The device of processing is absorbed for industrial waste gas
Technical field
The invention belongs to exhaust-gas treatment fields, more particularly, to a kind of device absorbing processing for industrial waste gas.
Background technology
Sulfur dioxide is most common, simplest oxysulfide.One of Air Pollutant Discharge.It can be sprayed when volcano eruption
The gas also will produce sulfur dioxide in many industrial process.Since coal and oil usually all contain element sulphur, burning
When can generate sulfur dioxide.Sulfur dioxide is directly reacted the processing of form waste gas of sulfur dioxide by present waste gas treatment equipment
It neutralizes, prevents sulfur dioxide to be discharged into air and pollute the environment, sulfur dioxide gas can not be recycled and be utilized, it is unfavorable
In environmental protection, it is unable to control dosing when to sulfur dioxide treatment, medicament is caused largely to waste.
Invention content
The present invention for overcome the deficiencies in the prior art, provide it is a kind of facilitate recycle sulfur dioxide gas be used for work
The device of industry waste gas absorption processing.
To achieve the goals above, the present invention uses following technical scheme:A kind of dress absorbing processing for industrial waste gas
It sets, including exhaust gas processing pool, conveying pipeline, catch box and oxidizing chamber, the industrial waste gas processing pond, catch box and oxidizing chamber pass through
The conveying pipeline connection, the exhaust gas processing pool is interior to be equipped with mud-scraping apparatus, and liquid collecting bucket, the liquid collecting are equipped with above the oxidizing chamber
Bucket bottom, which is equipped with, lets slip a remark, and described let slip a remark is equipped with current-limiting apparatus;Calcium hydroxide solution is held in exhaust gas processing pool, sulfur dioxide is useless
Gas enters in exhaust gas processing pool, since exhaust gas is passed through always, so that exhaust gas is entered in calcium hydroxide solution and occurs with calcium hydroxide
Reaction, sulfur dioxide is reacted with calcium hydroxide solution generates calcium sulfite precipitation, and calcium sulfite deposit buildup is in exhaust gas processing pool
Bottom, by the sediment scraping delivery in sedimentation basin to exhaust gas processing pool bottom side, sediment passes through conveying pipeline for mud-scraping apparatus work
It in transport to oxidizing chamber, is aoxidized in oxidation pond, so that calcium sulfite precipitation is oxidized to calcium sulfate precipitation, subsequently again to sulfuric acid
Calcium precipitate is recycled, and is conducive to environmental protection;Oxidant is held in liquid collecting bucket, oxidant is preferably hydrogen peroxide, is filled by current limliting
The setting set, oxidant is quickly reacted with calcium sulfite precipitation when oxidation reaction being enable just to proceed by, when oxidation is anti-
Should carry out it is similar when reduce the rate that oxidant flows into, the addition for avoiding oxidant excessive causes a large amount of waves of oxidant
Take.
Preferably, the current-limiting apparatus includes being set to the fold baffle let slip a remark on inner wall, in described let slip a remark
Sliding rail, the spring being fixedly connected with described sliding rail one end in wall and the sliding block being fixedly connected with the spring other end;Sliding block
It can be slided along sliding rail, sliding rail plays guide and limit to sliding block, can make sliding block after an end movement occurs by spring
It is returned to origin-location, realizes that reset function, fold baffle can be turned over downwards, increases the rate that oxidizing chamber is added in oxidant.
Preferably, described fold baffle bottom surface one end is flexibly connected with the inner wall of leting slip a remark;The flexible connection can be
Hinged, fold baffle can be rotated around the hinge joint of bottom surface one end, make to turn under fold baffle, increased oxidant and flowed into oxidizing chamber
Rate, so that the oxidation reaction of early period is quickly carried out.
Preferably, being equipped with cavity in the fold baffle, the cavity end is equipped with cross bar, and the cross bar is equipped with
Hook, the barb are connect with the sliding block by a connecting rope;When filling with oxidant in liquid collecting bucket, oxidant is to turning down baffle
Pressure be more than spring elastic force, make fold baffle push, turn down baffle push while, fold baffle pull connecting rope,
Make sliding block along sliding rail slid inward, spring extends, and oxidant is rapidly injected inside oxidizing chamber and reacts with sediment at this time,
Rapid reaction is set to carry out;When reaction carry out it is similar when, the oxidant surplus in liquid collecting bucket tails off, and baffle is turned down to bottom
Pressure becomes smaller, and sliding block resets under the action of the spring, and fold baffle resets under the drive of connecting rope, and the bore let slip a remark is made to become
It is small, cause the rate that oxidant injects to become smaller, so that oxidant is slowly injected into oxidizing chamber ensures fully to react in oxidizing chamber, avoids
Oxidant largely flows into the excessive waste that oxidant is caused in oxidizing chamber.
Preferably, described cavity one end is equipped with through-hole, the connecting rope is arranged in the through-hole, outside the connecting rope
Side is equipped with rubber tube, and the rubber tube is fixedly connected on the through-hole wall;Prevent the oxidant in liquid collecting bucket enter cavity and
Device is impacted in guide rail, using the preferable ductility of rubber tube, so that rubber tube is not interfered with the normal of fold baffle and turns over
Folding and reset, play preferable waterproof effect.
Preferably, the exhaust gas processing pool inner wall is equipped with fixed plate, the mud-scraping apparatus includes being set to the exhaust gas
Hydraulic pump at the top of processing pond, the first A-frame in the fixed plate, on first A-frame
Two A-frames and the cleaning shoe being connect with second A-frame by a connecting rod;Mud-scraping apparatus is carried out by hydraulic pump
Driving, the second A-frame are articulated on a triangle endpoint of the first A-frame, enable the second A-frame around hinged
Point is rotated, and to drive cleaning shoe to carry out scraping bricklayer's's work, is effectively carried out the sediment in exhaust gas processing pool at concentration
Reason.
Preferably, the hydraulic pressure pump output terminal is equipped with hydraulic stem, the hydraulic stem passes through a push rod and the described 2nd 3
Angle support is flexibly connected, and the cleaning shoe scrapes clod equipped with multiple;Hydraulic pump is by hydraulic stem driving push rod, to make to scrape mud
Plate moves, by the first A-frame and the second A-frame that the conversion of motion of hydraulic pump in the vertical direction is horizontal for cleaning shoe
To movement, scrape clod be strip, can preferably be contacted with the inner bottom surface of exhaust gas processing pool, promotion scrape mud effect, convenient for will
The sediment of bottom of pond pushes to bottom of pond side, facilitates and transports sediment in oxidizing chamber by conveying pipeline.
Preferably, the exhaust gas processing pool bottom is equipped with inclined-plane, material collecting tank, the material collecting tank are equipped with below the inclined-plane
One end is connected with the conveying pipeline;Sediment is pushed to by mud-scraping apparatus on inclined-plane, and sediment is tumbled along inclined-plane to gathering materials
In slot, the sediment generated in exhaust gas processing pool is made uniformly to focus in material collecting tank, it will be in exhaust gas processing pool convenient for conveying pipeline
Sediment carries out consolidated delivery, can preferably be recycled to sediment.
Preferably, the conveying pipeline is equipped with dredge pump and sieve plate, the catch box is set to below the sieve plate;
By the setting of dredge pump, the sediment in material collecting tank can be preferably transported out by the way that conveying pipeline is defeated, prevent conveying pipeline from existing
It results in blockage during transport sediment, dredge pump takes the hydrogen in a part of exhaust gas processing pool out of while extracting sediment out
Calcium oxide solution, when the sediment of suction is transported along with calcium hydroxide solution to the sieve plate of conveying pipeline, calcium hydroxide is molten
Under liquid oozes from sieve plate, falls into the catch box below sieve plate, calcium hydroxide solution is collected, sediment is then along sieve
Continue further to be aoxidized in transport to oxidation pond.
Preferably, the oxidizing chamber bottom side is globoidal structure;Oxidant is fallen to from liquid collecting bucket in oxidizing chamber, is fallen
It falls on the globoidal structure of oxidizing chamber bottom side, oxidant flow to oxidizing chamber bottom along cambered surface, makes oxidant and sediment
It comes into full contact with, preferably makes sediment that oxidation reaction occur, generate required product.
The present invention has the following advantages:Sulfur dioxide recovery can be utilized, be made while disposing form waste gas of sulfur dioxide
Sulfur dioxide, which further reacts, generates other substances convenient for recycling, and is conducive to environmental protection;In the production generated to sulfur dioxide reaction
Object can control the addition of medicament when being handled, avoid the input that medicament is excessive, prevent medicament from largely wasting.
Description of the drawings
Fig. 1 is the structural diagram of the present invention.
Fig. 2 is the structural schematic diagram that the present invention lets slip a remark.
Fig. 3 is the structural schematic diagram of present invention fold baffle.
Specific implementation mode
In order to make those skilled in the art be better understood from the present invention program, below in conjunction in the embodiment of the present invention
Attached drawing, technical solution in the embodiment of the present invention carry out clear, complete description, it is clear that described embodiment is only
A part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, ordinary skill people
The every other embodiment that member is obtained without making creative work should all belong to the model that the present invention protects
It encloses.
As shown in Figs. 1-3, a kind of device absorbing processing for industrial waste gas, including exhaust gas processing pool 1, conveying pipeline 2, collection
Liquid case 3 and oxidizing chamber 4, the exhaust gas processing pool 1, catch box 3 and oxidizing chamber 4 are connected to by the conveying pipeline 2, exhaust gas processing pool
1 side is equipped with exhaust gas entrance 11, calcium hydroxide solution is housed in exhaust gas processing pool 1, form waste gas of sulfur dioxide is from exhaust gas entrance 11
Into in exhaust gas processing pool 1, it is full of on 1 top of exhaust gas processing pool, form waste gas of sulfur dioxide is lasting to be passed through in exhaust gas processing pool 1,
So that exhaust gas is entered in calcium hydroxide solution, reacted with calcium hydroxide solution, sponge sulfur dioxide gas, it is heavy to generate calcium sulfite
Shallow lake is placed in 1 bottom of exhaust gas processing pool;Mud-scraping apparatus is equipped in the exhaust gas processing pool 1, mud-scraping apparatus can will be dispersed at exhaust gas
The sediment of reason 1 bottom of pond is concentrated, and sediment is concentrated at one convenient for processing;4 top of the oxidizing chamber is equipped with liquid collecting
Bucket 41, liquid collecting bucket 41 is built-in, and to have oxidant, the oxidant be preferably hydrogen peroxide, and 41 bottom of the liquid collecting bucket, which is equipped with, lets slip a remark 42,
Oxidant in liquid collecting bucket 41 42 is fallen in oxidizing chamber 4 by leting slip a remark, and described let slip a remark 42 is equipped with current-limiting apparatus, current-limiting apparatus
It prevents oxidant is excessive to be added in oxidation pond 4, causes the waste of oxidant, be unfavorable for environmental protection.
The current-limiting apparatus includes being set to the fold baffle 424 let slip a remark on 42 inner walls, set on 42 inner walls of leting slip a remark
It interior sliding rail 421, the spring 423 being fixedly connected with 421 one end of the sliding rail and is fixedly connected with 423 other end of the spring
Sliding block 422, sliding block 422 can be moved left and right along sliding rail 421 in sliding rail 421, pass through spring after sliding block 422 moves
423 make sliding block 422 reset;Described 424 bottom surface one end of fold baffle is flexibly connected with 42 inner walls of leting slip a remark, the flexible connection
Can be hinged, fold baffle 424 can be rotated around hinge joint, to realize the purpose of fold;In the fold baffle 424
Equipped with cavity 4241,4241 end of the cavity is equipped with cross bar 4242, and the cross bar 4242 is equipped with barb 4243, the barb
4243 are connect with the sliding block 422 by a connecting rope 425, and 4241 one end of the cavity is equipped with through-hole, and the connecting rope 425 is worn
In the through-hole, 425 outside of the connecting rope is equipped with rubber tube, and the rubber tube is fixedly connected on the through-hole wall,
Waterproofing protection is played to cavity 4241 and sliding rail 421 by rubber tube, prevents oxidant from entering in cavity 4241 and sliding rail 421
The normal work of equipment is impacted, and there is preferable ductility using rubber tube, when fold baffle 424 turns down
Rubber tube will not hinder to turn down the normal fold movement of baffle 424.
When oxidation reaction occurring in the oxidation pond 4, oxidant is filled in liquid collecting bucket 41, oxidant is to leting slip a remark at 42 at this time
Fold baffle 424 generates larger pressure, and fold baffle 424 is made to turn down, and fold baffle 424 is turned over around its hinge joint
Folding, make fold baffle front end diagonally downward, increase let slip a remark 42 through-current capacity, being oxidant can rapidly add in oxidation pond 4, turn over
Baffle 424 is rolled over after fold, pulls sliding block 422, to 42 internal motions of leting slip a remark, to be drawn simultaneously along sliding rail 421 by connecting rope 425
Spring 423 is stretched, spring 423 is made to be in elongation state;After oxidant is gradually added into oxidation pond 4, the oxygen in liquid collecting bucket 41
Agent amount is reduced, and oxidant reduces the pressure for turning down baffle 424, and the elastic force of spring 423 is more than oxidant and is kept off to fold at this time
The pressure of plate 424, sliding block 422 resets under the action of elastic force, so that fold baffle 424 is resetted by connecting rope 425, is reduced with this
Let slip a remark 42 through-current capacity, so that the oxidant in liquid collecting bucket 41 is slowly added into oxidizing chamber 4, avoid oxidant is excessive from being added to
A large amount of wastes of oxidant are caused in oxidizing chamber 4.
1 inner wall of the exhaust gas processing pool is equipped with fixed plate 14, and the mud-scraping apparatus includes being set to the exhaust gas processing pool 1
The hydraulic pump 12 at top, the first A-frame 15 in the fixed plate 14, on first A-frame 15
Second A-frame 16 and the cleaning shoe 18 being connect with second A-frame 16 by a connecting rod 17, the first A-frame
15 a lines are fixedly connected in fixed plate 14, and an endpoint of the second A-frame 16 and the first A-frame 15 is cut with scissors
It connects, the second A-frame 16 can be rotated around hinge joint;12 output end of the hydraulic pump is equipped with hydraulic stem 121, the liquid
Compression bar 121 is flexibly connected by a push rod 13 with second A-frame 16, and the cleaning shoe 18 scrapes clod equipped with multiple
181, it is strip to scrape clod 181, is evenly distributed in 18 bottom surface of cleaning shoe, cleaning shoe 18 is made to be more easy to 1 bottom of exhaust gas processing pool
The sediment in portion is struck off.
After form waste gas of sulfur dioxide, which is passed through, to react with the calcium hydroxide solution in processing pond in exhaust gas processing pool 1, production
Raw calcium sulfite precipitate distribution is in 1 bottom surface of exhaust gas processing pool, and starting hydraulic pump 12 makes mud-scraping apparatus operate, and hydraulic pump 12 drives
Hydrodynamic compression bar 121 works, and hydraulic stem 121 pushes push rod 13 to move downward, and push rod 13 pushes 16 one end of the second A-frame
It moves down, the second A-frame 16 is rotated around hinge joint, converts the vertical motion of hydraulic stem 121 to cleaning shoe 18
Transverse movement, so that the sediment that cleaning shoe 18 disperses 1 bottom surface of exhaust gas processing pool is struck off, sediment uniformly concentrated on
Together, conveying pipeline 2 carries out unified conveying to sediment.
1 bottom of the exhaust gas processing pool is equipped with inclined-plane, and material collecting tank 19,19 one end of the material collecting tank are equipped with below the inclined-plane
It is connected with the conveying pipeline 2;Mud-scraping apparatus strikes off the sediment of 1 bottom of exhaust gas processing pool, sediment is pushed to useless
The inclined-plane in gas disposal pond 1 goes out, and sediment is tumbled along inclined-plane to material collecting tank 19, and sediment concentration is made to be stored in material collecting tank 19
It is interior, facilitate conveying pipeline 2 to carry out unified conveying to the sediment in material collecting tank 19.
The conveying pipeline 2 is equipped with dredge pump 21 and sieve plate 22, and the catch box 3 is set to 22 lower section of the sieve plate;
When conveying pipeline 2 conveys the sediment in material collecting tank 19, start dredge pump 21, it will be in material collecting tank 19 by dredge pump 21
Sediment sucking conveying pipeline 2 in, when sediment enters in conveying pipeline 2, will certainly suck a part calcium hydroxide solution
Into in conveying pipeline 2, when sediment and calcium hydroxide solution when the transport in conveying pipeline 2, reach at sieve plate 22, due to sediment
Diameter is more than the aperture of 22 sieve pore of sieve plate, and sediment is moved on along floor lever of sieve tray, and calcium hydroxide solution then passes through sieve plate 22
It falls in the catch box 3 of 22 lower section of sieve plate, the calcium hydroxide solution in conveying pipeline 2 is collected by catch box 3, is prevented
Calcium hydroxide solution directly falls the inconvenience for causing to arrange on the ground.
4 bottom side of the oxidizing chamber is globoidal structure;Aggregate bin 41 is set on 4 bottom surface globoidal structure of the oxidizing chamber
Side, when the oxidant in aggregate bin 41 is fallen into oxidizing chamber 4, oxidant along 4 bottom surface of oxidizing chamber globoidal structure downstream to
4 bottom surface of oxidizing chamber makes oxidant be come into full contact with the sediment in 4 bottom surface of oxidizing chamber, so that sediment is fully reacted and generates institute
Product is needed, the recycling to sediment is conducive to.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.