CN108300522A - 生物柴油替代石化柴油的制备方法 - Google Patents

生物柴油替代石化柴油的制备方法 Download PDF

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CN108300522A
CN108300522A CN201710032866.4A CN201710032866A CN108300522A CN 108300522 A CN108300522 A CN 108300522A CN 201710032866 A CN201710032866 A CN 201710032866A CN 108300522 A CN108300522 A CN 108300522A
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biodiesel
petrifaction diesel
substitutes
preparation
diesel
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张�杰
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

生物柴油替代石化柴油的制备方法，本发明涉及一种用生物柴油替代石化柴油的制备方法，该制备方法是将生物柴油65，石化柴油20，甲醇6‑8，乙醇4‑5，正丁醇2‑3，石油醚1‑2，乙醇胺0.5‑1混合搅拌10分钟即可制成生物柴油替代石化柴油的成品，本发明克服了其它同类油品在制作工艺存在的制作流程复杂，保质期短，功率不足和高制作成本等缺陷。

Description

生物柴油替代石化柴油的制备方法
技术领域
本发明涉及一种用生物柴油替代石化柴油的制备方法。
背景技术
进入新世纪以来，世界对能源的需求量日益增大，能源供给的可持续性以及环境问题成为当今全球最关注的问题，人们为此相应采取各种开源与节能的措施方法，以保证能源的安全运行。
生物柴油由低值的植物或废油脂作原料经过加工而制成，由于其本质与石化柴油存在很多标准参数上的差异，在前人们曾进行二次加工，但一直未能在工艺上完全达到可替代石化柴油的技术要求，因此，至今很少用大比例的生物柴油来调制替代石化柴油，并可用于车船的发动机中的制备方法。
发明内容
本发明的目的；克服现有技术的缺陷和存在问题，通过有效易行的工艺技术对生物柴油进行调制处理，使其完全达到标准石化柴油的要求，并能低于石化柴油的成本，从而充分利用了丰富的生物质资源，另方面充分发挥生物质能源具有的难能可贵的环保效果，因此，本发明的实施有着深远的社会意义和经济意义。
本发明是通过以下技术方案实现的：生物柴油替代石化柴油的制备方法是由65％的生物柴油，20％的石化柴油，15％的溶剂混合搅拌10分钟制成成品，所述溶剂由甲醇40％，乙醇30％，正丁醇15％，石油醚10％，乙醇胺5％组成。
本发明的技术方案配比合理，溶剂的组成材料对生物柴油有很好的理化性能和稳定性，可长期存放不会油醇分层，调整了生物柴油的闪点和密度，对比现有的生物醇油降低了制作成本和增长了保质期，经调制后的成品经检验，各项参数都符合或优于石化柴油的标准。本技术方案的制备方法工艺简单安全，高效环保，实施容易，克服了其它同类油品的制作工艺存在着须经均质机和超声波处理等复杂流程，而由此造成高制作成本等缺陷，下表是本技术方案制作后的成品经广东出入境检验检疫局的检验结果，说明了本技术方案制作后的成品完全符合并优于国标要求。
检测项目 单位 技术要求 检测结果
硫含量 mg/kg ≤50 8
灰分 ％ ≤0.01 0.002
闪点(闭口) ℃ ≥55 69.0
10％蒸余物残炭(质量分数) ％ ≤0.3 0.04
铜片腐蚀(50℃，3h) 级 ≤1 1A
凝点 ℃ ≤0 -12
十六烷值 - ≥45 48
具体实施方式
下面实施例是对本发明进一步证明，本发明不限于此。
实施例1：
生物柴油65，石化柴油20，甲醇6-8，乙醇4-5，正丁醇2-3，石油醚1-2，乙醇胺0.5-1，上列材料混合搅拌10分钟即可制成生物柴油替代石化柴油的成品。
实施例2：
生物柴油65-75，石化柴油10-20，甲醇6-10，乙醇4-8，正丁醇2-5，石油醚1-3，乙醇胺0.5-1，上列材料混合搅拌15分钟即可制成生物柴油替代石化柴油的成品。

Claims (2)

1.生物柴油替代石化柴油的制备方法，其特征在于：将生物柴油65，石化柴油20，甲醇6-8，乙醇4-5，正丁醇2-3，石油醚1-2，乙醇胺0.5-1混合搅拌10分钟制成生物柴油替代石化柴油的成品。
2.根据权利要求1所述的生物柴油替代石化柴油的制备方法，其特征在于：将生物柴油65-75，石化柴油10-20，甲醇6-10，乙醇4-8，正丁醇2-5，石油醚1-3，乙醇胺0.5-1混合搅拌15分钟制成生物柴油替代石化柴油的成品。
CN201710032866.4A 2017-01-11 2017-01-11 生物柴油替代石化柴油的制备方法 Pending CN108300522A (zh)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101475855A (zh) * 2009-01-13 2009-07-08 中国林业科学研究院林产化学工业研究所 基于石化柴油和粗生物柴油的燃料油及其制备方法
CN101831327A (zh) * 2010-05-18 2010-09-15 杭州绿洲能源科技有限公司 一种新型高热值醇基燃料
CN101831326A (zh) * 2010-05-18 2010-09-15 杭州绿洲能源科技有限公司 一种生物质燃料油及其制备方法
CN102304394A (zh) * 2011-08-11 2012-01-04 宋元领 一种生物复合柴油及其制备方法
CN102382691A (zh) * 2010-08-30 2012-03-21 东莞市智造生物科技有限公司 一种高清洁生物柴油
CN102559300A (zh) * 2012-02-29 2012-07-11 上海鑫赛孚能源科技有限公司 一种车用醇醚柴油燃料及其配制方法
CN104745241A (zh) * 2015-03-10 2015-07-01 雷菊花 生物柴油大比例替代石化柴油及其工艺

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101475855A (zh) * 2009-01-13 2009-07-08 中国林业科学研究院林产化学工业研究所 基于石化柴油和粗生物柴油的燃料油及其制备方法
CN101831327A (zh) * 2010-05-18 2010-09-15 杭州绿洲能源科技有限公司 一种新型高热值醇基燃料
CN101831326A (zh) * 2010-05-18 2010-09-15 杭州绿洲能源科技有限公司 一种生物质燃料油及其制备方法
CN102382691A (zh) * 2010-08-30 2012-03-21 东莞市智造生物科技有限公司 一种高清洁生物柴油
CN102304394A (zh) * 2011-08-11 2012-01-04 宋元领 一种生物复合柴油及其制备方法
CN102559300A (zh) * 2012-02-29 2012-07-11 上海鑫赛孚能源科技有限公司 一种车用醇醚柴油燃料及其配制方法
CN104745241A (zh) * 2015-03-10 2015-07-01 雷菊花 生物柴油大比例替代石化柴油及其工艺

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