CN108300229A - A kind of water nano composite coating material and its preparation method and application - Google Patents
A kind of water nano composite coating material and its preparation method and application Download PDFInfo
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- CN108300229A CN108300229A CN201710787288.5A CN201710787288A CN108300229A CN 108300229 A CN108300229 A CN 108300229A CN 201710787288 A CN201710787288 A CN 201710787288A CN 108300229 A CN108300229 A CN 108300229A
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- water
- composite coating
- nano composite
- coating material
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 239000000463 material Substances 0.000 title claims abstract description 39
- 239000011248 coating agent Substances 0.000 title claims abstract description 36
- 238000000576 coating method Methods 0.000 title claims abstract description 36
- 239000002114 nanocomposite Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title abstract description 5
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 17
- 238000003756 stirring Methods 0.000 claims abstract description 16
- 239000000839 emulsion Substances 0.000 claims abstract description 15
- 239000002270 dispersing agent Substances 0.000 claims abstract description 14
- 229920002521 macromolecule Polymers 0.000 claims abstract description 14
- 239000012463 white pigment Substances 0.000 claims abstract description 9
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 229940113115 polyethylene glycol 200 Drugs 0.000 claims description 9
- 239000005543 nano-size silicon particle Substances 0.000 claims description 7
- 235000012239 silicon dioxide Nutrition 0.000 claims description 7
- 239000002518 antifoaming agent Substances 0.000 claims description 6
- 229920005749 polyurethane resin Polymers 0.000 claims description 6
- 229920000604 Polyethylene Glycol 200 Polymers 0.000 claims description 5
- 238000007641 inkjet printing Methods 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 claims 2
- 229940068918 polyethylene glycol 400 Drugs 0.000 claims 2
- 150000001336 alkenes Chemical class 0.000 claims 1
- 238000005260 corrosion Methods 0.000 claims 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims 1
- 238000001914 filtration Methods 0.000 abstract description 6
- 239000000853 adhesive Substances 0.000 abstract description 5
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 239000000976 ink Substances 0.000 description 11
- 235000013339 cereals Nutrition 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 5
- 238000007639 printing Methods 0.000 description 5
- 229910052726 zirconium Inorganic materials 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000012855 volatile organic compound Substances 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 231100001244 hazardous air pollutant Toxicity 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000010146 3D printing Methods 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 206010034719 Personality change Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007850 degeneration Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- -1 rate of drying Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/006—Additives being defined by their surface area
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of water nano composite coating materials and its preparation method and application, wherein the water nano composite coating material is made of the raw material of following parts by weight：02 parts of 100 132 parts of water-base resin, 14 66 parts of inorganic nano colloidal sol, 0 54 parts of white pigment, 24 parts of macromolecule dispersing agent and auxiliary agent.The method is that water-base resin is added in beaker, 0.5 30% water that water-base resin gross mass is added is diluted stirring, at the same time inorganic nano colloidal sol, macromolecule dispersing agent is added, pH value is adjusted to 79, continue to stir, obtain pre-emulsion, is shaken after which is ground, filtering is to get water nano composite coating material.Water nano composite coating material VOC content prepared by the present invention is less than 200g/L, prints colored picture and text again after being printed to stock surface, can improve the adhesive force and glossiness of layer of ink.
Description
Technical field
The present invention relates to a kind of water nano composite coating materials and its preparation method and application, belong to ink-jet printing technology
Field.
Background technology
Realize that picture and text printing is an emerging research hotspot in three-dimensional object surface at present, domestic and international researcher is positive
It conducts a research.Ink-jet technology have many characteristics, such as it is non-contact, without printing pressure, adaptable, be it in three-dimensional objects surface individual character
Change printing and provides possibility.
But since the ingredient of three-dimensional objects is varied, and the ink of inkjet printing, it is either water base or oily
Base, viscosity all very littles, mobility is all very big, and in air brushing forming process, ink can be in substrate surface stream after arriving at stock
Dynamic, dip dyeing to the position of neighbouring ink droplet had both influenced color rendition quality or had influenced resolution ratio；Furthermore, it is possible to there is also
The problems such as picture and text adhesive force caused by surface affinity difference is not good enough, image definition defect.Therefore it needs to increase on its surface
Corresponding coating makes colour picture in colored vividness, saturation to improve the ink absorption and image appearance power of stock
Degree, finely structured hierarchies, clarity, color rendition and color fastness are attained by good level.Used coating currently on the market
Mostly fast-drying solvent type, with the rapid development of industry, more and more noticeable, people the problem of environmental pollution, ecological degeneration
More and more stronger to the appealing of environmental protection, green science and technology has become the mainstream of scientific development, traditional solvent-based coating due to
The discharge of volatile organic compounds (VOC) and hazardous air pollutants (HAP) severely exceeds can be gradually by environment-friendly type aqueous painting
Layer is replaced.
Invention content
The purpose of the present invention is to provide one kind capable of shortening layer of ink surface drying time, and the excellent water nano of printing quality is multiple
Close coating material and its preparation method and application.
In order to achieve the above objectives, the technological means that the present invention uses for：
A kind of water nano composite coating material, is made of the raw material of following parts by weight：100-132 parts of water-base resin, nothing
0-2 parts of 14-66 parts of machine Nano sol, 0-54 parts of white pigment, 2-4 parts of macromolecule dispersing agent and auxiliary agent.
Preferably, the water-base resin is waterborne polyurethane resin, water-based acrylic resin, aqueous acrylic modified poly- ammonia
At least one of ester resin.
Preferably, the inorganic nano colloidal sol be water-based nano silicon dioxide alkaline sol, grain size 10-30nm, than
Surface area is 200-300m2/g。
Preferably, the ingredient of the white pigment includes nano-titanium dioxide.
Preferably, the macromolecule dispersing agent is polyvinylpyrrolidone (PVP), polyethylene glycol -200 (PEG-200), gathers
At least one of ethylene glycol -400 (PEG-400).
Preferably, the auxiliary agent is at least one of antifoaming agent, preservative and rheological agent.
Preferably, the grain size of the water-base resin, inorganic nano colloidal sol, white pigment, macromolecule dispersing agent and auxiliary agent is equal
Within 500nm.
The present invention also provides a kind of methods preparing the water nano composite coating material, include the following steps：
Water-base resin is added in beaker, the water that the 0.5-30% of water-base resin gross mass is added is diluted stirring, at the same time
Inorganic nano colloidal sol, macromolecule dispersing agent is added, adjusts pH value to 7-9, continues to stir, obtain pre-emulsion, by the pre-emulsion into
It is shaken, is filtered to get water nano composite coating material after row grinding.
Preferably, further include that white pigment is added and helps while inorganic nano colloidal sol, macromolecule dispersing agent is added
The step of agent.
The present invention water nano composite coating material be applied to inkjet printing in, can be used for 3D printing material (including
PLA, ABS, PMMA, photosensitive resin), the material surfaces such as wood materials and leather.
Compared with the existing technology, the beneficial effects of the present invention are：
Since resin used in water nano composite coating material of the present invention contains stronger polar group-NCO ,-OH, urea groups
Deng, and intermolecular formation hydrogen bond, there is higher cohesive force, and inorganic nano sol particles used have porosity and print to
Substrate surface can quickly absorb by itself intrinsic capillary force between particle and accommodate the moisture in ink droplet after forming coating,
Layer of ink surface drying time and excellent printing quality can be shortened.It is according to the invention to be formulated aqueous receiving of being prepared
Rice composite coating material VOC content is less than 200g/L, prints colored picture and text again after being printed to stock surface, can improve
The adhesive force and glossiness of layer of ink.
Specific implementation mode
Embodiment 1
50kg waterborne polyurethane resins PU is added in beaker, is diluted rear high-speed stirred with 5kg deionized waters, together
20kg water-based nano silicon dioxides alkaline sol is added in when, and (its grain size is 10-30nm, specific surface area 200-300m2/ g), side
Stirring side is slowly added to the 22kg white pigments diluted with deionized water, the preservative of 1kg polyvinylpyrrolidones and 1kg,
Adjusting pH value to 8.7 stirrings makes it be uniformly mixed for 1 hour, obtains pre-emulsion；
It is added in gained pre-emulsion by abrasive media of zirconium pearl, is ground to material particular diameter within 500nm, earthquake
Shake 15min on instrument, filtering is to get to water nano composite coating material.
Embodiment 2
The aqueous acrylic modified polyurethane resin PUA of 55kg are added in beaker, height after 10kg water is diluted is added
Speed stirring, while be added 33kg water-based nano silicon dioxides alkaline sol (its grain size be 10-30nm, specific surface area 200-
300m2/ g), polyethylene glycol -200 1kg, 2kg non-silicon defoaming agents that addition while stirring has been diluted with deionized water (wherein go from
Sub- water and each 1kg of antifoaming agent), adjusting pH value to 8.5 stirrings makes it be uniformly mixed for 1 hour, obtains pre-emulsion；
It is added in pre-emulsion using zirconium pearl as abrasive media, material particular diameter is ground within 500nm, on earthquake instrument
15min is shaken, filtering is to get to water nano composite coating material.
Embodiment 3
33kg waterborne polyurethane resin PU and 33kg water-based acrylic resins PAA is added in beaker, 13kg water is added
Be diluted rear high-speed stirred, at the same be added 7kg water-based nano silicon dioxides alkaline sol (its grain size be 10-30nm, specific surface
Product is 200-300m2/ g), 13kg white pigments and 1kg polyethylene glycol -200 (PEG-200) are added while stirring, adjusts pH value
Make it so that it is uniformly mixed in the continuous stirring of alkalescent 8.0, obtains pre-emulsion；
It is added in pre-emulsion using zirconium pearl as abrasive media, material particular diameter is ground within 500nm, on earthquake instrument
15min is shaken, filtering is to get to water nano composite coating material.
Embodiment 4
54kg waterborne polyurethane resins PU is added in beaker, 5kg deionized waters are added and are diluted rear high-speed stirred,
At the same time 12.5kg water-based nano silicon dioxides alkaline sol is added, and (its grain size is 10-30nm, specific surface area 200-
300m2/ g), be added while stirring 27kg white pigments, 1kg macromolecule dispersing agents (wherein each 0.5kg of PVP, PEG-200),
0.5kg non-silicon defoaming agents, adjusting pH value to 8.0 are mixed, and pre-emulsion is obtained.
It is added in pre-emulsion using zirconium pearl as abrasive media, material particular diameter is ground within 500nm, on earthquake instrument
15min is shaken, filtering is to get to water nano composite coating material.
Embodiment 5
62kg waterborne acrylic paints PAA is added in beaker, 5kg deionized waters are added and are diluted rear high-speed stirring
It mixes, 17.5kg water-based nano silicon dioxides alkaline sol is at the same time added, and (its grain size is 10-30nm, specific surface area 200-
300m2/ g), 12kg white pigments are added while stirring, (wherein PVP and PEG-200 mass ratioes are 2 to 2kg macromolecule dispersing agents:
1), 0.5kg non-silicon defoaming agents, adjusting pH value to 8.2 continuous stirrings makes it be uniformly mixed for 1 hour, obtains pre-emulsion.
It is added in pre-emulsion using zirconium pearl as abrasive media, material particular diameter is ground within 500nm, on earthquake instrument
15min is shaken, filtering is to get to water nano composite coating material.
Embodiment 6
It is coated in different bases with the water nano composite coating material that embodiment 1-5 is prepared No. 0 ink silk stick
Material surface tests it and coats effect and adhesive force after dry, then continue to coat one layer of inkjet printing aqueous ink on coating
Water, rate of drying, adhesive force and glossiness of the tested inks on coating, test result are as shown in table 1.
Table 1
The embodiment of the present invention content is disclosed above, however the present embodiment is not limited to the range that the present invention is implemented,
Simple equivalent changes and modifications made by claims according to the present invention and description, still fall within the technology of the present invention
In the range of scheme.
Claims (10)
1. a kind of water nano composite coating material, which is characterized in that be made of the raw material of following parts by weight：Water-base resin 100-
0-2 parts of 132 parts, 14-66 parts of inorganic nano colloidal sol, 0-54 parts of white pigment, 2-4 parts of macromolecule dispersing agent and auxiliary agent.
2. water nano composite coating material as described in claim 1, which is characterized in that the water-base resin is aqueous poly- ammonia
At least one of ester resin, water-based acrylic resin, aqueous acrylic modified polyurethane resin.
3. water nano composite coating material as described in claim 1, which is characterized in that the inorganic nano colloidal sol is aqueous
Nano silicon dioxide alkaline sol, grain size 10-30nm, specific surface area 200-300m2/g。
4. water nano composite coating material as described in claim 1, which is characterized in that the ingredient of the white pigment includes
Nano-titanium dioxide.
5. water nano composite coating material as described in claim 1, which is characterized in that the macromolecule dispersing agent is poly- second
At least one of alkene pyrrolidone (PVP), polyethylene glycol -200 (PEG-200), polyethylene glycol-400 (PEG-400).
6. water nano composite coating material as described in claim 1, which is characterized in that the auxiliary agent is antifoaming agent, anti-corrosion
At least one of agent and rheological agent.
7. water nano composite coating material as described in claim 1, which is characterized in that the water-base resin, inorganic nano
Colloidal sol, white pigment, macromolecule dispersing agent and auxiliary agent grain size within 500nm.
8. a kind of preparing the method such as claim 1-7 any one of them water nano composite coating materials, which is characterized in that
Include the following steps：Water-base resin is added in beaker, the water that the 0.5-30% of water-base resin gross mass is added is diluted
At the same time inorganic nano colloidal sol, macromolecule dispersing agent is added in stirring, adjust pH value to 7-9, continue to stir, obtain pre-emulsion,
It shakes, is filtered to get water nano composite coating material after the pre-emulsion is ground.
9. method as claimed in claim 8, which is characterized in that gone back while inorganic nano colloidal sol, macromolecule dispersing agent is added
Include the steps that white pigment and auxiliary agent is added.
10. application of the claim 1-7 any one of them water nano composite coating materials in inkjet printing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710787288.5A CN108300229A (en) | 2017-09-04 | 2017-09-04 | A kind of water nano composite coating material and its preparation method and application |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710787288.5A CN108300229A (en) | 2017-09-04 | 2017-09-04 | A kind of water nano composite coating material and its preparation method and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108300229A true CN108300229A (en) | 2018-07-20 |
Family
ID=62869264
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710787288.5A Pending CN108300229A (en) | 2017-09-04 | 2017-09-04 | A kind of water nano composite coating material and its preparation method and application |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109021802A (en) * | 2018-08-16 | 2018-12-18 | 界首市翰墨文化艺术传媒有限公司 | A kind of weather-proof color for woodwork |
| CN111286237A (en) * | 2019-12-30 | 2020-06-16 | 南阳市星光数码材料有限公司 | Printing coating and preparation method thereof |
| CN112376291A (en) * | 2020-11-02 | 2021-02-19 | 吴江市斌缘纺织喷绘材料有限公司 | Preparation method of water-based textile coating |
| CN113174164A (en) * | 2021-05-25 | 2021-07-27 | 珠海纳思达企业管理有限公司 | Aqueous pigment ink and preparation method thereof |
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