CN108301226A - A kind of preparation method of fire resistant textile - Google Patents

A kind of preparation method of fire resistant textile Download PDF

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Publication number
CN108301226A
CN108301226A CN201711089980.7A CN201711089980A CN108301226A CN 108301226 A CN108301226 A CN 108301226A CN 201711089980 A CN201711089980 A CN 201711089980A CN 108301226 A CN108301226 A CN 108301226A
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CN
China
Prior art keywords
parts
fire resistant
fabric
flame
base fabric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711089980.7A
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Chinese (zh)
Inventor
张根法
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Ruida Textile Technology Co Ltd
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Jiangsu Ruida Textile Technology Co Ltd
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Priority to CN201711089980.7A priority Critical patent/CN108301226A/en
Publication of CN108301226A publication Critical patent/CN108301226A/en
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
    • C09D191/06—Waxes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C3/00—Stretching, tentering or spreading textile fabrics; Producing elasticity in textile fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0043—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/183—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials the layers are one next to the other
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/06—Properties of the materials having thermal properties
    • D06N2209/067—Flame resistant, fire resistant

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a kind of preparation methods of fire resistant textile; its manufacture craft is simple; its fire resistant textile is when encountering high temperature or open fire; flame-retardant expanded coatings volume expands rapidly; effective invasion of the trap heat to human body of energy; the damage that clothing calcination is brought is avoided simultaneously, the textile of this anti-flaming thermal-insulation can protect the body of people to escape injury in the scene of a fire.By stenter to the stretching of fabric width and by stenter to fabric gait of march adjustment come the control to fabric longitudinal stretching force, controllable wax line lines can be made respectively to be adapted with it, since the cracking of semi-products fabric is according to the physical action to expand with heat and contract with cold, so not having the generation of the defects such as " point " fallen and occurred in wax line processed.

Description

A kind of preparation method of fire resistant textile
Technical field
The present invention relates to fire prevention textile field more particularly to a kind of preparation methods of fire resistant textile.
Background technology
Weaving original meaning is taken from the general name of spinning and woven fabric, but with the continuous hair of textile knowledge system and subject system Exhibition and perfect, after the technologies such as especially non-woven textile material and three-dimensional be composite braided generate, weaving is not only traditional spinning And woven fabric, also include nonwoven fabric technology, three dimensional weaving technique, electrostatic nano-netting technology etc., so, modern textile refers to one kind The multiscale structure processing technology [1-2] of fiber or fiber assembly.The weaving of ancient Chinese has very long-drawn-out with printing technology Long history, early in primitive society period, ancients have understood and have gathered materials on the spot for the variation of acclimatization, utilize natural resources As the raw material of weaving and printing and dyeing, and the textile tool that is simple to manufacture.Until today, our daily clothing, certain lives use Product and the art work are all the products of weaving and printing technology.
Since 2012, the international competitiveness of China's textile product is decreased obviously.Especially to Europe and Japanese market, The two markets are two big staple markets of China textile product outlet, by Europe debt crisis, the deleterious effects of Sino-Japanese relations, to Europe Portion dropped once again after 2011 in alliance and Japanese market declines 11.5% and 5.7% respectively.1-10 months in 2013, in State's textile continues to decline to European Union outlet, is gone up to Japan outlet, but the market share further declines.
Industry growth rate glides or even atrophy, and there is an urgent need to seek to make the transition, the following industry, which faces, shuffles for enterprise in the industry.Enterprise Industry transition faces several aspect problems：
First：Improve environmental protection concept.Energy-saving and emission-reduction are future developing trends, and textile industry high pollution and not environmentally problem are full It is denounced, it is unfavorable to be formed to industry development, and environmental pollution becomes industry development bottleneck.Secondly, brand image is promoted, brand is improved Popularity and occupation rate of market.Third expands Sales Channel, since 2012, although industry is sluggish, and online retailing on line It is still hot, its power has been played significantly.4th, reinforce cost control, if the research and development of new raw material utilize, it is competing to re-establish market Strive advantage.5th, exploitation diversification, differentiated products meet the market demand, break away from the serious shape of product homogeneity in industry State.Therefore therefore the textile fabric of various special typeizations also comes into being.
With the progress of production science and technology, the fabric of various functions also emerges one after another, and can meet people in different occasions Under requirement to fabric, especially in particular circumstances for fabric it is functional require it is stronger.Fireproof facing material is then to endanger People can be protected to escape injury in the case of machine, but common flame retardant fabric is only capable of fire-retardant, but heat-proof quality is bad, so i.e. Energy textile that is fire-retardant and having good thermal insulation, could preferably protect the personal safety of people in the scene of a fire.
Invention content
To solve the above-mentioned problems, the present invention provides a kind of productions can foam rapidly when encountering high temperature or open fire, uses Carry out the technical solution of the fire prevention textile of anti-flaming thermal-insulation：
A kind of preparation method of fire resistant textile includes the following steps：
(1) textile is carried out pre-treatment work by the pre-treatment of base fabric, spare as base fabric；
(2) it is coated with flame-retardant expanded coating, the ready upper flame-retardant expanded coating of scrim surfaces coating in step (1)；
(3) it dries：The base fabric that flame-retardant expanded coating is carried in step (2) to be dried, drying temperature is 80-90 DEG C, Time is 3-5 minutes；
(4) wax coat is coated with, and one wax of base fabric obtained in step (3) is carried out at a temperature of 100-140 DEG C two-sided Printing, base fabric carry out the stretching of breadth or longitudinal direction on tenter system, and extensibility is respectively in 0.5-15%；
(5) cloth cools down, and the fabric under tensional state obtained in step (4) is cold in 0~8 DEG C of environment But, finished product fire resistant textile is obtained.
It is mixed preferably, wax is rosin, paraffin and beeswax, the mass mixing ratio of rosin, paraffin and beeswax is 1 : 0.1~3: 0.1~2.
Preferably, flame-retardant expanded coating includes 900-1100 parts of formaldehyde, and 500-600 parts of melamine, carbamate 250-350 parts, 20-30 parts of boric acid, 50-150 parts of diammonium hydrogen phosphate, 5-10 parts of starch, 40-60 parts of ethanol amine, sucrose 1300- 1500 parts, 1500-1700 parts of silicone resin.
Preferably, flame-retardant expanded coating is coated on using brushing or spray figure mode in base fabric.
The beneficial effects of the present invention are：
(1) manufacture craft of the present invention is simple, and fire resistant textile is when encountering high temperature or open fire, flame-retardant expanded coatings volume Rapid expansion, effective invasion of the trap heat to human body of energy, while the damage for avoiding clothing calcination from bringing, it is this in the scene of a fire The textile of anti-flaming thermal-insulation can protect the body of people to escape injury.
(2) by stenter to the stretching of fabric width and by stenter to the adjustment of fabric gait of march come to fabric The control of longitudinal stretching force can make controllable wax line lines and be adapted with it, respectively due to the cracking of semi-products fabric It is according to the physical action to expand with heat and contract with cold, so not having the generation of the defects such as " point " fallen and occurred in wax line processed.
Specific implementation mode
To keep the goal of the invention, technical solution and advantage of the present invention clearer, embodiments of the present invention are made below Further it is described in detail.
The preparation method of the fire resistant textile of the present invention is prepared by following steps：
(1) textile is carried out pre-treatment work by the pre-treatment of base fabric, spare as base fabric；
(2) it is coated with flame-retardant expanded coating, the ready upper flame-retardant expanded coating of scrim surfaces coating in step (1)；
(3) it dries：The base fabric that flame-retardant expanded coating is carried in step (2) to be dried, drying temperature is 80-90 DEG C, Time is 3-5 minutes；
(4) wax coat is coated with, and one wax of base fabric obtained in step (3) is carried out at a temperature of 100-140 DEG C two-sided Printing, base fabric carry out the stretching of breadth or longitudinal direction on tenter system, and extensibility is respectively in 0.5-15%；
(5) cloth cools down, and the fabric under tensional state obtained in step (4) is cold in 0~8 DEG C of environment But, finished product fire resistant textile is obtained.
Its manufacture craft is simple, and for fire resistant textile when encountering high temperature or open fire, flame-retardant expanded coatings volume is swollen rapidly It is swollen, can effective invasion of the trap heat to human body, while the damage for avoiding clothing calcination from bringing, in the scene of a fire it is this it is fire-retardant every The textile of heat can protect the body of people to escape injury.
Wherein wax is that rosin, paraffin and beeswax mix, and the mass mixing ratio of rosin, paraffin and beeswax is 1: 0.1 ~3: 0.1~2.Flame-retardant expanded coating includes 900-1100 parts of formaldehyde, 500-600 parts of melamine, carbamate 250-350 Part, 20-30 parts of boric acid, 50-150 parts of diammonium hydrogen phosphate, 5-10 parts of starch, 40-60 parts of ethanol amine, 1300-1500 parts of sucrose, silicon 1500-1700 parts of oxygen alkane resin.Flame-retardant expanded coating is coated on using brushing or spray figure mode in base fabric.By stenter to knitting The stretching of object breadth and the adjusting come the control to fabric longitudinal stretching force to fabric gait of march by stenter, can distinguish Controllable wax line lines is made to be adapted with it, since the cracking of semi-products fabric is the physical action that foundation is expanded with heat and contract with cold, So not having the generation of the defects such as " point " fallen and occurred in wax line processed.
Above-described embodiment is presently preferred embodiments of the present invention, is not the limitation to technical solution of the present invention, as long as Without the technical solution that creative work can be realized on the basis of the above embodiments, it is regarded as falling into patent of the present invention Rights protection scope in.

Claims (4)

1. a kind of preparation method of fire resistant textile, it is characterised in that：Include the following steps：
(1) textile is carried out pre-treatment work by the pre-treatment of base fabric, spare as base fabric；
(2) it is coated with flame-retardant expanded coating, the ready upper flame-retardant expanded coating of scrim surfaces coating in step (1)；
(3) it dries：The base fabric that flame-retardant expanded coating is carried in step (2) is dried, drying temperature is 80-90 DEG C, the time It is 3-5 minutes；
(4) wax coat is coated with, and the base fabric obtained in step (3) is carried out double-sided printing with wax at a temperature of 100-140 DEG C, Base fabric carries out the stretching of breadth or longitudinal direction on tenter system, and extensibility is respectively in 0.5-15%；
(5) cloth cools down, and the fabric under tensional state obtained in step (4) is cooling in 0~8 DEG C of environment, obtains To finished product fire resistant textile.
2. a kind of preparation method of fire resistant textile according to claim 1, it is characterised in that：The wax is pine Fragrant, paraffin and beeswax mix, and the mass mixing ratio of rosin, paraffin and beeswax is 1: 0.1~3: 0.1~2.
3. a kind of preparation method of fire resistant textile according to claim 1, it is characterised in that：The flame-retardant expanded painting Material includes 900-1100 parts of formaldehyde, 500-600 parts of melamine, 250-350 parts of carbamate, 20-30 parts of boric acid, phosphoric acid hydrogen 50-150 parts of diammonium, 5-10 parts of starch, 40-60 parts of ethanol amine, 1300-1500 parts of sucrose, 1500-1700 parts of silicone resin.
4. a kind of preparation method of fire resistant textile according to claim 1, it is characterised in that：The flame-retardant expanded coating It is coated in base fabric using brushing or spray figure mode.
CN201711089980.7A 2017-11-08 2017-11-08 A kind of preparation method of fire resistant textile Withdrawn CN108301226A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711089980.7A CN108301226A (en) 2017-11-08 2017-11-08 A kind of preparation method of fire resistant textile

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711089980.7A CN108301226A (en) 2017-11-08 2017-11-08 A kind of preparation method of fire resistant textile

Publications (1)

Publication Number Publication Date
CN108301226A true CN108301226A (en) 2018-07-20

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CN201711089980.7A Withdrawn CN108301226A (en) 2017-11-08 2017-11-08 A kind of preparation method of fire resistant textile

Country Status (1)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020211444A1 (en) * 2019-04-17 2020-10-22 扬州腾飞电缆电器材料有限公司 Recognizable fireproofing tape and method for preparation thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020211444A1 (en) * 2019-04-17 2020-10-22 扬州腾飞电缆电器材料有限公司 Recognizable fireproofing tape and method for preparation thereof

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Application publication date: 20180720