、氧化锆6份、阻燃剂75份、阻燃协效剂12份、促进剂TMTM 4份、硫化剂4份、抗氧剂2份。
所述贝壳粉为扇贝磨制而成的贝壳粉。
所述阻燃剂为氢氧化铝与氢氧化镁复配的阻燃体系，其重量配比为42：20。
所述阻燃协效剂为六苯氧基环三磷腈与三聚氰胺聚磷酸盐的组合。
以上所述仅为本发明的优选实施例而已，并不用于限制本发明，对于本领域的技术人员来说，本发明可以有各种更改和变化。凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (6)

1.一种环保阻燃贝壳粉橡胶复合材料，其特征在于，其原料按重量份计为：三元乙丙橡胶30~50份、氯丁橡胶30~50份、贝壳粉15~50份、稀土磷酸盐12~18份、三聚磷酸铝10~15份、四氧化三铁6~9份、氧化锆5~7份、阻燃剂60~90份、阻燃协效剂10~15份、促进剂3~6份、硫化剂3~6份、抗氧剂1~4份。
2.如权利要求1所述的环保阻燃贝壳粉橡胶复合材料，其特征在于，其原料按重量份计为：三元乙丙橡胶38份、氯丁橡胶35份、贝壳粉40份、稀土磷酸盐15份、三聚磷酸铝12份、四氧化三铁7份、氧化锆6份、阻燃剂75份、阻燃协效剂12份、促进剂4份、硫化剂4份、抗氧剂2份。
3.如权利要求1所述的环保阻燃贝壳粉橡胶复合材料，其特征在于，所述贝壳粉为贻贝、扇贝、牡蛎壳、河蚬壳、花甲壳中一种或多种磨制而成的贝壳粉。
4.如权利要求1所述的环保阻燃贝壳粉橡胶复合材料，其特征在于，所述阻燃剂为氢氧化铝与氢氧化镁复配的阻燃体系，其重量配比为30~50：15~25。
5.如权利要求1所述的环保阻燃贝壳粉橡胶复合材料，其特征在于，所述阻燃协效剂为六苯氧基环三磷腈与三聚氰胺聚磷酸盐的一种或组合。
6.如权利要求1所述的环保阻燃贝壳粉橡胶复合材料，其特征在于，所述促进剂为促进剂TMTM。
CN201810135707.1A 2018-02-09 2018-02-09 一种环保阻燃贝壳粉橡胶复合材料 Withdrawn CN108314814A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115124765A (zh) * 2022-06-10 2022-09-30 安徽建筑大学 一种通用橡胶用阻燃导热剂、其制备方法及应用

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115124765A (zh) * 2022-06-10 2022-09-30 安徽建筑大学 一种通用橡胶用阻燃导热剂、其制备方法及应用
CN115124765B (zh) * 2022-06-10 2023-04-14 安徽建筑大学 一种通用橡胶用阻燃导热剂、其制备方法及应用

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