CN108294358A - A kind of cigarette filter biological fiber and preparation method thereof - Google Patents
A kind of cigarette filter biological fiber and preparation method thereof Download PDFInfo
- Publication number
- CN108294358A CN108294358A CN201810068500.7A CN201810068500A CN108294358A CN 108294358 A CN108294358 A CN 108294358A CN 201810068500 A CN201810068500 A CN 201810068500A CN 108294358 A CN108294358 A CN 108294358A
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- China
- Prior art keywords
- parts
- cigarette
- fiber
- biological fiber
- cigarette filter
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Classifications
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/062—Use of materials for tobacco smoke filters characterised by structural features
- A24D3/063—Use of materials for tobacco smoke filters characterised by structural features of the fibers
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/08—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
- A24D3/10—Use of materials for tobacco smoke filters of organic materials as carrier or major constituent of cellulose or cellulose derivatives
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
The invention discloses a kind of cigarette filter biological fibers and preparation method thereof, based on its parts by weight, including following raw material：8 10 parts of canna starch, 20 22 parts of tapioca, 57 parts of cigarette glue, use reproducible non-grain farmer crop for raw material with biological fiber by cigarette filter made from batch mixing, spice, molding, green, environmental protection, low-carbon, degradable, resource is renewable, overcomes acetate fiber（CA）It uses wood pulp as the critical defect of raw material, has prodigious foreground under Chinese environmental protection overall background and in the American-European country for advocating environmental protection, compared with acetate fiber, biological fiber lowering harm and decreasing coking effect is more excellent, after testing smoking nicotine content（Mg/ branch）≤0.85（Detected value：0.82）, tar content（Mg/ branch）≤10（Detected value：9.8）, an oxidationization carbon amounts（Mg/ branch）≤7.5（Detected value：7.5）, it is not necessary that tobacco cigarette chartered plane equipment is transformed, instead of acetate fiber and tacryl（PP）Industrialized production does not have obstacle, and price is cheaper.
Description
Technical field
The present invention relates to biotechnologies to also relate to more particularly to a kind of cigarette filter biological fiber
The preparation method of the cigarette filter biological fiber.
Background technology
Cigarette filter is by obbbin, the water for filtering the filter stick of harmful substance in flue gas and for rolling up packet filter stick
The compositions such as loose paper.
In the prior art, fibre bundle filter stick is mainly made of Diacetate cellulose tow or polypropylene fibre strand material.
Its filter effect depends on the physicochemical properties of their chemical molecular structure and organic compound.Wherein acetate silk
The shortcoming of filter stick is：Acetate silk filter material, due to being limited by active group is lacked, the segment polarity knot contained
Structure, can only be miscellaneous as the aldehyde ketone and lactones in carboxyl compound to the stronger substance of the polarity containing oxygen atom in flue gas compound
Cycle compound such as furans and aldehydes matter have certain affinity, there is certain selective filter effect；And to right in burning smoke product
The low pole compound and minor metallic element adsorption capacity of the aromatic hydrocarbon such as the harmful carbon radicals of human body and propylene class are relatively low, right
The cut-off filter rate of maximum tar is wherein endangered 35% or so；Acetate silk filter material carries negative electrical charge, and many in flue gas
Particle is with negative electrical charge, there are about 2 × 109 negative electrical charge particles in every milliliter of flue gas, due to the repulsive interaction of identical charges,
This filter tip is mainly with the granule phase substance matter in mechanical stop and diffusional deposition retention flue gas；Its raw material is timber, without fibril
Dimension, strainability are restricted；Acetate silk filter material easily absorbs tobacco moisture and fragrance and goes mouldy and generate musty.It is poly-
Tacryl tow filter material is the saturated alkane compound of high molecular weight, without the stable compound of any electronegative group, by
In molecular structure stabilized, physicochemical properties show as inertia, molecular structure pole torpescence；It is non-pole that it, which contains hydrophobic grouping,
Property structure, does not have the polar structure of high affinity, therefore to polar substances molecule cut-off filter in flue gas with polarity flue gas composition
Rate is low；Lack the ability of selective filter flue gas polar compound, the variation of pressure drop does not influence the selectivity to flue gas polar compound
Filtration；Low to the cigarette smell mid-boiling point and lower pungent miscellaneous odoring substance molecule cut-off filter poor performance of stimulation, pungent stimulation
Miscellaneous taste is apparent；Polypropylene fibre tow does not have suitable plasticizer and curing agent when manufacturing filter stick, therefore uses organic solvent
Type adhesive, not only curing rate is slow, upper adhesive easy to stick on thread delivering roller, and filter stick is made to carry solvent odor；Polypropylene is fine
Tow intensity ambassador cutting blade and former serious wear are tieed up, is not suitable with high-energy-rate forming machine, device efficiency is low, causes working hour
And energy consumption increases；Polypropylene fiber tow filter rods hardness is relatively low, causes tipping rate low, and substandard products increase, and cost improves.Filter tip obtained
It is not soluble in water, it is difficult to decompose, prodigious pollution be caused to environment, the mankind spend processing of the substantial contribution for stub.
Biological fiber filter tip：It is green, environmentally friendly, degradable, resource is renewable, the effect of lowering harm and decreasing coking is better than traditional acetic acid
Fiber, the market price are less than acetate fiber, are a kind of new materials, are the third fine and vinegar fibre filter tip very ideal substitutes.
Biological fiber cigarette-filter tow is a kind of reproducible high molecular synthetic material, it has linear molecule, again
Containing great amount of hydroxy group, there is highly polar gene, to absorption, absorption, it is affine, integrate that polar substances are very competent, tow it is special
It is low to the gas gas-phase objects transmitance such as N2, CO2, H2, CO that structure is made cigarette filter, affine to granule phase substance in flue gas, stop, filtering
Rate is high.
Biological fiber rough inner surface has bayonet fittings, when passing through tow to aerosol toxic substance in flue gas
Stroke, time much than acetate fiber (CA), the stroke of tacryl (PP) tow structure, time lengthening, same horizontal
Pressure drop under, aerosol toxin in flue gas biological fiber tow filter mouth it is affine, retain, adsorb, absorb, filter, melt
Jie, integration rate ratio CA, PP tow are much higher.
Banana dasheen (Canna Edulis Ker), also known as non-irrigated lotus root, any of several broadleaf plants lotus root, edible canna originate in for the plant that Lowiaceae canna belongs to
In South America, there is plantation in the major production areas, Southeast Asia and some American States that the Xingyi in China Guizhou is canna starch.
The starch accumulated in banana dasheen rhizome is just eaten as the object of humans and animals for a long time, in the southwest in China and one band of Vietnam
Consumption figure is larger.Banana dasheen has become the new raw material sources of high value starch in Asia, has starch granules grain size big, gelatinization
Temperature is low, and paste transparency is good, the high feature of content of starch.The utilization of banana dasheen at present have to produce based on starch
The food item of starch deep processed product and bean vermicelli, vermicelli is developed for many years, but its added value of product is relatively low, currently, there is not yet
There is canna starch to prepare the document report of biological fiber.
Cassava (Manihot esculenta Crantz) is Euphorbiaceae casava, originating from tropical America Amazon
River valley is one of three big tuber crops, is important starch tropical crops, and root tuber is that production ative starch and all types of industries become
The primary raw material of property starch.Tapioca is the powder that cassava dehydrates etc. that processes obtain after starch isolation.Cassava
Starch has ative starch and various converted starch two major classes, is widely used in food industry and non-food industries.Since cassava original is formed sediment
The ratio of amylopectin and amylose is high in powder, has very high spike viscosity.Tapioca is widely used, food grade cassava
Starch is applied to the raw material substitute of the food such as cake, biscuit, bread and bean vermicelli more.Currently, there is not yet tapioca is used for
Prepare the document report of biological fiber.
On acetate fiber (CA) strand there is polarity gene to be conducive to absorption, affine polar substances, and polypropylene fibre
(PP) on strand nonpolarity gene cannot adsorb, affine polar substances.PP tow surface is extremely smooth, big to waterpower, PP
Beam filter stick is high to the gas gas-phase objects transmitance such as N2, CO2, H2, CO in flue gas, S type tow structure tight beam power can only be relied on to flue gas
Middle granule phase substance rise limited interception, CA fiber tow filter rods to the saturating transmitance of the gas gas-phase objects such as N2, CO2, H2, CO in flue gas also compared with
Height, to the absorption, absorption, filtering of low-boiling polar substances ingredient in these flue gases, it is affine, stop, melt Jie's functionality than
PLA tow are poor, and it is more pungent that this just necessarily causes CA tow filters cigarette, PP tow filter cigarette ratio PLA filter tip cigarettes to manifest
Peppery, bitter miscellaneous peculiar smell.
PLA tow filter mouths are a kind of high molecular synthetic materials, it has linear molecule, and contains great amount of hydroxy group, are had strong
Polarity gene.To absorption, absorption, it is affine, integrate polar substances it is very competent, be prepared into cigarette filter to N2, CO2, H2,
The gas gas-phase objects transmitance such as CO is low, and, obstruction affine to granule phase substance in flue gas, filterability are high.Because carrying a large amount of medicine in PLA tow
Object ingredient, stroke, time ratio CA vinegar when will be by PLA tow to aerosol toxic substance in flue gas be fine, PP polypropylene fibers
The stroke of structure, time lengthening are much.
Under same level of pressure drop, the aerosol toxin in flue gas is in the affine of PLA filter tips, retention, absorption, absorption, mistake
It filters, melt that Jie, integration rate ratio CA vinegar is fine, PP polypropylene fibers are much higher.Aerosol (CO, hydrogen cyanide, oxychloride in every flue gas
Object, ammonia, methacrylaldehyde etc.) harmful substance, by PLA tow filters, PLA filter tips have external lung function, prior to people
Body lung tissue carries out cyanogenation, and the drug with additive is heated to be instant steam activation by moisture, melts on PLA tow surface
It is situated between, neutralizes, integrates, absorbs, can more effectively removes the noxious material of polar water soluble ingredient, play popularity filtration.
PLA filter tips will can averagely reduce by 5 milligram/of tar, and can reduce and remove to popularity the harmful substance in flue gas (in cigarette
Poisonous and harmful substances up to more than 3700 kinds).In brief, PLA filter tips can moisture-proof, flavoring, fire-retardant, degradation, anti-fake, popularity
The harmful toxins in flue gas are reduced and remove, with the advantage that other filter tips are incomparable.
Invention content
The purpose of the present invention is to provide a kind of good filtration effect, environmental protection easily to decompose, shapes easy cigarette filter uses
Biological fiber.
Another object of the present invention is to provide the preparation methods of the cigarette filter biological fiber.
A kind of cigarette filter biological fiber of the present invention, based on its parts by weight, including following raw material：Canna starch
8-10 parts, 20-22 parts of tapioca, 5-7 parts of cigarette glue.
A kind of preparation method of cigarette filter biological fiber of the present invention, includes the following steps：
(1) batch mixing：8-10 parts of canna starch, 20-22 parts of tapioca are placed in blender, with 14-16 revs/min of rotating speed
Under, it mixes well 40-44 minutes；
(2) spice：By 5-7 parts of cigarette glue, pours into blender and continue stirring 30-34 minutes；
(3) it is molded：The material being stirred pours into molding machine, and material passes through under 150-170 DEG C, 380-420 revs/min of rotating speed
Screw extruding is sprayed from ejiction opening, is cooled down at 14-16 DEG C subsequently into air cooling system, the filament cooled down is put into volume
Bent machine is crimped, be packaged to get.
A kind of cigarette filter biological fiber of the present invention, it is characterised in that：The cigarette glue is lactic acid glue.
The present invention has clear advantage and advantageous effect compared with prior art.By above technical scheme it is found that this hair
It is bright that biological fiber is made as raw material using canna starch, tapioca, it has the following advantages：
(1) use reproducible non-grain farmer crop for raw material, green, environmental protection, low-carbon, degradable, resource is renewable, overcomes
Acetate fiber (CA) uses wood pulp as the critical defect of raw material, under Chinese environmental protection overall background and in the American-European state for advocating environmental protection
There is prodigious foreground in family；
(2) compared with acetate fiber, biological fiber lowering harm and decreasing coking effect is more excellent, smoking nicotine content (mg/ branch)≤0.85 (detection
Value：0.82), tar content (mg/ branch)≤10 (detected value：9.8) a, oxidationization carbon amounts (mg/ branch)≤7.5 (detected value：7.5)
(3) it is not necessarily to that tobacco cigarette chartered plane equipment is transformed, there is no obstacle instead of acetate fiber and tacryl (PP) industrialized production,
And price is cheaper.
Specific implementation mode：
Embodiment 1
A kind of preparation method of cigarette filter biological fiber, includes the following steps：
(1) batch mixing：Canna starch 10Kg, tapioca 20Kg are placed in blender, under 16 revs/min of rotating speed, fully
Mixing 40 minutes；
(2) spice：By cigarette glue 7Kg, pours into blender and continue stirring 30 minutes；
(3) it is molded：The material being stirred pours into molding machine, and material passes through screw extruding under 170 DEG C, 380 revs/min of rotating speed
It is sprayed from ejiction opening, is cooled down at a temperature of 16 DEG C subsequently into air cooling system, the filament cooled down is put into crimping machine
Be crimped, be packaged to get.
Embodiment 2
A kind of preparation method of cigarette filter biological fiber, includes the following steps：
(1) batch mixing：Canna starch 9Kg, tapioca 21Kg are placed in blender, under 15 revs/min of rotating speed, fully to mix
Even 42 minutes；
(2) spice：By cigarette glue 6Kg, pours into blender and continue stirring 32 minutes；
(3) it is molded：The material being stirred pours into molding machine, and material passes through screw extruding under 160 DEG C, 400 revs/min of rotating speed
It is sprayed from ejiction opening, is cooled down at a temperature of 15 DEG C subsequently into air cooling system, the filament cooled down is put into crimping machine
Be crimped, be packaged to get.
Embodiment 3
A kind of preparation method of cigarette filter biological fiber, includes the following steps：
(1) batch mixing：Canna starch 8Kg, tapioca 22Kg are placed in blender, under 14 revs/min of rotating speed, fully to mix
Even 44 minutes；
(2) spice：By cigarette glue 5Kg, pours into blender and continue stirring 34 minutes；
(3) it is molded：The material being stirred pours into molding machine, and material passes through screw extruding under 150 DEG C, 420 revs/min of rotating speed
It is sprayed from ejiction opening, is cooled down at a temperature of 14 DEG C subsequently into air cooling system, the filament cooled down is put into crimping machine
Be crimped, be packaged to get.
The present invention uses reproducible non-grain farmer crop for raw material, and green, environmental protection, low-carbon, degradable, resource can be again
It is raw, industrial chain is formed from plantation to processing, banana dasheen and Cassava industry development is promoted, increases income, while overcoming acetic acid
Fiber (CA) uses wood pulp as the critical defect of raw material, has under Chinese environmental protection overall background and in the American-European country for advocating environmental protection
Prodigious foreground, compared with acetate fiber, biological fiber lowering harm and decreasing coking effect is more excellent, after testing smoking nicotine content (mg/ branch)≤
0.85 (detected value：0.82), tar content (mg/ branch)≤10 (detected value：9.8) a, oxidationization carbon amounts (mg/ branch)≤7.5 (inspection
Measured value：7.5), it is not necessary that tobacco cigarette chartered plane equipment is transformed, do not hinder instead of acetate fiber and tacryl (PP) industrialized production
Hinder, and price is cheaper.
Such as using filter tip made from biological fiber made from above-described embodiment and with CA, PP tow filter mouth comparative descriptions
Following table
The above described is only a preferred embodiment of the present invention, being not intended to limit the present invention in any form, Ren Hewei
Be detached from technical solution of the present invention content, according to the technical essence of the invention to made by above example it is any it is simple modification, etc.
With variation and modification, in the range of still falling within technical solution of the present invention.
Claims (3)
1. a kind of cigarette filter biological fiber, based on its parts by weight, including following raw material：8-10 parts of canna starch, wood
20-22 parts of sweet potato starch, 5-7 parts of cigarette glue.
2. a kind of preparation method of cigarette filter biological fiber, includes the following steps：
（1）Batch mixing：8-10 parts of canna starch, 20-22 parts of tapioca are placed in blender, with 14-16 revs/min of rotating speed
Under, it mixes well 40-44 minutes；
（2）Spice：By 5-7 parts of cigarette glue, pours into blender and continue stirring 30-34 minutes；
（3）Molding：The material being stirred pours into molding machine, and material passes through under 150-170 DEG C, 380-420 revs/min of rotating speed
Screw extruding is sprayed from ejiction opening, is cooled down at 14-16 DEG C subsequently into air cooling system, the filament cooled down is put into volume
Bent machine is crimped, be packaged to get.
3. a kind of cigarette filter biological fiber as described in claim 1, it is characterised in that：The cigarette glue is lactic acid glue
Water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810068500.7A CN108294358A (en) | 2018-01-24 | 2018-01-24 | A kind of cigarette filter biological fiber and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810068500.7A CN108294358A (en) | 2018-01-24 | 2018-01-24 | A kind of cigarette filter biological fiber and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN108294358A true CN108294358A (en) | 2018-07-20 |
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ID=62866004
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810068500.7A Pending CN108294358A (en) | 2018-01-24 | 2018-01-24 | A kind of cigarette filter biological fiber and preparation method thereof |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101487204A (en) * | 2008-01-17 | 2009-07-22 | 伟盟工业股份有限公司 | Polylactic acid colloid formulation and its preparation method |
| CN101805583A (en) * | 2010-03-18 | 2010-08-18 | 上海同杰良生物材料有限公司 | Degradable adhesive for polylactic acid cigarette tows and preparation method thereof |
| CN102080275A (en) * | 2009-11-30 | 2011-06-01 | 北京中科高意引擎技术有限公司 | Biodegradable cigarette fiber material and cigarette filter |
| CN103074716A (en) * | 2013-02-07 | 2013-05-01 | 中国烟草总公司郑州烟草研究院 | Sheath-core polylactic acid tobacco tow and filter stick and preparation method thereof |
| CN103584281A (en) * | 2013-11-25 | 2014-02-19 | 湖北中烟工业有限责任公司 | Cigarette filter tip and manufacturing method thereof |
| CN104532386A (en) * | 2014-12-18 | 2015-04-22 | 红塔烟草(集团)有限责任公司 | Polylactic acid filter stick paper element and manufacturing method thereof |
| CN107119460A (en) * | 2017-06-29 | 2017-09-01 | 滁州卷烟材料厂 | A kind of preparation method of cigarette filter fiber |
-
2018
- 2018-01-24 CN CN201810068500.7A patent/CN108294358A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101487204A (en) * | 2008-01-17 | 2009-07-22 | 伟盟工业股份有限公司 | Polylactic acid colloid formulation and its preparation method |
| CN102080275A (en) * | 2009-11-30 | 2011-06-01 | 北京中科高意引擎技术有限公司 | Biodegradable cigarette fiber material and cigarette filter |
| CN101805583A (en) * | 2010-03-18 | 2010-08-18 | 上海同杰良生物材料有限公司 | Degradable adhesive for polylactic acid cigarette tows and preparation method thereof |
| CN103074716A (en) * | 2013-02-07 | 2013-05-01 | 中国烟草总公司郑州烟草研究院 | Sheath-core polylactic acid tobacco tow and filter stick and preparation method thereof |
| CN103584281A (en) * | 2013-11-25 | 2014-02-19 | 湖北中烟工业有限责任公司 | Cigarette filter tip and manufacturing method thereof |
| CN104532386A (en) * | 2014-12-18 | 2015-04-22 | 红塔烟草(集团)有限责任公司 | Polylactic acid filter stick paper element and manufacturing method thereof |
| CN107119460A (en) * | 2017-06-29 | 2017-09-01 | 滁州卷烟材料厂 | A kind of preparation method of cigarette filter fiber |
Non-Patent Citations (1)
| Title |
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| 宋修军 等: "《临床骨科药物学》", 31 May 2010, 科学技术文献出版社 * |
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Application publication date: 20180720 |