CN108314473A - A kind of method of wood vinegar and biomass coproduction Liquid Fertilizer and high-quality biological matter charcoal - Google Patents
A kind of method of wood vinegar and biomass coproduction Liquid Fertilizer and high-quality biological matter charcoal Download PDFInfo
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- CN108314473A CN108314473A CN201810315336.5A CN201810315336A CN108314473A CN 108314473 A CN108314473 A CN 108314473A CN 201810315336 A CN201810315336 A CN 201810315336A CN 108314473 A CN108314473 A CN 108314473A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/02—Soil-conditioning materials or soil-stabilising materials containing inorganic compounds only
- C09K17/04—Soil-conditioning materials or soil-stabilising materials containing inorganic compounds only applied in a physical form other than a solution or a grout, e.g. as granules or gases
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- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Fertilizers (AREA)
Abstract
The invention belongs to agricultural technology fields, and in particular to a kind of method of co-producing bio matter charcoal and fertilizer.The method of wood vinegar provided by the invention and biomass coproduction Liquid Fertilizer and high-quality biological matter charcoal, it is initiative in such a way that wood vinegar extracts biomass carbonated gained solid phase carbonizing production, the purifying of wood vinegar and one step of nutriment enrichment process are completed.Suspended matter, tar and unstable material etc. in wood vinegar can be adsorbed, while reduce the coloration of wood vinegar.It is worth noting that, directly wood vinegar is utilized to extract biomass carbonated gained solid product, it can extract and wherein be conducive to the substances such as the water-soluble organic aromatic of small-molecular-weight of plant growth, improve the soluble humic acid ingredient in wood vinegar, reach enrichment of the nutriment in wood vinegar.
Description
Technical field
The invention belongs to agricultural technology fields, and in particular to a kind of method of co-producing bio matter charcoal and fertilizer.
Background technology
How agricultural wastes to be carried out efficiently utilizing the research hotspot in always agricultural technology.By taking stalk as an example, most
Early straw utilization mode is straw-returning.There are two types of traditional straw-returning modes, respectively stalk crush direct returning to farmland and
Stalk on-site incineration is made after plant ash and carries out returning to the field again.But stalk directly crushes and carries out returning to the field and easily lead to pest and disease damage and ask
Topic;And by although returning to the field will not bring pest and disease damage problem, open incineration that can cause organic in stalk again after stalk on-site incineration
The waste of matter, a large amount of dense smokes generated in burning process can also cause serious air pollution.The above problem makes people always
Seek the new way using agricultural wastes, in recent years, it is more as studying to prepare biomass carbon using agricultural wastes
A kind of new method.
Agricultural wastes are pyrolyzed under limit oxygen or anoxic condition, are carbonized, you can obtains biomass carbon, while can also
Obtain the by-products such as stalk oily (or wood tar), wood vinegar.Wherein, wood vinegar contains a variety of active ingredients, including a variety of organic
Matter such as organic acid, aldehyde, ketone, alcohol, phenol etc., also plant growth necessary element such as calcium, magnesium, sodium, iron etc., so wood vinegar is not
Only have effects that desinsection, sterilization, while the growth of plant can also be promoted.Biomass carbon can be used as soil conditioner or be used for
Carbon-based fertilizer etc. is prepared, and wood vinegar can be used for making medical material, food additives, plant growth promoter etc..Wood vinegar at
It is point more complex, containing water-soluble substances such as phenols, carboxylic acids, alcohols, also containing a small amount of wood tar and suspended matter, so applying
It needs first to refine before, when making different purposes, required refined degree is different.It is that one kind can using wood vinegar production liquid fertilizer
Make full use of the mode of wood vinegar active ingredient.Wood tar and suspended matter contained in wood vinegar are unfavorable for wood vinegar and directly use
It is applied to crop as Liquid Fertilizer, when preparing Liquid Fertilizer using wood vinegar in the prior art, often first using the methods of absorption, distillation
Wood vinegar is carried out to remake use after suitably refining.
For example, Chinese patent literature CN103724128A discloses a kind of method preparing foliar fertilizer using wood vinegar,
The technology aoxidizes wood vinegar first with hydrogen peroxide, then active carbon adsorption and ion exchange resin is used to adsorb successively
Method by after oxidation macromolecular and other impurity remove, then wood vinegar is concentrated using reverse osmosis membrane so that the wooden vinegar
Nutritional ingredient is enriched in liquid, is subsequently added into the additives such as humic acid, magnesium sulfate as nutritional supplementation, blade face is made in last coating
Fertilizer.But not only process is complicated, complex steps for the foliar fertilizer technology of preparing, production cost is also higher, it is also necessary to consume dioxygen
Water, ion exchange resin and reverse osmosis membrane;Also, the loss of organic matter will certainly be caused in preparation process, such as science and technology
Paper《Application of the membrane technology in wood vinegar purifying process》Middle announcement, when using the reverse osmosis concentration for carrying out wood vinegar, meeting
There is nearly 10% small molecule organic matter to be detached from wood vinegar with dilute side.
For another example Chinese patent literature CN105669257A discloses a kind of sunflower stalk, pachyrhizus stalk and peanut straw system
The method of standby wood vinegar Water soluble fertilizer.The technology by sunflower stalk, pachyrhizus stalk and peanut straw by being first granulated destructive distillation again, gas phase
Crude pyroligneous acid is obtained after product condensation, 8~10 hours is stood after crude pyroligneous acid is evaporated under reduced pressure, takes middle layer air-distillation 3 again
~5 hours, acetum pyrolignosum rectificatum liquid is obtained, is used as wood vinegar Water soluble fertilizer.As it can be seen that the processing time of crude pyroligneous acid need to be up in the technology
Ten more than hour, and be evaporated under reduced pressure and air-distillation also needs to consumption mass energy, this undoubtedly substantially increases and is produced into
This.
Therefore, how efficient, simple, low cost using wooden while active ingredient in reservation wood vinegar to greatest extent
Vinegar liquid prepares Liquid Fertilizer and is a problem to be solved by those skilled in the art.
Invention content
Technical problem to be solved by the present invention lies in overcome the process for preparing Liquid Fertilizer using wood vinegar in the prior art
Defect complicated, cumbersome, of high cost, and then a kind of side that Liquid Fertilizer is prepared using wood vinegar efficiently, simple, inexpensive is provided
Method.
The present invention adopts the following technical scheme that in order to achieve the above objectives:
A kind of method of wood vinegar and biomass coproduction Liquid Fertilizer and high-quality biological matter charcoal, includes the following steps,
Agricultural wastes are carbonized under limit oxygen or anoxic condition, and collect solid phase carbonizing production;
Wood vinegar is contacted with the solid phase carbonizing production, then detaches, wood vinegar and high-quality biological matter charcoal must be enriched with;
The enrichment wood vinegar is Liquid Fertilizer;
Or nutriment is added into the enrichment wood vinegar and is used as Liquid Fertilizer.
The weight ratio of the biomass carbon and the wood vinegar is (0.2~0.8):1.
The time of the extraction is 0.5~3h;And/or
The temperature of the extraction is 50~90 DEG C.
The time of the extraction is 0.5~1h;And/or
The temperature of the extraction is 80~90 DEG C.
The wood vinegar is the by-product of the carbonization.
Average cell size >=0.04cm of the solid phase carbonizing production3/g。
The high-quality that the method for the wood vinegar and biomass coproduction Liquid Fertilizer and high-quality biological matter charcoal is prepared
Biomass carbon is used as soil conditioner or the purposes for producing carbon-based fertilizer.
A kind of dress for realizing the wood vinegar and biomass coproduction Liquid Fertilizer and the method for high-quality biological matter charcoal
It sets, including biomass carbonated unit, product separative element and sequentially connected extraction unit, solid-liquid separation unit, liquid storage list
Member and composite fertilizer's reaction member;
The liquid-phase outlet of the solid-liquid separation unit is connected with the entrance of the liquid storage unit.
Heretofore described extraction is sensu lato extraction, refers to by the way that wood vinegar is in contact with solid phase carbonizing production
So that the water-soluble substances in solid phase carbonizing production are released into the process of wood vinegar.Heretofore described average cell size is to adopt
It is measured with nuclear magnetic resonance nanoaperture analyzer.
Technical scheme of the present invention has the advantages that:
1. the method for wood vinegar provided by the invention and biomass co-producing bio matter charcoal and Liquid Fertilizer, initiative uses wood
Vinegar liquid extracts the mode of biomass carbonated solid product, and the purifying of wood vinegar and one step of nutriment enrichment process are completed.Energy
It is enough to adsorb suspended matter, tar and the unstable material etc. in wood vinegar, while reducing the coloration of wood vinegar.It is worth noting
, directly wood vinegar is utilized to extract solid phase carbonizing production, can extract has conducive to the small-molecular-weight water solubility of plant growth
The substances such as machine aromatic improve the soluble humic acid ingredient in wood vinegar, reach enrichment of the nutriment in wood vinegar.
The process detached again by above-mentioned extraction, success realize mass exchange between biomass carbon and the interface of wood vinegar so that
The quality of wood vinegar and biomass carbon is improved simultaneously.
Liquid Fertilizer fertilizer efficiency obtained by method provided by the invention is good, for being applied to tomato after diluting 500 times, by this
Liquid Fertilizer made from application method is compared with directly using wood vinegar as Liquid Fertilizer, the raising of Vitamin C content in tomato
Up to 46%, soluble protein improves 19%, and total output improves 26%, and single fruit weight improves 6%.
The present invention efficiently can prepare Liquid Fertilizer using the by-product wood vinegar during biomass carbonated, need not consume
Other materials, preparation process are efficient, simple, inexpensive.
2. the method for wood vinegar provided by the invention and biomass co-producing bio matter charcoal and Liquid Fertilizer, solid using charing gained
Phase product handles wood vinegar, and there is obtained wood vinegar pervasive practicability can be adjusted flexibly using it as matrix
The formula of Liquid Fertilizer, also to coordinate the demand in various plant growths each stage while improving fertilizer efficiency.In addition, present invention gained
High-quality biological matter charcoal due to having adsorbed the active ingredient in wood vinegar, while the function of sterilization is had also obtained, in this way, this hair
The wood vinegar and the method for biomass carbon co-producing bio matter charcoal and Liquid Fertilizer of bright offer are not only able to significantly improve the attached of wood vinegar
It is value added, additionally it is possible to improve the quality of biomass carbon, and production process is simple to operation, green non-pollution meets diversified agriculture
Industry technical need.
3. utilizing process units provided by the present invention, wood vinegar and biomass coproduction wood vinegar and high-quality can be optimized
The production technology of biomass carbon reduces energy consumption, improves production efficiency.It realizes pipeline system production, while obtaining liquid composite fertilizer
With soil conditioner and carbon-based fertilizer.
Specific implementation mode
Technical scheme of the present invention is clearly and completely described below in conjunction with attached drawing, it is clear that described implementation
Example is a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, ordinary skill
The every other embodiment that personnel are obtained without making creative work, shall fall within the protection scope of the present invention.
In addition, technical characteristic involved in invention described below different embodiments is as long as they do not conflict with each other
It can be combined with each other.
Description of the drawings:
1- wood vinegar, 2- solid phase carbonizing productions, 3- pot for solvent extraction, the outlet of 4- pot for solvent extraction, 5- centrifuges, 6- filters, 7- storages
Flow container, 8- reaction kettles, 9- loading hoppers, 10- service hatches, 11- blowdowns, 12- high-quality biological matter charcoals, 13- water, 14- liquid are compound
Fertilizer.
Embodiment 1
A kind of method of wood vinegar and biomass carbon coproduction Liquid Fertilizer and high-quality biological matter charcoal is present embodiments provided, is wrapped
Include following steps,
Maize straw is carbonized under anoxic condition, collects solid phase carbonizing production, and carry out to gas phase carbonizing production
Spray settles spray liquid using water as initial spray agent, takes middle level liquid phase as spray agent after spray liquid layering
Spray operation is continued cycling through, and spray liquid is settled, pH value detection is carried out to middle level liquid phase, when its pH value is less than 5.5,
The spray liquid is collected as wood vinegar.
20kg solid phases carbonizing production and 100kg wood vinegar are mixed at 80 DEG C, stirring so that wood vinegar carbonizes solid phase
Product is completely soaked, and is kept stirring 1h, and operation then is centrifuged to gained solid, liquid mixture, collects liquid phase as liquid
Body fertilizer, gained solid phase is high-quality biological matter charcoal.
Embodiment 2
A kind of method of wood vinegar and biomass carbon coproduction Liquid Fertilizer and high-quality biological matter charcoal is present embodiments provided, is wrapped
Include following steps,
Rice husk is carbonized under anoxic condition, collects solid phase carbonizing production, carbonizes the 80kg solid phases at 90 DEG C
Product and the mixing of 100kg wood vinegar, stirring so that the solid phase carbonizing production is completely soaked by wood vinegar, is kept stirring 0.5h, so
Operation is centrifuged to gained solid, liquid mixture afterwards, gained solid phase is high-quality biological matter charcoal, and gained liquid is at 30 DEG C
Under stood, further to remove tiny suspended particulate therein, then collect liquid phase as Liquid Fertilizer.
Wood vinegar used is commercially available wood vinegar coarse raw materials in the present embodiment.
Embodiment 3
A kind of method of wood vinegar and biomass carbon coproduction Liquid Fertilizer and high-quality biological matter charcoal is present embodiments provided, is wrapped
Include following steps,
Wheat stalk is carbonized under anoxic condition, collects solid phase carbonizing production, and carry out to gas phase carbonizing production
Spray settles spray liquid using water as initial spray agent, takes middle level liquid phase as spray agent after spray liquid layering
Spray operation is continued cycling through, and spray liquid is settled, pH value detection is carried out to middle level liquid phase, when its pH value is less than 5.5,
The spray liquid is collected as wood vinegar.
The obtained solid phase carbonizing productions of 30kg and 100kg wood vinegar are mixed at 50 DEG C, stirring so that wood vinegar should
Solid phase carbonizing production is completely soaked, and is kept stirring 3h, is then filtered operation to gained solid, liquid mixture, to carry out phase point
From then collection liquid phase collects solid phase as high-quality biological matter charcoal as Liquid Fertilizer.
Embodiment 4
A kind of method of wood vinegar and biomass carbon coproduction Liquid Fertilizer and high-quality biological matter charcoal is present embodiments provided, is wrapped
Include following steps,
Shell is carbonized under limited oxygen condition, collects solid phase carbonizing production, it then will be solid obtained by 50kg at 70 DEG C
Phase carbonizing production and the mixing of 100kg wood vinegar, stirring so that solid phase carbonizing production is completely soaked by wood vinegar, is kept stirring 2h,
Then operation is centrifuged to gained solid, liquid mixture, obtained solid is high-quality biological matter charcoal, and gained liquid is 50
It is stood at DEG C, further to remove tiny suspended particulate therein, then collects liquid phase.The liquid phase being collected into is as matrix
Carry out the production of liquid composite fertilizer.
Embodiment 5
The method of wood vinegar and biomass carbon coproduction Liquid Fertilizer and high-quality biological matter charcoal provided in this embodiment is to utilize
What Liquid Fertilizer process units provided by the present invention was prepared, Fig. 1 is the schematic diagram of process units part-structure, is not wrapped in figure
Include biomass carbonated unit and product separative element.As shown, the device includes sequentially connected pot for solvent extraction, centrifuge, storage
Flow container and reaction kettle.The pot for solvent extraction is provided with wood vinegar entrance, solid phase carbonizing production entrance, material outlet, is additionally provided with stirring
Device and temperature regulating device.The material outlet being arranged on pot for solvent extraction is connected with a centrifuge, the solid-phase outlet of the centrifuge with
One helical conveyer device is connected, and liquid-phase outlet is connected by first filter with fluid reservoir, the liquid-phase outlet of the fluid reservoir and
The wood vinegar entrance of composite fertilizer's reactor is connected, and the outlet of composite fertilizer's reactor is additionally provided with the second filter.
Its production stage is as follows:
Maize straw is carbonized in biomass carbonated unit first, solid phase charing is obtained by product separative element
Product, then it is respectively that the 50kg solid phase carbonizing productions and 100kg is wooden by the wood vinegar entrance and biomass carbon entrance of pot for solvent extraction
Vinegar liquid is added, and it is 70 DEG C then to control the temperature in pot for solvent extraction, and is stirred 2.5 hours, to complete to extract.After the completion of extraction
Material exported by the material outlet of pot for solvent extraction, then enter centrifuge.The solid phase separated by the centrifuge is
It is sent to packaging, as soil conditioner or for producing charcoal base manure by high-quality biological matter charcoal by helix transporting device;
The liquid phase separated by the centrifuge is settled by being delivered to fluid reservoir after first filter at 40 DEG C, with into
One step removes fine suspension therein.The solid impurity come out by sedimentation separation in fluid reservoir is discharged by sewage draining exit, is passed through
Liquid phase after sedimentation is squeezed by pumping in composite fertilizer's reaction kettle, and the addition of other nutrients is carried out from feed inlet, is carried out compound
The preparation of fertilizer, obtained material can be by being pumped to packaging or use after the second filter.
Comparative example 1
The Liquid Fertilizer that this comparative example provides is made from following methods:
The commercially available activated carbons of 20kg and 100kg wood vinegar are mixed at 80 DEG C, stirring so that wood vinegar is by commercially available activated carbon
It is completely soaked, is kept stirring 1h, operation then is centrifuged to gained solid, liquid mixture, collect liquid phase as Liquid Fertilizer.
Effect example
Clear water, commercial liquid fertilizer, wood vinegar stoste, embodiment 1 and 1 gained Liquid Fertilizer of comparative example is respectively adopted and is applied to west
Red persimmon experimental plot.Frequency of administration:It sprays weekly once, sprays 6 weeks altogether, the single amount of spraying is 25L/hm2。
It is harvested when ripe, metering overground part yield, single fruit weight and the sampling analysis index of quality, as a result such as Tables 1 and 2 institute
Show.
Influence of the 1 each Liquid Fertilizer of table to tomato production, single fruit weight and quality
Note:M, wood vinegar stoste used in embodiment 1;M+C, the Liquid Fertilizer that embodiment 1 obtains;D, commercial liquid fertilizer;CK, clearly
Water sprays;Number is extension rate when spraying after processing name;M+AC, comparative example gained Liquid Fertilizer.
From table, it is apparent that wood vinegar dilution spray processing decrease than commercial liquid fertilizer Vc contents, other
Indicator difference is little;And the Liquid Fertilizer being prepared with the method that embodiment 1 provides dilutes 500 times and sprays, yield and quality is equal
It is significantly improved.
It should be noted that wood vinegar of the present invention and biomass coproduction Liquid Fertilizer and high-quality biological matter charcoal
Method, wherein different from traditional active carbon adsorption using the method that solid phase carbonizing production handles wood vinegar.Activated carbon
Production technology includes charing, cooling, washing and activation.Technical paper《The discussion of wood vinegar process for purification》Middle announcement,
The operation principle of active carbon adsorption is to adsorb wood tar using the big specific surface area of activated carbon, due to activated carbon adsorptive capacity
Greatly, the dosage of activated carbon can not be too many, generally the 2%~15% of wood vinegar, to prevent required ingredient absorption in wood vinegar
Fall.And the present invention is that the water-soluble organic molecule in solid phase carbonizing production is released into wood vinegar, and by first extracting again
The mode of separation makes biomass carbon surface that mass exchange occur.
Obviously, the above embodiments are merely examples for clarifying the description, and does not limit the embodiments.It is right
For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of variation or
It changes.There is no necessity and possibility to exhaust all the enbodiments.And it is extended from this it is obvious variation or
Variation is still in the protection scope of this invention.
Claims (8)
1. a kind of method of wood vinegar and biomass coproduction Liquid Fertilizer and high-quality biological matter charcoal, which is characterized in that including following
Step,
Agricultural wastes are carbonized under limit oxygen or anoxic condition, and collect solid phase carbonizing production;
Wood vinegar is extracted into the solid phase carbonizing production, is then detached, wood vinegar and high-quality biological matter charcoal must be enriched with;
The enrichment wood vinegar is Liquid Fertilizer;
Or nutriment is added into the enrichment wood vinegar and is used as Liquid Fertilizer.
2. the method for wood vinegar according to claim 1 and biomass coproduction Liquid Fertilizer and high-quality biological matter charcoal, special
Sign is, in the leach step, the weight ratio of the solid phase carbonizing production and the wood vinegar is (0.2~0.8):1.
3. the method for wood vinegar according to claim 1 or 2 and biomass coproduction Liquid Fertilizer and high-quality biological matter charcoal,
It is characterized in that,
The time of the extraction is 0.5~3h;And/or
The temperature of the extraction is 50~90 DEG C.
4. according to the side of claim 1-3 any one of them wood vinegar and biomass coproduction Liquid Fertilizer and high-quality biological matter charcoal
Method, which is characterized in that
The time of the extraction is 0.5~1h;And/or
The temperature of the extraction is 80~90 DEG C.
5. according to the side of claim 1-4 any one of them wood vinegar and biomass coproduction Liquid Fertilizer and high-quality biological matter charcoal
Method, which is characterized in that the wood vinegar is the by-product of the carbonization.
6. according to the side of claim 1-5 any one of them wood vinegar and biomass coproduction Liquid Fertilizer and high-quality biological matter charcoal
Method, which is characterized in that average cell size >=0.04cm of the solid phase carbonizing production3/g。
7. according to the side of claim 1-6 any one of them wood vinegar and biomass coproduction Liquid Fertilizer and high-quality biological matter charcoal
The high-quality biological matter charcoal that method is prepared is used as soil conditioner or the purposes for producing carbon-based fertilizer.
8. one kind is for realizing claim 1-6 any one of them wood vinegar and biomass coproduction Liquid Fertilizer and high-quality biological
The device of the method for matter charcoal, which is characterized in that including biomass carbonated unit, product separative element and sequentially connected leaching
Bill of lading member, solid-liquid separation unit, liquid storage unit and composite fertilizer's reaction member;
The liquid-phase outlet of the solid-liquid separation unit is connected with the entrance of the liquid storage unit.
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CN110683920A (en) * | 2019-11-20 | 2020-01-14 | 江苏省农业科学院 | Rhododendron growth promoting carbon-based liquid fertilizer and preparation method and application thereof |
CN110698278A (en) * | 2019-11-20 | 2020-01-17 | 江苏省农业科学院 | Rhododendron formation promoting charcoal-based liquid fertilizer and preparation method and application thereof |
CN113233456A (en) * | 2021-06-18 | 2021-08-10 | 南京林业大学 | Method for preparing activated carbon and liquid fertilizer through biomass pyrolysis based on combined action of biomass vinegar and biomass oil |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110698278A (en) * | 2019-11-20 | 2020-01-17 | 江苏省农业科学院 | Rhododendron formation promoting charcoal-based liquid fertilizer and preparation method and application thereof |
CN113233456A (en) * | 2021-06-18 | 2021-08-10 | 南京林业大学 | Method for preparing activated carbon and liquid fertilizer through biomass pyrolysis based on combined action of biomass vinegar and biomass oil |
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